Journal of Materials Science & Technology最新文献

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CoFe alloy realizing enhanced Fe-bridged electron superhighways in Mott-Schottky heterojunctions for efficient water and urea electrolysis CoFe合金在Mott-Schottky异质结中实现了增强的铁桥电子高速公路,用于高效的水和尿素电解
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-10-17 DOI: 10.1016/j.jmst.2025.10.012
Xu Yu, Xinyu Wang, Pinyi He, Guohui Yang, Fu Qin, Yongkang Yao, Lili Ren
{"title":"CoFe alloy realizing enhanced Fe-bridged electron superhighways in Mott-Schottky heterojunctions for efficient water and urea electrolysis","authors":"Xu Yu, Xinyu Wang, Pinyi He, Guohui Yang, Fu Qin, Yongkang Yao, Lili Ren","doi":"10.1016/j.jmst.2025.10.012","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.10.012","url":null,"abstract":"As a typical Mott-Schottky, the conventional single-metal/semiconductor junctions suffer from limited electronic modulation capability and reaction adaptability. This work developed a controllable synthesis strategy based on the Mott-Schottky theory and Prussian blue analog precursors, successfully constructing a CoFe/Co<sub>2</sub>P heterostructure by integrating bimetallic nanoalloys with phosphide semiconductors. Experimental characterization and theoretical calculations confirmed the continuous electron enrichment at the Co site. The low electronegativity of Fe, as the electron donor, expanded the interfacial work function difference (ΔΦ), and synergistically optimized the <em>d</em>-band electronic structure and intermediate adsorption by accelerating charge transfer kinetics. Consequently, the CoFe/Co<sub>2</sub>P heterostructure exhibits superior multi-reaction activity compared to pure Co<sub>2</sub>P and Co/Co<sub>2</sub>P in the urea oxidation reaction, oxygen evolution reaction (OER), and hydrogen evolution reaction in alkaline media. In situ characterization further demonstrated that the urea molecule was directly oxidized at the CoFe/Co<sub>2</sub>P interface site, avoiding the formation of the rate-limiting step CoOOH in the OER, which has rarely been mentioned in previous studies, thereby achieving faster kinetics at a significantly reduced potential. Accordingly, the assembled two-electrode urea oxidation-assisted hydrogen production electrolytic cell only requires 1.314 V to drive a current density of 10 mA cm<sup>−2</sup>, which is lower than the overall water splitting (1.691 V). This research provides a new interface control strategy for the rational design of efficient hydrogen production catalysts.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"58 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145306157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Laser-selective curing for enhancement of interlayer bonding of 3D-printing polydimethylsiloxane-based structures 激光选择性固化增强3d打印聚二甲基硅氧烷基结构的层间键合
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-10-17 DOI: 10.1016/j.jmst.2025.09.064
Qianshuai Cheng, Fei Wang, Wenzhuo Wang, Wenzhao Yang, Zhimin Ren, Wenying Xi, Changping Feng, Fan Zhang, Xin Lin
{"title":"Laser-selective curing for enhancement of interlayer bonding of 3D-printing polydimethylsiloxane-based structures","authors":"Qianshuai Cheng, Fei Wang, Wenzhuo Wang, Wenzhao Yang, Zhimin Ren, Wenying Xi, Changping Feng, Fan Zhang, Xin Lin","doi":"10.1016/j.jmst.2025.09.064","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.09.064","url":null,"abstract":"Polydimethylsiloxane (PDMS), renowned for its exceptional stretchability and biocompatibility, has been extensively employed as a flexible substrate for wearable and stretchable electronics. However, the functional failure of 3D-printed PDMS structures caused by insufficient interlayer bonding strength significantly limits their applications. To address this challenge, this study innovatively proposes a manufacturing method for selective PDMS curing based on photothermal conversion, in which polyimide (PI) film is introduced as an intermediate thermally conductive medium to enable selective laser heating and localized curing of highly transparent PDMS. This strategy not only provides structural support for functional layers via laser-selective curing of PDMS but also retains substantial uncured regions to enable covalent crosslinking between adjacent PDMS layers, thereby effectively improving the interlayer bonding strength. Moreover, the laser-cured zones are encapsulated within these uncured portions, further achieving the