Journal of Materials Science & Technology最新文献

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Achieving interpretable and efficient design of lightweight multi-principal element alloys via machine learning with optimized strengthening-toughening models 利用优化的强化-增韧模型,通过机器学习实现轻量化多主元素合金的可解释和高效设计
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-08 DOI: 10.1016/j.jmst.2025.07.070
Xutao Li, Zheng Li, Zhichao Meng, Weiji Lai, Li Kang, Dingxin Liu, Hao Wang, Xiaowei Zuo
{"title":"Achieving interpretable and efficient design of lightweight multi-principal element alloys via machine learning with optimized strengthening-toughening models","authors":"Xutao Li, Zheng Li, Zhichao Meng, Weiji Lai, Li Kang, Dingxin Liu, Hao Wang, Xiaowei Zuo","doi":"10.1016/j.jmst.2025.07.070","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.07.070","url":null,"abstract":"Body-centered cubic multi-principal element alloys (BCC MPEAs) face inherent strength-ductility trade-offs. Given their vast compositional space, identifying key factors governing strength and ductility, as well as developing novel strengthening-toughening models to accelerate the property-oriented design, remains an outstanding challenge. Here, we developed an interpretable machine learning (ML) framework for BCC MPEAs to identify the key factors governing yield strength (YS) and fracture elongation (FE). The results demonstrate that FE mainly arises from the synergistic effects of multiple factors (electronegativity difference Δ<em>χ</em><sup>pauling</sup>, valence electron concentration VEC, and density <em>ρ</em>), while average shear modulus mismatch <em>δG</em><sup>ave</sup> is the dominant factor controlling YS. Using these screened features as inputs, we propose optimized YS and FE models that achieve high predictive accuracy (YS: <em>R</em><sup>2</sup>=0.96, FE: <em>R</em><sup>2</sup>=0.84) and outperform existing models. By transforming these ML insights into strengthening/toughening theories via feature-to-mechanical performance/element property mapping, we designed three novel Ti-Zr-based BCC MPEAs with exceptional properties: YS of 1.07–1.16 GPa, FE of 16.6%–24.5%, and specific yield strength of ∼170 MPa cm<sup>3</sup> g<sup>-1</sup>, surpassing most reported BCC MPEAs. This work not only provides a data-driven strategy to overcome the strength-ductility trade-off in BCC MPEAs but also establishes interpretable design principles for accelerating the discovery of advanced structural materials.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"35 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145009367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hardness-strength-toughness synergy of (NbMoTaW)C through TiC-TiO2 dual-phase engineering TiC-TiO2双相工程制备(NbMoTaW)C的硬度-强度-韧性协同效应
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-07 DOI: 10.1016/j.jmst.2025.07.069
Heqiang Chang, Hao Lu, Haibin Wang, Xuemei Liu, Chao Hou, Qiang Hu, Yuli Wang, Xiaoyan Song
{"title":"Hardness-strength-toughness synergy of (NbMoTaW)C through TiC-TiO2 dual-phase engineering","authors":"Heqiang Chang, Hao Lu, Haibin Wang, Xuemei Liu, Chao Hou, Qiang Hu, Yuli Wang, Xiaoyan Song","doi":"10.1016/j.jmst.2025.07.069","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.07.069","url":null,"abstract":"High-entropy carbide ceramics (HECs) face critical limitation in engineering applications due to their inherent brittleness and inadequate flexural strength. Notably, there are pronounced trade-offs between hardness and toughness, and between strength and toughness in HECs. To address these challenges, a dual-phase engineering strategy is proposed in this study to synergistically enhance the mechanical properties of HECs, with (NbMoTaW)C as a representative example. Through the combined effects of TiC solid solution strengthening and in-situ TiO<sub>2</sub> toughening, the (NbMoTaW)C demonstrated superior comprehensive mechanical properties, achieving simultaneously high Vickers hardness (20.23±0.26 GPa), high flexural strength (857±23 MPa), and high fracture toughness (4.97±0.16 MPa m<sup>1/2</sup>), thus resolving the trade-offs between these properties. The formation and adjustment mechanisms of the oxide phase were elucidated. The integrated multiscale characterizations and density functional theory (DFT) calculations illustrated that the lattice distortion induced by the TiC solid solution, along with d-orbital hybridization in the electronic structure, resulted in a significant enhancement in both structural stability and mechanical properties of HEC. Furthermore, the TiO<sub>2</sub> particles, strategically formed from oxygen impurities and predominantly located at grain boundaries, significantly enhanced the HEC’s flexural strength. At the same time, the TiO<sub>2</sub> particles remarkably improved the toughness of the HEC through crack deflection, bridging, and branching mechanisms. This work has established a synergistic phase optimization strategy that enables overcoming the traditional trade-offs in mechanical properties of HECs.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"35 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145007340","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance SWIR photodetector using vertically-aligned Ge/Si core–shell nanowires 使用垂直排列的Ge/Si核壳纳米线的高性能SWIR光电探测器
