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Journal of The Chemical Society D: Chemical Communications最新文献

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X-Ray crystal and molecular structure of ‘tetrazene’, (‘Tetracene’), C2H8N10O “四烯”，(“四烯”)，C2H8N10O的x射线晶体和分子结构
Journal of The Chemical Society D: Chemical Communications Pub Date : 1971-01-01 DOI: 10.1039/C29710000002
J. R. Duke
{"title":"X-Ray crystal and molecular structure of ‘tetrazene’, (‘Tetracene’), C2H8N10O","authors":"J. R. Duke","doi":"10.1039/C29710000002","DOIUrl":"https://doi.org/10.1039/C29710000002","url":null,"abstract":"The primary explosive tetrazene exists in the solid state as the zwitterion (guanidinium) form of 1-amino-1-[(1H-tetrazol-5-yl)azo]guanidine hydrate; the A and B crystal modifications have the same molecular conformation and are related as polymorphs.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"80 1","pages":"2-3"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81262265","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 10
X-Ray study of the co-ordination geometry about iron in the {fluoro[6,6′,6″-phosphinidynetris(α-picolinaldehyde oximato)(3–)]borato(1–)}iron(1+) cation. Trigonal prismatic encapsulation vs. octahedral ligand-field stabilization energy 铁在{氟[6,6 '，6″-膦酸钠(α-吡啶醛肟)(3 -)]硼(1 -)}铁(1+)阳离子中的配位几何的x射线研究。三角棱柱封装与八面体配体场稳定能量
Journal of The Chemical Society D: Chemical Communications Pub Date : 1971-01-01 DOI: 10.1039/C29710001307
M. Churchill, A. Reis
{"title":"X-Ray study of the co-ordination geometry about iron in the {fluoro[6,6′,6″-phosphinidynetris(α-picolinaldehyde oximato)(3–)]borato(1–)}iron(1+) cation. Trigonal prismatic encapsulation vs. octahedral ligand-field stabilization energy","authors":"M. Churchill, A. Reis","doi":"10.1039/C29710001307","DOIUrl":"https://doi.org/10.1039/C29710001307","url":null,"abstract":"A single crystal X-ray diffraction study of [{FB(ONCH·C5H3N)3P}FeII]+[BF4]–, CH2Cl2 shows the co-ordination geometry about the iron atom to be distorted by approximately 21·5° from the ideal trigonal primatic case.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"38 1","pages":"1307-1308"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81581595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
The tautomeric structure of 1-methyl-5-methylaminotetrazole and a warning regarding nuclear magnetic resonance spectral determinations in deuteriated dimethyl sulphoxide 1-甲基-5-甲基氨基四唑的互变异构体结构及对氘化二甲基亚砜中核磁共振光谱测定的警告
Journal of The Chemical Society D: Chemical Communications Pub Date : 1971-01-01 DOI: 10.1039/C29710000846
G. Bianchi, A. Katritzky
{"title":"The tautomeric structure of 1-methyl-5-methylaminotetrazole and a warning regarding nuclear magnetic resonance spectral determinations in deuteriated dimethyl sulphoxide","authors":"G. Bianchi, A. Katritzky","doi":"10.1039/C29710000846","DOIUrl":"https://doi.org/10.1039/C29710000846","url":null,"abstract":"1-Methyl-5-methylaminotetrazole exists in the amino-form; conclusions to the contrary are shown to be due to deuterium oxide contamination in the (CD3)2SO used.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"31 1","pages":"846-846"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81644734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Trialkylcyanoborates as intermediates in a new conversion of trialkylboranes into trialkylcarbinols 三烷基氰硼酸盐在三烷基硼烷转化为三烷基甲醇中的中间体作用
Journal of The Chemical Society D: Chemical Communications Pub Date : 1971-01-01 DOI: 10.1039/C29710001048
A. Pelter, M. G. Hutchings, Keith Smith
{"title":"Trialkylcyanoborates as intermediates in a new conversion of trialkylboranes into trialkylcarbinols","authors":"A. Pelter, M. G. Hutchings, Keith Smith","doi":"10.1039/C29710001048","DOIUrl":"https://doi.org/10.1039/C29710001048","url":null,"abstract":"Warming trialkylcyanoborates with an excess of trifluoroacetic anhydride results in three migrations from boron to carbon to give, on oxidation, high yields of trialkylcarbinols.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"12 1","pages":"1048-1048"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81861427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
Infrared spectroscopic study of the hydrates of hydrogen chloride and hydrogen bromide 氯化氢和溴化氢水合物的红外光谱研究
Journal of The Chemical Society D: Chemical Communications Pub Date : 1971-01-01 DOI: 10.1039/C29710000337
A. S. Gilbert, N. Sheppard
{"title":"Infrared spectroscopic study of the hydrates of hydrogen chloride and hydrogen bromide","authors":"A. S. Gilbert, N. Sheppard","doi":"10.1039/C29710000337","DOIUrl":"https://doi.org/10.1039/C29710000337","url":null,"abstract":"The i.r. spectra for HX,xH2O (X = Cl, Br; x= 1–4) and evidence for the existence of the complex HCl,4H2O are reported; the spectra of the dihydrates show the presence of a very strong central hydrogen bond in H5O2+, and other spectra indicate the presence of H2O, H3O+, or H5O2+ units, consistent with X-ray crystal structures.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"14 1","pages":"337-338"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81929856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Dimethylthallium(III) derivatives of decaborane(14) 二甲基铊(III)十硼烷(14)衍生物
