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Equivalent Circuit Model for Electrochemical Impedance Spectroscopy of Commercial 18650 Lithium-Ion Cell Under Over-Discharge and Overcharge Conditions 过放电和过充电条件下商用 18650 锂离子电池电化学阻抗谱分析的等效电路模型
IF 2.7 3区 化学
Electroanalysis Pub Date : 2024-09-09 DOI: 10.1002/elan.202300232
Salim Erol
{"title":"Equivalent Circuit Model for Electrochemical Impedance Spectroscopy of Commercial 18650 Lithium-Ion Cell Under Over-Discharge and Overcharge Conditions","authors":"Salim Erol","doi":"10.1002/elan.202300232","DOIUrl":"10.1002/elan.202300232","url":null,"abstract":"<p>This study endeavors to assess the impedance responses exhibited by 18650 Graphite||LiCoO<sub>2</sub> (C<sub>6</sub>||LCO) cells under conditions of over-discharge and overcharge. The impedance measurements are conducted at a potential of 4.20 V, followed by subjecting the cells to over-discharge and overcharge scenarios. It is observed that the impedance magnitude experiences augmentation in both instances. Upon reaching a potential of 2.70 V, the electrochemical attributes of the cells revert to their normal state post over-discharge. However, the impedance characteristics persist even upon exceeding a potential of 4.70 V. These observations imply that overcharge induces enduring alterations in impedance behavior, while over-discharge is a reversible phenomenon. To delve deeper into the underlying mechanisms, an equivalent circuit process model is constructed. This model elucidates that over-discharge of Li-ion batteries is reversible, indicating the potential for restoration of original impedance behavior upon recharge. Conversely, overcharge precipitates permanent alterations in impedance behavior, engendering irreversible changes in battery characteristics. In summation, this study underscores the criticality of meticulously managing the charging and discharging processes of Li-ion batteries to avert irreversible impairment to impedance behavior, thereby safeguarding battery performance and longevity.</p>","PeriodicalId":162,"journal":{"name":"Electroanalysis","volume":"36 10","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/elan.202300232","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142213748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green Electrochemical Sensors, Their Applications and Greenness Metrics Used: A Review 绿色电化学传感器及其应用和所用的绿色指标：综述
IF 2.7 3区 化学
Electroanalysis Pub Date : 2024-09-09 DOI: 10.1002/elan.202400286
Caglar Berkel, Oguz Özbek
{"title":"Green Electrochemical Sensors, Their Applications and Greenness Metrics Used: A Review","authors":"Caglar Berkel,&nbsp;Oguz Özbek","doi":"10.1002/elan.202400286","DOIUrl":"10.1002/elan.202400286","url":null,"abstract":"<p>Green analytical methods are important techniques that aim to reduce or eliminate the use of harmful chemicals and waste in various analyses. These methods, based on green chemistry principles, are environmentally friendly and reliable. Electrochemical techniques have an essential role in diverse analyses, and are presented as a superior alternative to existing analytical devices in terms of different parameters. In the present review, we have comprehensively covered electrochemistry-based sensors that are developed using green chemistry principles and evaluated their performance characteristics and specific working conditions. We here included sensors developed based on potentiometry and voltammetry methodologies, and detailed their greenness potentials based on certain metrics. Considering the advantages provided by these environmentally friendly new generation sensors, it will be inevitable for researchers working in this field to direct their attention to sensors that can be produced with green approaches.</p>","PeriodicalId":162,"journal":{"name":"Electroanalysis","volume":"36 11","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/elan.202400286","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142213749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biomass‐derived porous carbon modified with black phosphorus nanosheets as effective sulfur host for lithium‐sulfur batteries 用黑磷纳米片修饰的生物质多孔碳作为锂硫电池的有效硫宿主
