Journal of The Serbian Chemical Society最新文献_第4页

Zn(II) complex with pyridine based 1,3-selenazolyl-hydrazone: Synthesis, structural characterization and DFT study 吡啶基1,3-硒化偶氮腙配合物Zn(II)的合成、结构表征及DFT研究

4区化学

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI: 10.2298/jsc230831079a

Jovana Araskov, Predrag Ristic, Aleksandar Visnjevac, Andrej Milivojac, Dragana Mitic, Nenad Filipovic, Tamara Todorovic

引用次数: 0

Synthesis and structural analysis of tetranuclear Zn(II) complex with 2,3-dihydroxybenzaldehyde-aminoguanidine 2,3-二羟基苯甲醛-氨基胍四核配合物Zn(II)的合成及结构分析

4区化学

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI: 10.2298/jsc230808067k

Marijana Kostic, Marko Rodic, Ljiljana Vojinovic-Jesic, Mirjana Radanovic

{"title":"Synthesis and structural analysis of tetranuclear Zn(II) complex with 2,3-dihydroxybenzaldehyde-aminoguanidine","authors":"Marijana Kostic, Marko Rodic, Ljiljana Vojinovic-Jesic, Mirjana Radanovic","doi":"10.2298/jsc230808067k","DOIUrl":"https://doi.org/10.2298/jsc230808067k","url":null,"abstract":"Here we report a new Schiff base of aminoguanidine and 2,3- dihydroxybenzaldehyde (H2L) and its physicochemical characterization, along with an investigation into its coordination affinities towards zinc. By reacting zinc acetate with the chloride salt of the ligand in the MeCN-H2O solution, yellow single-crystals of tetranuclear, centrosymmetric complex, with the formula [Zn2(?-L)(?-OAc)2]2?2MeCN, were obtained. The complex was characterized by IR spectroscopy, conductometry, elemental analysis, and single-crystal X-ray diffraction analysis. Notably, both nitrogen atoms of the aminoguanidine residue coordinate to the same zinc atom, while both deprotonated phenyl oxygen atoms achieve bridging coordination. Furthermore, two acetate anions bridge adjacent zinc atoms in addition to the Schiff base anion. Meaningful insights into the hierarchy and significance of intermolecular interactions within the crystal structure were gained by estimating the energies using the CrystalExplorer model. The calculations revealed that the crystal structure can be classified as a layer type, with notably stronger interactions occurring along the [0 0 1] and [0 1 1] directions.","PeriodicalId":17489,"journal":{"name":"Journal of The Serbian Chemical Society","volume":"66 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135550339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structure and DNA/BSA binding study of zinc(II) complex with 4-ethynyl-2,2’-bipyridine 4-乙基-2,2′-联吡啶配合物锌(II)的结构及DNA/BSA结合研究

4区化学

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI: 10.2298/jsc230605066a

Tina Andrejevic, Darko Asanin, Aurélien Crochet, Nevena Stevanovic, Ivana Vucenovic, Fabio Zobi, Milos Djuran, Biljana Glisic

