Journal of Materials Science & Technology最新文献

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A novel fine-grained TiZrCu alloy tailored for marine environment with high microbial corrosion-resistance 为海洋环境量身定制的新型细粒度 TiZrCu 合金具有很强的抗微生物腐蚀能力
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2024-11-10 DOI: 10.1016/j.jmst.2024.10.018
Jiaqi Li, Xi Ouyang, Diaofeng Li, Hang Yu, Yaozong Mao, Qing Jia, Zhiqiang Zhang, Mingxing Zhang, Chunguang Bai, Fuhui Wang, Dake Xu
{"title":"A novel fine-grained TiZrCu alloy tailored for marine environment with high microbial corrosion-resistance","authors":"Jiaqi Li, Xi Ouyang, Diaofeng Li, Hang Yu, Yaozong Mao, Qing Jia, Zhiqiang Zhang, Mingxing Zhang, Chunguang Bai, Fuhui Wang, Dake Xu","doi":"10.1016/j.jmst.2024.10.018","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.10.018","url":null,"abstract":"Titanium alloys, usually known as non-corrodible material, are susceptible to microbiologically influenced corrosion (MIC) in marine environment. While titanium-zirconium (TiZr) alloys have been extensively studied in medical applications, the influence of microorganisms, especially marine microorganisms, on their corrosion behavior has not been explored. In this work, a TiZrCu alloy with a combination of excellent mechanical, anti-corrosion, and antibacterial properties was developed by optimizing the Cu content and grain refinement. Its MIC and antibacterial mechanisms against <em>Pseudomonas aeruginosa</em>, a representative marine microorganism, were systematically investigated. 5.5 wt% was determined as the optimal copper content. The fine-grained Ti-15Zr-5.5Cu (TZC-5.5FG) alloy maintained high MIC resistance, exhibiting a corrosion current of 5.7 ± 0.1 nA/cm<sup>2</sup> and an antibacterial rate of 91.8 % against <em>P. aeruginosa</em>. The mechanism of improved corrosion resistance was attributed to the denser passive film with high TiO<sub>2</sub> content and the lower surface potential difference Δ<em>E</em>. The release of Cu<sup>2+</sup> ions, Δ<em>E,</em> and the generation of ROS are three major factors that contribute to the antibacterial performance of TiZrCu alloys. Compared to other available marine metals, TZC-5.5FG alloy exhibited superior comprehensive performance, including excellent mechanical properties and anti-MIC capacity, which make it a promising material for load-bearing applications in marine environment.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrastrong and ductile superalloy joints bonded with a novel composite interlayer modified by high entropy alloy 用高熵合金改性的新型复合夹层粘接的超强韧性超级合金接头
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2024-11-10 DOI: 10.1016/j.jmst.2024.08.072
L. Yuan, F.Y. Jiang, D. Hao, Y.Z. Yang, T.H. Chou, J.X. Zhang, J. Gan, J.L. Li, J.T. Xiong, T. Yang
{"title":"Ultrastrong and ductile superalloy joints bonded with a novel composite interlayer modified by high entropy alloy","authors":"L. Yuan, F.Y. Jiang, D. Hao, Y.Z. Yang, T.H. Chou, J.X. Zhang, J. Gan, J.L. Li, J.T. Xiong, T. Yang","doi":"10.1016/j.jmst.2024.08.072","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.072","url":null,"abstract":"Diffusion bonding (DB) with interlayers is sought-after for manufacturing high-performance turbine disks of powder metallurgy (PM) superalloys with precise and intricate inner cavity structures. Developing novel interlayer materials is challenging but crucial for enhancing bonding quality and joint properties. We designed a multi-interlayer composite bonding (MICB) method, employing sandwich-structured interlayers of “BNi2/high entropy alloy (HEA)/BNi2”, to join a PM superalloy FGH98. The MICB joint exhibited an ultrahigh shear strength of ∼1132 MPa and exceptional ductility, indicating a typical ductile fracture pattern with numerous dimples. Owing to the introduction of liquid BNi2 interlayer, initial bonding interfaces were eliminated and replaced by newborn grain boundaries (GBs), preventing brittle