IF 3 3区 化学
Electroanalysis Pub Date : 2024-09-07 DOI: 10.1002/elan.202400277
Zhe Yang, Xinyuan Liang, Chengzhuo Xiao, Jicheng Ma
{"title":"Biomass‐derived porous carbon modified with black phosphorus nanosheets as effective sulfur host for lithium‐sulfur batteries","authors":"Zhe Yang, Xinyuan Liang, Chengzhuo Xiao, Jicheng Ma","doi":"10.1002/elan.202400277","DOIUrl":"https://doi.org/10.1002/elan.202400277","url":null,"abstract":"The shuttle effect and slow oxidation‐reduction reactions of the cathode in lithium‐sulfur batteries limit its practical application and development. Herein, porous carbon derived from pollen modified by black phosphorus nanosheets (BP/N‐C) have been synthesized and utilized as a sulfur host in Li‐S batteries. From the compositional outlook, the biomass‐derived carbon forms a unique three‐dimensional skeleton structure, exhibiting excellent properties, such as high porosity and high conductivity. Upon modified with black phosphorus, the BP/N‐C composite materials demonstrate enhanced adsorption ability and catalytic activity toward lithium polysulfide","PeriodicalId":162,"journal":{"name":"Electroanalysis","volume":"2 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142213750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An electrochemical bioplatform based on acrylamide‐induced inhibition of DNA‐RNA hybridization for the determination of acrylamide 基于丙烯酰胺诱导的 DNA-RNA 杂交抑制的电化学生物平台，用于测定丙烯酰胺
IF 3 3区 化学
Electroanalysis Pub Date : 2024-09-06 DOI: 10.1002/elan.202400175
Mohamed Zouari, Víctor Ruiz-Valdepeñas Montiel, María Gamella, Nouha Setti Boubaker, José Pingarrón, Susana Ruiz, Noureddine Raouafi
{"title":"An electrochemical bioplatform based on acrylamide‐induced inhibition of DNA‐RNA hybridization for the determination of acrylamide","authors":"Mohamed Zouari, Víctor Ruiz-Valdepeñas Montiel, María Gamella, Nouha Setti Boubaker, José Pingarrón, Susana Ruiz, Noureddine Raouafi","doi":"10.1002/elan.202400175","DOIUrl":"https://doi.org/10.1002/elan.202400175","url":null,"abstract":"NA","PeriodicalId":162,"journal":{"name":"Electroanalysis","volume":"31 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142213752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self‐calibrating copper‐based metal organic frameworks for ratiometric electrochemical sensing of creatinine 用于肌酐比率电化学传感的自校准铜基金属有机框架
IF 3 3区 化学
Electroanalysis Pub Date : 2024-09-06 DOI: 10.1002/elan.202400173
Ahmed Z. Alanazi, Khalid Alhazzani, Al-Montaser Bellah H. Ali, Mahmoud Darweesh, Hossieny Ibrahim, mohamed el-wekil
{"title":"Self‐calibrating copper‐based metal organic frameworks for ratiometric electrochemical sensing of creatinine","authors":"Ahmed Z. Alanazi, Khalid Alhazzani, Al-Montaser Bellah H. Ali, Mahmoud Darweesh, Hossieny Ibrahim, mohamed el-wekil","doi":"10.1002/elan.202400173","DOIUrl":"https://doi.org/10.1002/elan.202400173","url":null,"abstract":"NA","PeriodicalId":162,"journal":{"name":"Electroanalysis","volume":"2 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142213751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mercury detection in novel foods by a smart pocket sensor 用智能袖珍传感器检测新型食品中的汞含量
IF 3 3区 化学
Electroanalysis Pub Date : 2024-09-04 DOI: 10.1002/elan.202400192
Ilaria Vitale, Giulia Selvolini, Sara Failli, Cristina Truzzi, giovanna Marrazza