{"title":"Structure and DNA/BSA binding study of zinc(II) complex with 4-ethynyl-2,2’-bipyridine","authors":"Tina Andrejevic, Darko Asanin, Aurélien Crochet, Nevena Stevanovic, Ivana Vucenovic, Fabio Zobi, Milos Djuran, Biljana Glisic","doi":"10.2298/jsc230605066a","DOIUrl":"https://doi.org/10.2298/jsc230605066a","url":null,"abstract":"In the present study, a zinc(II) complex with 4-ethynyl-2,2?-bipyridine (ebpy), [Zn(ebpy)Cl2], was synthesized and characterized by spectroscopic (1H NMR, IR and UV-Vis) methods and molar conductivity measurement. The crystal structure of the [Zn(ebpy)Cl2] complex was determined by single-crystal X-ray diffraction analysis, confirming the bidentate coordination of the ebpy ligand through its two nitrogen atoms, while the remaining two coordination sites are occupied by two chloride ions. With the aim to investigate the reactivity of the synthesized zinc(II) complex toward biologically important molecules, its binding affinity to calf thymus DNA (ct-DNA) and bovine serum albumin (BSA) was studied by fluorescence emission spectroscopy. From the obtained results, it can be concluded that [Zn(ebpy)Cl2] complex binds to BSA reversibly, while the combination of ethidium bromide (EthBr) and Hoechst 33258 (2?-(4-hydroxyphenyl)-5-[5-(4-methylpiperazine- 1-yl)benzimidazo-2-yl]-benzimidazole) competitive binding study suggests that this complex interacts with ct-DNA through the minor groove binding, which is in agreement with molecular docking study.","PeriodicalId":17489,"journal":{"name":"Journal of The Serbian Chemical Society","volume":"81 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135550599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Spectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganate 二溴高锰酸六胺钴(III)的光谱和结构表征

4区化学

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI: 10.2298/jsc230702062b

Berta Barta Holló, Niloofar Bayat, Laura Bereczki, Vladimir Petrusevski, Kende Béres, Attila Farkas, Imre Szilágyi, László Kótai

引用次数: 0

Health risk assessment of potentially harmful substances from fly ashes generated by coal and coal waste combustion 煤炭和煤矸石燃烧产生的飞灰中潜在有害物质的健康风险评估

IF 1 4区化学

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI: 10.2298/jsc220130048m

Jovana Buha-Markovic, Ana Marinkovic, J. Savić, Aleksa Krstić, A. Savic, M. Ristić

{"title":"Health risk assessment of potentially harmful substances from fly ashes generated by coal and coal waste combustion","authors":"Jovana Buha-Markovic, Ana Marinkovic, J. Savić, Aleksa Krstić, A. Savic, M. Ristić","doi":"10.2298/jsc220130048m","DOIUrl":"https://doi.org/10.2298/jsc220130048m","url":null,"abstract":"Lignite and coal waste used as feed fuels in thermal power plants (TPPs) and semi-industrial fluidized bed boiler (FBB), as well as their representative fly ashes (FAs), were examined. Fly ashes were compared employing anions and cations content in correspondent water extracts, trace elements and polycyclic aromatic hydrocarbon concentrations, as well as health risk assessments of substances known to be of concern for public health. Fluoride and sulfate contents in water extracted FAs are far below the legislation limits for waste, classifying all investigated FAs as non-hazardous. Among investigated trace elements, Cd content is the lowest, while Mn content is the highest. The highest enrichment ratios are noticed for As, Pb, Hg, Cu, V and Cr. The results indicate that total PAHs content is elevated in FA from the combustion of coal waste (AFB), with fluoranthene prevailing. The cancer risk of As and the non-cancer risk of As and Ni in some FAs surpass their respective permissible limits. The incremental lifetime cancer risk of an adult population indicates a potential PAHs risk in AFB, whereas all other fly ashes are within safe limits.","PeriodicalId":17489,"journal":{"name":"Journal of The Serbian Chemical Society","volume":"58 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68513313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Physicochemical properties of the heterogeneous system Li2CO3-Na2CO3-K2CO3/MgO Li2CO3-Na2CO3-K2CO3/MgO非均相体系的物理化学性质

IF 1 4区化学

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI: 10.2298/jsc230201023z

I. Zakiryanova, E. Nikolaeva, I. Korzun

引用次数: 0

Click mediated synthesis of functionalized glycolipids with peptide-peptoid linkages 点击介导的具有肽-肽-类肽键的功能化糖脂合成

IF 1 4区化学

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI: 10.2298/jsc230201030s

Anadi Singhamahapatra, Chinmayee Pattnaik, Prasad Kar, Chandra Nayak, Narayan Sahoo, Satyanarayan Sahoo

