{"title":"二甲基铊(III)十硼烷(14)衍生物","authors":"N. N. Greenwood, N. F. Travers, D. Waite","doi":"10.1039/C29710001027","DOIUrl":null,"url":null,"abstract":"Reaction of trimethylthallium with decaborane (14) yields the simple salt [Me2Tl]+[B10H13]–, (A), and the complex [Me2Tl]+[B10H12TlMe2]–, (B), which contains two distinct dimethylthallium(III) groups, one of which is chelated by the dodecahydro-nido-decaborate (2–) ion.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"6 1","pages":"1027-1027"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"Dimethylthallium(III) derivatives of decaborane(14)\",\"authors\":\"N. N. Greenwood, N. F. Travers, D. Waite\",\"doi\":\"10.1039/C29710001027\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Reaction of trimethylthallium with decaborane (14) yields the simple salt [Me2Tl]+[B10H13]–, (A), and the complex [Me2Tl]+[B10H12TlMe2]–, (B), which contains two distinct dimethylthallium(III) groups, one of which is chelated by the dodecahydro-nido-decaborate (2–) ion.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"6 1\",\"pages\":\"1027-1027\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710001027\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710001027","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Dimethylthallium(III) derivatives of decaborane(14)
Reaction of trimethylthallium with decaborane (14) yields the simple salt [Me2Tl]+[B10H13]–, (A), and the complex [Me2Tl]+[B10H12TlMe2]–, (B), which contains two distinct dimethylthallium(III) groups, one of which is chelated by the dodecahydro-nido-decaborate (2–) ion.
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