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Synergistic effect of various nanoparticles infused biodiesel/diesel blends on combustion, performance, and environmental characteristics of a CI engine
IF 5.6 2区 工程技术
Journal of The Energy Institute Pub Date : 2025-04-22 DOI: 10.1016/j.joei.2025.102117
Aqueel Ahmad , Ashok Kumar Yadav , Ashok Kumar Dewangan
{"title":"Synergistic effect of various nanoparticles infused biodiesel/diesel blends on combustion, performance, and environmental characteristics of a CI engine","authors":"Aqueel Ahmad ,&nbsp;Ashok Kumar Yadav ,&nbsp;Ashok Kumar Dewangan","doi":"10.1016/j.joei.2025.102117","DOIUrl":"10.1016/j.joei.2025.102117","url":null,"abstract":"<div><div>The growing demand for sustainable and green alternatives to conventional diesel has driven the search of biodiesel blends, with nanoparticle additives improving combustion efficiency and emission reduction. This study explores the performance, combustion, and emissions characteristics of a diesel engine using biodiesel-diesel blended with graphene oxide (GO), magnesium oxide (MgO), and multi-walled carbon nanotubes (MWCNT) nanoparticles. The B20 biodiesel blend was prepared with 80 % diesel and 20 % waste cooking oil-driven biodiesel, and the nanoparticles were added at 90 ppm using a water bath sonicator for proper dispersion. Engine tests were conducted under variable load conditions for test blends (B20, B20+GO, B20+MgO, and B20+MWCNT) and compared with baseline diesel (D100). The results exhibited substantial enhancements in engine performance and combustion efficiency for nanoparticle-dispersed biodiesel blends as compared to D100 and B20 blends without nanoparticles. The B20+MWCNT blend achieved a 12.40 % higher BTE and a 9.67 % lower in BSFC compared to baseline diesel. Additionally, this blend presented higher heat release rate (HRR), peak cylinder pressure (PCP), and exhaust gas temperature (EGT). Emission reductions were observed, with CO, CO<sub>2</sub>, UBHC, and NO<sub>x</sub> emissions decreasing by 60 %, 16 %, 36.84 %, and 9.02 %, respectively, compared to baseline diesel at full load condition. The study emphasizes the potential of nanoparticle-enhanced biodiesel blends to enhance engine efficiency while reducing harmful emissions.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"120 ","pages":"Article 102117"},"PeriodicalIF":5.6,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143869103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic catalysis of Ni3P/N@C for efficient hydrodeoxygenation: Unraveling the role of Ni3P-N interactions in hydrogen transfer and C-O bond cleavage
IF 5.6 2区 工程技术
Journal of The Energy Institute Pub Date : 2025-04-19 DOI: 10.1016/j.joei.2025.102103
Yu-Qian Zhang , Xing Fan , Zhong-Qiu Liu , Yang-Chao Zhang , Yang-Yang Xu , Jian-Fang Xu , Hai-Xu Zou , Xian-Yong Wei
{"title":"Synergistic catalysis of Ni3P/N@C for efficient hydrodeoxygenation: Unraveling the role of Ni3P-N interactions in hydrogen transfer and C-O bond cleavage","authors":"Yu-Qian Zhang ,&nbsp;Xing Fan ,&nbsp;Zhong-Qiu Liu ,&nbsp;Yang-Chao Zhang ,&nbsp;Yang-Yang Xu ,&nbsp;Jian-Fang Xu ,&nbsp;Hai-Xu Zou ,&nbsp;Xian-Yong Wei","doi":"10.1016/j.joei.2025.102103","DOIUrl":"10.1016/j.joei.2025.102103","url":null,"abstract":"<div><div>The catalytic hydrodeoxygenation (CHDO) of coal-derived oxygenates into high-value aromatic hydrocarbons is pivotal for sustainable coal valorization, yet challenges remain in achieving efficient hydrogen activation and selective C-O bond cleavage. Although the individual catalytic roles of metals and alkaline sites in CHDO are well established, in which metals primarily activate H<sub>2</sub> to form H<strong><sup>…</sup></strong>H species and alkaline sites facilitate C-O bond cleavage by providing H<sup>−</sup> species, the structure-activity relationship and hydrogen transfer dynamics in composite catalysts integrating both components remain inadequately understood. This