Minghe Du, Songyu Yang, Jianjun Zhang, Dmitrii A. Syrtsov, Jahan B. Ghasemi, Matvey V. Fedin, Liuyang Zhang
{"title":"Hyper-release regulation of localized surface plasmon resonance in tungsten oxide for efficient S-scheme heterojunction photocatalysts","authors":"Minghe Du, Songyu Yang, Jianjun Zhang, Dmitrii A. Syrtsov, Jahan B. Ghasemi, Matvey V. Fedin, Liuyang Zhang","doi":"10.1016/j.jmst.2025.05.016","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.05.016","url":null,"abstract":"In transition metal oxides, introducing high concentrations of charge carriers can induce localized surface plasmon resonance (LSPR), akin to noble metals, thus broadening the photocatalyst's response spectrum. However, a lack of comprehensive theoretical understanding of LSPR limits its full exploitation in photocatalytic systems. In this study, we propose a strategy to regulate the hyper-release of LSPR in S-scheme heterojunctions. By leveraging Mie-Gans theory and hot electron transfer kinetics, we achieve a finely tuned balance between the trapping and release of LSPR-induced hot electrons through defect concentration optimization. Using femtosecond transient absorption spectroscopy, we distinguish LSPR-related signals in the infrared region and quantify the hot electron transfer efficiency in the heterojunction, providing compelling evidence for the hyper-release mechanism. An S-scheme heterojunction between monoclinic W<sub>18</sub>O<sub>49</sub> and cubic CdS was constructed via an in-situ growth strategy without the use of noble metal co-catalysts, resulting in a composite that achieves an outstanding photocatalytic hydrogen evolution rate of 3125 μmol h<sup>−1</sup> g<sup>−1</sup>, outperforming conventional designs. This work not only offers fresh insights into the electron dynamics of the LSPR effect but also sets a benchmark for designing plasmonic-semiconductor hybrid systems, opening new horizons for sustainable energy conversion technologies.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"3 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144176870","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Bio-inspired muscle fascicle-like core–shell fiber bundle structure for enhanced toughness of Cf/Si3N4 composites","authors":"Chuanliang Chen, Yanjun Jiang, Yanxin Zhang, Juntong Miao, Baolong Guo, Pianpian Zhang, Dongdong Lv, Yanan Yang, Xinyu Wang, Long Xia","doi":"10.1016/j.jmst.2025.04.038","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.04.038","url":null,"abstract":"Modeling the microstructure of materials inspired by biomaterials opens up a proven route to making composites with higher toughness. Combined with the concept of bionics, this paper utilized a bio-inspired muscle fascicle-like fiber bundle structure to improve the toughness of C<sub>f</sub>/Si<sub>3</sub>N<sub>4</sub> composites. Li<sub>2</sub>O-Al<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub> (LAS) was chosen as the raw material to grow SiC nanowires (SiCnw) in situ on the surface of carbon fibers. Subsequently, in the sintering process, the fibers were encapsulated with the Li-O-Al system to form a continuous nanolayer structure. Notably, the carbon fibers wrapped by the nanolayers formed a muscle fascicle-like fiber bundle structure. Compared with single fibers, the muscle fascicle-like structure has stronger toughness. When subjected to external forces, the strong toughness makes it less likely to break during the fracture process, resulting in a more pronounced pull-out. Muscle fascicle-like structures utilize this pull-out mechanism to absorb a large amount of fracture energy, resulting in a 24.5% increase in fracture toughness and a 98.4% improvement in work of fracture. This suggests that connecting the fibers into a fiber bundle structure through the intermediate phase can effectively exert the energy absorption mechanism, which provides a new idea to improve the mechanical properties of fiber-toughened composites.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"48 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144176872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Microstructure evolution and oxidation behavior of in-situ oxide-dispersion-strengthened AlCoCrFeNi2.1 composite coatings manufactured by high-speed laser cladding","authors":"Peng Wang, Xianglin Zhou, Zhipei Chen, Yu Shi, Yudong Liang, Mina Zhang, Jian Sun, Zhiyong Yu, Peixin Xu, Xianglong Wang, Xinggang Li","doi":"10.1016/j.jmst.2025.05.017","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.05.017","url":null,"abstract":"To develop thermal barrier coatings (TBCs) that protect against high-temperature oxidation, it is critical to explore and develop new bonded coating materials and fabrication techniques. Here, oxide-dispersion-strengthened (ODS) AlCoCrFeNi<sub>2.1</sub> composite coatings were formed using high-speed laser cladding (HSLC), of which long-term oxidation behavior at 1000, 1100, and 1200°C was studied. The