{"title":"Click mediated synthesis of functionalized glycolipids with peptide-peptoid linkages","authors":"Anadi Singhamahapatra, Chinmayee Pattnaik, Prasad Kar, Chandra Nayak, Narayan Sahoo, Satyanarayan Sahoo","doi":"10.2298/jsc230201030s","DOIUrl":"https://doi.org/10.2298/jsc230201030s","url":null,"abstract":"The present work describes the synthesis of a new class of glycolipids with systematic variation in the linkage region as well as in the aglycon part using Cu(I) catalyzed click reaction. The linkage region between sugar and the aglycon part was diversified using amide, amido-triazole, and 5-benzoyl triazole moieties. The structural diversity of glycolipids was further amplified by incorporating several polar peptide foldamer groups such as triazole, amide, peptide, or N-aryl peptoid in the aglycon part of it. The newly designed glycolipids were derived from the amalgamation of different peptide bond mimics. This work reports the first use of N-aryl peptoid in the synthesis of glycolipids. The newly synthesized glycolipids were characterized using different spectroscopic and spectrometric analyses. The impact of the amide bond as well as the triazole ring in the linkage region on the morphology of the glycolipids was analyzed by comparing their self-assembly using SEM analysis. The geometries of the glycolipids were also optimized using density functional theory and the optimized structures were found to be minima in the potential energy surfaces.","PeriodicalId":17489,"journal":{"name":"Journal of The Serbian Chemical Society","volume":"33 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68516850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preventing hydrolysis of AlN powders with organophosphate coating in aqueous media 用有机磷包覆防止AlN粉末在水介质中水解

IF 1 4区化学

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI: 10.2298/jsc230321029k

Ceren Kaya, O. Bayındır, Saruhan Saklar, O. Atakol, Hüseyin Çelikkan

引用次数: 0

Health risk assessment of toxic elements in sedimentable dust from landfills 垃圾填埋场可沉降粉尘中有毒元素的健康风险评估

IF 1 4区化学

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI: 10.2298/jsc230413032m

U. Marceta, M. Vučinić-Vasić, Jordana Ninkov, Strahinja Ilic, B. Vujic

{"title":"Health risk assessment of toxic elements in sedimentable dust from landfills","authors":"U. Marceta, M. Vučinić-Vasić, Jordana Ninkov, Strahinja Ilic, B. Vujic","doi":"10.2298/jsc230413032m","DOIUrl":"https://doi.org/10.2298/jsc230413032m","url":null,"abstract":"Four monitoring campaigns of sedimentable dust were provided from two large non-sanitary landfills (Zrenjanin and Novi Sad) in Serbia during 2021. Particle size analysis by laser diffraction and inductively coupled plasma - optical emission spectrometry (ICP-OES) were carried out in order to obtain particle size distribution (PSD) and toxic elements (TEs) concentrations. The health risk assessment of the landfill employees was performed according to United States Environmental Protection Agency (US EPA) methods based on TEs concentrations. The particle size distribution results demonstrated that the majority of sedimentable dust samples mass were not concentrated neither within PM2.5 neither within PM10 fraction. Analysis revealed high concentration of TEs at both landfills: an extremely high concentration of Cr and Zn in samples from Zrenjanin landfill was detected. Health risk potential of elements was as follows for both landfills: Cr > Co > Pb > Ni > Zn > Cu. According to the results, maximal hazard index (HI) for landfill employees in Zrenjanin (1.97*10-1) and Novi Sad (1.13*10-1) showed that non-cancer risk was very low. For both landfill sites, cancer risk (CR) was highest for Cr (2.75*10-5 for Zrenjanin and 2.02*10-7 for Novi Sad), though still within the defined threshold for tolerable cancer risk.","PeriodicalId":17489,"journal":{"name":"Journal of The Serbian Chemical Society","volume":"1 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68517446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthetic study on the angular triquinanes 角型三醌类化合物的合成研究

IF 1 4区化学

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI: 10.2298/jsc230627046s

M. Stjepanović, A. Janković, B. Vulovic, R. Matovic, R. Saicic

引用次数: 0