knowledge gap hinders the rational design of catalysts with enhanced performance in CHDO. In this study, a series of Ni<sub>3</sub>P/N@C catalysts, integrating both Ni<sub>3</sub>P and N-alkaline functionalities, were synthesized via calcination of Ni<sub>3</sub>P precursors at 400–800 °C, resulting in integrates metallic Ni<sub>3</sub>P nanoparticles with N-doped carbon supports to synergistically enhance hydrogen transfer and deoxygenation. Among these catalysts, Ni<sub>3</sub>P/N@C-600 exhibited superior catalytic activity and stability in CHDO reactions, effectively removing oxygen from the oxygen-containing compounds in the sequential thermal dissolution products, converting 91.6 % of O<sub>4</sub>-O<sub>6</sub> class species to lower oxygen class (O<sub>3</sub>-O<sub>1</sub>) compounds. Structural characterization and mechanistic analysis revealed that the synergistic interaction between Ni<sub>3</sub>P and N-alkaline sites enhances hydrogen activation, with Ni<sub>3</sub>P facilitating H<sub>2</sub> dissociation and N-alkaline sites providing mobile H<sup>−</sup> and surface-bound H<sup>+</sup>, thereby promoting selective C-O bond cleavage and accelerating CHDO efficiency. This work offers fundamental insights into the cooperative mechanisms of metal-alkaline catalysts and provides a strategic framework for the design of highly efficient catalysts for coal-derived aromatic hydrocarbon production.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"120 ","pages":"Article 102103"},"PeriodicalIF":5.6,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143873856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluate the effect of different butanol isomers on engine exhaust soot particles
IF 5.6 2区 工程技术
Journal of The Energy Institute Pub Date : 2025-04-19 DOI: 10.1016/j.joei.2025.102104
Xiaoyu Guo , Lina Zhang , Hui Wang , Haozhong Huang , Yi Wang , Kongzhao Xing
{"title":"Evaluate the effect of different butanol isomers on engine exhaust soot particles","authors":"Xiaoyu Guo ,&nbsp;Lina Zhang ,&nbsp;Hui Wang ,&nbsp;Haozhong Huang ,&nbsp;Yi Wang ,&nbsp;Kongzhao Xing","doi":"10.1016/j.joei.2025.102104","DOIUrl":"10.1016/j.joei.2025.102104","url":null,"abstract":"<div><div>The chemical properties of soot particles are correlate with the catalytic regeneration efficiency of DPF. The surface chemistry of soot particles generated from the combustion of oxygenated fuels merits focused investigation, especially considering that the particle chemistry among isomer fuels remains insufficiently characterized. In this study, the chemical properties and oxidative activity of soot particles from different butanol isomers were analysed by FT-IR, XPS and TGA. The results indicated that, compared with D100, the O/C ratio of oxygenated fuel particles increased by approximately 159–358 % under 1.2 MPa load, whereas the difference was not significant at 0.6 MPa load. The content of oxygenated functional groups on particle surface increased with the load increase. When the load was increased to 1.2 MPa, the C-O (aliphatics) groups in D100 and TB50 particles were converted to C=O groups, while the corresponding groups in other fuel particles were converted mainly to C-O (aromatics) groups. Moreover, IB50 exhibited the smallest sp3/sp2 ratio (0.15 and 0.22 respectively), indicating a low degree of carbon layer disorder, fewer surface defects, and a lower content of aliphatic/oxygenated functional groups, which consequently led to the highest Ea. Linear analysis revealed a high linear correlation between the O/C ratio and Ea. For instance, NB50 had a high O/C ratio (0.3 and 0.62 respectively), resulting in a lower Ea and higher oxidative activity. Furthermore, changes in engine load altered the particle structure. Some functional groups showed little or no linear relationship with the oxidative activity of soot particles at high loads.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"120 ","pages":"Article 102104"},"PeriodicalIF":5.6,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143860064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of temperature-dependent speciation data on the development of HyChem Model for RP-3 kerosene
