Journal of Food Composition and Analysis最新文献

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Voltammetric methods to quantify hazardous elements (Ni, Pb and Cd) in chocolate and cacao products 用伏安法定量巧克力和可可制品中有害元素(Ni、Pb和Cd)
IF 4 2区 农林科学
Journal of Food Composition and Analysis Pub Date : 2025-04-23 DOI: 10.1016/j.jfca.2025.107682
Diana Amorello , Salvatore Barreca , Francesca Gioè , Santino Orecchio , Silvia Orecchio
{"title":"Voltammetric methods to quantify hazardous elements (Ni, Pb and Cd) in chocolate and cacao products","authors":"Diana Amorello ,&nbsp;Salvatore Barreca ,&nbsp;Francesca Gioè ,&nbsp;Santino Orecchio ,&nbsp;Silvia Orecchio","doi":"10.1016/j.jfca.2025.107682","DOIUrl":"10.1016/j.jfca.2025.107682","url":null,"abstract":"<div><div>This study focuses on optimizing voltammetric methods to quantify three elements of toxicological interest (lead, cadmium and nickel) in 52 chocolate and cocoa-based products. Using microwave-assisted mineralization followed by anodic re-dissolution and differential pulse voltammetry, the methods demonstrated high sensitivity, precision, and low cost-efficiency for detecting trace metals in complex food matrices. Ni was the most abundant element followed by Pb and Cd. Results revealed Ni exceeds legal limits in over 50 % of samples. While concentrations of Cd were generally compliant with regulations, Pb levels surpassed legal limits in certain dark chocolate samples. The Ni concentration varies between the limit of quantification (23 μg kg<sup>−1</sup>) and 12100 μg kg<sup>−1</sup> with an average of 2064 μg kg<sup>−1</sup>. It is present in higher concentrations (8500–12100 μg kg<sup>−1</sup>) in three samples of white chocolate. A dark chocolate cream produced by a famous industry, shows the highest concentration. Cadmium in the analysed samples is the element having the lowest concentrations. It is present in the range between the limit of quantification (37 μg kg<sup>−1</sup>) and 610 μg kg<sup>−1</sup> with an average of 63 μg kg<sup>−1</sup>. The highest concentration was quantified in a gianduia chocolate.</div></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":"144 ","pages":"Article 107682"},"PeriodicalIF":4.0,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143873932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hazardous chemicals in extruded food: A comprehensive review of their occurrence, detection, toxicity, and mitigation strategies 挤压食品中的有害化学物质:对其发生、检测、毒性和缓解策略的全面审查
IF 4 2区 农林科学
Journal of Food Composition and Analysis Pub Date : 2025-04-23 DOI: 10.1016/j.jfca.2025.107685
Oladapo Ajala , Oluwasola Abayomi Adelusi , Joseph Oghenewogaga Owheruo , Adewale Olusegun Obadina
{"title":"Hazardous chemicals in extruded food: A comprehensive review of their occurrence, detection, toxicity, and mitigation strategies","authors":"Oladapo Ajala ,&nbsp;Oluwasola Abayomi Adelusi ,&nbsp;Joseph Oghenewogaga Owheruo ,&nbsp;Adewale Olusegun Obadina","doi":"10.1016/j.jfca.2025.107685","DOIUrl":"10.1016/j.jfca.2025.107685","url":null,"abstract":"<div><div>The extrusion process is a widely utilized food processing technique that involves forcing a mixture of ingredients through a perforated plate or die under high pressure and temperature. This method not only shapes the food but also induces significant structural changes in its components, leading to various nutritional benefits. Despite the nutritional attributes of extruded food products, the extrusion process is known to produce hazardous chemicals such as polycyclic aromatic hydrocarbons (PAHs), acrylamide, furan, and heterocyclic aromatic amines (HCAs). These compounds, formed due to high temperatures and complex chemical reactions, pose significant health risks due to their carcinogenic and toxic properties. This review paper comprehensively examines the