results showed that the ODS AlCoCrFeNi<sub>2.1</sub> composite coatings exhibited better oxidation resistance than the conventional NiCoCrAlY coatings and some other high-entropy alloy (HEA) coatings at 1000 and 1100°C. This was because Y<sub>2</sub>Hf<sub>2</sub>O<sub>7</sub> nanoparticles decreased the thermally-grown oxide (TGO) growth rate and thermal expansion mismatch stresses, and increased the coating/TGO interfacial toughness. The composite coating rapidly failed after only 200 h of oxidation at 1200°C, primarily due to the formation of coarse Al<sub>2</sub>Y<sub>4</sub>O<sub>9</sub> oxide aggregates within the TGO, which caused the rapid transport of Fe, Cr, Hf, Y, Al, and O atoms. Moreover, the formation of Y<sub>2</sub>Hf<sub>2</sub>O<sub>7</sub> nanoparticles within the composite coating was induced by regulating the Marangoni convection intensity in the melt pool during HSLC. This report provides a candidate for the next-generation, low-cost, oxidation-resistant bonded coatings.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"25 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144176868","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synergistic wedge effect for low-temperature doping in dual-phase dielectric ceramics","authors":"Yanzhao Zhang, GuoXiang Zhou, Yuhang Zhang, Ning Xie, Lanlan Yang, Kunpeng Lin, Zhe Zhao, Meiling Yang, Huatay Lin, Zhihua Yang, Dechang Jia, Yu Zhou","doi":"10.1016/j.jmst.2025.04.037","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.04.037","url":null,"abstract":"Selective ion doping is a promising method to enhance the overall performance of perovskite dielectric ceramics. However, the confrontations among the dielectric constant (<em>ε</em><sub>r</sub>), near-zero temperature coefficient of resonant frequency (TCF), and quality factor (<em>Q × f</em>) remain key challenges in high-performance dielectric ceramics. To leverage the trade-off conflicts, using dual-phase perovskite-based dielectric ceramic composites could be a potentially ideal solution. Unfortunately, the selected ions are hard to be doped into the perovskite phase due to the sintering temperature disparity of the two phases, thereby significantly impacting the modification effect. In this study, a “wedge” strategy was employed in a MgTiO<sub>3</sub>-CaTiO<sub>3</sub> dual-phase dielectric ceramic composite by using Ce as an auxiliary dopant to realize the main Hf doping in the CaTiO<sub>3</sub> phase due to the lattice distortion. This strategy also harmonizes the confrontation of the sintering temperature disparity between the two components of CaTiO<sub>3</sub> and MgTiO<sub>3</sub>. The Hf<sup>4+</sup> doping level of as high as 40 mol.% with a reduced sintering temperature of over 200 °C was successfully achieved by using this “wedge” strategy. Most importantly, the trade-off conflicts among the <em>ε</em><sub>r</sub>, near-zero TCF, and <em>Q × f</em> have been considerably reduced and harmonized due to the successful introduction of a high dosage of Hf dopant in the CaTiO<sub>3</sub> phase without sacrificing the intact structure of MgTiO<sub>3</sub>. This strategy not only sheds light on manufacturing high-performance dual-phase dielectric ceramics with trade-off conflicts of properties but also provides an innovative pathway to address the challenge of mismatch of sintering temperature for selective ion doping in multiple-phase ceramic composites.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"41 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144176869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Evolution mechanism of Ni3Si precipitate and anisotropic Frank loop variation in Ni-based alloy revealed by proton irradiation and MD simulations","authors":"Zhenbo Zhu, Ping Yu, Wenqing Liu, Chengpeng Liu, Weichi Ji, Hefei Huang","doi":"10.1016/j.jmst.2025.04.039","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.04.039","url":null,"abstract":"Proton irradiation with a low damage rate was conducted on the Ni-based alloy GH3535 to investigate the evolution behavior of dislocation loops and irradiation-induced segregation (RIS), both of which are known to degrade mechanical properties. This study identified that RIS induced the nucleation of Ni₃Si precipitates from Ni-Si clusters in the irradiated Ni-based alloys, which is considered a significant contributor to irradiation hardening in stainless steel. Atomic probe tomography (APT) analysis revealed Ni enrichment on both sides of the dislocation loop edges, forming a \"W-shaped\" profile. Meanwhile, Si accumulated along the edge, inhibiting loop growth and leading to the formation of shadows. Molecular dynamics (MD) simulations confirmed the mechanism of this enrichment distribution. With increasing irradiation dose, Ni₃Si nucleates at loop edges and coarsens by absorbing nearby Si atoms, ultimately resulting in the dissolution of the loop. This RIS at dislocation loops results in a Si-depleted matrix, stabilizing the nucleation of CrMo-enriched M₂C carbides and newly formed Frank loops. Meanwhile, four Frank loop (FL) variants were found to have anisotropic behavior. Scanning transmission electron microscopy (STEM) characterization across several crystal orientations revealed that the highest density of Frank loops occurred in the variant perpendicular to the crystal orientation. MD simulations indicated a distinct increase in the formation energy of the four variants under compressive stress, highlighting the influence of stress from ion penetration on Frank loop nucleation. These findings provide valuable insights into the evolution of precipitates and quantitative analysis of dislocation loops in Ni-based alloys.