interfacial fracture. Due to the diffusion of Al/Ti/Ta from the base metals (BMs), massive ordered γ' nanoparticles also precipitated in the joint. Moreover, the addition of HEA foil reduced the stacking fault energy (SFE) of the joint and facilitated the formation of deformation twins (DTs). Thus, during the deformation process, the γ' nanoparticles, and multiple substructures like stacking faults (SFs), Lomer-Cottrell (L-C) locks, DTs, and 9R phases enhanced the work-hardening capability and strengthened the joint. Simultaneously, the multiplication and interaction of DTs induced a softening mechanism of dynamic recrystallization (DRX) during the entire deformation process and dominated when the plastic instability occurred, resulting in numerous adiabatic shear bands (ASBs) consisting of γ/γ' nano-bands, which indicates a significant improvement of the joint ductility.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pioneering SubPc-Br/CdS S-scheme heterojunctions: Achieving superior photocatalytic oxidation through enhanced radical synergy and photocorrosion mitigation 开创性的 SubPc-Br/CdS S 型异质结:通过增强自由基协同作用和减缓光腐蚀实现卓越的光催化氧化作用
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2024-11-09 DOI: 10.1016/j.jmst.2024.10.017
Shengqian Liang, Min Ma, Zheng Zheng, Jiahang Song, Yijian Zhou, Enzhou Liu, Haixia Ma, Bing Wang, Bo Zhou, Yan Nie, Zhuo Li
{"title":"Pioneering SubPc-Br/CdS S-scheme heterojunctions: Achieving superior photocatalytic oxidation through enhanced radical synergy and photocorrosion mitigation","authors":"Shengqian Liang, Min Ma, Zheng Zheng, Jiahang Song, Yijian Zhou, Enzhou Liu, Haixia Ma, Bing Wang, Bo Zhou, Yan Nie, Zhuo Li","doi":"10.1016/j.jmst.2024.10.017","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.10.017","url":null,"abstract":"For the efficient harnessing of solar energy and mitigation of environmental pollution, the development and application of semiconductor photocatalysis technology is paramount. Herein, a novel SubPc-Br/CdS supramolecular array with an S-scheme heterojunction was synthesized through the intermolecular π-stacked self-assembly of subphthalocyanine (SubPc-Br) and nanometer cadmium sulfide (CdS). This self-assembly system features a highly structured architecture and excellent stability. Experiments and ground-state differential charge calculations demonstrate that SubPc-Br and CdS form a built-in electric field during the self-assembly process, a critical factor in promoting the dissociation of electrons and holes. Additionally, this study utilized time-dependent density functional theory (TDDFT) to simulate the dynamic adsorption behavior of excited oxygen molecules on the SubPc-Br/CdS interface for the first time. The analysis of molecular charge differential density under different excited states proved that the addition of SubPc-Br molecules not only improves the photocorrosion resistance of CdS in an O<sub>2</sub> adsorption environment but also enhances the production of advanced reactive oxygen species under the synergistic action of h<sup>+</sup> and ·O<sub>2</sub><sup>–</sup>. When subjected to visible light, the degradation efficiency of minocycline (MC) achieved 96.8% within 60 min and maintained 80.3% after 5 cycles. In summary, this study highlights the feasibility of creating advanced S-scheme heterojunction photocatalysts through the strategic incorporation of organic supramolecules with semiconductor catalysts.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A significant improvement in corrosion resistance and biocompatibility in ZrNbTiCrCu high-entropy films induced by the precipitation of Cu 铜沉淀诱导 ZrNbTiCrCu 高熵薄膜耐腐蚀性和生物相容性的显著改善
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2024-11-08 DOI: 10.1016/j.jmst.2024.10.016
Xiaofei Ma, Ping Ren, Shangzhou Zhang, Xiaochun He, Yang Li, Xuelei Yin, Huanyu Li, Shizeng Dang, Daliang Yu, Jianxun Qiu, Xin Zhou, Bing Zhou
