Journal of Materials Science & Technology最新文献

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Semiconductor-based electromagnetic wave absorption materials: Review and perspectives 半导体基电磁波吸收材料:综述与展望
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-05 DOI: 10.1016/j.jmst.2025.09.001
Xiuyun Ren, Di Lan, Zhenguo Gao, Siyuan Zhang, Yu Zhang, Mukun He, Zirui Jia, Guanglei Wu
{"title":"Semiconductor-based electromagnetic wave absorption materials: Review and perspectives","authors":"Xiuyun Ren, Di Lan, Zhenguo Gao, Siyuan Zhang, Yu Zhang, Mukun He, Zirui Jia, Guanglei Wu","doi":"10.1016/j.jmst.2025.09.001","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.09.001","url":null,"abstract":"The diverse charge and band structures of semiconductor materials have necessitated the development of semiconductor-based electromagnetic wave absorption materials (SEMAs). This review provides a comprehensive analysis of the latest advancements in SEMAs of various semiconductor categories, including but not limited to n-type semiconductors, p-type semiconductors, Mott-Schottky heterojunctions, p–n heterojunctions, etc. Furthermore, the review summarizes strategies for optimizing absorption performance through defect engineering, interface engineering, hybrid engineering, topology engineering, and multi-component optimization. It also delves into the intricate relationship between semiconductor structure, electromagnetic properties, and absorption performance. Finally, current challenges and future research directions for SEMAs are proposed, emphasizing the need for the optimization of new structural materials, in-depth exploration of mechanisms, intelligent design and control, practical applications, and industrialization. This review aims to offer new perspectives for the development of next-generation SEMAs, facilitating fundamental breakthroughs in the mechanistic understanding of electromagnetic wave absorption in semiconductors and advancing diverse applications in military stealth, electromagnetic protection, and wireless communication.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"24 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144996015","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polarization-enhanced sub-5 nm Janus MoSiGeN4 FET for high-performance and low-power applications 偏振增强的亚5nm Janus MoSiGeN4场效应管,适用于高性能和低功耗应用
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-05 DOI: 10.1016/j.jmst.2025.07.066
Mi-Mi Dong, Chuan-Kui Wang, Xiao-Xiao Fu, Ming-Wen Zhao
{"title":"Polarization-enhanced sub-5 nm Janus MoSiGeN4 FET for high-performance and low-power applications","authors":"Mi-Mi Dong, Chuan-Kui Wang, Xiao-Xiao Fu, Ming-Wen Zhao","doi":"10.1016/j.jmst.2025.07.066","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.07.066","url":null,"abstract":"Achieving ultra-short channel field-effect transistors (FETs) that cater to both high-performance (HP) and low-power (LP) applications simultaneously is an unremitting pursuit in the field. Herein, employing first-principles calculations, we investigate the performance of sub-5 nm FETs based on the Janus MoSiGeN<sub>4</sub> material and reveal the role of intrinsic out-of-plane electric polarization. We demonstrate that the synergistic effect of the intrinsic polarization field and the external electric field enhances the performance of Janus MoSiGeN<sub>4</sub> FETs over MoSi<sub>2</sub>N<sub>4</sub> and MoGe<sub>2</sub>N<sub>4</sub> FETs. Our simulations show that a 3 nm gate-length cold-source Janus MoSiGeN<sub>4</sub> FET, utilizing LaOCl as the dielectric material and an appropriate underlap structure, fulfills the HP and LP standards set by the International Technology Roadmap for Semiconductors (ITRS), with a subthreshold swing approaching the Boltzmann tyranny of 60 mV/dec. Notably, the optimized 1 nm gate-length MoSiGeN<sub>4</sub> FET achieves an on-state current of 990 μΑ/μm (HP) and 690 μΑ/μm (LP), surpassing other theoretical two-dimensional FETs at the same gate length. Taking the defect effects into account, the MoSiGeN<sub>4</sub> FET maintains a high on-state current that surpasses the ITRS for HP and LP standards. Our results provide a promising approach for designing ultra-short channel FETs suitable for both HP and LP applications.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"28 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144996020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