Journal of The Chemical Society D: Chemical Communications Pub Date : 1971-01-01 DOI: 10.1039/C29710001027
N. N. Greenwood, N. F. Travers, D. Waite
{"title":"Dimethylthallium(III) derivatives of decaborane(14)","authors":"N. N. Greenwood, N. F. Travers, D. Waite","doi":"10.1039/C29710001027","DOIUrl":"https://doi.org/10.1039/C29710001027","url":null,"abstract":"Reaction of trimethylthallium with decaborane (14) yields the simple salt [Me2Tl]+[B10H13]–, (A), and the complex [Me2Tl]+[B10H12TlMe2]–, (B), which contains two distinct dimethylthallium(III) groups, one of which is chelated by the dodecahydro-nido-decaborate (2–) ion.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"6 1","pages":"1027-1027"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84379955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Formation of 5,6-dinitrocyclohex-3-enones in the nitration of polyalkylbenzenes 聚烷基苯硝化反应中5,6-二硝基环己烯酮的生成
Journal of The Chemical Society D: Chemical Communications Pub Date : 1971-01-01 DOI: 10.1039/C29710001509
Hitomi Suzuki, M. Sawaki, R. Sakimoto
{"title":"Formation of 5,6-dinitrocyclohex-3-enones in the nitration of polyalkylbenzenes","authors":"Hitomi Suzuki, M. Sawaki, R. Sakimoto","doi":"10.1039/C29710001509","DOIUrl":"https://doi.org/10.1039/C29710001509","url":null,"abstract":"Nitration of polyalkylbenzenes with fuming nitric acid gives small amounts of dinitrocyclohexenones besides ring and side-chain substitution products.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"39 1","pages":"1509-1510"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84415440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Crystal structures of the (±)-β- and (±)-γ-promedol alcohols (±)-β-和(±)-γ-丙美酚醇的晶体结构
Journal of The Chemical Society D: Chemical Communications Pub Date : 1971-01-01 DOI: 10.1039/C29710001102
W. Camp, F. Ahmed
{"title":"Crystal structures of the (±)-β- and (±)-γ-promedol alcohols","authors":"W. Camp, F. Ahmed","doi":"10.1039/C29710001102","DOIUrl":"https://doi.org/10.1039/C29710001102","url":null,"abstract":"X-Ray analyses have shown that the isomeric β- and γ-promedol alcohols (1,2,5-trimethyl-4-phenylpiperidin-4-ol) differ only in having the phenyl group oriented axially in the former and equatorially in the latter.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"27 1","pages":"1102-1103"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84434376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Intramolecular photocycloaddition of 3-allyloxy- and 3-allylamino-cyclohex-2-enones: formation of oxa- and aza-bicyclo[2,1,1]hexanes 3-烯丙氧基-和3-烯丙基-环己烯酮的分子内光环加成:氧-和氮-双环己烯[2,1,1]己烷的形成
Journal of The Chemical Society D: Chemical Communications Pub Date : 1971-01-01 DOI: 10.1039/C29710001167
Y. Tamura, Y. Kita, H. Ishibashi*, M. Ikeda
{"title":"Intramolecular photocycloaddition of 3-allyloxy- and 3-allylamino-cyclohex-2-enones: formation of oxa- and aza-bicyclo[2,1,1]hexanes","authors":"Y. Tamura, Y. Kita, H. Ishibashi*, M. Ikeda","doi":"10.1039/C29710001167","DOIUrl":"https://doi.org/10.1039/C29710001167","url":null,"abstract":"Photo-irradiation of 3-allyloxy- and 3-allylamino-cyclohex-2-enones results in an intramolecular cyclo-addition to produce oxa- and aza-bicyclo[2,1,1]hexane derivatives.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"11 1","pages":"1167-1167"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84835709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 13
1-Azabicyclo[3,2,0]hept-3-ene-2,7-diones. A new heterocyclic system 1-Azabicyclo (3 2 0) hept-3-ene-2 7-diones。一个新的杂环体系
Journal of The Chemical Society D: Chemical Communications Pub Date : 1971-01-01 DOI: 10.1039/C29710001364
N. Hatanaka, H. Ohta, O. Simamura, Masayuki Yoshida
{"title":"1-Azabicyclo[3,2,0]hept-3-ene-2,7-diones. A new heterocyclic system","authors":"N. Hatanaka, H. Ohta, O. Simamura, Masayuki Yoshida","doi":"10.1039/C29710001364","DOIUrl":"https://doi.org/10.1039/C29710001364","url":null,"abstract":"4-Methoxy-1-azabicyclo[3,2,0]hept-3-ene-2,7-dione (III) has been prepared both by a Beckmann rearrangement of 4-methoxy-o-benzoquinone 1-(O-phenyl-sulphonyl)oxime (I) followed by ring contraction and by cyclization of 5-cyano-3-methoxypenta-cis-2,trans-4-dienoic acid (V).","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"39 1","pages":"1364-1364"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85107027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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