{"title":"A significant improvement in corrosion resistance and biocompatibility in ZrNbTiCrCu high-entropy films induced by the precipitation of Cu","authors":"Xiaofei Ma, Ping Ren, Shangzhou Zhang, Xiaochun He, Yang Li, Xuelei Yin, Huanyu Li, Shizeng Dang, Daliang Yu, Jianxun Qiu, Xin Zhou, Bing Zhou","doi":"10.1016/j.jmst.2024.10.016","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.10.016","url":null,"abstract":"Utilizing nanotechnology and composites to create a protective film on titanium alloy is an effective means of achieving the desired high performance. Self-assembly of nanocomposite structures offers a promising route to forming high entropy alloy films (HEAFs), but controlled preparation remains challenging. This work used magnetron sputtering through adjusting preparation parameters to prepare ZrNbTiCrCu HEAFs, achieving a significant improvement in corrosion resistance and biocompatibility induced by the precipitation of Cu. According to the electrochemical corrosion test, without obvious corrosion pits on the surface of S2 after corrosion, a passivation film composed of bimetallic oxide CuCrO<sub>2</sub> formed on the film surface, indicating that ZrNbTiCrCu HEAFs have remarkable corrosion resistance performance. In the cytocompatibility experiment, the cell viability of HEAFs reached over 95 % due to the precipitation of Cu, suggesting their excellent biocompatibility. In addition, ZrNbTiCrCu HEAFs exhibit outstanding antibacterial ability, especially when the sputtering current is 0.6 A, and the in vitro antibacterial rate of the sample against Escherichia coli is close to 99 %.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Anisotropic stress corrosion cracking susceptibility of Mg-8Gd-3Y-0.5Zr alloy Mg-8Gd-3Y-0.5Zr 合金的各向异性应力腐蚀开裂敏感性
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2024-11-08 DOI: 10.1016/j.jmst.2024.11.001
Jia Zeng, Jiaqi Li, Jingya Wang, Kai Chen, Zhao Shen
{"title":"Anisotropic stress corrosion cracking susceptibility of Mg-8Gd-3Y-0.5Zr alloy","authors":"Jia Zeng, Jiaqi Li, Jingya Wang, Kai Chen, Zhao Shen","doi":"10.1016/j.jmst.2024.11.001","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.11.001","url":null,"abstract":"This study investigates the stress corrosion cracking (SCC) behavior of a Mg-8Gd-3Y-0.5Zr alloy in a 3.5 wt.% NaCl solution using slow strain rate tensile (SSRT) testing. The results reveal that SCC susceptibility increases as the strain rate decreases, with hydrogen embrittlement (HE) becoming more dominant at lower strain rates, leading to brittle fracture. Anodic dissolution (AD) plays a more significant role at higher strain rates, resulting in mixed fracture modes. Additionally, the mechanical properties and SCC resistance are strongly influenced by the sample orientation. TD-oriented samples show higher SCC susceptibility than RD-oriented ones due to the alignment of Gd- and Y-rich precipitates and grain boundaries, which act as initiation sites for SCC. These precipitates form micro-galvanic couples with the Mg matrix, accelerating localized corrosion and HE. The findings provide insights into the SCC mechanisms of VW83 alloy and highlight the importance of optimizing microstructure and processing conditions to improve its corrosion resistance.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A facile strategy for customizing multifunctional magnetic‑dielectric carbon microflower superstructures deposited with carbon nanotubes 定制碳纳米管沉积的多功能磁介质碳微花超结构的简便策略
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2024-11-08 DOI: 10.1016/j.jmst.2024.10.019
Chengjuan Wang, Yanxiang Wang, Haotian Jiang, Yanqiu Feng, Deli Yang, Chengguo Wang