nutritional benefits of extruded food samples. It also highlights the occurrence and mechanism of the formation of certain chemicals in extruded samples during the extrusion process. Advanced analytical techniques, including gas chromatography-mass spectrometry (GC-MS), high-performance liquid chromatography (HPLC), and liquid chromatography-tandem mass spectrometry (LC-MS/MS), are discussed for their efficacy in identifying and quantifying these compounds in extruded food. Furthermore, the paper explores the toxicity profiles of PAHs, acrylamide, furan, and HCAs, emphasizing their health impacts. Mitigation strategies are critically reviewed, highlighting approaches such as optimizing extrusion parameters, improving material selection, and employing post-extrusion treatments. Additionally, the importance of real-time monitoring systems and the potential of innovative non-thermal processing techniques are evaluated. This review underscores the necessity of integrated strategies to minimize the formation of hazardous chemicals during extrusion, ensuring extruded product safety and consumer health. Through continued research and technological advancements, the extrusion industry can enhance its practices to mitigate these risks effectively.</div></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":"144 ","pages":"Article 107685"},"PeriodicalIF":4.0,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143873928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Species-specific preferences vs. soil composition impact – interplay in bioaccumulation of elements in edible mycorrhizal mushrooms 物种特异性偏好与土壤成分影响-食用菌根蘑菇中元素生物积累的相互作用
IF 4 2区 农林科学
Journal of Food Composition and Analysis Pub Date : 2025-04-22 DOI: 10.1016/j.jfca.2025.107662
Sylwia Budzyńska , Patrycja Mleczek , Marek Siwulski , Przemysław Niedzielski , Anna Budka , Natalia Kuczyńska-Kippen , Jędrzej Proch , Július Árvay , Małgorzata Szostek , Mirosław Mleczek
{"title":"Species-specific preferences vs. soil composition impact – interplay in bioaccumulation of elements in edible mycorrhizal mushrooms","authors":"Sylwia Budzyńska ,&nbsp;Patrycja Mleczek ,&nbsp;Marek Siwulski ,&nbsp;Przemysław Niedzielski ,&nbsp;Anna Budka ,&nbsp;Natalia Kuczyńska-Kippen ,&nbsp;Jędrzej Proch ,&nbsp;Július Árvay ,&nbsp;Małgorzata Szostek ,&nbsp;Mirosław Mleczek","doi":"10.1016/j.jfca.2025.107662","DOIUrl":"10.1016/j.jfca.2025.107662","url":null,"abstract":"<div><div>Soil characteristics and species identity are two important predictors of the mineral composition of wild-growing mushrooms. Identifying the key influencing factors is crucial. Therefore, this study aimed to explore the bioaccumulation of 18 elements (Ag, As, Ba, Ca, Cd, Co, Cu, Fe, Hg, K, Mg, Mn, Mo, Na, Ni, Pb, Se, Zn) in 7 edible mycorrhizal mushroom species (<em>Ampulloclitocybe clavipes</em>, <em>Cantharellus cibarius</em>, <em>Laccaria amethystina</em>, <em>Leccinum scabrum</em>, <em>Sarcodon imbricatus</em>, <em>Tricholoma equestre</em>, and <em>Xerocomus subtomentosus</em>) from the corresponding soils beneath their fruiting bodies. The soil characteristics (pH, SOC, N, C:N, sand/soil/clay percentage, and granulometric group) were also analyzed. The study revealed that similarities in soil mineral composition did not consistently translate to corresponding elemental content in mushroom fruiting bodies, indicating that species-specific factors may have a more significant role in elemental bioaccumulation than soil composition. Certain species, such as <em>A. clavipes</em> (Ag, Cu, Hg, Mo, Pb, Se), <em>L. amethystina</em> (As), and <em>T. equestre</em> (Na, Zn), displayed higher selectivity in bioaccumulating specific elements. All species effectively accumulated Cu, K, and Zn while excluding elements like Ba, Fe, Mn, and Pb. The species provided substantial levels of K, Cu, and Se, contributing up to 22.8, 52.5, and 42.4 % of the calculated Adequate Intake, respectively, with minimal health risks from Hg and Pb. These results suggest that mushroom species may play a pivotal role in element migration and cycling within forest ecosystems, affecting soil chemistry and plant uptake. Further research is needed to investigate the broader ecological implications.