{"title":"Mercury detection in novel foods by a smart pocket sensor","authors":"Ilaria Vitale, Giulia Selvolini, Sara Failli, Cristina Truzzi, giovanna Marrazza","doi":"10.1002/elan.202400192","DOIUrl":"https://doi.org/10.1002/elan.202400192","url":null,"abstract":"Mercury is one of the most well‐known toxic contaminants of natural and anthropogenic origin in aquatic ecosystems that can bioaccumulate in vegetal and animal organisms. In this work, we propose a smart detection system for Hg(II) ions by square wave anodic stripping voltammetry at nanocomposite graphite screen‐printed electrodes, as an analytical tool to be applied in food quality control. The nanocomposite surfaces were obtained by the modification of screen‐printed graphite electrodes with poly(l‐aspartic acid) and gold nanoparticles and were characterized by means of electrochemical techniques. An exhaustive study of the experimental conditions involved both in the e","PeriodicalId":162,"journal":{"name":"Electroanalysis","volume":"117 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142213753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Detection of Diclofenac and Carbamazepine using Voltammetry and Flow Injection Analysis at Boron‐Doped Diamond Thin‐Film Electrodes 在掺硼金刚石薄膜电极上使用伏安法和流动注射分析法检测双氯芬酸和卡马西平
IF 3 3区 化学
Electroanalysis Pub Date : 2024-09-04 DOI: 10.1002/elan.202400157
Aaron Jacobs, Simphiwe Zwane, Romana Jarošová, Marissa D. Zamora, Alex Kuvarega, Greg Swain
{"title":"Detection of Diclofenac and Carbamazepine using Voltammetry and Flow Injection Analysis at Boron‐Doped Diamond Thin‐Film Electrodes","authors":"Aaron Jacobs, Simphiwe Zwane, Romana Jarošová, Marissa D. Zamora, Alex Kuvarega, Greg Swain","doi":"10.1002/elan.202400157","DOIUrl":"https://doi.org/10.1002/elan.202400157","url":null,"abstract":"The electrochemical detection of two pharmaceuticals, diclofenac (DCF) and carbamazepine (CBZ), was investigated as an oxidation current using boron‐doped nanocrystalline diamond (BDD) thin‐film electrodes. Both voltammetry and flow injection analysis with amperometric detection (FIA‐EC) were used to measure the drugs in standard solutions and a urine simulant. The oxidation potential of DCF was &lt;i&gt;ca.&lt;/i&gt; 0.8 V vs. Ag/AgCl (3 M KCl) in 0.1 M phosphate buffer (pH 7.2) and was &lt;i&gt;ca.&lt;/i&gt; 1.2 V for CBZ in 0.1 M perchloric acid. The DCF oxidation reaction was diffusion controlled at the detection potential with evidence of some surface fouling by","PeriodicalId":162,"journal":{"name":"Electroanalysis","volume":"279 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142213609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photoelectrochemical immunoassay of alpha‐fetoprotein based on Au nanoparticles‐decorated ZnO microrods 基于金纳米颗粒装饰的氧化锌微晶的甲胎蛋白光电化学免疫分析法
IF 3 3区 化学
Electroanalysis Pub Date : 2024-09-02 DOI: 10.1002/elan.202400257
Shaohua Xu, Ming Wang, Minyong Chen, Jin Zou, Mingji Zhang, Lihui Yu, Yongfa Ke, Chenjun Zhang, Hui Zhang, Jingfeng Liu
{"title":"Photoelectrochemical immunoassay of alpha‐fetoprotein based on Au nanoparticles‐decorated ZnO microrods","authors":"Shaohua Xu, Ming Wang, Minyong Chen, Jin Zou, Mingji Zhang, Lihui Yu, Yongfa Ke, Chenjun Zhang, Hui Zhang, Jingfeng Liu","doi":"10.1002/elan.202400257","DOIUrl":"https://doi.org/10.1002/elan.202400257","url":null,"abstract":"NA","PeriodicalId":162,"journal":{"name":"Electroanalysis","volume":"412 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142213789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of a Solid-State Potentiometric Sensor for Point-of-care Diagnostics of Flucloxacillin in Spiked Human Plasma; Whiteness Evaluation 将固态电位计传感器用于加标人血浆中氟氯西林的床旁诊断；白度评估
IF 2.7 3区 化学
Electroanalysis Pub Date : 2024-09-02 DOI: 10.1002/elan.202400069
Rehab Moussa Tony, Maha M. Galal, Amr M. Mahmoud, Aya T. Soudi