{"title":"A facile strategy for customizing multifunctional magnetic‑dielectric carbon microflower superstructures deposited with carbon nanotubes","authors":"Chengjuan Wang, Yanxiang Wang, Haotian Jiang, Yanqiu Feng, Deli Yang, Chengguo Wang","doi":"10.1016/j.jmst.2024.10.019","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.10.019","url":null,"abstract":"The novel fabrication of multiple components and unique heterostructure can inject infinite vitality into the electromagnetic wave (EMW) attenuation field. Herein, through the self-assembly of polyimide complexes and catalytic chemical vapor deposition, porous carbon microflowers were synthesized accompanied by carbon nanotubes (CNTs). By regulating the metal ions, the composition and structure of the as-obtained hybrids are modified correspondingly, and thus the adjustable thermal management and EMW absorption capabilities are obtained. In detail, the rich pores and huge specific surface area endow the hierarchical structures with distinguished thermal insulation ability (<em>λ</em>&lt;0.07). The carbon framework and CNTs are beneficial for consuming EMWs via conductive loss and defect polarization loss while reducing the filling ratio and thickness. The doped heteroatoms and abundant heterointerfaces generate ample dipole polarization and interface polarization losses (supported by DFT calculation). The metal nanoparticles uniformly embedded in the carbon framework offer optimized impedance matching, proper defect polarization, and suitable magnetic loss. Accordingly, the synergy of magnetic-dielectric balance and flower-like superstructure enables FNCFN2 and NNCFN2 to accomplish remarkable microwave absorbing capacity with thin thickness (14 wt.%). Therefore, respectable specific reflection loss and specific effective absorption bandwidth are acquired (215.39 dB mm<sup>–1</sup> and 22.10 GHz mm<sup>–1</sup>, 257.23 dB mm<sup>–1</sup> and 22.12 GHz mm<sup>–1</sup> respectively), superior to those of certain renowned carbon-based absorbers. The simulation results of electric field intensity distributions, power loss density, and radar cross section reduction (maximum value of 36.02 dBm<sup>2</sup>) also verify the prominent radar stealth capability. Moreover, the customizable approach can be applied to other metals to obtain fulfilling behaviors. Henceforth, this work provides profound insights into the relationship between structure and performance, and proposes an efficient path for mass-producing multifunctional and high-performance EMW absorbers with excellent thermal properties.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High volumetric-energy-density flexible supercapacitors based on PEDOT:PSS incorporated with carbon quantum dots hybrid electrodes 基于 PEDOT:PSS 与碳量子点混合电极的高体积能量密度柔性超级电容器
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2024-11-08 DOI: 10.1016/j.jmst.2024.08.073
Dinh Cung Tien Nguyen, Seonghan Kim, Bo-Seok Kim, Sejung Kim, Soo-Hyoung Lee
{"title":"High volumetric-energy-density flexible supercapacitors based on PEDOT:PSS incorporated with carbon quantum dots hybrid electrodes","authors":"Dinh Cung Tien Nguyen, Seonghan Kim, Bo-Seok Kim, Sejung Kim, Soo-Hyoung Lee","doi":"10.1016/j.jmst.2024.08.073","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.073","url":null,"abstract":"Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) is a highly successful conductive polymer utilized as an electrode material in energy storage units for portable and wearable electronic devices. Nevertheless, employing PEDOT:PSS in supercapacitors (SC) in its pristine state presents challenges due to its suboptimal electrochemical performance and operational instability. To surmount these limitations, PEDOT:PSS has been integrated with carbon-based materials to form flexible electrodes, which exhibit physical and chemical stability during SC operation. We developed a streamlined fabrication process for high-performance SC electrodes composed of PEDOT:PSS and carbon quantum dots (CQDs). The CQDs were synthesized under microwave irradiation, yielding green- and red-light emissions. Through optimizing the ratios of CQDs to PEDOT:PSS, the SC electrodes were prepared using a spray-coating technique, marking a significant improvement in device performance with a high volumetric capacitance (104.10 F cm<sup>−3</sup>), impressive energy density (19.68 Wh cm<sup>−3</sup>), and excellent cyclic stability, retaining ∼85% of its original volumetric capacitance after 15,000 repeated GCD cycles. Moreover, the SCs, when utilized as a flexible substrate, demonstrated the ability to maintain up to ∼85% of their electrochemical performance even after 3,000 bending cycles (at a bending angle of 60°). These attributes render this hybrid composite an ideal candidate for a lightweight smart energy storage component in portable and wearable electronic technologies.