Journal of The Electrochemical Society最新文献_第4页

C-undecylcalix[4]resorcinarene LB Film/MoS₂-rGO Nanocomposite Modified Electrode for Ultrasensitive Detection of Levodopa c -癸基杯[4]间苯二甲酸LB膜/MoS2-rGO纳米复合修饰电极用于左旋多巴的超灵敏检测

4区工程技术

Journal of The Electrochemical Society Pub Date : 2025-07-01 DOI: 10.1149/1945-7111/adee4c

Keyu Chen, Yujie Wang, Shi‐Man Du, Yang Xiao, Fei Wang

{"title":"C-undecylcalix[4]resorcinarene LB Film/MoS2-rGO Nanocomposite Modified Electrode for Ultrasensitive Detection of Levodopa","authors":"Keyu Chen, Yujie Wang, Shi‐Man Du, Yang Xiao, Fei Wang","doi":"10.1149/1945-7111/adee4c","DOIUrl":"https://doi.org/10.1149/1945-7111/adee4c","url":null,"abstract":"In this research, an innovative electrochemical detection platform for identifying levodopa (L-dopa) was effectively created. The platform is constructed of a carbon paste electrode (CPE) modified with molybdenum disulfide-reduced graphene oxide (MoS 2 -rGO) nanocomposites serving as the matrix electrode and a Langmuir-Blodgett (LB) film of C-undecylcalix[4]resorcinarene (CUCR) acting as the selective recognition layer. Characterizations of the developed platform were conducted using ultraviolet-visible (UV–vis) spectroscopy, electrochemical impedance spectroscopy (EIS), atomic force microscopy (AFM), Raman spectroscopy, X-ray diffraction (XRD) spectroscopy, and scanning electron microscopy (SEM). Meanwhile, systematic electrochemical tests of L-dopa on CUCR-LB/MoS 2 -rGO/CPE were performed. The results revealed that the developed platform exhibited a good electrochemical response to L-dopa, featuring a linear range from 1.0 × 10 –7 to 1.0 × 10 –5 mol l −1 and a detection limit of 4.0 × 10 –8 mol l −1 . In addition, this analytical approach was successfully utilized for quantifying L-dopa content in pharmaceutical samples, yielding satisfactory results.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"172 7","pages":"076507-076507"},"PeriodicalIF":0.0,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147909164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

A Novel Colorimetric and ECL Dual-Mode Aptasensor for Detecting Malathion Based on CuFe₂O₄ Nanocrystalline Cluster 基于CuFe2O4纳米晶簇的马拉硫磷比色- ECL双模适体传感器

4区工程技术

Journal of The Electrochemical Society Pub Date : 2025-06-16 DOI: 10.1149/1945-7111/ade506

Mengyao Wang, Peipei Chen, Y.-S. Wu, Xiaoli Zhu, Dong Tian, Fangquan Xia

{"title":"A Novel Colorimetric and ECL Dual-Mode Aptasensor for Detecting Malathion Based on CuFe2O4 Nanocrystalline Cluster","authors":"Mengyao Wang, Peipei Chen, Y.-S. Wu, Xiaoli Zhu, Dong Tian, Fangquan Xia","doi":"10.1149/1945-7111/ade506","DOIUrl":"https://doi.org/10.1149/1945-7111/ade506","url":null,"abstract":"To achieve rapid, efficient, and cost-effective screening and quantification of malathion in agricultural products and environmental samples, a novel dual-mode aptasensor strategy was developed, including colorimetric and electrochemiluminescent (ECL) methods. The synthesized CuFe 2 O 4 exhibited enhanced enzyme-loading capacity while the established aptamer system could preserve enzymatic activity. As a result, the ascorbic acid generated by enzymatic hydrolysis effectively accelerated the decolorization of methylene blue in the colorimetric mode, as well as quenched the luminescence of luminol in the ECL mode. The samples could be rapidly screened through visual assessment in the colorimetric mode, and be further quantified by dual-mode detection. The linear detection ranges for the colorimetric and ECL modes were determined to be 1.0 pM ∼1.0 μM and 1.0 fM ∼1.0 nM, with corresponding detection limits of 0.7 pM and 0.1 fM, respectively. This dual-mode aptasensor platform enabled both qualitative and quantitative analysis. Significantly, it could dramatically improve detection efficiency and reduce operational costs. Furthermore, the proposed strategy demonstrated exceptional selectivity and stability. Consequently, this detection method was successfully applied to detect malathion residues in environmental as well as agricultural products, and demonstrated substantial potential for practical applications.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"172 7","pages":"077513-077513"},"PeriodicalIF":0.0,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147918328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Degradation of Sulfamethazine by Ni-Doped Lead Dioxide Electrode in Electrocatalytic Ozonation Process 镍掺杂二氧化铅电极在电催化臭氧氧化过程中降解磺胺甲基嗪的研究