All-organic S-scheme carbon nitride/perylene imide heterojunction with π-π stacking modulates the PCET process for CO2 photoreduction 具有π-π堆叠的全有机S-scheme氮化碳/苝酰亚胺异质结调节CO2光还原PCET过程
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-04 DOI: 10.1016/j.jmst.2025.08.026
Jinbo Xue, Qiurong Li, Shuhan Sun, Shilong Feng, Hengrui Jian, Zhanfeng Li, Qianqian Shen, Yuxing Yan
{"title":"All-organic S-scheme carbon nitride/perylene imide heterojunction with π-π stacking modulates the PCET process for CO2 photoreduction","authors":"Jinbo Xue, Qiurong Li, Shuhan Sun, Shilong Feng, Hengrui Jian, Zhanfeng Li, Qianqian Shen, Yuxing Yan","doi":"10.1016/j.jmst.2025.08.026","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.08.026","url":null,"abstract":"It is a critical proposition to efficiently convert CO<sub>2</sub> into hydrocarbon fuel utilizing photocatalytic technology. However, the insufficient thermodynamic potential of photogenerated carriers and the sluggish multi-proton coupled electron transfer (PCET) process severely hinder the formation of CH<sub>4</sub> and other hydrocarbons. Hence, we constructed an all-organic S-scheme heterojunction photocatalyst (CN/UPDI-<em>x</em>) with large π-delocalization via π-π interactions, with CO and CH<sub>4</sub> yields of 34.10 and 4.55 μmol g<sup>−1</sup> h<sup>−1</sup>, where the CH<sub>4</sub> yields were 12.3 and 11.7 times higher than those of pristine CN and UPDI, respectively. The S-scheme heterojunction improves the separation efficiency of photogenerated electron-hole pairs, preserves the highly oxidizing holes required for accelerating water oxidation for H* production, and enables a substantial accumulation of high-energy electrons that drive the conversion of reaction intermediates. Moreover, the extensive π-electron delocalization system formed by CN and UPDI offers an efficient pathway for the rapid transport of photogenerated electrons. The high-efficiency supply of H* coupled with CO<sub>2</sub> adsorbed on the CN at the heterojunction interface to form intermediate *CHO. This intermediate is further transformed into CH<sub>4</sub> through a multi-step hydrogenation process. This work provides novel perspectives for the design and development of organic polymer semiconductor photocatalysts applicable to environmental protection and clean energy production.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"71 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144987560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Yttria enhanced CuCr composites fabricated by laser powder bed fusion: Microstructure, properties and strengthening mechanisms 激光粉末床熔合制备氧化钇增强CuCr复合材料:显微组织、性能及强化机理
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-04 DOI: 10.1016/j.jmst.2025.08.027
Chengrui Xu, Haiou Zhuo, Jie Mao, Changzhi Sun, Ziyi Gong, Yan Chen, Li Ma, Jiancheng Tang
{"title":"Yttria enhanced CuCr composites fabricated by laser powder bed fusion: Microstructure, properties and strengthening mechanisms","authors":"Chengrui Xu, Haiou Zhuo, Jie Mao, Changzhi Sun, Ziyi Gong, Yan Chen, Li Ma, Jiancheng Tang","doi":"10.1016/j.jmst.2025.08.027","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.08.027","url":null,"abstract":"Complex and harsh service environments impose higher demands on comprehensive performance of high-strength and high-conductivity Cu-Cr series alloys. This work introduces Y<sub>2</sub>O<sub>3</sub> nanoparticles into CuCr alloy by the laser powder bed fusion (LPBF) process, aiming to further enhance its mechanical properties while preserving its electrical conductivity. The spherical Cu-0.7Cr-2Y<sub>2</sub>O<sub>3</sub> composite powders with excellent flowability are prepared using the spray drying and pre-sintering