Réka Somogyfoki, Alessio Famá, Liliana Restuccia, Peter Ván
{"title":"Thermodynamics and dynamic stability: extended theories of heat conduction","authors":"Réka Somogyfoki, Alessio Famá, Liliana Restuccia, Peter Ván","doi":"10.1515/jnet-2024-0041","DOIUrl":"https://doi.org/10.1515/jnet-2024-0041","url":null,"abstract":"The stability of homogeneous thermodynamic equilibrium is analyzed in heat conduction theories in the framework of nonequilibrium thermodynamics, where the internal energy, the heat flux and a second order tensor are thermodynamic state variables. It is shown, that the thermodynamic conditions of concave entropy and nonnegative entropy production can ensure the linear stability. Various special heat conduction theories, including Extended Thermodynamics, are compared in the general framework.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"6 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142317728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Performance analysis of quantum harmonic Otto engine and refrigerator under a trade-off figure of merit","authors":"Kirandeep Kaur, Shishram Rebari, Varinder Singh","doi":"10.1515/jnet-2024-0034","DOIUrl":"https://doi.org/10.1515/jnet-2024-0034","url":null,"abstract":"We investigate the optimal performance of the quantum Otto engine and refrigeration cycles of a time-dependent harmonic oscillator under a trade-off figure of merit for both adiabatic and nonadiabatic (sudden-switch) frequency modulations. For heat engines (refrigerators), the chosen trade-off figure of merit is an objective function defined by the product of efficiency (coefficient of performance) and work output (cooling load), thus representing a compromise between them. We obtain analytical expressions for the efficiency and coefficient of performance of the harmonic Otto cycle for the optimal performance of the thermal machine in various operational regimes. Particularly, in the sudden-switch regime, we discuss the implications of the nonadiabatic driving on the performance of the thermal machine under consideration and obtain analytic expressions for the maximum achievable efficiency and coefficient of performance of the harmonic Otto thermal machine. Particularly, we show that the quantum harmonic Otto cycle driven by sudden-switch protocol cannot work as a heat engine or refrigerator in the low-temperature limit. Finally, we show that in the high-temperature limit, the frictional effects give rise to a richer structure of the phase diagram of the harmonic Otto cycle. We identify the parametric regime for the operation of the Otto cycle as a heat engine, refrigerator, accelerator, and heater.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"5 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142090068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Investigation of the operating characteristics of diesel engines with chromium oxide (Cr2O3) nanoparticles dispersed in Mesua ferrea biodiesel: an experimental and predictive approach using ANNs and RSM","authors":"Jagadish Kari, Vanthala Varaha Siva Prasad, Jaikumar Sagari","doi":"10.1515/jnet-2024-0021","DOIUrl":"https://doi.org/10.1515/jnet-2024-0021","url":null,"abstract":"This study investigates the effects of using biodiesel from <jats:italic>Mesua ferrea</jats:italic> (BD20) and chromium oxide (Cr<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>) nanoparticles in diesel engines. The Response Surface Methodology (RSM) model and artificial neural networks (ANNs) were developed to make precise predictions of the operating parameters. The amount of Cr<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> nanoparticles was set at 80 mg/L, and surfactant and dispersant were applied to the nanoparticles in the same amounts. The study was carried out with different compression ratios and load conditions. The parameters evaluated were engine load, fuel samples and compression ratio as inputs and BTE, BSFC, CP, NHRR, CO, UHC, NO<jats:sub> <jats:italic>x</jats:italic> </jats:sub> and smoke opacity as outputs. The addition of the QPAN80 additive at the same dosage of 80 mg/L together with the BD20 fuel blend containing Cr<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> at a concentration of 80 mg/L resulted in a significant increase in BTE by 16.58 % and a reduction in BSFC by 0.58 %. While the NHRR increased by 85.40 %, the CP increased sharply by 24.47 %. The CO concentration decreased by 31.85 %, the UHC concentration by 22.22 %, the NO<jats:sub> <jats:italic>x</jats:italic> </jats:sub> concentration by 6.16 % and the smoke emission by 62.61 %. For each output parameter, the correlation coefficient (<jats:italic>R</jats:italic> <jats:sup>2</jats:sup>), calculated using ANNs and RSM was between 0.96 and 0.98. The observed range of values demonstrates a robust correlation between the experimental data and the predicted outcomes.