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the interaction between corrosion products and oxygen reduction on the corrosion of Mg–4Nd–0.4Zr alloy under thin electrolyte layers 揭示腐蚀产物和氧还原对薄电解质层下 Mg-4Nd-0.4Zr 合金腐蚀的相互作用
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2024-11-02 DOI: 10.1016/j.jmst.2024.10.010
Ningning Dan, Yao Yang, Tao Ying, Xiaoqin Zeng
{"title":"Unveiling the interaction between corrosion products and oxygen reduction on the corrosion of Mg–4Nd–0.4Zr alloy under thin electrolyte layers","authors":"Ningning Dan, Yao Yang, Tao Ying, Xiaoqin Zeng","doi":"10.1016/j.jmst.2024.10.010","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.10.010","url":null,"abstract":"Although hydrogen evolution reaction (HER) is considered to be the main cathodic reaction of Mg corrosion, oxygen reduction reaction (ORR) has been recently confirmed to be a secondary cathodic reaction. The factors affecting ORR of magnesium (Mg) alloys are still unclear, especially in cases under thin electrolyte layers (TEL). In this work, the influence of the corrosion product films on the cathodic reactions of Mg alloys under TEL and in a bulk solution was investigated. ORR does not influence the hydrogen evolution rates in the corrosion of Mg alloys. Therefore, with the existence of oxygen, corrosion rates of Mg alloys measured by hydrogen evolution tests are not accurate under TEL. And weight loss test is a more accurate method to evaluate Mg corrosion rates under TEL. ORR was confirmed to participate in the corrosion of Mg–4Nd–0.4Zr, Mg–4Nd and Mg–0.4Zr alloys under TEL. In 100-μm TEL, the highest contribution of ORR in cathodic reactions for the corrosion of Mg–4Nd–0.4Zr, Mg–4Nd and Mg–0.4Zr alloys are 28.6%, 39.1%, and 35.8%, respectively. The more protective film on Mg–4Nd–0.4Zr alloy provides a stronger inhibition effect against the diffusion of oxygen, leading to decreased ORR contribution in cathodic reactions. In addition, it is suggested that the preparation of Mg alloys with protective corrosion product films can inhibit the corrosion induced by ORR in the atmosphere. This work emphasizes the effects of corrosion product films on ORR in <span><span>Mg corrosion</span><svg aria-label=\"Opens in new window\" focusable=\"false\" height=\"20\" viewbox=\"0 0 8 8\"><path d=\"M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z\"></path></svg></span>, especially under TEL.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142566103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phase separation in hexagonal α phase during lamellar formation of TiAl alloys and its effect on subsequent phase transformations 钛铝合金薄片形成过程中六方α相的相分离及其对后续相变的影响
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2024-11-01 DOI: 10.1016/j.jmst.2024.10.013
Yonghao Yu, Hongchao Kou, Tingting Zhao, Zilong Zhang, Yarong Wang, Xiaoxuan Xu, Peixuan Li, Mingxiang Zhu, Zhihong Wu, William Yi Wang, Jinshan Li