4区工程技术

Journal of The Electrochemical Society Pub Date : 2025-06-01 DOI: 10.1149/1945-7111/addf85

Zhuowei Li, Lianzhong Shen, Ye Yu, Qizhou Dai

{"title":"Degradation of Sulfamethazine by Ni-Doped Lead Dioxide Electrode in Electrocatalytic Ozonation Process","authors":"Zhuowei Li, Lianzhong Shen, Ye Yu, Qizhou Dai","doi":"10.1149/1945-7111/addf85","DOIUrl":"https://doi.org/10.1149/1945-7111/addf85","url":null,"abstract":"The Ni-doped PbO 2 electrode (Ti/TNAs/Ni-PbO 2 ) with titanium dioxide nanotube arrays (TNAs) self-growth on the titanium metal surface as an intermediate layer was prepared by electrodeposition. Characterization and electrochemical testing of the Ti/TNAs/Ni-PbO 2 showed a denser surface structure, a larger surface active area (0.50 m 2 g −1 ), and smaller crystallite size (38.61 nm), which provided more surface active sites and promoted the generation of hydroxyl radicals (·OH). The electrocatalytic ozonation process was established using the electrode. The sulfamethazine (SMT) was selected as the target contaminant. The performance on SMT removal in electrocatalytic ozonation was systematically evaluated. The effects of initial SMT concentration, current density, electrolyte concentration, initial pH, and ozone dosage on the degradation rate of SMT and chemical oxygen demand (COD) removal were also investigated. Under optimal conditions, after 60 min of degradation, the removal rates of SMT and COD reached 100% and 46.13%, respectively. Intermediates in the degradation process were identified by ultra-performance liquid chromatography-quadrupole time-of-flight tandem mass spectrometry, and the degradation mechanism and degradation pathways of the Ti/TNAs/Ni-PbO 2 anode in the electrocatalytic ozonation process were explored. The excellent efficacy and stability of this anode in this process were verified and showed a potential for widespread application in highly concentrated organic wastewater treatment.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"172 6","pages":"063504-063504"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147906662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Synergistic Effect of Electrochemical Prelithiation and Biomass Porous Carbon for Dendrite-Free Zn Metal Anode 电化学预锂化与生物质多孔碳对无枝晶锌金属阳极的协同效应

4区工程技术

Journal of The Electrochemical Society Pub Date : 2025-06-01 DOI: 10.1149/1945-7111/addd6c

Jiaxin Peng, Li Yang, Jing Zhao

{"title":"Synergistic Effect of Electrochemical Prelithiation and Biomass Porous Carbon for Dendrite-Free Zn Metal Anode","authors":"Jiaxin Peng, Li Yang, Jing Zhao","doi":"10.1149/1945-7111/addd6c","DOIUrl":"https://doi.org/10.1149/1945-7111/addd6c","url":null,"abstract":"The inhomogeneous interfacial electrochemical reaction process of the metallic zinc anode in aqueous zinc-ion batteries will lead to serious problems of dendrite growth and side reactions, resulting in poor cycle stability. In this study, through a structure - interface collaborative regulation strategy, a biomass-derived porous carbon/zinc composite electrode (LiPBC@Zn) with a lithium-activated interface has been developed, which significantly improves the cycle stability and dendrite suppression ability of zinc-based batteries. Biomass-derived porous carbon (PBC) has a three-dimensional interconnected hierarchical pore network structure, a specific surface area of 242.39 m 2 g −1 , and an average pore diameter of 2.43 nm. The prelithiation treatment induces the formation of a Li 2 O interfacial layer, which can increase the proportion of interfacial lithium atoms from 3.53% to 19.11%, and regulate the zinc nucleation behavior through charge redistribution. The full - cell test shows that V 2 O 5 -LiPBC@Zn has no capacity decay after 1000 cycles at 1 A g −1 and still retains 61.3% of its capacity after 2000 cycles. This study guides the uniform deposition of zinc through the dual mechanism of “lithium-induced and carbon-confined,” effectively suppressing dendrite growth, and provides a theoretical basis and technical path for the interfacial engineering design of high-safety zinc-based energy-storage devices.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"172 6","pages":"060501-060501"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147891550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hypermagnesemia in preterm neonates exposed to antenatal magnesium sulfate. 接触产前硫酸镁的早产新生儿的高镁血症。

IF 3.1 4区工程技术

Journal of The Electrochemical Society Pub Date : 2025-06-01 Epub Date: 2022-04-04 DOI: 10.23736/S2724-5276.22.06683-6

Ana L Correia, Carolina Castro, Joana M Morais, Alexandrina Portela, Sara Peixoto