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-07 DOI: 10.1016/j.jmst.2025.09.002
Guanghui Wang, Chao Le, Wipakorn Jevasuwan, Naoki Fukata
{"title":"High-performance SWIR photodetector using vertically-aligned Ge/Si core–shell nanowires","authors":"Guanghui Wang, Chao Le, Wipakorn Jevasuwan, Naoki Fukata","doi":"10.1016/j.jmst.2025.09.002","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.09.002","url":null,"abstract":"Ge/Si core–shell nanowires (CSNWs) are regarded as strong candidates for next-generation electronic and optoelectronic devices, as they have a structure in which the carrier transport region is isolated from the impurity-doped region by hole gas that has accumulated between the interfaces. In this study, vertically-aligned i-Ge/p-Si CSNWs with different diameters were successfully fabricated using the top-down method, employing electron beam lithography (EBL) combined with chemical vapor deposition (CVD). Raman analysis exhibits hole gas accumulation that is clearly controllable by adjusting the size of the Ge core. A high-performance short-wave infrared (SWIR) photodetector was fabricated using i-Ge/p-Si CSNWs. Even without applied bias voltage, maximum responsivity reached 2.78 A/W under illumination with 1200 nm (near infrared) light. Maximum responsivity reached 16.57 A/W by controlling the hole gas concentration. Our results confirm that hole gas accumulation in i-Ge/p-Si CSNWs enables the fabrication of high-performance SWIR photodetectors.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"20 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145007341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-pressure induced microstructural evolution and phase transition in Ti-55511 alloy 高压诱导Ti-55511合金组织演化与相变
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-07 DOI: 10.1016/j.jmst.2025.08.030
Changchang Liu, Yanghuanzi Li, Lin Guo, Ji Gu, Min Song
{"title":"High-pressure induced microstructural evolution and phase transition in Ti-55511 alloy","authors":"Changchang Liu, Yanghuanzi Li, Lin Guo, Ji Gu, Min Song","doi":"10.1016/j.jmst.2025.08.030","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.08.030","url":null,"abstract":"This study demonstrates how high-pressure thermal treatment achieves a breakthrough in the trade-off relation between strength and ductility in Ti-55511 alloy, providing critical insights for aerospace materials design. When Ti-55511 alloy was processed at 5 GPa across temperatures (room temperature, 700°C, 900°C), temperature-dependent gradient microstructures were formed and governed by stress heterogeneity. This heterogeneity arises from friction constraints induced by high-pressure stress at the contacting surfaces. The surface region exhibited stress concentration with higher hardness values, while the center region displayed a lower stress state with lower hardness values. A gradient distribution of the shear bands was induced at room temperature, with shear band-assisted phase transformation occurring in the surface region. Comparing the α-phase distributions emerging in the specimens treated in single-phase and dual-phase regions, the stress promoted α precipitation for the former one and suppressed α precipitation for the latter one in the surface region. Notably, a unique α-phase fragmentation mechanism was identified in high-temperature-high-pressure treatment, with the nucleation of the β phase within the α phase, induced by α-to-β phase transformation. When the interior β phase grew up to connect the α/β interfaces on both sides of the α precipitates, the fragmentation process was completed. Besides, dynamic recrystallization occurred in the center of the specimen treated by high-pressure treatment in the single-phase region with limited α precipitation. This leads to a notable enhancement in the mechanical properties, with plasticity increased by over 11% and strength increased by ∼160 MPa compared with the original solid-solution state. These findings demonstrate the uniqueness of the high-pressure thermal treatment process and its potential as a preparation technique for titanium alloys with high-strength and high-ductility.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"31 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145007339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Configurational disorder engineering in entropy-increasing conjugated polymers boosts photocatalytic performance 增熵共轭聚合物的构型无序工程提高了光催化性能
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-07 DOI: 10.1016/j.jmst.2025.08.031