{"title":"Phase separation in hexagonal α phase during lamellar formation of TiAl alloys and its effect on subsequent phase transformations","authors":"Yonghao Yu, Hongchao Kou, Tingting Zhao, Zilong Zhang, Yarong Wang, Xiaoxuan Xu, Peixuan Li, Mingxiang Zhu, Zhihong Wu, William Yi Wang, Jinshan Li","doi":"10.1016/j.jmst.2024.10.013","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.10.013","url":null,"abstract":"TiAl alloys with the (α<sub>2</sub> + γ) lamellar structure are highly valued for their excellent high-temperature strength and creep resistance. Understanding the formation mechanism of the lamellar structure is crucial for tuning the microstructure and properties. This work investigates the formation of lamellar structure in Ti-48Al-7Nb-2.5V-1Cr alloy, revealing the presence of hcp-based long-period superstructure (hcp-LPS) as a metastable phase during lamellar formation. The identification of hcp-LPS demonstrates that the necessary solute enrichment for the formation of γ lamellae occurs on the hexagonal α matrix, implying that phase separation of α → Al-rich α lamellae + Al-depleted α lamellae is the first step of lamellar formation. Once phase separation is completed, all subsequent phase transitions occur within the Al-rich α lamellae. Additionally, the formation of twin lamellae is further discussed. The formation of the twin lamellae occurs sequentially. Pre-existing lamella promotes the formation of later lamella by inducing solute enrichment in its surrounding region, and then the successive slip of Shockley partial dislocations with opposite Burgers vectors ensures special stacking of later lamellae. These findings not only contribute to the fundamental understanding of spinodal mechanisms in hexagonal crystals, but also provide novel insights into the formation of twin lamellae.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142563075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Deciphering the multi-electron redox chemistry of metal-sulfide electrode toward advanced aqueous Cu ion storage 解密金属硫化物电极的多电子氧化还原化学,实现先进的水性铜离子存储
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2024-11-01 DOI: 10.1016/j.jmst.2024.08.071
Zhenxin Zhao, Zonglin Yi, Rong Niu, Jiajun Chen, Rajesh Pathak, Yongzhen Wang, Jeffrey W Elam, Xiaomin Wang
{"title":"Deciphering the multi-electron redox chemistry of metal-sulfide electrode toward advanced aqueous Cu ion storage","authors":"Zhenxin Zhao, Zonglin Yi, Rong Niu, Jiajun Chen, Rajesh Pathak, Yongzhen Wang, Jeffrey W Elam, Xiaomin Wang","doi":"10.1016/j.jmst.2024.08.071","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.071","url":null,"abstract":"While neutral aqueous metal batteries, featuring cost-effectiveness and non-flammability, hold significant potential for large-scale energy storage, their practical application is hampered by the limited specific capacity of cathode materials (less than 500 mAh g<sup>−1</sup>). Herein, capacity-oriented CoS<sub>2</sub> and rate-optimized Co<sub>9</sub>S<sub>8</sub> cathodes are developed based on the aqueous copper ion system. The charge-storage mechanism is systematically investigated through a series of ex-situ tests and density functional theory calculations, focusing on the reversible transitions of Co<sub>9</sub>S<sub>8</sub>→Cu<sub>7</sub>S<sub>4</sub>→Cu<sub>9</sub>S<sub>5</sub>/Cu<sub>1.8</sub>S and CoS<sub>2</sub>→Cu<sub>7</sub>S<sub>4</sub>→Cu<sub>2</sub>S, which are associated with the redox reactions of Cu<sup>2+</sup>/Cu<sup>+</sup>‖Co<sup>2+</sup>/Co and Cu<sup>2+</sup>/Cu<sup>+</sup>‖S<sub>2</sub><sup>2−</sup>/S<sup>2−</sup>, respectively. The electrochemical results show that CoS<sub>2</sub> can exhibit a superior capacity of 619 mAh g<sup>−1</sup> at 1 A g<sup>−1</sup> after 400 cycles, while Co<sub>9</sub>S<sub>8</sub> maintains an outstanding rate performance of 497 mAh g<sup>−1</sup> at 10 A g<sup>−1</sup> (the retention rate is 95% compared to 521 mAh g<sup>−1</sup> at 1 A g<sup>−1</sup>). As a proof of concept, an advanced CoS<sub>2</sub>//Zn hybrid aqueous battery demonstrates a working voltage of 1.20 V and a specific energy of 663 Wh kg<sub>cathode</sub><sup>−1</sup>. This work provides an alternative direction for developing sulfide cathodes in energetic aqueous metal batteries.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142562227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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