Jaime Arturo de la Torre, Jesús Sánchez-Rodríguez, Pep Español
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引用次数: 0
Abstract
Intrinsic thermal fluctuations within a real solid challenge the rigid body assumption that is central to Euler’s equations for the motion of a free body. Recently, we have introduced a dissipative and stochastic version of Euler’s equations in a thermodynamically consistent way (European Journal of Mechanics – A/Solids 103, 105,184 (2024)). This framework describes the evolution of both orientation and shape of a free body, incorporating internal thermal fluctuations and their concomitant dissipative mechanisms. In the present work, we demonstrate that, in the absence of angular momentum, the theory predicts that the principal axes unit vectors of a body undergo an anisotropic Brownian motion on the unit sphere, with the anisotropy arising from the body’s varying moments of inertia. The resulting equilibrium time correlation function of the principal eigenvectors decays exponentially. This theoretical prediction is confirmed in molecular dynamics simulations of small bodies. The comparison of theory and equilibrium MD simulations allow us to measure the orientational diffusion tensor. We then use this information in the Stochastic Dissipative Euler’s Equations, to describe a non-equilibrium situation of a body spinning around the unstable intermediate axis. The agreement between theory and simulations is excellent, offering a validation of the theoretical framework.
期刊介绍:
The Journal of Non-Equilibrium Thermodynamics serves as an international publication organ for new ideas, insights and results on non-equilibrium phenomena in science, engineering and related natural systems. The central aim of the journal is to provide a bridge between science and engineering and to promote scientific exchange on a) newly observed non-equilibrium phenomena, b) analytic or numeric modeling for their interpretation, c) vanguard methods to describe non-equilibrium phenomena.
Contributions should – among others – present novel approaches to analyzing, modeling and optimizing processes of engineering relevance such as transport processes of mass, momentum and energy, separation of fluid phases, reproduction of living cells, or energy conversion. The journal is particularly interested in contributions which add to the basic understanding of non-equilibrium phenomena in science and engineering, with systems of interest ranging from the macro- to the nano-level.
The Journal of Non-Equilibrium Thermodynamics has recently expanded its scope to place new emphasis on theoretical and experimental investigations of non-equilibrium phenomena in thermophysical, chemical, biochemical and abstract model systems of engineering relevance. We are therefore pleased to invite submissions which present newly observed non-equilibrium phenomena, analytic or fuzzy models for their interpretation, or new methods for their description.