Journal of Magnesium and Alloys最新文献_第2页

Interfacial processes of Mg anodes for magnesium-sulfur batteries: An EIS study 镁硫电池镁阳极界面过程的EIS研究

IF 17.6 1区材料科学

Journal of Magnesium and Alloys Pub Date : 2025-05-08 DOI: 10.1016/j.jma.2025.04.001

Joachim Häcker, Tobias Rommel, Pia Lange, Felix Kampmann, Jürgen Remmlinger, Zhirong Zhao-Karger, K. Andreas Friedrich, Maryam Nojabaee

{"title":"Interfacial processes of Mg anodes for magnesium-sulfur batteries: An EIS study","authors":"Joachim Häcker, Tobias Rommel, Pia Lange, Felix Kampmann, Jürgen Remmlinger, Zhirong Zhao-Karger, K. Andreas Friedrich, Maryam Nojabaee","doi":"10.1016/j.jma.2025.04.001","DOIUrl":"https://doi.org/10.1016/j.jma.2025.04.001","url":null,"abstract":"The development of magnesium batteries strongly relies on the use of a Mg metal anode and its benefits of high volumetric capacity, reduction potential, low cost and improved safety, however, to date, it still lacks sufficient cycling stability and reversibility. Along with the electrolyte selection, the interfacial processes can be affected by the anode itself applying electrode engineering strategies. In this study, six different Mg anode approaches – namely bare Mg metal, Mg foil with an organic and inorganic artificial solid electrolyte interphase, Mg alloy, Mg pellet and a tape-casted Mg slurry – are selected to be investigated by means of electrochemical impedance spectroscopy in Mg|Mg and Mg|S cells. While a plating/stripping overpotential asymmetry was observed and assigned to the desolvation during Mg plating, the impedance spectra of stripping and plating hardly differ for all applied anodes. In contrast, the sulfur species significantly influence the impedance response by altering the surface layer composition. By systematic process assignment of the gained spectra in Mg|Mg and Mg|S cells, specific equivalent circuit models for different anodes and cell conditions are derived. Overall, the study aims to give valuable insights into the interfacial processes of Mg anodes to support their further development toward long-lasting Mg batteries.","PeriodicalId":16214,"journal":{"name":"Journal of Magnesium and Alloys","volume":"53 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143926341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of element Ce on the strain rate sensitivity of Mg-Zn-Zr alloy 元素Ce对Mg-Zn-Zr合金应变速率敏感性的影响

IF 17.6 1区材料科学

Journal of Magnesium and Alloys Pub Date : 2025-05-07 DOI: 10.1016/j.jma.2025.04.017

引用次数: 0

Achieving high modulus and strength in ultra-light Mg-Li alloys through in situ-synthesized Mg2Si phase 通过原位合成Mg2Si相实现超轻Mg-Li合金的高模量和高强度

IF 17.6 1区材料科学

Journal of Magnesium and Alloys Pub Date : 2025-05-07 DOI: 10.1016/j.jma.2025.04.009

Yangyang Xu, Meng Li, Yuchuan Huang, Jiawei Sun, Peng Sun, Hongchao Xiao, Gang Zeng, Qi Li, Youjie Guo, Guohua Wu, Wencai Liu

引用次数: 0

Exploring high-performance magnesium-sulfur pouch cells using nitrogen-rich doped nano porous carbon 利用富氮掺杂纳米多孔碳探索高性能镁硫袋电池

IF 17.6 1区材料科学

Journal of Magnesium and Alloys Pub Date : 2025-05-07 DOI: 10.1016/j.jma.2025.03.028

Yingying Yao, Yinghui Li, Zhao Li, Hao Xu, Yang Zhan, Fengzhan Sun, Ya Yang, Richard M. Laine, Liang Fu, Jianxin Zou