IF 5.6 2区 工程技术
Journal of The Energy Institute Pub Date : 2025-04-19 DOI: 10.1016/j.joei.2025.102112
Yecheng Song , Shijie Bai , Shilong Li , Minglei Wang , Shumeng Zhang , Dongping Chen , Kun Wang
{"title":"Impact of temperature-dependent speciation data on the development of HyChem Model for RP-3 kerosene","authors":"Yecheng Song ,&nbsp;Shijie Bai ,&nbsp;Shilong Li ,&nbsp;Minglei Wang ,&nbsp;Shumeng Zhang ,&nbsp;Dongping Chen ,&nbsp;Kun Wang","doi":"10.1016/j.joei.2025.102112","DOIUrl":"10.1016/j.joei.2025.102112","url":null,"abstract":"<div><div>Modeling the combustion chemistry of multi-component liquid fuels, such as RP-3 kerosene, faces intricate challenges. A recently proposed HyChem approach offers a physics-based modeling path, with models constrained by experimental speciation data followed by validation by global combustion properties. Intermediate speciation data obtained under appropriate temperature and/or reaction time are crucial for the HyChem model development, yet their impact has not been fully elucidated. The primary objective of the present study was to investigate the impact of temperature-dependent speciation data on the development of HyChem models. Pyrolysis and oxidation experiments were conducted in a flow reactor system over a temperature range of 1000 K–1355 K to characterize the distribution of critical intermediate species during RP-3 decomposition. Multiple HyChem models were developed based on speciation data obtained from experiments conducted at various temperatures. These models were subsequently validated using global combustion properties, specifically ignition delay time and laminar flame speed. The HyChem models were developed using speciation datasets from various temperatures, resulting in different stoichiometric and rate coefficients in their fuel decomposition submodel. Despite these differences, most models showed remarkably consistent predictions that closely aligned with experimental measurements of global combustion properties. The above findings in the present study may relieve the researchers in the selection and determination of experimental conditions for obtaining speciation data to the development of HyChem models.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"120 ","pages":"Article 102112"},"PeriodicalIF":5.6,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143873854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gasification characteristics and kinetics of pyrolysis-derived coal chars under a CH4-containing atmosphere 在含 CH4 的大气中热解衍生煤炭的气化特性和动力学
IF 5.6 2区 工程技术
Journal of The Energy Institute Pub Date : 2025-04-19 DOI: 10.1016/j.joei.2025.102113
Cheng Ma , Silin Meng , Yuzhen Zhao , Yang Zhao , Chong Zou , Zongcheng Miao
{"title":"Gasification characteristics and kinetics of pyrolysis-derived coal chars under a CH4-containing atmosphere","authors":"Cheng Ma ,&nbsp;Silin Meng ,&nbsp;Yuzhen Zhao ,&nbsp;Yang Zhao ,&nbsp;Chong Zou ,&nbsp;Zongcheng Miao","doi":"10.1016/j.joei.2025.102113","DOIUrl":"10.1016/j.joei.2025.102113","url":null,"abstract":"<div><div>The CO<sub>2</sub> gasification technology of char represents a crucial approach for achieving environmentally sustainable and effective utilization of low-rank coal. Thermogravimetric analysis (TGA) was applied to investigate the CO<sub>2</sub> gasification properties and kinetics of chars prepared by low-rank coal pyrolyzed in the N<sub>2</sub> and CH<sub>4</sub>-containing atmospheres. The physicochemical properties of the chars were analyzed through Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), micro-Raman spectroscopy, and CO<sub>2</sub> adsorption techniques. The gasification activation energy (<em>E</em><sub><em>α</em></sub>) of chars was determined by the