methods. Different laser powers and scanning speeds are utilized to optimize the LPBF forming processes. The CuCr-Y<sub>2</sub>O<sub>3</sub> composites with a high relative density of 99.4% are successfully fabricated at a laser power of 250 W and a scanning speed of 400 mm/s. The effect of aging treatments on the evolution of the microstructure and properties of as-printed CuCr-Y<sub>2</sub>O<sub>3</sub> composites is systematically analyzed. In the LPBF samples, Y<sub>2</sub>O<sub>3</sub> particles with an average size of 46.7 nm are homogeneously dispersed in the copper matrix, and few Cr nano-precipitates are observed. Following aging treatment, the morphology and size of Y<sub>2</sub>O<sub>3</sub> particles remain consistent, while a greater density of Cr phases, with an average size of 7.3 nm, precipitate and exhibit a coherent interface relationship with the matrix. Aging treatment conducted at 460°C for 1.5 h results in a peak tensile strength of 691.6 MPa, elongation of 21.5%, electrical conductivity reaching 79.6% IACS, microhardness values of 152.7 HV at room temperature and 112.2 HV at 500°C. Moreover, the conductivity mechanisms and strengthening mechanisms are discussed. The full aging of solid solution Cr elements and minimal negative effects of Y<sub>2</sub>O<sub>3</sub> particles on electron scattering, contribute to the excellent electrical conductivity. The superior mechanical properties at both room and elevated temperatures are primarily attributed to the synergistic strengthening effect provided by the shearing mechanism of fine Cr precipitates and the Orowan mechanism of Y<sub>2</sub>O<sub>3</sub> particles and lager Cr precipitates.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"163 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144996021","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Strength-toughness relation of single crystalline and nano-polycrystalline silicon specified by atomic-/nano-crystalline microstructures 单晶与纳米多晶硅的强度-韧性关系由原子/纳米晶微观结构决定
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-03 DOI: 10.1016/j.jmst.2025.07.062
Yabin Deng, Linmei Wu, Shiwei Zhao, Xiaozhi Hu, Yiru Ren
{"title":"Strength-toughness relation of single crystalline and nano-polycrystalline silicon specified by atomic-/nano-crystalline microstructures","authors":"Yabin Deng, Linmei Wu, Shiwei Zhao, Xiaozhi Hu, Yiru Ren","doi":"10.1016/j.jmst.2025.07.062","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.07.062","url":null,"abstract":"An asymptotic non-LEFM model is developed for shallow surface cracks comparable to material microstructures. The characteristic microstructure size (<em>C</em><sub>ch</sub>) of single crystal silicon (SCS) is the atomic diameter (0.235 nm), and <em>C</em><sub>ch</sub> of a nano-grained polycrystalline silicon (N-PCS) is its average grain size. N-PCS with <em>C</em><sub>ch</sub> from 150 nm to 3 μm is considered in this study. The fracture toughness (<em>K</em><sub>IC</sub>) of both SCS and N-PCS can be predicted from their intrinsic strengths and respective <em>C</em><sub>ch</sub>. Predicted <em>K</em><sub>IC</sub> values of 0.90–1.40 MPa √m for SCS and 1.56–5.31 MPa √m for N-PCS are confirmed by collected experimental data of 0.74–1.38 MPa √m for SCS and 1.43–3.46 MPa √m for N-PCS. The intrinsic relation between the <em>K</em><sub>IC</sub>, intrinsic strength and characteristic microstructure is both practically useful and fundamentally significant. The macroscopic <em>K</em><sub>IC</sub> and intrinsic strength, previously considered as two separate material properties, are now linked together by the atomic-/nano-scale microstructures. This fundamental relation on strength, toughness and microstructure for brittle solids, verified by SCS and N-PSC, is comparable to the classic “Hall-Petch relation” for ductile metals.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"62 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144987696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CTAB-induced VS4 yolk-shelled microspheres with sulfur vacancies for enhanced magnesium storage ctab诱导的带有硫空位的VS4蛋黄壳微球增强了镁的储存