{"title":"Exploring high-performance magnesium-sulfur pouch cells using nitrogen-rich doped nano porous carbon","authors":"Yingying Yao, Yinghui Li, Zhao Li, Hao Xu, Yang Zhan, Fengzhan Sun, Ya Yang, Richard M. Laine, Liang Fu, Jianxin Zou","doi":"10.1016/j.jma.2025.03.028","DOIUrl":"https://doi.org/10.1016/j.jma.2025.03.028","url":null,"abstract":"Magnesium-sulfur batteries (MSBs) are promising due to Mg's lower propensity to form dendrites, its natural abundance, and high volumetric energy densities for large-scale energy storage. Nonetheless, Mg2+ ions have poor diffusion kinetics and the magnesium polysulfide (MgPS) shuttle effect present significant challenges for MSBs. Herein, a Mg-S pouch cell is designed using rich N-doped porous carbon (ZIF8-NC) and a Cu current collector. This architecture provides numerous benefits: i) ZIF8-NC offers a conductive skeleton that significantly enhances electron and Mg2+ ion conduction, ii) zeolite imidazolate frameworks (ZIF-8) derived N rich sites demonstrate superior MgPS anchoring capability, iii) the Cu collector not only accelerates conversion of anchored MgPS to MgS, but also participates in the electrode reaction and iv) the material is easy to synthesize on a large scale, facilitating its potential for practical applications. Mg-S/ZIF8-NC coin cells maintain ∼310 mAh·g-1 after 1000 cycles even at 1C. Furthermore, Mg-S/ZIF8-NC pouch cells achieve high cathodic energy densities of ∼120 Wh·kg-1 and ∼330 mAh·g-1 after 300 cycles at 1C, outperforming the state-of-the-art results in the literature. Soft X-ray absorption spectroscopy (sXAS) revealed that the initial catalytic reaction of Cu follows Cu0↔Cu2S, and later Cu2S↔CuxS. Theoretical calculations and experimental results reveal that pyridine nitrogen acts as catalytic site for polysulfide adsorption. Therefore, this work not only provides a facile method to prepare high-performance Mg-S pouch cells, but also proposes mechanisms whereby N active sites and Cu catalytic reactions promote all aspects of performance.","PeriodicalId":16214,"journal":{"name":"Journal of Magnesium and Alloys","volume":"12 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143915573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Unusual tensile strengths and strain-hardening behaviors and their structural correlation of Mg-RE solid solution Mg-RE固溶体不同寻常的拉伸强度和应变硬化行为及其结构相关性

IF 17.6 1区材料科学

Journal of Magnesium and Alloys Pub Date : 2025-05-02 DOI: 10.1016/j.jma.2025.04.002

Wenbo Luo, Rongsheng Bai, Zhilei Yu, Xiuzhu Han, Tong Guo, Zhiyong Xue, Chen Wen, Mingyue Zheng, Feng Li, Zhihao Lin

{"title":"Unusual tensile strengths and strain-hardening behaviors and their structural correlation of Mg-RE solid solution","authors":"Wenbo Luo, Rongsheng Bai, Zhilei Yu, Xiuzhu Han, Tong Guo, Zhiyong Xue, Chen Wen, Mingyue Zheng, Feng Li, Zhihao Lin","doi":"10.1016/j.jma.2025.04.002","DOIUrl":"https://doi.org/10.1016/j.jma.2025.04.002","url":null,"abstract":"This study systematically investigates the unusual tensile mechanical behavior of Mg-RE solid solution (SS) alloys, exhibiting anomalous tensile strengths (ATS) and an enhanced strain-hardening rate at high temperature. Both the peak ultimate tensile strength (UTS) and tensile yield strength (TYS) values occur at 150–200 °C, which are 12–50% higher compared to those at room temperature (RT). Meanwhile, the strain-hardening rate increases with the temperature rising from RT to 200 °C during the plastic deformation process. The results reveal that the formation of stacking faults (SFs) and the locking of dislocations, particularly immobile 〈c〉 partial dislocations, enhance resistance to plastic deformation, leading to higher strengths at high temperature. Furthermore, the interactivity between SFs and 〈c + a〉 dislocations intensify with rising of temperature. The presence of RE atoms in the SS plays a critical role in this unique mechanical behavior, as they preferentially occupy non-basal planes rather than basal planes, thereby reducing the stacking fault (SF) formation energy. This study provides new insights into the high-temperature strengthening mechanisms of Mg-RE based alloys, offering potential guidance for the design of advanced lightweight materials with superior mechanical properties.","PeriodicalId":16214,"journal":{"name":"Journal of Magnesium and Alloys","volume":"1 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143901320","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Orientation-dependence of incipient plasticity in a coarse-grained Mg revealed by nanoindentation pop-ins 纳米压痕突入揭示粗晶Mg初始塑性的取向依赖性

IF 17.6 1区材料科学

Journal of Magnesium and Alloys Pub Date : 2025-05-01 DOI: 10.1016/j.jma.2025.04.004

Moein Imani Foumani, Syed Taha Khursheed, Yushun Liu, Guo-zhen Zhu

引用次数: 0

Clarifying interfacial microstructures of Ti particle reinforced Mg-Zn-Mn composites to achieve good strength-ductility synergy 澄清Ti颗粒增强Mg-Zn-Mn复合材料的界面微观结构，实现良好的强度-延性协同

IF 17.6 1区材料科学

Journal of Magnesium and Alloys Pub Date : 2025-04-26 DOI: 10.1016/j.jma.2025.03.030

Jichuan Fan, Hong Yang, Wenlong Xie, Gong Chen, Yunxuan Zhou, Kaihong Zheng, Jun Xu, Jun Tan, Xianhua Chen, Fusheng Pan