enhancement of interlayer bonding strength of PDMS-based 3D-printed devices. The results demonstrate that compared with conventional fully curing layer-by-layer printing approaches, the samples prepared by this strategy exhibited cohesive failure during the T-peel test, while pull-off testing demonstrated a minimum 2.36-fold enhancement in interfacial bonding strength, and optical microscopy observations at 20× magnification revealed no delamination at the interfaces. Leveraging this method, a flexible strain sensor with stable performance over 1,000 cycles and a microfluidic chip capable of withstanding a flow rate of 1000 μL/min without leakage were successfully fabricated.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"26 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-cycle fatigue behaviors of twinning-induced plasticity steels fabricated by laser powder bed fusion 激光粉末床熔合制备孪晶塑性钢的高周疲劳行为
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-10-17 DOI: 10.1016/j.jmst.2025.09.061
Yongtao Hu, Fulin Liu, Yao Chen, Lang Li, Hong Zhang, Chao He, Delong He, Yongjie Liu, Chong Wang, Jinbo Bai, Qingyuan Wang
{"title":"High-cycle fatigue behaviors of twinning-induced plasticity steels fabricated by laser powder bed fusion","authors":"Yongtao Hu, Fulin Liu, Yao Chen, Lang Li, Hong Zhang, Chao He, Delong He, Yongjie Liu, Chong Wang, Jinbo Bai, Qingyuan Wang","doi":"10.1016/j.jmst.2025.09.061","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.09.061","url":null,"abstract":"Twinning-induced plasticity (TWIP) steels fabricated by laser powder bed fusion (LPBF) were subjected to heat treatments at 400°C for 1 h and 800°C for 30 min, followed by high-cycle fatigue (HCF) testing. The results reveal that, despite the high static strength achieved in LPBF TWIP steels, their fatigue strength remains relatively low. The heat treatments improved fatigue resistance by relieving residual stresses and/or disrupting cellular structures, particularly under low stress amplitudes. A predictive H-parameter model was proposed by integrating defect size, location, circularity, along with a weighting factor (<em>h</em>), to evaluate fatigue life under various conditions. In the as-built condition, decreasing stress amplitude caused a transition in crack initiation modes from surface lack-of-fusion (LOF) defects to internal {111} slip planes governed by microstructural features. The latter involves the activation of multiple slip systems with maximum Schmid factors exceeding 0.4 along the crack path, driven by the inhibition of dislocation motion by cellular structures. This promotes strong interactions among nano-twins and stacking faults (SFs) within multiple active slip systems, leading to localized stress concentrations at these intersections and twin boundaries. In addition, both low-angle grain boundaries (LAGBs) and cellular structures may hinder intragranular crack propagation and contribute to crack deflection.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"4 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145306158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the role of DRXed grain orientation configuration in the deformation behavior of Mg alloys with bimodal grain structures 揭示了DRXed晶粒取向构型在具有双峰晶粒组织的镁合金变形行为中的作用
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-10-17 DOI: 10.1016/j.jmst.2025.09.062
Zelin Wu, Taiki Nakata, Enyu Guo, Chao Xu, Huafeng Liu, Xu Zhang, Xuelin Zhang, Shuanglong Cong, Wenhao Chen, Xiaojun Wang, Shigeharu Kamado, Lin Geng
{"title":"Unveiling the role of DRXed grain orientation configuration in the deformation behavior of Mg alloys with bimodal grain structures","authors":"Zelin Wu, Taiki Nakata, Enyu Guo, Chao Xu, Huafeng Liu, Xu Zhang, Xuelin Zhang, Shuanglong Cong, Wenhao Chen, Xiaojun Wang, Shigeharu Kamado, Lin Geng","doi":"10.1016/j.jmst.2025.09.062","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.09.062","url":null,"abstract":"Bimodal magnesium (Mg) alloys exhibit a favorable strength-ductility synergy through the interaction between dynamically recrystallized (DRXed) and unDRXed regions. However, the influence of orientation configurations within DRXed regions on the deformation behavior remains insufficiently understood. In this study, four bimodal AZ31 samples with comparable DRXed grain sizes and fractions but distinct grain orientation configurations were fabricated via hot extrusion. The global and local orientation configurations of soft-oriented