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-03 DOI: 10.1016/j.jmst.2025.07.063
Yiyi Wang, Zhenfeng Guan, Lingxiao Luo, Guiyang Gao, Jiajia Han, Jie Lin, Laisen Wang, Baihua Qu, Dong-Liang Peng, Qingshui Xie
{"title":"CTAB-induced VS4 yolk-shelled microspheres with sulfur vacancies for enhanced magnesium storage","authors":"Yiyi Wang, Zhenfeng Guan, Lingxiao Luo, Guiyang Gao, Jiajia Han, Jie Lin, Laisen Wang, Baihua Qu, Dong-Liang Peng, Qingshui Xie","doi":"10.1016/j.jmst.2025.07.063","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.07.063","url":null,"abstract":"To address the challenges of rapid capacity decay and limited cycle life in rechargeable magnesium batteries (RMBs), which are primarily caused by slow Mg<sup>2+</sup> diffusion kinetics and structural collapse of the cathode material, we propose a strategy integrating cationic surfactant with metal compounds. A sulfur vacancy-rich CTAB-VS<sub>4</sub> composite with yolk-shell structure is successfully synthesized by in-situ introduction of cationic surfactant cetyltrimethylammonium bromide (CTAB). The CTAB modification achieves a multifunctional “one stone, three birds” effect: (1) Expanding the interlayer spacing and inducing rich sulfur vacancies, the diffusion rate of Mg<sup>2+</sup> and the magnesium storage sites are increased. (2) Constructing a yolk-shell structure with a high specific surface area, providing ample active sites for accommodating Mg<sup>2+</sup>. (3) Reducing the interface impedance, optimizing the electronic structure, and stabilizing the Mg anode. Consequently, the CTAB-VS<sub>4</sub> cathode exhibits exceptional electrochemical performances in RMBs, delivering high discharge specific capacities of 258 and 173 mAh g<sup>−1</sup> at 0.5 and 3 A g<sup>−1</sup> after 180 and 700 cycles, respectively. Systematic characterizations confirm the reversible Mg<sup>2+</sup> intercalation mechanism. This synergistic modulation through cationic surfactant provides a promising pathway toward high-performance RMBs.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"63 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144930742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Carbon cloth-based nitrogen-doped carbon nanotube-encapsulated Co nanoparticles as bifunctional oxygen electrocatalysts for flexible Zn-air batteries 碳布基氮掺杂碳纳米管包封Co纳米颗粒作为柔性锌空气电池双功能氧电催化剂
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-03 DOI: 10.1016/j.jmst.2025.08.024
Qihao Wu, Jiahui Jiang, Heju Gao, Hongli Jia, Chunyan Wu, Changyi Deng, Guancheng Xu, Muhammad Ammar, Hao Jiang, Li Zhang
{"title":"Carbon cloth-based nitrogen-doped carbon nanotube-encapsulated Co nanoparticles as bifunctional oxygen electrocatalysts for flexible Zn-air batteries","authors":"Qihao Wu, Jiahui Jiang, Heju Gao, Hongli Jia, Chunyan Wu, Changyi Deng, Guancheng Xu, Muhammad Ammar, Hao Jiang, Li Zhang","doi":"10.1016/j.jmst.2025.08.024","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.08.024","url":null,"abstract":"To enhance the performance of Zn-air batteries (ZABs), it is critical to reduce the energy barriers of the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) at the air cathode while accelerating their reaction kinetics. In this study, a self-supported bifunctional oxygen catalyst was prepared by growing nitrogen-doped carbon nanotubes (NCNTs) encapsulating Co nanoparticles on carbon cloth (CC), denoted as Co/NCNTs/CC. Benefiting from abundant active sites and a self-supported structure, the optimized Co/NCNTs/CC-1 exhibits a half-wave potential of 0.86 V for ORR and an overpotential of 243 mV at a current density of 10 mA cm<sup>−2</sup> for OER. Density functional theory (DFT) calculations combined with experimental results reveal that the combination of Co nanoparticles and NCNTs improves the adsorption-desorption ability of oxygenated intermediates, synergistically enhancing the bifunctional catalytic efficiency. ZABs constructed with Co/NCNTs/CC-1 exhibit an open-circuit voltage of 1.45 V and demonstrate superior stability compared to ZABs assembled with Pt/C+RuO<sub>2</sub>. Additionally, flexible ZABs exhibit good battery performance and bending charge-discharge capabilities. This research offers a promising strategy for the development of non-precious metal catalysts for ZABs.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"33 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144930743","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic engineering of oxygen vacancies and Schottky junctions for enhanced solar-driven nitrogen fixation on hierarchical hollow Bi4Ti3O12 氧空位和肖特基结协同工程增强太阳能驱动的分层中空Bi4Ti3O12固氮