{"title":"Clarifying interfacial microstructures of Ti particle reinforced Mg-Zn-Mn composites to achieve good strength-ductility synergy","authors":"Jichuan Fan, Hong Yang, Wenlong Xie, Gong Chen, Yunxuan Zhou, Kaihong Zheng, Jun Xu, Jun Tan, Xianhua Chen, Fusheng Pan","doi":"10.1016/j.jma.2025.03.030","DOIUrl":"https://doi.org/10.1016/j.jma.2025.03.030","url":null,"abstract":"In the field of particle reinforced magnesium (Mg) matrix composites (MMCs), the interfacial microstructures between reinforcements and Mg matrix are a subject of interest for most researchers. In this work, the 2 wt.% Ti particle reinforced Mg-6 Zn alloy composites with different contents (0, 0.5, 1, 1.5, 2 wt.%) of Mn were prepared using semi-solid stirring assisted ultrasonic treatment followed by hot extrusion. With the increment of Mn element, the characteristics of mixed-grain structure became obvious and the DRX was inhibited. Meanwhile, the interfacial product gradually changed from MgZn2 to Mn2Ti. The tensile test demonstrated that the 2Ti/Mg-6Zn-1.5Mn composite exhibited an excellent strength-ductility synergy, achieving the highest yield stress (YS), ultimate tensile stress (UTS) of 239 MPa, 366 MPa, respectively, along with a notable elongation (El.) of 20.6%. The increased strength is mainly due to the grain refinement, the precipitation strengthening, the HDI strengthening and the strong interfacial bonding including the tightly Ti/Mn2Ti bonding and the Mn2Ti/Mg coherent orientation relationship. The ideal El. is the result of fine/coarse bimodal structure and the proper interfacial reaction, which can reduce the occurrence of cracks.","PeriodicalId":16214,"journal":{"name":"Journal of Magnesium and Alloys","volume":"60 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143878023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Design of 8HQ@ZIF-8/PDA smart nanocontainers via host-guest nanoconfinement and surface self-assembly for enhanced corrosion protection and self-healing of magnesium alloy epoxy composite coatings 通过主客体纳米约束和表面自组装设计8HQ@ZIF-8/PDA智能纳米容器，增强镁合金环氧复合涂层的防腐蚀和自修复能力

IF 17.6 1区材料科学

Journal of Magnesium and Alloys Pub Date : 2025-04-26 DOI: 10.1016/j.jma.2025.04.006

Xiaomeng Yu, Yuejun Ouyang, Jilan Long, Dan Xu, Guangming Liang, Zhiyuan Feng, Dongmei Pu, Qiwen Yong, Zhi-Hui Xie

{"title":"Design of 8HQ@ZIF-8/PDA smart nanocontainers via host-guest nanoconfinement and surface self-assembly for enhanced corrosion protection and self-healing of magnesium alloy epoxy composite coatings","authors":"Xiaomeng Yu, Yuejun Ouyang, Jilan Long, Dan Xu, Guangming Liang, Zhiyuan Feng, Dongmei Pu, Qiwen Yong, Zhi-Hui Xie","doi":"10.1016/j.jma.2025.04.006","DOIUrl":"https://doi.org/10.1016/j.jma.2025.04.006","url":null,"abstract":"Conventional nanoparticles incorporated into epoxy coatings suffer from poor compatibility and insufficient corrosion improvement, hindering their practical applications. A dual-strategy approach integrating in-situ host–guest nanoconfinement and surface self-assembly was devised to fabricate 8HQ@ZIF-8/PDA smart nanocontainers. The guest 8-hydroxyquinoline (8HQ) was encapsulated within the zeolitic imidazolate framework-8 (ZIF-8) host, leveraging nanoconfinement effects. A bioinspired polydopamine (PDA) layer was then self-assembled on the 8HQ@ZIF-8 surface through dopamine oxidative self-polymerization, resulting in a robust nanocontainer architecture. Density functional theory (DFT) calculations verify that the molecular interactions between the PDA and the ZIF-8 surface was the chemical adsorption. The resultant 8HQ@ZIF-8/PDA retained the rhombic dodecahedral morphology and crystallinity of ZIF-8, demonstrating controlled pH-responsive release behavior. When incorporated into an epoxy (EP) resin matrix on magnesium alloy, the 8HQ@ZIF-8/PDA/EP smart composite coatings exhibited outstanding interfacial compatibility and long-term stability, achieving a low-frequency impedance (|Z|₀.₀₁Hz) of 2.49 × 10⁷ Ω cm², a maximum phase angle of 82.8°, and a breakpoint frequency (fb) of 63.34 Hz after 50 days of immersion in a 3.5 wt% NaCl solution. These findings highlight the exceptional self-healing and corrosion-resistant properties of the 8HQ@ZIF-8/PDA/EP smart composite coatings, underscoring its potential for protecting magnesium alloys in aggressive environments.","PeriodicalId":16214,"journal":{"name":"Journal of Magnesium and Alloys","volume":"7 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143876464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Physical and chemical interfacial engineering of mg anodes for rechargeable magnesium batteries 可充电镁电池镁阳极的物理化学界面工程