Chaohui Sun, Shuhan Sun, Xianghua Zeng, Yanting Tian, Hong Sun, Haili Jiao, Song Wang, Shixiong Liang, Zhanfeng Li, Yue Tian, Xianqiang Xiong
{"title":"Configurational disorder engineering in entropy-increasing conjugated polymers boosts photocatalytic performance","authors":"Chaohui Sun, Shuhan Sun, Xianghua Zeng, Yanting Tian, Hong Sun, Haili Jiao, Song Wang, Shixiong Liang, Zhanfeng Li, Yue Tian, Xianqiang Xiong","doi":"10.1016/j.jmst.2025.08.031","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.08.031","url":null,"abstract":"High-entropy polymers (HEPs) represent a transformative approach to overcoming the intrinsic limitations of conjugated polymer photocatalysts through deliberate configurational disorder engineering. The designed high-entropy conjugated polymer Py-CNTh demonstrates exceptional photocatalytic performance, achieving hydrogen evolution and H<sub>2</sub>O<sub>2</sub> production rates of 248.34 and 15.55 μmol h⁻<sup>1</sup>, respectively—representing 8.8 and 43-fold enhancements over conventional counterparts (Py-Th). Comprehensive characterization reveals that entropy-driven structural disorder induces synergistic optoelectronic enhancements, as evidenced by a 33% reduction in exciton binding energy and a prolonged carrier lifetime of 919 ps, both of which contribute to significantly improved charge separation efficiency. The high-entropy architecture further strengthens interfacial processes through enhanced built-in electric fields and improved hydrophilicity. Systematic studies across an entropy increase establish a direct correlation between configurational disorder and photocatalytic performance, highlighting the critical role of entropy in optimizing charge transport and surface reactivity simultaneously. This work establishes high-entropy engineering as a general design principle for advanced polymeric photocatalysts, offering new opportunities for solar energy conversion applications.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"35 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145009384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Densification mechanism and microstructure evolution of large-sized Al2O3/YAG/ZrO2 eutectic ceramics by hot-pressing sintering based on micro-nano eutectic-structured powders 微纳共晶结构粉体热压烧结大尺寸Al2O3/YAG/ZrO2共晶陶瓷致密化机理及显微组织演变
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-07 DOI: 10.1016/j.jmst.2025.08.032
Baohao Lu, Haijun Su, Di Zhao, Hao Jiang, Minghui Yu, Ruotong Wang, Zhonglin Shen, Zhuo Zhang, Min Guo
{"title":"Densification mechanism and microstructure evolution of large-sized Al2O3/YAG/ZrO2 eutectic ceramics by hot-pressing sintering based on micro-nano eutectic-structured powders","authors":"Baohao Lu, Haijun Su, Di Zhao, Hao Jiang, Minghui Yu, Ruotong Wang, Zhonglin Shen, Zhuo Zhang, Min Guo","doi":"10.1016/j.jmst.2025.08.032","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.08.032","url":null,"abstract":"This study resolved the long-standing trade-off between densification and microstructural coarsening in large oxide eutectic ceramics by fabricating bulk Al<sub>2</sub>O<sub>3</sub>/YAG/ZrO<sub>2</sub> ceramics (120 mm × 10 mm) with an ultra-high density (99.83%) and retained submicron eutectic structure (spacing 0.408 μm). This achievement was enabled by an integrated innovative approach combining ultrafine micro-nano powders synthesized via laser floating zone melting at 300 μm/s (spacing 0.141 μm), ultrasonic wet sieving for interfacial purification, and low-temperature hot-pressing sintering at 1550°C (150°C below conventional temperatures), full densification within 45 min under 60 MPa pressure is enabled through a plasticity-dominated mechanism synergistically assisted by short-range interfacial diffusion. This plasticity-driven process, activated at 1200–1550°C yielded ultrathin reconnected interfaces (0.7 μm thickness) while avoiding grain coarsening. The sintered ceramics exhibited exceptional properties: Vickers hardness 16.25 ± 0.46 GPa, fracture toughness 4.57 ± 0.81 MPa m<sup>1/2</sup>, and flexural strength 516.3 ± 34.6 MPa at room temperature, significantly surpassing conventional sintered eutectic counterparts. High-temperature strength was retained at 290.1 ± 33.6 MPa at 1200°C through suppressed lattice expansion and micro-nano plasticity. Remarkably, after 500 h exposure at 1400°C, constrained microstructural coarsening (eutectic spacing evolved from 0.408 to 1.097 μm; Al<sub>2</sub>O<sub>3</sub>/ZrO<sub>2</sub>/YAG phases limited to 0.651/0.406/0.434 μm) resulted in enhanced hardness (16.74 ± 0.37 GPa) and serviceable fracture toughness (3.09 ± 0.17 MPa m<sup>1/2</sup>), demonstrating superior thermal stability via interface pinning effects. This work establishes a scalable plasticity-enabled low-temperature sintering strategy for manufacturing large-sized structural components with high performance in extreme environments.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"30 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145007343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improved interfacial compatibility of carbon fibers/PEEK laminated composites via incorporating biphenyl-branched poly(aryl-ether-nitrile) 通过添加联苯支化聚芳醚腈改善碳纤维/PEEK复合材料的界面相容性