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"23 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141994468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Analytical solutions for nonequilibrium bioheat transfer in tumor during magnetic nanoparticles hyperthermia","authors":"Zuhur Alqahtani, Ibrahim Abbas","doi":"10.1515/jnet-2024-0035","DOIUrl":"https://doi.org/10.1515/jnet-2024-0035","url":null,"abstract":"This paper presents mathematical responses for the dual-phase-lag (DPL) hypothesis, which accounts for nonequilibrium heat transfer during magnetic nanoparticle hyperthermia in tumor. To get this precision, volume averaging is used for the local instantaneous energy formulation for tissues and blood. This study proposes a hybrid numerical strategy to solve this problem by combining change of variables, improved discretization techniques, and Laplace transforms. Using the Arrhenius formulas, the range of denatured proteins is used to assess the degree of heat damages to the tumor and healthy tissues. The impacts of porosity, the blood perfusion and metabolism on the temperature and the thermal injuries are studied. The numerical estimations of temperature and the resulting of thermal injuries are shown on a graph, and a comparison with earlier research establishes the results’ validity.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"80 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141755075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Composite liquids under high-power heating: superheat of water in micro-explosion of water-in-fuel droplets","authors":"Alexey Melkikh, Pavel Skripov","doi":"10.1515/jnet-2024-0017","DOIUrl":"https://doi.org/10.1515/jnet-2024-0017","url":null,"abstract":"The article analyses the degree of water superheating with respect to the liquid-vapour equilibrium line in experiments on the micro-explosion of a composite droplet comprised of two immiscible liquids. The analyses were carried out for water-in-fuel drops under conditions of high-power heating. This degree is compared with the mechanical effect of droplet decay, involving the formation of daughter droplets. Our attention was drawn to the smallness of the degree of superheating preceding the decay. A model of the boiling up of such a droplet is constructed taking into account the sources of premature boiling up of water inherent in micro-explosive experiments. The dependencies of the boiling up temperature of water on the heating rate obtained in the model turned out to be in accordance with the experimental data across a wide range of heating rates. A hypothesis about the local superheating of the transition layer, which is not detected in the experiment, is formulated. Thus, a step has been taken to clarify the essence of the mismatch of the degree of superheating of water recorded by macroscopic equipment along with a completely satisfactory generation of daughter droplets serving as the basis for advanced fuel technology.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"51 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141755085","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Application of a three-laser optical digital interferometry in a thermogravitational analysis for binary and ternary mixtures","authors":"Ane Errarte, Antton Sanjuan, Aliaksandr Mialdun, Marcos Alonso, Imanol Andonegui, Valentina Shevtsova, M. Mounir Bou-Ali","doi":"10.1515/jnet-2023-0126","DOIUrl":"https://doi.org/10.1515/jnet-2023-0126","url":null,"abstract":"We discuss the application of the three-laser optical digital interferometry method for the determination of transport properties such as the thermodiffusion, the molecular diffusion and the Soret coefficients by the thermogravitational column technique. The primary objective of this study is to illustrate the capabilities and limitations of the method for quantifying these properties in both binary and ternary liquid mixtures from an optical viewpoint. It is concluded that the system is highly robust for the analysis of binary mixtures, with the combination of the results obtained by the three wavelengths increasing the accuracy of the measurement. The study of ternary mixtures, on the contrary, is limited to certain types of conditions. While the accuracy of a three-laser interferometer can be improved, the method may be compromised if the optical contrast factor matrices are poorly conditioned.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"240 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141631399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mass transfer at vapor-liquid interfaces of H2O + CO2 mixtures studied by molecular dynamics simulation","authors":"Simon Stephan, Vilde Bråten, Hans Hasse","doi":"10.1515/jnet-2024-0010","DOIUrl":"https://doi.org/10.1515/jnet-2024-0010","url":null,"abstract":"In many industrial applications as well as in nature, the mass transfer of CO<jats:sub>2</jats:sub> at vapor-liquid interfaces in aqueous systems plays an important role. In this work, this process was studied on the atomistic level using non-equilibrium molecular dynamics simulations. In a first step, a molecular model of the system water + CO<jats:sub>2</jats:sub> was developed that represents both bulk and interfacial equilibrium properties well. This system is characterized by a very large adsorption and enrichment of CO<jats:sub>2</jats:sub> at the vapor-liquid interface. Then, non-equilibrium mass transfer simulations were carried out using a method that was developed recently: CO<jats:sub>2</jats:sub> is inserted into the vapor phase of a simulation box which contains a liquid slab. Surprising effects are observed at the interface such as a net repulsion of CO<jats:sub>2</jats:sub> particles from the interface and a complex time dependence of the amount of CO<jats:sub>2</jats:sub> adsorbed at the interface.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"26 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141631476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Giuseppe Colella, Allan D. Mackie, James P. Larentzos, John K. Brennan, Martin Lísal, Josep Bonet Avalos
