{"title":"三烷基氰硼酸盐在三烷基硼烷转化为三烷基甲醇中的中间体作用","authors":"A. Pelter, M. G. Hutchings, Keith Smith","doi":"10.1039/C29710001048","DOIUrl":null,"url":null,"abstract":"Warming trialkylcyanoborates with an excess of trifluoroacetic anhydride results in three migrations from boron to carbon to give, on oxidation, high yields of trialkylcarbinols.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"12 1","pages":"1048-1048"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"16","resultStr":"{\"title\":\"Trialkylcyanoborates as intermediates in a new conversion of trialkylboranes into trialkylcarbinols\",\"authors\":\"A. Pelter, M. G. Hutchings, Keith Smith\",\"doi\":\"10.1039/C29710001048\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Warming trialkylcyanoborates with an excess of trifluoroacetic anhydride results in three migrations from boron to carbon to give, on oxidation, high yields of trialkylcarbinols.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"12 1\",\"pages\":\"1048-1048\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"16\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710001048\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710001048","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Trialkylcyanoborates as intermediates in a new conversion of trialkylboranes into trialkylcarbinols
Warming trialkylcyanoborates with an excess of trifluoroacetic anhydride results in three migrations from boron to carbon to give, on oxidation, high yields of trialkylcarbinols.
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