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-07 DOI: 10.1016/j.jmst.2025.09.003
Xiaoxi Zeng, Xuetao Shi, Yuhan Lin, Wenfeng Zhu, Houbu Li, Junliang Zhang, Junwei Gu
{"title":"Improved interfacial compatibility of carbon fibers/PEEK laminated composites via incorporating biphenyl-branched poly(aryl-ether-nitrile)","authors":"Xiaoxi Zeng, Xuetao Shi, Yuhan Lin, Wenfeng Zhu, Houbu Li, Junliang Zhang, Junwei Gu","doi":"10.1016/j.jmst.2025.09.003","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.09.003","url":null,"abstract":"The insufficient interfacial adhesion between carbon fibers and the PEEK matrix remains a key obstacle to realizing the full mechanical and thermal performance of CF/PEEK composites. This work proposes a biphenyl-containing branched poly(aryl-ether-nitrile) (BPEN) with controlled branching degree as an interfacial compatibilizer and subsequently processed with PEEK via a powder-impregnation assisted hot-pressing method to fabricate CF@BPEN/PEEK laminated composites. When the BPEN branching degree is 10 %, the CF@BPEN/PEEK laminated composites exhibit interlaminar shear strength of 39.7 MPa and a flexural strength of 506.5 MPa, which are 66.1 % and 39.2 % higher than pristine CF/PEEK laminated composites (23.9 and 363.9 MPa), respectively. In addition, the modified laminated composites show enhanced thermal conductivity (1.45 W m⁻¹ K⁻¹), an elevated glass transition temperature by approximately 4 °C, and a remarkable X-band electromagnetic interference shielding effectiveness of 41.0 dB. These multifunctional enhancements originate from a robust, diffusion-driven interphase, constructed through π–π stacking interactions between BPEN biphenyl units and PEEK chains, as well as hydrogen bonding between cyano groups and oxygen-containing sites on the fiber surface. Furthermore, the polarization induced by the strong polar BPEN structure contributes to effective EMI performance.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"28 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145007342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanotwin-assisted dynamic recrystallization achieves high strength and ductility in nanocrystalline CrMnFeCoNi high entropy alloy 纳米孪晶辅助动态再结晶使纳米晶crmnnfeconi高熵合金具有较高的强度和延展性
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-06 DOI: 10.1016/j.jmst.2025.07.068
Junnan Jiang, Fan Zhang, Shuangxi Song, Hao Du, Pan Liu
{"title":"Nanotwin-assisted dynamic recrystallization achieves high strength and ductility in nanocrystalline CrMnFeCoNi high entropy alloy","authors":"Junnan Jiang, Fan Zhang, Shuangxi Song, Hao Du, Pan Liu","doi":"10.1016/j.jmst.2025.07.068","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.07.068","url":null,"abstract":"Nanocrystalline (NC) high entropy alloys (HEAs) possess superior strength but often exhibit poor ductility due to suppressed dislocation activity and limited strain hardening. Dynamic recrystallization (DRX) has been recognized as an effective mechanism to improve plasticity and strength in coarse-grained materials. However, its activation in NC HEAs at room temperature is typically constrained by insufficient thermal activation and the requirement for extremely high local strains. In this work, a high density of pre-existing nanotwins was introduced into NC CrMnFeCoNi HEA to facilitate DRX through a nanotwin-assisted dynamic recrystallization (ntDRX) mechanism during deformation. The alloy, fabricated by magnetron sputtering, exhibits a single-phase face-centered cubic (FCC) structure with columnar grains of approximately 60 nm. Micropillar compression tests demonstrate a high yield strength of 2.3 GPa and a compressive strain exceeding 40%. During deformation, in addition to dislocation slip and grain boundary (GB) activities, DRX is activated within shear bands, leading to the formation of equiaxed nanograins. These newly formed grains increase interface density, impede dislocation motion, and elevate the flow stress to 2.75 GPa. Additionally, the newly formed GBs of equiaxed grains facilitate GB-mediated deformation at large strains, improving plasticity and suppressing shear localization. Furthermore, tensile experiments reveal two interconnected ntDRX mechanisms. One involves dislocation accumulation at twin boundaries (TBs) leading to subgrain formation through dislocation rearrangement and its evolution into high-angle grain boundaries (HAGBs), while the other involves the direct transformation of coherent TBs into HAGBs through dislocation interactions. This study advances the understanding of room-temperature DRX in NC HEAs and highlights nanotwin engineering as a promising strategy for optimizing mechanical performance.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"25 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145003435","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interfacial regulation of aluminum-air batteries by biomass carbon quantum dots: Corrosion inhibition and electrochemical enhancement 生物质碳量子点对铝-空气电池界面的调控:缓蚀和电化学增强