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"58 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144176873","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Fabrication of high-performance (TiC + (TiZr)5Si3)/TA15 composites via spark plasma extrusion","authors":"Qiang Wang, Zhao-Hui Zhang, Xing-Wang Cheng, Xiao-Tong Jia, Yang-Yu He, Jin-Zhao Zhou, Yuan-Hao Sun","doi":"10.1016/j.jmst.2025.05.018","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.05.018","url":null,"abstract":"To address the room-temperature brittleness of (TiC + (TiZr)5Si3)/TA15 composites, this study introduces a novel thermomechanical approach—spark plasma extrusion (SPE). The microstructure and mechanical properties of the extruded samples were systematically evaluated. The extruded composites exhibited a yield strength of 1267 MPa, an ultimate tensile strength of 1383 MPa, and an elongation of 7.0%, all markedly superior to those of the as-sintered counterparts. The enhanced ductility is attributed to the more homogeneous distribution of TiC and (TiZr)<sub>5</sub>Si<sub>3</sub> reinforcements and the activation of additional <<em>c</em> + <em>a</em>> dislocations during deformation. Furthermore, at 600, 650, and 700 °C, the tensile strengths of the extruded composites reached 840, 652 , and 480 MPa, respectively, representing increases of 75.9%, 53.1%, and 44.0% over the TA15 alloy. During high-temperature tensile tests, matrix softening facilitated greater ductility, with dislocation slip identified as the dominant deformation mechanism. This study provides a new and feasible approach for the fabrication of high-strength, high-ductility titanium matrix composites.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"5 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144176871","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yu Che, Ke Wang, Cong Wang, Bo Weng, Shifu Chen, Sugang Meng
{"title":"Lattice match-enabled Zn3In2S6@CdS S-scheme heterojunction with S covalent bond bridge for simultaneous H2O2 photosynthesis and H2 production","authors":"Yu Che, Ke Wang, Cong Wang, Bo Weng, Shifu Chen, Sugang Meng","doi":"10.1016/j.jmst.2025.04.030","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.04.030","url":null,"abstract":"The key to realizing artificial photosynthesis of hydrogen peroxide coupled with hydrogen generation lies in the construction of efficient bifunctional photocatalysts. Herein, we have successfully prepared core-shell Zn<sub>3</sub>In<sub>2</sub>S<sub>6</sub>@CdS (ZIS@CdS) S-scheme heterojunction with matched interfacial lattices and S covalent bonding bridges by ion-exchange method. The combination of density functional theory calculations and experimental tests exhibit that the ZIS@CdS heterojunction interface with a lattice mismatch of ∼5% and the presence of two S covalent bonding forms, which provides stable and efficient channels for photogenerated charge transfer. Moreover, the photogenerated charges at the ZIS@CdS heterojunction interface follow the S-scheme transfer pathway, enabling spatial charge separation and high redox potentials. Under the synergistic effect of the matched interfacial lattice, covalent bond bridges, and built-in electric field, the ZIS@CdS heterojunction achieves an impressive H<sub>2</sub> evolution rate of 195.9 μmol g<sup>−1</sup> h<sup>−1</sup> and H<sub>2</sub>O<sub>2</sub> production rate of 92.0 μmol g<sup>−1</sup> h<sup>−1</sup> without the need of sacrificial agent and oxygen bulging, respectively. This work verifies that coupling lattice matching and covalent bonding is an effective strategy for constructing efficient bifunctional photocatalysts.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"13 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165593","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhengxiao Li, Minggang Zhu, Xiaolong Song, Ziqi Deng, Dongmin Zhang, Xian Wu, Zhongxin An, Qisong Sun, Wei Li
