{"title":"铁在{氟[6,6 '，6″-膦酸钠(α-吡啶醛肟)(3 -)]硼(1 -)}铁(1+)阳离子中的配位几何的x射线研究。三角棱柱封装与八面体配体场稳定能量","authors":"M. Churchill, A. Reis","doi":"10.1039/C29710001307","DOIUrl":null,"url":null,"abstract":"A single crystal X-ray diffraction study of [{FB(ONCH·C5H3N)3P}FeII]+[BF4]–, CH2Cl2 shows the co-ordination geometry about the iron atom to be distorted by approximately 21·5° from the ideal trigonal primatic case.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"38 1","pages":"1307-1308"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"X-Ray study of the co-ordination geometry about iron in the {fluoro[6,6′,6″-phosphinidynetris(α-picolinaldehyde oximato)(3–)]borato(1–)}iron(1+) cation. Trigonal prismatic encapsulation vs. octahedral ligand-field stabilization energy\",\"authors\":\"M. Churchill, A. Reis\",\"doi\":\"10.1039/C29710001307\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A single crystal X-ray diffraction study of [{FB(ONCH·C5H3N)3P}FeII]+[BF4]–, CH2Cl2 shows the co-ordination geometry about the iron atom to be distorted by approximately 21·5° from the ideal trigonal primatic case.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"38 1\",\"pages\":\"1307-1308\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710001307\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710001307","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
X-Ray study of the co-ordination geometry about iron in the {fluoro[6,6′,6″-phosphinidynetris(α-picolinaldehyde oximato)(3–)]borato(1–)}iron(1+) cation. Trigonal prismatic encapsulation vs. octahedral ligand-field stabilization energy
A single crystal X-ray diffraction study of [{FB(ONCH·C5H3N)3P}FeII]+[BF4]–, CH2Cl2 shows the co-ordination geometry about the iron atom to be distorted by approximately 21·5° from the ideal trigonal primatic case.
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