DRXed grains (basal Schmid factor ˃ 0.3) were quantitatively assessed. A soft-surrounding-soft configuration facilitated early basal slip and enhanced ductility but led to pronounced plastic incompatibility and low yield strength (YS). A hard-surrounding-soft configuration increased but limited ductility due to poor slip transfer. In contrast, the B1 sample exhibited a (soft+hard)-surrounding-soft configuration that moderated stress gradients and enhanced crack resistance, achieving the best strength-ductility combination. These findings highlight the critical role of multiscale orientation configurations within DRXed regions in controlling deformation mechanisms and provide guidance for designing high-performance bimodal Mg alloys.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"52 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145314750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Activating synergistic strengthening-toughening mechanisms by tailoring complex lamellar microstructure in a 2 GPa low-carbon alloy TRIP steel 通过调整2gpa低碳合金TRIP钢的复杂层状组织,激活增强韧化机制
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-10-17 DOI: 10.1016/j.jmst.2025.09.060
Hao Du, Yuantao Xu, Xunwei Zuo, Genqi Tian, Bo Wang, Xin You, Kaihao Guo, Xuejun Jin
{"title":"Activating synergistic strengthening-toughening mechanisms by tailoring complex lamellar microstructure in a 2 GPa low-carbon alloy TRIP steel","authors":"Hao Du, Yuantao Xu, Xunwei Zuo, Genqi Tian, Bo Wang, Xin You, Kaihao Guo, Xuejun Jin","doi":"10.1016/j.jmst.2025.09.060","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.09.060","url":null,"abstract":"Breaking through the strength-toughness (ductility) tradeoff of ultrastrong steels has been an enduring pursuit in the scientific community. In the present work, superior synergistic combinations of ultrahigh strength (ultimate tensile strength, ∼2026 Mpa), desirable ductility (total elongation, ∼13%), and exceptional fracture toughness (<em>K</em><sub>JIC</sub>, ∼119 Mpa m<sup>−1/2</sup>) were achieved in a low-carbon alloy transformed-induced plasticity (TRIP) steel by microstructural architecture, specifically, by utilizing multi-delamination crack toughening evolved from microvoids induced toughening and deformation-induced martensitic transformation (DIMT) toughening strategy. Firstly, nanoscale lamellar ferrite (<em>α</em>) and metastable austenite (<em>γ</em>) strengthened by high-density Cu-rich precipitations were obtained by warm rolling (WR). Fabricated numerous lamellar interfaces and surrounding ductile <em>α</em> and <em>γ</em> phases in the WR620 steel trigger a microvoids-induced toughening mechanism that is characterized by high-density non-aggregated microvoids (∼2.5 × 10<sup>4</sup> mm<sup>−2</sup>), resulting in superior crack-initiation and crack-growth toughness. Secondly, maintaining these microstructure characteristics, further strengthening of constituent phases was achieved by cold rolling deformation at cryogenic temperature, which implants preferentially high-density dislocations in <em>γ</em> and ensures ultrahigh mechanical stability regarding DIMT in WR620-N2CR steel. Combined with ultrastrong <em>α</em>/<em>α</em>’, optimized TRIP-assisted lamellar microstructure conquers the dilemma of strength-ductility tradeoff at ultrahigh yield strengths, meanwhile, without significantly deteriorating fracture toughness. These fabricated lamellar interfaces serve as preferential sites for the initiation of delamination microcracks, resulting in excellent crack-initiation fracture toughness. Nanoscale lamellar constituent phases with ultrahigh strength and deformed <em>γ</em> with ultrahigh critical martensitic transformation stress further retard catastrophic propagation and coalescence of delamination microcracks, which demonstrates a multi-delamination crack toughening mechanism from the perspective of observed fractographic features and derived micro-mechanically ductile fracture model. Additionally, the <em>in</em>-<em>situ</em> DIMT toughening enhances fracture toughness by simultaneously absorbing energy, which determined contribution accounts for 28.0% and 21.3% of the total fracture toughness in WR620 and WR620-N2CR steels, respectively. To summarize, our findings provide a microstructural architecture strategy and reveal synergistic strengthening-toughening mechanisms to design steel with ultrahigh strength-ductility and superior damage-resistance synergy.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"75 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145306159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Janus-structured ion-bridged MXene@PDA@PNF flexible composite films for synergistic infrared stealth, Joule thermal management, and EMI shielding janus结构离子桥接MXene@PDA@PNF柔性复合薄膜,用于协同红外隐身,焦耳热管理和EMI屏蔽