{"title":"Generalized energy-conserving dissipative particle dynamics with mass transfer: coupling between energy and mass exchange","authors":"Giuseppe Colella, Allan D. Mackie, James P. Larentzos, John K. Brennan, Martin Lísal, Josep Bonet Avalos","doi":"10.1515/jnet-2023-0129","DOIUrl":"https://doi.org/10.1515/jnet-2023-0129","url":null,"abstract":"The complete description of energy and material transport within the Generalized energy-conserving dissipative particle dynamics with mass transfer (GenDPDE-M) methodology is presented. In particular, the dynamic coupling between mass and energy is incorporated into the GenDPDE-M, which was previously introduced with dynamically decoupled fluxes (J. Bonet Avalos et al., <jats:italic>J. Chem. Theory Comput.</jats:italic>, 18 (12): 7639–7652, 2022). From a theoretical perspective, we have derived the appropriate Fluctuation-Dissipation theorems along with Onsager’s reciprocal relations, suitable for mesoscale models featuring this coupling. Equilibrium and non-equilibrium simulations are performed to demonstrate the internal thermodynamic consistency of the method, as well as the ability to capture the Ludwig–Soret effect, and tune its strength through the mesoscopic parameters. In view of the completeness of the presented approach, GenDPDE-M is the most general Lagrangian method to deal with complex fluids and systems at the mesoscale, where thermal agitation is relevant.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"20 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141182431","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Power and efficient power optimization of one-qubit Novikov quantum heat engines with an external dissipative heat leak","authors":"Julio Juan Fernández","doi":"10.1515/jnet-2023-0118","DOIUrl":"https://doi.org/10.1515/jnet-2023-0118","url":null,"abstract":"We optimize one-qubit Novikov quantum heat engines with a dissipative heat leak using the formalisms of open-system Quantum Mechanics and the Finite-Time Thermodynamics. We show that the leak changes the power-efficiency and the efficient-power-efficiency curves, reduces the maximum efficiency of the machine and does not change its power. We also discuss the effects of the leak on the power that is rejected from the machine to the environment. Finally, we study the high-temperature limit to check that the engine reduces in this limit to a classic Novikov heat engine.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"76 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141177412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Antton Sanjuan, Daniel Sommermann, Werner Köhler, Valentina Shevtsova, M. Mounir Bou-Ali
{"title":"Thermodiffusion, diffusion and Soret coefficients of binary polymeric mixtures in toluene and cyclohexane","authors":"Antton Sanjuan, Daniel Sommermann, Werner Köhler, Valentina Shevtsova, M. Mounir Bou-Ali","doi":"10.1515/jnet-2023-0125","DOIUrl":"https://doi.org/10.1515/jnet-2023-0125","url":null,"abstract":"We present the results of experimental study on measuring the thermodiffusion, molecular diffusion and Soret coefficients of polystyrene (4,880 g/mol) in the pure solvents toluene and cyclohexane at 298 K and atmospheric pressure. The experiments have been carried out for a wide range of concentrations, starting from the diluted state with 2 % polystyrene mass fraction (proposed in the DCMIX4 project) up to the semidilute regime of 20 % polystyrene mass fraction. In addition, we present a complete characterisation of the thermophysical properties of the analysed mixtures. Thermodiffusion, molecular diffusion and Soret coefficients of binary polymeric samples have been measured by combining the traditional thermogravitational column technique, the thermogravitational microcolumn and the optical beam deflection method. In toluene, the obtained experimental results are consistent with literature, showing that the magnitude of the mass transport thermoproperties decrease significantly with increasing polystyrene concentration, which is a first indication of an approaching glass transition in the concentrated regime. The results for thermodiffusion and molecular diffusion coefficients in cyclohexane as a function of concentration exhibit a similar trend. Nevertheless, the Soret coefficient seems to show an opposite tendency for the two solvents, increasing in magnitude for cyclohexane, at least up to the analysed polystyrene concentration.","PeriodicalId":16428,"journal":{"name":"Journal of Non-Equilibrium Thermodynamics","volume":"54 1","pages":""},"PeriodicalIF":6.6,"publicationDate":"2024-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141096700","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}