IF 17.6 1区材料科学

Journal of Magnesium and Alloys Pub Date : 2025-04-26 DOI: 10.1016/j.jma.2025.03.025

Hyungjin Lee, Jangwook Pyun, Inkyoung Han, Haewon Kim, Seunghyeop Baek, Yeonu Lee, Jihun Roh, Doron Aurbach, Seung-Tae Hong, Munseok S. Chae

{"title":"Physical and chemical interfacial engineering of mg anodes for rechargeable magnesium batteries","authors":"Hyungjin Lee, Jangwook Pyun, Inkyoung Han, Haewon Kim, Seunghyeop Baek, Yeonu Lee, Jihun Roh, Doron Aurbach, Seung-Tae Hong, Munseok S. Chae","doi":"10.1016/j.jma.2025.03.025","DOIUrl":"https://doi.org/10.1016/j.jma.2025.03.025","url":null,"abstract":"Rechargeable magnesium batteries are promising alternatives to traditional lithium batteries because of the high abundance of Mg compounds in earth crust, their low toxicity, and possible favorable properties as electrodes’ material. However, Mg metal anodes face several challenges, notably the natively existence of an inactive oxide layer on their surfaces, which reduces their effectiveness. Additionally, interactions of Mg electrodes with electrolyte solutions’ components can lead to the formation of insulating surface layers, that can fully block them for ions transport. This review addresses these issues by focusing on surface treatments strategies to enhance electrochemical performance of Mg anodes. It highlights chemical and physical modification techniques to prevent oxidation and inactive-layers formation, as well as their practical implications for MIBs. We also examined the impact of Mg anodes’ surface engineering on their electrochemical reversibility and cycling efficiency. Finally, future research directions to improve the performance and commercial viability of magnesium anodes and advance development of high-capacity, safe, and cost-effective energy storage systems based on magnesium electrochemistry are discussed.","PeriodicalId":16214,"journal":{"name":"Journal of Magnesium and Alloys","volume":"17 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143876465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Achieving excellent strength-ductility synergy of wire-arc additive manufactured Mg-Gd-Y-Zr alloy via friction stir processing 通过搅拌摩擦加工制备的Mg-Gd-Y-Zr合金实现了优异的强延性协同作用

IF 17.6 1区材料科学

Journal of Magnesium and Alloys Pub Date : 2025-04-25 DOI: 10.1016/j.jma.2025.03.029

Wenzhe Yang, Kuitong Yang, Haiou Yang, Zihong Wang, Chenghui Hu, Xin Lin

{"title":"Achieving excellent strength-ductility synergy of wire-arc additive manufactured Mg-Gd-Y-Zr alloy via friction stir processing","authors":"Wenzhe Yang, Kuitong Yang, Haiou Yang, Zihong Wang, Chenghui Hu, Xin Lin","doi":"10.1016/j.jma.2025.03.029","DOIUrl":"https://doi.org/10.1016/j.jma.2025.03.029","url":null,"abstract":"Friction stir processing (FSP) was applied to wire-arc additively manufactured (WAAM) Mg-9.54Gd-1.82Y-0.44Zr (GW92K) alloy to address coarse microstructure and porosity defects inherent to layer-by-layer deposition. FSP induced complete dissolution of the coarse Mg5(Gd,Y) eutectic network (initial size: 3.3 ± 0.5 µm) and triggered dynamic recrystallization, achieving a 69.5% grain refinement from 16.4 µm (WAAMed) to 5.0 µm (FSPed). This microstructural transformation enhanced ultimate tensile strength (UTS) by 32% (217 ± 3 MPa → 286 ± 2 MPa), yield strength (YS) by 46% (124 ± 2 MPa → 182 ± 7 MPa), and elongation (EL) by 35% (9.7 ± 1.1% → 13.1 ± 1.4%). Quantitative analysis via Hall-Petch relationship confirmed that grain refinement contributed ∼50 MPa (79%) of the total YS increment, while nano-precipitation (β′′/β′ phases <20 nm) effects accounted for the remaining ∼13 MPa. The simultaneous strength-ductility enhancement originates from FSP-induced defect elimination (porosity reduction: 1.75% → 0.18%) and dual-phase grain boundary pinning by Zr particles and β-Mg5(Gd,Y) precipitates. These findings establish FSP as a viable post-treatment for overcoming WAAM limitations in high-performance Mg-RE alloy fabrication.","PeriodicalId":16214,"journal":{"name":"Journal of Magnesium and Alloys","volume":"71 1","pages":""},"PeriodicalIF":17.6,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143872854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0