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-03 DOI: 10.1016/j.jmst.2025.07.064
Mingliang Sun, Ao Sun, Qi Wu, Hongwei Zhu, Xianchun Liu, Yan Xing
{"title":"Synergistic engineering of oxygen vacancies and Schottky junctions for enhanced solar-driven nitrogen fixation on hierarchical hollow Bi4Ti3O12","authors":"Mingliang Sun, Ao Sun, Qi Wu, Hongwei Zhu, Xianchun Liu, Yan Xing","doi":"10.1016/j.jmst.2025.07.064","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.07.064","url":null,"abstract":"Developing highly efficient photocatalysts for nitrogen fixation remains a significant challenge due to the difficult activation of N<sub>2</sub> and rapid recombination of photogenerated carriers. Herein, 3D hierarchical hollow Bi/Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub> Schottky junction photocatalysts with tunable surface oxygen vacancies (OVs) are fabricated by a facile hydro/solvothermal method. Due to the synergistic effect of surface OVs and the Schottky junctions at the Bi/Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub> interface, efficient light utilization and enhanced separation and migration of photogenerated carriers are achieved. Additionally, the Schottky junctions facilitate unidirectional electron transfer from Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub> to metallic Bi NPs. The electron-rich metallic Bi serves as the active sites for N<sub>2</sub> reduction reaction. The optimized 1% Bi/HBTO-OV3 composite achieves an outstanding ammonia production rate of 24.25 μmol g<sup>−1</sup> h<sup>−1</sup> in pure water without sacrificial agents, which is 5.66 times higher than that of pristine Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub>. In situ experiments and DFT calculation elucidate the photocatalytic nitrogen fixation mechanism, confirming an associative distal pathway for the hydrogenation of N<sub>2</sub>. This work provides a rational strategy for designing high-efficiency photocatalysts by integrating surface defect engineering with Schottky junctions, paving the way for sustainable solar-driven nitrogen fixation.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"59 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144987564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Construction of a sea-urchin liked S-Scheme heterojunction: A case study using 3D CoNiO2/W18O49 composite for efficient CO2 photoreduction 类海胆S-Scheme异质结的构建:三维CoNiO2/W18O49复合材料用于高效CO2光还原的案例研究
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-03 DOI: 10.1016/j.jmst.2025.08.025
Erhan Qin, Lili Yang, Jihui Lang, Qi Zhang, Huilian Liu, Xuefei Li, Zhe Chen, Maobin Wei, Jinghai Yang, Pengwei Huo, Xin Li
{"title":"Construction of a sea-urchin liked S-Scheme heterojunction: A case study using 3D CoNiO2/W18O49 composite for efficient CO2 photoreduction","authors":"Erhan Qin, Lili Yang, Jihui Lang, Qi Zhang, Huilian Liu, Xuefei Li, Zhe Chen, Maobin Wei, Jinghai Yang, Pengwei Huo, Xin Li","doi":"10.1016/j.jmst.2025.08.025","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.08.025","url":null,"abstract":"The CO<sub>2</sub> photoreduction (CO<sub>2</sub> PR) technique is widely acknowledged as a promising approach to mitigating energy shortage crises. Among various strategies, enhancing the efficiency of charge carrier separation and broadening the spectral response range are effective means to advance the development of CO<sub>2</sub> PR. In this study, a novel S-scheme heterojunction CoNiO<sub>2</sub>/W<sub>18</sub>O<sub>49</sub> composite