Flynn-Wall-Ozawa (FWO) approach, and the gasification reaction mechanisms were elucidated through the Malek method. The findings suggest that the CH<sub>4</sub>-containing atmosphere significantly increased the proportion of graphitic carbon (C-C) structures and enhanced the graphitization degree (<em>A</em><sub>G</sub>/<em>A</em><sub>All</sub>) in char, while reducing its specific surface area. Further analysis revealed that the C-C structure proportion, volatile matter content, <em>A</em><sub>G</sub>/<em>A</em><sub>All</sub>, and specific surface area of char-CH<sub>4</sub> showed strong linear correlations (<em>R</em><sup>2</sup> &gt; 0.9) with its gasification reactivity and activation energy. The CH<sub>4</sub>-containing atmosphere reduced the gasification activity of char. Additionally, the CO<sub>2</sub> gasification processes of char could be described by the two-dimensional diffusion mechanism (<em>α</em> = 0.2–0.5) and the three-dimensional diffusion model (<em>α</em> = 0.6–0.9), respectively.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"120 ","pages":"Article 102113"},"PeriodicalIF":5.6,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143869105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrogen production from methane dry reforming on coke-resistant Pr-doped Co/mesoporous alumina catalysts 耐焦掺杂钴/介孔氧化铝催化剂在甲烷干转化过程中制氢
IF 5.6 2区 工程技术
Journal of The Energy Institute Pub Date : 2025-04-19 DOI: 10.1016/j.joei.2025.102116
Bui T. Thu-Thao , Ngoc-Dung Lai , Ponnusamy Senthil Kumar , Tan Ji Siang , Thuy-Phuong T. Pham , Natarajan Rajamohan , Shams Forruque Ahmed , G. Abdulkareem-Alsultan , Aishah Abdul Jalil , Mohammad Yusuf , Dai-Viet N. Vo
{"title":"Hydrogen production from methane dry reforming on coke-resistant Pr-doped Co/mesoporous alumina catalysts","authors":"Bui T. Thu-Thao ,&nbsp;Ngoc-Dung Lai ,&nbsp;Ponnusamy Senthil Kumar ,&nbsp;Tan Ji Siang ,&nbsp;Thuy-Phuong T. Pham ,&nbsp;Natarajan Rajamohan ,&nbsp;Shams Forruque Ahmed ,&nbsp;G. Abdulkareem-Alsultan ,&nbsp;Aishah Abdul Jalil ,&nbsp;Mohammad Yusuf ,&nbsp;Dai-Viet N. Vo","doi":"10.1016/j.joei.2025.102116","DOIUrl":"10.1016/j.joei.2025.102116","url":null,"abstract":"<div><div>Dry reforming of methane, DRM is largely recognized as a promising route for generating H<sub>2</sub> energy to substitute fossil fuels. In this work, the promotional effect of praseodymium dopant (0-7 wt %) on the performance and coking resistance of mesoporous alumina (MA)-dispersed Co catalysts was investigated at a stoichiometric DRM feed composition and 650–750 °C. Pr promotion considerably reduced Co<sub>3</sub>O<sub>4</sub> crystal dimension from 16.8 to 7.8 nm and 5Pr10Co/MA possessed the smallest Co<sub>3</sub>O<sub>4</sub> crystallite size. The total basic site concentration was boosted with Pr addition from 66.8 to 169.7 μmol CO<sub>2</sub> <span><math><mrow><msubsup><mi>g</mi><mrow><mi>c</mi><mi>a</mi><mi>t</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msubsup></mrow></math></span>. Stable CH<sub>4</sub> conversion with time-on-stream was evidenced on Pr-promoted catalysts (1 %-5 %Pr) because of enhancing basic site concentration and CO<sub>2</sub> adsorption. Notably, 5Pr10Co/MA achieved the greatest CH<sub>4</sub> (90.91 %) and CO<sub>2</sub> (82.13 %) conversions at 700 °C and exhibited the highest coke resistance with the least carbon deposition percentage (0.87 %) and carbon formation rate (2.42 × 10<sup>−5</sup> <span><math><mrow><msub><mi>g</mi><mrow><mi>c</mi><mi>a</mi><mi>r</mi><mi>b</mi><mi>o</mi><mi>n</mi></mrow></msub><mspace></mspace><msubsup><mi>g</mi><mrow><mi>c</mi><mi>a</mi><mi>t</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msubsup></mrow></math></span> min<sup>−1</sup>) owing to the smallest Co<sub>3</sub>O<sub>4</sub> crystallite size, oxygen vacancy and redox attributes. An enhancement in H<sub>2</sub> yield from 52.52 % to 87.94 % was evidenced on 5Pr10Co/MA with rising temperature from 650 to 750 °C. The two-step mechanism for coke suppression triggered by a redox PrO<sub>2</sub>/Pr<sub>2</sub>O<sub>3</sub> pair was also elaborated in this study.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"120 ","pages":"Article 102116"},"PeriodicalIF":5.6,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143869104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Co-pyrolysis of Chlorella pyrenoidosa and polystyrene: kinetics and product distributions