{"title":"Hypermagnesemia in preterm neonates exposed to antenatal magnesium sulfate.","authors":"Ana L Correia, Carolina Castro, Joana M Morais, Alexandrina Portela, Sara Peixoto","doi":"10.23736/S2724-5276.22.06683-6","DOIUrl":"10.23736/S2724-5276.22.06683-6","url":null,"abstract":"Background: One of the possible adverse outcomes of magnesium sulfate (MgSO<inf>4</inf>) administration for preterm fetal neuroprotection is hypermagnesemia in the newborn. The objectives of this study were to evaluate the association between antenatal MgSO<inf>4</inf> administration for neuroprotection and neonatal serum magnesium levels in the first days of life.Methods: A single-center retrospective case-control study was conducted on preterm neonates born in our institution between January 2017 and December 2019. Prenatal, perinatal, and postnatal parameters were recorded, and demographic information was collected. Comparative analysis between the group of neonates exposed to antenatal MgSO<inf>4</inf> and the control group was performed.Results: A total of 98 patients were enrolled in the study, 49 of them were exposed to antenatal MgSO<inf>4</inf> for neuroprotection. The serum magnesium levels in the 5 first days of life were higher in the case group, and higher than the normal range of serum magnesium levels (>2.4 mg/dL), with a statistical significance. The number of days needed to normalize serum magnesium levels was higher in the case group compared to the control group (median of 7 days [1-8] versus 2 days [1-5]).Conclusions: Our findings show that antenatal administration of MgSO<inf>4</inf> is associated with high serum magnesium levels in neonates. This group of patients needs close electrolyte monitoring during the first days of life. Parenteral nutrition supplemented with magnesium should only be considered after evaluation of serum magnesium levels.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"151 1","pages":"242-249"},"PeriodicalIF":3.1,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86167330","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The Ability of Clinical Decision Rules to Detect Peripheral Arterial Disease: A Narrative Review. 临床决策规则检测外周动脉疾病的能力：叙述性综述。

IF 3.1 4区工程技术

Journal of The Electrochemical Society Pub Date : 2025-06-01 Epub Date: 2022-05-30 DOI: 10.1177/15347346221104590

Amaraporn Rerkasem, Rawee Nopparatkailas, Sothida Nantakool, Rath Rerkasem, Chayatorn Chansakaow, Poon Apichartpiyakul, Arintaya Phrommintikul, Kittipan Rerkasem

引用次数: 0

Revealing the Correlation between Coating Content and Li⁺ Diffusion Kinetics of Nickel-Rich Cathode in Li-Ion Batteries 富镍锂离子电池阴极镀层含量与Li+扩散动力学关系的研究

4区工程技术

Journal of The Electrochemical Society Pub Date : 2025-06-01 DOI: 10.1149/1945-7111/adde88

Mengyuan Zhou, Yaqi Jing, Zhen Wang, Huolin L. Xin

{"title":"Revealing the Correlation between Coating Content and Li+ Diffusion Kinetics of Nickel-Rich Cathode in Li-Ion Batteries","authors":"Mengyuan Zhou, Yaqi Jing, Zhen Wang, Huolin L. Xin","doi":"10.1149/1945-7111/adde88","DOIUrl":"https://doi.org/10.1149/1945-7111/adde88","url":null,"abstract":"Coating is a promising strategy for optimizing cathode active materials to enhance the cycle life of nickel-rich cathodes in Li-ion batteries. However, the effects of coating content on Li + diffusion kinetics remain insufficiently understood, limiting the full utilization of the reversible capacity of cathode active materials. In this study, a model system, zirconia-coated LiNi 0.83 Mn 0.05 Co 0.12 O 2 (NMC), is used to investigate the effect of coating content on the Li + diffusion kinetics. We used a wet-coating method to load the surface of the NMC cathode with varying amounts of Zr-O deposits (ZrO 2 and Li 2 ZrO 3 ). Electrochemical performance, including capacity, stability, and rate capability, exhibits a volcano-like trend with respect to coating content. This suggests that while Zr-O coatings can protect cathode particles, excessive coating increases cell internal resistance (IR) and polarization. The combined kinetics analyses using CV, GITT, and EIS reveal that polarization and cathode-electrolyte interphase (CEI) impedance are dependent on coating content, with high coating content impeding Li + diffusion across the interface. These electrochemical insights rationalize the optimization of coating content for NMC cathode materials, i.e., finding optimal balance between surface stability and Li + diffusion kinetics is key to improving the reversibility of the cathode active material. Specifically, for the model system in our study, a 1.5 wt% Zr coating achieves the best overall electrochemical performance.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"172 6","pages":"060517-060517"},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147920975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced Photoelectrochemical Response and Stability of ZnO/C₃N₄ Electrode through In Situ Growth of the C₃N₄ Layer on Electrodeposited ZnO Electrode 电沉积ZnO电极上原位生长C3N4层提高ZnO/C3N4电极的光电响应和稳定性