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-10-16 DOI: 10.1016/j.jmst.2025.10.007
Nan Pang, Xiao Cheng, Xiaoqing Yin, Yanyan Wang, Wang Liu, Meijie Yu, Chengguo Wang, Chuanjian Zhou
{"title":"Janus-structured ion-bridged MXene@PDA@PNF flexible composite films for synergistic infrared stealth, Joule thermal management, and EMI shielding","authors":"Nan Pang, Xiao Cheng, Xiaoqing Yin, Yanyan Wang, Wang Liu, Meijie Yu, Chengguo Wang, Chuanjian Zhou","doi":"10.1016/j.jmst.2025.10.007","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.10.007","url":null,"abstract":"With the rapid advancement of wearable electronics and the growing demand for integrated infrared stealth, electromagnetic protection, and intelligent thermal management in modern civilian and military applications, lightweight, ultrathin, flexible, and high-performance multifunctional composite materials have become a research focus. This study employs a Janus heterogeneous interface strategy to construct a spatially functional Ca<sup>2+</sup>-MXene@PDA@PNF composite film (CMDP) through the synergistic effects of biomimetic polydopamine-mediated non-covalent modification of the PNF substrate and Ca<sup>2+</sup> bridging densification of MXene. With just 11 wt.% MXene and a thickness of 26 μm, the film achieves low infrared emissivity (<em>ε</em> = 0.128, 8–14 μm), high in-plane thermal conductivity (14.406 W m<sup>−1</sup> K<sup>−1</sup>), and reduces the infrared radiation temperature of a 300°C target by 205.2°C. It exhibits rapid thermal response (<em>t</em> &lt; 10 s) and wide temperature control (27.6–352.6°C) under 0.5–5 V, enabling self-adaptive dynamic infrared stealth. The film also provides excellent electromagnetic shielding (14512 dB cm<sup>2</sup> g<sup>−1</sup>, X-band) and outstanding mechanical properties, including tensile strength (184.2 MPa), elongation at break (28.7%), and thermal stability (<em>T</em><sub>d,5%</sub> = 558.1°C). These features position CMDP as a promising material for wearable infrared stealth, electromagnetic shielding, and thermal management applications.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"31 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145306162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multifunctional Janus composite films with spontaneous gravity-induced asymmetric gradient for absorption-dominated electromagnetic interference shielding and high-efficiency thermal management 具有自发重力诱导不对称梯度的多功能Janus复合膜,用于吸收主导的电磁干扰屏蔽和高效热管理
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-10-16 DOI: 10.1016/j.jmst.2025.10.009
Mengxin Liu, Haoran Zhang, Xinmeng Huang, Ziyi Zhang, Shulin Huang, Qihui Wen, Jintang Zhou, Lei Pan
{"title":"Multifunctional Janus composite films with spontaneous gravity-induced asymmetric gradient for absorption-dominated electromagnetic interference shielding and high-efficiency thermal management","authors":"Mengxin Liu, Haoran Zhang, Xinmeng Huang, Ziyi Zhang, Shulin Huang, Qihui Wen, Jintang Zhou, Lei Pan","doi":"10.1016/j.jmst.2025.10.009","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.10.009","url":null,"abstract":"With the rapid advancement of high-power electronics, developing advanced multifunctional electromagnetic interference (EMI) shielding materials that simultaneously realize high shielding effectiveness (SE), low reflection, and mechanical adaptability remains a critical challenge. This work presents a gravity-driven assembly strategy to construct asymmetric gradient structures by spatially distributing low-density MXene nanosheets@hollow Fe<sub>3</sub>O<sub>4</sub> nanospheres (MXene@HFO) and high-density silver-coated tetraneedle ZnO whiskers (T-ZnO@Ag) within a waterborne polyurethane (WPU) matrix. The self-organized Janus architecture optimizes impedance matching and enables a multiple “absorption-reflection-reabsorption” loss mechanism. The resulting composite film achieves absorption-dominated EMI shielding with an SE of 72.4 dB and an absorption coefficient (<em>A</em>) of 0.54. Notably, it also exhibits exceptional mechanical properties, including over 400% reversible stretchability, robust durability for 1000 cycles, and strain-responsive shielding tunability, addressing key limitations in practical applications. Moreover, the interconnected conductive network delivers rapid Joule heating (174°C in 30 s at 2.5 V) and high thermal conductivity (9.53 W m<sup>−1</sup> K<sup>−1</sup>), enabling efficient thermal management. The proposed multifunctional film holds great promise for next-generation electronics requiring simultaneous EMI protection and thermal management, while the one-step fabrication methodology offers scalability advantages suitable for industrial production.