IF 5.6 2区 工程技术
Journal of The Energy Institute Pub Date : 2025-04-18 DOI: 10.1016/j.joei.2025.102109
Dezhi Kong , Susu Wang , Yuqi Wang , Haitao Chen , Qiangu Yan , Yijiang Gong , Rui Li
{"title":"Co-pyrolysis of Chlorella pyrenoidosa and polystyrene: kinetics and product distributions","authors":"Dezhi Kong ,&nbsp;Susu Wang ,&nbsp;Yuqi Wang ,&nbsp;Haitao Chen ,&nbsp;Qiangu Yan ,&nbsp;Yijiang Gong ,&nbsp;Rui Li","doi":"10.1016/j.joei.2025.102109","DOIUrl":"10.1016/j.joei.2025.102109","url":null,"abstract":"<div><div>Co-pyrolysis of algae with polystyrene (PS) offers a promising and efficient approach to enhancing the quality of algae-derived bio-oil. This study investigated the thermal decomposition behavior, activation energy, and product distribution during the co-pyrolysis of <em>Chlorella pyrenoidosa</em> (CP) and PS. Thermal decomposition behavior was analyzed using non-isothermal thermogravimetric analysis (TGA) at heating rates of 10–40 °C/min. The activation energies were calculated using the OFW, KAS, and STK methods. Product distributions were examined using Py-GC/MS at 600 °C. TGA results revealed that the co-pyrolysis of CP and PS proceeded through four stages. Increasing CP proportions shifted pyrolysis temperatures toward higher values. The addition of PS significantly reduced the apparent activation energy, with the strongest positive synergistic effect at a CP5PS5 ratio. The average apparent activation energies for CP5PS5 were 180, 179, and 179 kJ/mol, as determined by the OFW, KAS, and STK methods, respectively. Py-GC/MS analysis revealed significant changes in the bio-oil composition with increasing PS content. The yields of MAHs and PAHs increased, while aliphatic hydrocarbons, oxygen-containing compounds, and nitrogen-containing compounds decreased. At a CP5PS5 ratio, MAHs increased to 67.09 %, PAHs increased to 30.22 %, oxygen-containing compounds dropped to 2.05 %, and nitrogen-containing compounds became undetectable. Co-pyrolysis of algae with PS provides a simple, effective, and scalable approach for upgrading bio-oil quality while simultaneously contributing to the management of plastic waste.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"120 ","pages":"Article 102109"},"PeriodicalIF":5.6,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143850673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on decoupling of in-cylinder combustion process of diesel/ammonia dual fuel engine
IF 5.6 2区 工程技术
Journal of The Energy Institute Pub Date : 2025-04-18 DOI: 10.1016/j.joei.2025.102106
Li Ruina , Liu Feifan , Yang Dahai , Hu Quan , Yue Hua , Meng Yang , Liu Shuai
{"title":"Research on decoupling of in-cylinder combustion process of diesel/ammonia dual fuel engine","authors":"Li Ruina ,&nbsp;Liu Feifan ,&nbsp;Yang Dahai ,&nbsp;Hu Quan ,&nbsp;Yue Hua ,&nbsp;Meng Yang ,&nbsp;Liu Shuai","doi":"10.1016/j.joei.2025.102106","DOIUrl":"10.1016/j.joei.2025.102106","url":null,"abstract":"<div><div>Ammonia molecules contain no carbon atoms, which is a kind of clean fuel for diesel engines. The dual-fuel mode, combining ammonia and diesel, is an effective way for ammonia used in diesel engine, which complicates the combustion process. In order to decouple the combustion of diesel and ammonia, a bench test was conducted at 2700 rpm and 75 % load, and the in-cylinder pressure and instantaneous heat release at ammonia substitution rates of 0 %, 10 %, and 20 % were measured and analyzed. In addition, a combustion process model for ammonia and diesel fuel was