{"title":"Low thermal expansion and corrosion resistance characteristics of high-coercivity Nd-Fe-B magnets through TbMg diffusion","authors":"Zhengxiao Li, Minggang Zhu, Xiaolong Song, Ziqi Deng, Dongmin Zhang, Xian Wu, Zhongxin An, Qisong Sun, Wei Li","doi":"10.1016/j.jmst.2025.04.033","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.04.033","url":null,"abstract":"The design of permanent magnets is typically tailored to exhibit specific characteristics according to diverse application scenarios, such as high corrosion resistance and superior thermal stability. This study developed a multifunctional Nd-Fe-B magnet through grain boundary diffusion with a low-melting-point TbMg alloy. The most remarkable performance enhancement was manifested in its low thermal expansion coefficient. Thermal expansion behavior analysis revealed that the expanded coefficient of the diffused magnets was significantly reduced. A binary TbMg low-melting-point alloy diffusion source was innovatively designed, and microstructural investigations demonstrated that Mg incorporation effectively suppresses the formation of surface anti core-shell structures during the diffusion process, achieving an extraordinary coercivity enhancement of 10.17 kOe. Beyond magnetic performance improvements, electrochemical experiments confirmed substantial corrosion resistance enhancement in the modified magnets. Consequently, the developed magnet simultaneously integrates three critical advantages: reduced thermal expansion coefficient, elevated coercivity, and enhanced corrosion resistance. This breakthrough would address the stringent performance requirements for rare-earth permanent magnets in specialized applications such as humanoid robotics and industrial sensors, where multi-property optimization is essential for operational reliability under complex environmental conditions.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"5 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165589","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Decoupling the orientation dependence of deformation-induced martensitic transformation via single-crystal micropillar compression","authors":"Guosheng Sun, Shilong Lv, Yunfei Zhang, Lirong Xiao, Peng Yong, Yuntian Zhu, Kehong Wang, Jizi Liu","doi":"10.1016/j.jmst.2025.04.034","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.04.034","url":null,"abstract":"This study explores the significant orientation dependence of deformation-induced martensitic transformation. By employing single crystalline micropillar compression, three typical low-index crystallographic orientations were selected to examine their influence on the martensitic transformation of metastable austenitic stainless steel. Results demonstrate that the [011] orientation significantly inhibits the formation of α'-martensite, whereas the [001] and [111] orientations more effectively facilitate phase transformation, which is closely related to the transformation mechanisms. Specifically, the [001] orientation, which is prone to stacking fault formation, promotes martensitic transformation significantly with the aid of ε-martensite and the decreased effective stacking fault energy during compression. Meanwhile, the [111] oriented pillars demonstrate the highest yield strength, with shear deformation responsible for the relatively high fraction of α'-martensite. Additionally, the non-Schmid behavior occurred in the [011]- and [111]- oriented micropillars were found and discussed. This research advances the understanding of orientation-dependent martensitic transformation and provides an optional way to tailor the Transformation-induced plasticity effect via grain orientation engineering.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"134 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enhancement of high-temperature performance in titanium alloys through rapid heating: a novel boundary engineering approach","authors":"Wentao Chen, Kehuan Wang, Gang Liu","doi":"10.1016/j.jmst.2025.05.014","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.05.014","url":null,"abstract":"How to upgrade the comprehensive performance in high-temperature titanium alloys is a long-lasting topic in the industry due to the inherent cost and time limitations of conventional methods. In this study, a novel boundary engineering approach utilizing rapid heating and aging (RHA) is proposed for the commercial Ti60 alloy. By fabricating a heterogeneous microstructure comprising submicron-sized lamellar α phase (α<sub>m</sub>), nanosized lamellar α phase (α<sub>n</sub>) and multiscale silicides, the RHA-treated alloy achieved an exceptional combination of strength and ductility at both 600°C and room temperature. Compared with the initial material, the ultimate tensile strength (UTS) and creep rupture life were significantly enhanced. The greatly enhanced performance is predominantly attributed to grain boundary strengthening of refined lamellar α phase and multiscale silicides. The present work provides a novel strategy to unlock the potential of existing titanium alloys for extreme-temperature applications.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"148 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144165590","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}