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"101 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145306161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Overcoming the trade-off among strength, ductility, and electrical conductivity in an ultra-high strength Cu-3Ti-0.2Fe alloy through regulating precipitates and nanostructures 通过调节析出相和纳米结构,克服了超高强度Cu-3Ti-0.2Fe合金强度、延展性和导电性之间的平衡
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-10-16 DOI: 10.1016/j.jmst.2025.10.010
Yunqing Zhu, Lijun Peng, Mingxing Guo, Guojie Huang, Kuaishe Wang, Junsheng Wu, Dongmei Liu, Haofeng Xie
{"title":"Overcoming the trade-off among strength, ductility, and electrical conductivity in an ultra-high strength Cu-3Ti-0.2Fe alloy through regulating precipitates and nanostructures","authors":"Yunqing Zhu, Lijun Peng, Mingxing Guo, Guojie Huang, Kuaishe Wang, Junsheng Wu, Dongmei Liu, Haofeng Xie","doi":"10.1016/j.jmst.2025.10.010","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.10.010","url":null,"abstract":"Ultrahigh-strength Cu-Ti alloys are considered ideal materials for next-generation elastic electronic components, but face a critical bottleneck among the strength, electrical conductivity, and plasticity. Here in this study, the synergistic effect of Ti and Fe elements optimized precipitation behavior and nanostructure design, thereby overcoming the inherent strength-plasticity and strength-conductivity trade-offs in Cu-Ti alloys. Trace Fe additions promote dispersed nucleation of nanoscale β'-Cu<sub>4</sub>Ti precipitates, leading to a significantly higher density and finer size of the strengthening phase. Atom probe tomography analyses reveal that the Fe initially co-precipitates with the β'-Cu<sub>4</sub>Ti phase, subsequently segregating from the core toward the growth tips. The enrichment of Fe atoms significantly raises the diffusion energy barrier for Ti within the β'-Cu<sub>4</sub>Ti phase, thereby facilitating sufficient precipitation of residual Ti solutes. The precipitation of nanoscale spherical Fe<sub>2</sub>Ti phases is attributed to their favorable heterogeneous nucleation at the interfaces of β'-Cu<sub>4</sub>Ti precipitates. The formation of primary Ti<sub>2</sub>FeCu and TiFe phases refines the grain size of Cu-3Ti-0.2Fe alloy from 127 to 7 μm, and further reaches 310 nm after processing. After thermomechanical treatment, we report a 1228 MPa strength Cu-Ti-Fe alloy with improved conductivity and elongation to 16.8 %IACS and 5.5%. The uniform nanocrystalline and the enhanced precipitation behavior of β'-Cu<sub>4</sub>Ti phases contribute significantly to the comprehensive properties. This study leads us to reevaluate the synergistic effects between these two conductivity-detrimental elements and delivers a novel processing strategy for the development of conductivity and plasticity in ultra-high-strength Cu-Ti alloys.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"1 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145306160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Truss-inspired ultra-high strength, fire-safe, and thermal insulating double-crosslinked wood aerogels 桁架启发超高强度,防火,隔热双交联木气凝胶
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-10-15 DOI: 10.1016/j.jmst.2025.09.044
Yue Xu, Shuhui Liang, Wanying Wang, Chentao Yan, Lubin Liu, Dawei Jiang, Min Hong, Miaojun Xu, Bin Li, Siqi Huo