developed, and a method for decoupling combustion characteristics based on consistent starting time of heat release was proposed. The results indicated that in the dual-fuel combustion mode (diesel/ammonia), the heat release curve was changed from a single peak to a double peak. The addition of ammonia reduced the pre-premixed heat release ratio, leading to a decrease in the peak instantaneous heat release rate and an extension of the combustion duration. As the ammonia substitution rate increased, the rate of ammonia consumption at the same crankshaft angle was significantly reduced. The burned mass center of ammonia (M50-NH<sub>3</sub>) was delayed by 4.2°CA, and the amount of unburned ammonia escaping was increased. After ammonia was added, the combustion area in the cylinder was extended toward the combustion chamber wall, and the high-temperature area in the center of the combustion chamber was decreased. With the increase in ammonia substitution rate, NH<sub>2</sub>+NO<sub>2</sub>=H<sub>2</sub>NO + NO became the most sensitive reaction, which was the main reaction that promoted ammonia combustion. The maximum ammonia substitution rate was 40 % at the maximum torque condition.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"120 ","pages":"Article 102106"},"PeriodicalIF":5.6,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143854926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Combustion characteristics in a diesel engine running on a diesel fuel produced by the Fischer-Tropsch synthesis process from lignite
IF 5.6 2区 工程技术
Journal of The Energy Institute Pub Date : 2025-04-18 DOI: 10.1016/j.joei.2025.102115
Mersin Hürpekli , Ahmet Necati Özsezen
{"title":"Combustion characteristics in a diesel engine running on a diesel fuel produced by the Fischer-Tropsch synthesis process from lignite","authors":"Mersin Hürpekli ,&nbsp;Ahmet Necati Özsezen","doi":"10.1016/j.joei.2025.102115","DOIUrl":"10.1016/j.joei.2025.102115","url":null,"abstract":"<div><div>In this study, Fischer-Tropsch (FT) diesel produced by the liquefaction synthesis of lignite mined in Türkiye was used as an alternative to conventional diesel and its combustion and emission characteristics were observed. The fuel injection timing was also varied on a diesel engine running on FT diesel and petrol-based diesel to evaluate the effect of fuel injection timing. The findings indicated that the initiation and completion of combustion occurred earlier with FT diesel compared to petroleum-based diesel, resulting in elevated in-cylinder gas temperatures. The advancement of injection timing was observed to enhance the engine's knock tendency for both fuels, while the retardation of injection timing exhibited a mitigating effect on engine knock. The findings indicate that the combination of FT diesel with injection strategies has the potential to reduce emissions of total hydrocarbons, carbon monoxide, carbon dioxide, and soot by 50 %, 48.7 %, 7.8 %, and 50 %, respectively, while only experiencing a slight power reduction of up to 4.6 %. The analysis of its fuel properties, combustion characteristics, knock tendency, and emissions performance indicates that FT diesel is a viable alternative fuel for diesel engines without the necessity for modifications to engine systems. It is also worth noting that the use of FT diesel can lead to a reduction in knock tendency through the optimization of fuel injection strategies.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"120 ","pages":"Article 102115"},"PeriodicalIF":5.6,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143850672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Infrared imaging for two-dimensional soot and temperature measurements in laminar premixed and non-premixed flames
IF 5.6 2区 工程技术
Journal of The Energy Institute Pub Date : 2025-04-18 DOI: 10.1016/j.joei.2025.102111
Jiwei Zhou , Lei Xu , Jianguo Du , Liuhao Ma , Yu Wang
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