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-06 DOI: 10.1016/j.jmst.2025.08.029
Yusheng Li, Ziyang Guo, Wenyue Zhang, Seeram Ramakrishna, Yujie Qiang
{"title":"Interfacial regulation of aluminum-air batteries by biomass carbon quantum dots: Corrosion inhibition and electrochemical enhancement","authors":"Yusheng Li, Ziyang Guo, Wenyue Zhang, Seeram Ramakrishna, Yujie Qiang","doi":"10.1016/j.jmst.2025.08.029","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.08.029","url":null,"abstract":"Alkaline aluminum-air batteries (AABs) are promising candidates for next-generation energy storage technologies owing to their exceptional energy density, low cost, and inherent safety. However, their practical deployment is hindered by severe self-corrosion of the aluminum anode, leading to performance degradation and a shortened operational lifespan. Here, carbon quantum dots derived from Sophora japonica leaves (SCDs) are innovatively employed as electrolyte additives in alkaline AABs to improve anode corrosion resistance and achieve high-performance output. Corrosion evaluation reveals that 0.2 g L<sup>−1</sup> SCDs effectively modulate the interfacial stability of the anode, achieving a corrosion inhibition efficiency of 41.5%. Moreover, incorporating SCDs enables AABs to achieve a high anode utilization of 51.7%, with a specific capacity of 1538.5 mAh g<sup>−1</sup> and an energy density of 1800 Wh kg<sup>−1</sup>, markedly surpassing the additive-free counterpart. A detailed mechanistic analysis indicates that SCDs form a stable, parallel-configured adsorption film on the Al surface, which modulates Al dissolution and enhances interfacial integrity, thereby facilitating more controlled battery reactions. This work offers new insights into the selection of AABs additives and reveals the interaction of carbon quantum dots with the Al surface on a molecular/atomic scale.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"40 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145003436","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electron beam powder bed fusion of Ti–6Al–4V: Augmenting mechanical properties with low porosity and fine microstructure 电子束粉末床熔合Ti-6Al-4V:提高低孔隙率和微结构的力学性能
IF 10.9 1区 材料科学
Journal of Materials Science & Technology Pub Date : 2025-09-05 DOI: 10.1016/j.jmst.2025.07.067
Chao Xiang Ngiam, Zhiheng Hu, Beng Loon Aw, Zhili Dong, Kun Zhou, Pan Wang
{"title":"Electron beam powder bed fusion of Ti–6Al–4V: Augmenting mechanical properties with low porosity and fine microstructure","authors":"Chao Xiang Ngiam, Zhiheng Hu, Beng Loon Aw, Zhili Dong, Kun Zhou, Pan Wang","doi":"10.1016/j.jmst.2025.07.067","DOIUrl":"https://doi.org/10.1016/j.jmst.2025.07.067","url":null,"abstract":"Electron beam powder bed fusion (PBF-EB) is a distinct class of additive manufacturing technique, capable of fabricating high-strength material, such as Ti–6Al–4V. Precise control of the process parameters plays a fundamental role in achieving the desired characteristics and process optimization has been extensively studied. However, discrepancies persist in the optimization of PBF-EB printed Ti–6Al–4V due to variations in machine configurations, study scopes, and parameter combinations. To address this issue, we herein investigate the individual effects of key parameters-scan speed, line offset, focus offset, and preheating temperature-on surface morphology, porosity, microstructure, and mechanical properties. While focus offset had a limited impact on the microstructure, increasing scan speed or line offset, thus decreasing the energy density, led to a refined microstructure and improved microhardness. However, excessive scan speed, line offset, or focus offset led to insufficient bonding, which compromised the tensile properties. In contrast, reducing scan speed and line offset, thus increasing the energy density, ensured sufficient fusion but yielded a coarse microstructure, which diminishes hardness and tensile strength. The lowest scan speed caused surface distortion and large spherical pores. These results culminated in a process map, which expounded the intricate relationships between the parameters in PBF-EB. These findings not only facilitated the optimization process to achieve fine microstructure and low porosity but may also serve as an anchoring framework for developing new material systems.","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":"83 1","pages":""},"PeriodicalIF":10.9,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144996023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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