catalyst was synthesized through a two-step hydrothermal method. By leveraging its heterostructure and enhanced visible-light absorption capacity, the composite demonstrates improved carrier separation efficiency and superior CO<sub>2</sub> molecule capture capability, thereby achieving exceptional CO<sub>2</sub> PR performance. The optimized CW-3 sample exhibited remarkable CO and CH<sub>4</sub> evolution rates of 87.17 and 92.42 μmol g<sup>−1</sup> h<sup>−1</sup>, respectively, representing 6-fold and 33-fold enhancements compared to pristine CoNiO<sub>2</sub>. Combined theoretical calculations and systematic characterizations conclusively demonstrated the formation mechanism of the intrinsic electric field at the S-scheme heterojunction interface. The composite material simultaneously enhanced visible-light absorption through optimized band alignment and significantly improved charge carrier separation efficiency driven by synergistic interfacial charge transfer and band bending effects. This integrated enhancement mechanism stemmed from the complementary electronic interactions between CoNiO<sub>2</sub> and W<sub>18</sub>O<sub>49</sub> components within the heterostructure architecture.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"33 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144987565","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimizing mechanical properties in Al-Li alloys through synergistic regulation of dislocations and precipitates during creep aging 通过对蠕变时效过程中位错和析出相的协同调节优化Al-Li合金的力学性能
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-03 DOI: 10.1016/j.jmst.2025.07.065
Guantao Wang, Lei Liu, Fuyuan Liu, Kaiyang Li, Keqiang Su, Enyu Guo, Zongning Chen, Huijun Kang, Yanjin Xu, Zhirou Zhang, Tongmin Wang
{"title":"Optimizing mechanical properties in Al-Li alloys through synergistic regulation of dislocations and precipitates during creep aging","authors":"Guantao Wang, Lei Liu, Fuyuan Liu, Kaiyang Li, Keqiang Su, Enyu Guo, Zongning Chen, Huijun Kang, Yanjin Xu, Zhirou Zhang, Tongmin Wang","doi":"10.1016/j.jmst.2025.07.065","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.07.065","url":null,"abstract":"Creep aging is a coupled process that integrates both processing and precipitation strengthening in age-hardening alloys. However, inhomogeneous precipitation resulting from dislocation accumulation can significantly degrade the mechanical properties. In this study, an attempt was made to establish a correlation between creep stress, dislocation density and precipitation strengthening to address the degradation in plasticity. The results show that the application of creep stress does not significantly change the low-angle grain boundaries (LAGBs). The distinct microstructure of the T<sub>1</sub> phase and the disappearance of the precipitation-free zones (PFZs) at the grain boundaries (GBs) are the main factors responsible for the improved mechanical properties. The micro-elastic lattice strain induced by creep stress can effectively mitigate the depletion of dislocations by aging precipitation, and the nucleation kinetics of precipitates can be significantly enhanced. During the creep aging process under 150 MPa stress, the T<sub>1</sub> phase forms a sandwich structure via interstitial nucleation, with its number density increasing from 2.25 × 10<sup>14</sup>/m<sup>2</sup> to 4.04 × 10<sup>14</sup>/m<sup>2</sup>. The dislocation density induced by creep stress also contributes to the narrowing or disappearance of the PFZs at the GBs, further improving the capacity for localized plastic deformation. Finally, the Al-Li alloy with excellent ultimate tensile strength (∼754.0 MPa), yield strength (∼718.1 MPa) and elongation (∼8.8%) was obtained. This study provides strategies for optimizing the microstructure and improving the mechanical properties of Al-Li alloys.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"3 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144987588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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