{"title":"Truss-inspired ultra-high strength, fire-safe, and thermal insulating double-crosslinked wood aerogels","authors":"Yue Xu, Shuhui Liang, Wanying Wang, Chentao Yan, Lubin Liu, Dawei Jiang, Min Hong, Miaojun Xu, Bin Li, Siqi Huo","doi":"10.1016/j.jmst.2025.09.044","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.09.044","url":null,"abstract":"Bio-based wood aerogel is one of the most promising materials to replace traditional petrochemical-based insulation materials. However, the flammability and poor mechanical strength of bio-based wood aerogels limit their applications in emerging fields. Inspired by a truss-supporting system, this study prepared a multifunctional bio-based cross-linked wood aerogel (TSP@Ca) by a dual hydrogen-ionic bonding strategy involving an oxidized wood cellulose framework, sodium alginate, phytic acid (PA), and Ca<sup>2+</sup>. Finite element simulation and mechanical analysis indicated that the multi-point support structure, resembling a truss framework, formed in the oxidized wood template significantly improved the strength of TSP@Ca aerogel (9.99 MPa), with a 154.84% enhancement relative to that of oxidized delignified wood (TODW). The limiting oxygen index of TSP@Ca3 aerogel was as high as 43.3%, and it can extinguish immediately when the fire was removed. The introduction of PA and Ca<sup>2+</sup> promoted the dehydration, cross-linking, and charring of TSP@Ca aerogel, while the produced phosphorus-containing free radicals played an inhibitory role in the gas phase. Therefore, the peak of heat release rate of TSP@Ca aerogel was 80.66% lower than that of TODW, showing excellent fire safety. Benefiting from the complex heat conduction path and enhanced interface resistance, the thermal conductivity of TSP@Ca was 46.4% lower than that of TODW. The resulting aerogel combines ultra-high mechanical strength, excellent fire resistance, and thermal insulation, aligning with “green” development goals and offering broad application potential in construction, rail transport, and new energy sectors.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"71 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145295455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance FeSiAl SMCs for MHz applications enabled by insulating coatings of bioinspired NiZn ferrite nanoparticles 用于兆赫应用的高性能fesal SMCs由仿生NiZn铁氧体纳米颗粒的绝缘涂层实现
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-10-15 DOI: 10.1016/j.jmst.2025.08.072
Jiacheng Yu, Zhaocheng Li, Wenmiao Zhang, Tongwei Zhang, Renchao Che, Yuele Zhang, Fengjiao Fang, Changqian Cao, Yongxin Pan
{"title":"High-performance FeSiAl SMCs for MHz applications enabled by insulating coatings of bioinspired NiZn ferrite nanoparticles","authors":"Jiacheng Yu, Zhaocheng Li, Wenmiao Zhang, Tongwei Zhang, Renchao Che, Yuele Zhang, Fengjiao Fang, Changqian Cao, Yongxin Pan","doi":"10.1016/j.jmst.2025.08.072","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.08.072","url":null,"abstract":"The exponential growth of artificial intelligence (AI) computational power has imposed more stringent demands on developing high-performance electronic components capable of operating efficiently at high frequencies. However, achieving high-frequency operation, enhanced power capacity, and miniaturization simultaneously in soft magnetic composites (SMCs) remains a formidable challenge. Traditional insulation coating approaches to improving the high-frequency performance of SMCs have been limited by difficulties in controlling coating thickness, susceptibility to decomposition during heat treatment, and magnetic dilution effects caused by non-magnetic insulating materials. This study addresses these limitations by introducing a novel biomineralization-inspired strategy to coat FeSiAl powders with NiZn ferrite nanoparticles. Inspired by the biomineralization in natural protein nanocages, we synthesized NiZn ferrite nanoparticles with uniform size distribution, exceptional monodispersity, and superparamagnetism through a confined mineralization strategy. The resulting NiZn ferrite/FeSiAl composites, prepared via mechanical mixing, exhibited an heterogenous insulation coating that significantly enhanced magnetic domain wall mobility and electrical resistivity compared to uncoated FeSiAl SMCs. Consequently, the FeSiAl/NiZn (FSA-NZ) SMCs demonstrated enhanced relative permeability, a high domain-wall resonance frequency, and remarkably low high-frequency power loss (944.8 mW/cm<sup>3</sup> at 1 MHz/50 mT). This study bridges the gap between bioinspired materials engineering and high-frequency soft magnetic materials and provides a viable solution to the long-standing challenges in developing high-performance SMCs for MHz applications.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"1 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145295456","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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