4区工程技术

Journal of The Electrochemical Society Pub Date : 2025-05-22 DOI: 10.1149/1945-7111/addc45

Hanben Zhou, Run Liu

引用次数: 0

Integrated Soft-Hard Carbon Derived from Hawthorn Seeds as a High Performance Anode for Sodium Storage 山楂籽合成软硬碳作为储钠阳极的研究进展

4区工程技术

Journal of The Electrochemical Society Pub Date : 2025-05-01 DOI: 10.1149/1945-7111/adda78

Shangye Liu, Yongxiang Wang, Lei Jin, Xinru Wang, Chunting Wang, Yu‐Shi He, Weimin Zhang

{"title":"Integrated Soft-Hard Carbon Derived from Hawthorn Seeds as a High Performance Anode for Sodium Storage","authors":"Shangye Liu, Yongxiang Wang, Lei Jin, Xinru Wang, Chunting Wang, Yu‐Shi He, Weimin Zhang","doi":"10.1149/1945-7111/adda78","DOIUrl":"https://doi.org/10.1149/1945-7111/adda78","url":null,"abstract":"Biomass-derived hard carbon has emerged as a highly promising anode material for sodium-ion batteries (SIBs), owing to its exceptional sodium storage capacity, cost-effectiveness, and sustainable sourcing advantages. However, its widespread commercialization faces significant challenges, including unsatisfactory carbon yield and inadequate rate capability. To address these limitations, this study presents a facile approach to synthesize high-performance soft-hard carbon composites through the strategic combination of pitch and hawthorn seeds. Our research demonstrates that the presence of highly graphitized soft carbon effectively mitigates the inherent drawbacks of hard carbon material. Specifically, the optimized composite with a hawthorn seed-to-pitch mass ratio of 100:10 exhibits superior electrochemical performance compared to pure hawthorn seed-derived hard carbon prepared under identical conditions. The incorporation of pitch-derived soft carbon enhanced the carbon yield from 45.8% to 51.5%. The composite anode delivers a high capacity of 295.9 mAh g −1 (at 20 mA g −1 ), an outstanding cycling stability (retaining 75.0% capacity retention after 1000 cycles at 500 mA g −1 ), and significantly enhanced rate capability. Through these studies, we attempted to establish fundamental structure-property relationships and provide valuable guidance for their commercial implementation in SIB systems.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"172 5","pages":"050538-050538"},"PeriodicalIF":0.0,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147915538","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Open-framework Layered Na₂[(VO)₂(HPO₄)₂(C₂O₄)] for High Voltage/Rate Sodium-ion Batteries via Ion Intercalation Mechanism 基于离子嵌入机制的高电压/速率钠离子电池开放框架层状Na2[(VO)2(HPO4)2（C2O4）

4区工程技术

Journal of The Electrochemical Society Pub Date : 2025-05-01 DOI: 10.1149/1945-7111/add778

Xinming Fan, Ke-Bo Lin, Peiyao Li, Jiafeng Zhang, Lingjun Li, Jiexi Wang, Xiahui Zhang, Junchao Zheng

{"title":"Open-framework Layered Na2[(VO)2(HPO4)2(C2O4)] for High Voltage/Rate Sodium-ion Batteries via Ion Intercalation Mechanism","authors":"Xinming Fan, Ke-Bo Lin, Peiyao Li, Jiafeng Zhang, Lingjun Li, Jiexi Wang, Xiahui Zhang, Junchao Zheng","doi":"10.1149/1945-7111/add778","DOIUrl":"https://doi.org/10.1149/1945-7111/add778","url":null,"abstract":"The exponentially growing global demand for lithium resources has accelerated the development of sodium-ion batteries (SIBs) as a promising alternative to conventional lithium-ion batteries. In this work, we successfully synthesized a novel open-framework layered material, Na 2 [(VO) 2 (HPO 4 ) 2 (C 2 O 4 )] (designated as NaVPC), through an eco-friendly one-step hydrothermal method that eliminates energy-intensive post-calcination processes. The unique architecture of NaVPC features (1) three-dimensional ion diffusion channels enabling reversible Na + extraction/insertion, (2) minimal lattice contraction (<3%) during cycling, and (3) an exceptional average operating voltage of 3.8 V vs Na + /Na. When composited with single-walled carbon nanotubes, the hybrid electrode delivers enhanced electrochemical performance, achieving a specific capacity of 80.6 mAh g −1 at 0.1 C and maintaining 91.7% capacity retention after 100 cycles at 2 C. Through a combination of ex situ X-ray diffraction, X-ray photoelectron spectroscopy, and density functional theory calculations, we systematically investigated the structural evolution and Na + migration mechanism, establishing a fundamental framework for understanding the charge storage behavior in this open-framework material.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"172 5","pages":"050532-050532"},"PeriodicalIF":0.0,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147922593","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0