{"title":"Application of a Solid-State Potentiometric Sensor for Point-of-care Diagnostics of Flucloxacillin in Spiked Human Plasma; Whiteness Evaluation","authors":"Rehab Moussa Tony,&nbsp;Maha M. Galal,&nbsp;Amr M. Mahmoud,&nbsp;Aya T. Soudi","doi":"10.1002/elan.202400069","DOIUrl":"10.1002/elan.202400069","url":null,"abstract":"<p>Antibiotic resistance is a crisis that is escalating nowadays. Thus, therapeutic drug monitoring (TDM) is crucial to personalize the dose. Point-of-care (POC) devices are very effective in TDM where drug concentration can be easily and continuously monitored. This work describes for the first time the use of inexpensive, transportable, efficacious, and eco-friendly POC solid-state potentiometric sensor for the TDM of Flucloxacillin (FLU) in spiked plasma samples. This was achieved by using an innovative glassy carbon electrode modified with ion sensing membrane doped with carbon nanotubes. Optimization of the sensing membrane composition was performed using different plasticizers and by adding an ionophore. This was followed by doping the ion sensing membrane with carbon nanotubes which resulted in enhancing the sensor's sensitivity towards FLU. Over a concentration range from 1.0×10<sup>−5</sup>–1.0×10<sup>−2</sup> M FLU, a linear response was obtained with a slope of 56.6 mV/decade. Our proposed sensor has been validated according to IUPAC recommendations with acceptable results.</p><p>It was effectively employed for a selective determination of FLU in the presence of a co-formulated antibiotic (Amoxicillin), along with other excipients in the dosage form, and in spiked plasma samples, without any interference. The whiteness of the method was assessed, which proves the high greenness and superb functionality of our proposed method.</p>","PeriodicalId":162,"journal":{"name":"Electroanalysis","volume":"36 11","pages":""},"PeriodicalIF":2.7,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142213754","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Molecularly Imprinted Nanoparticle‐Based polymer (Acrylamide‐N‐Vinyl imidazol)/Nafion Film Modified Screen‐Printed Electrode System for Rapid Determination of Hemoglobin 基于分子印迹纳米粒子的聚合物（丙烯酰胺-N-乙烯基咪唑）/纳菲欧薄膜改性丝网印刷电极系统，用于快速测定血红蛋白
IF 3 3区 化学
Electroanalysis Pub Date : 2024-08-29 DOI: 10.1002/elan.202400274
Hilal Özçelik, Esra Yaşar, Timuçin Güner, Emre Dokuzparmak, Koray Şarkaya, Sinan Akgöl
{"title":"Molecularly Imprinted Nanoparticle‐Based polymer (Acrylamide‐N‐Vinyl imidazol)/Nafion Film Modified Screen‐Printed Electrode System for Rapid Determination of Hemoglobin","authors":"Hilal Özçelik, Esra Yaşar, Timuçin Güner, Emre Dokuzparmak, Koray Şarkaya, Sinan Akgöl","doi":"10.1002/elan.202400274","DOIUrl":"https://doi.org/10.1002/elan.202400274","url":null,"abstract":"In medical diagnostics, variations in hemoglobin levels can reveal a variety of prevalent health conditions. Abnormal hemoglobin is known to be connected with diseases like anemia, diabetes, hematemesis, hematuria, and hemoglobinuria. Consequently, there is a significant demand for advanced detection technologies and precise methodologies to accurately track and assess hemoglobin levels. This study demonstrates the potential of a novel molecularly imprinted nanoparticle‐based sensor system to rapidly analyze hemoglobin levels without the need for a laboratory environment. Hemoglobin imprinted‐poly(acrylamide‐ &lt;i&gt;co&lt;/i&gt;‐vinyl imidazole) [Hb‐imp‐p(AAm‐ &lt;i&gt;co&lt;/i&gt;‐VIM)] nanoparticles with high affinity and selectivity for hemoglobin were synthesized and loaded onto the","PeriodicalId":162,"journal":{"name":"Electroanalysis","volume":"179 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142213788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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