</div></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":"144 ","pages":"Article 107662"},"PeriodicalIF":4.0,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143869778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Carbon isotope ratios in honey and proteins: A novel method for regional differentiation 蜂蜜和蛋白质中的碳同位素比率:一种区域分化的新方法
IF 4 2区 农林科学
Journal of Food Composition and Analysis Pub Date : 2025-04-22 DOI: 10.1016/j.jfca.2025.107676
Hülya Güçlü , Pelin Yücel , Okan Oktar , Nizamettin Yazıcı , Sema Bilge Ocak
{"title":"Carbon isotope ratios in honey and proteins: A novel method for regional differentiation","authors":"Hülya Güçlü ,&nbsp;Pelin Yücel ,&nbsp;Okan Oktar ,&nbsp;Nizamettin Yazıcı ,&nbsp;Sema Bilge Ocak","doi":"10.1016/j.jfca.2025.107676","DOIUrl":"10.1016/j.jfca.2025.107676","url":null,"abstract":"<div><div>This study examines honey samples to determine their regional differences using carbon isotope values and to investigate the correlation between honey and the protein isolated from the honey utilizing regression analysis. For the analyses, 196 honey samples were collected from 56 cities in Türkiye in collaboration with the Turkish Honey Producers Association.</div><div>One-way analysis of variance, followed by Tukey-Kramer post-hoc and independent t-tests, revealed statistically significant differences in δ¹ ³C isotope ratios among regions (p &lt; 0.05). Based on these results, seven geographical regions in Türkiye were categorized into three distinct groups: Group A (Southeastern Anatolia Region, Eastern Anatolia Region, Central Anatolia Region), Group B (Black Sea Region, Marmara Region, Aegean Region), and Group C (Mediterranean Region). Characterized by the lowest mean δ¹ ³C values, the Mediterranean Region was significantly differentiated from others and classified independently as Group C. On the other hand, Group A was found to have the highest mean δ¹ ³C values.</div><div>A regression analysis was conducted to examine the relationship between the carbon isotope values of honey and its protein content, yielding a high regression coefficient. The regression analysis suggested a strong positive correlation between the carbon isotope ratios of honey and protein content across different regions.</div><div>The analysis results indicate that the combination of carbon isotope ratio analysis and statistical methods may be a highly effective approach for determining the geographical origin of honey.</div></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":"144 ","pages":"Article 107676"},"PeriodicalIF":4.0,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143873930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative analysis of microgreens and germinated seeds from three Brassicaceae cultivars: Macro- and micro-nutrient and glucosinolate composition 3个芸苔科品种微芽和发芽种子的比较分析:宏量和微量营养及硫代葡萄糖苷组成
IF 4 2区 农林科学
Journal of Food Composition and Analysis Pub Date : 2025-04-22 DOI: 10.1016/j.jfca.2025.107673
Maharshi Bhaswant , Taiki Miyazawa , Chizumi Abe , Ritsuko Fukasawa , Ohki Higuchi , Teruo Miyazawa
{"title":"Comparative analysis of microgreens and germinated seeds from three Brassicaceae cultivars: Macro- and micro-nutrient and glucosinolate composition","authors":"Maharshi Bhaswant ,&nbsp;Taiki Miyazawa ,&nbsp;Chizumi Abe ,&nbsp;Ritsuko Fukasawa ,&nbsp;Ohki Higuchi ,&nbsp;Teruo Miyazawa","doi":"10.1016/j.jfca.2025.107673","DOIUrl":"10.1016/j.jfca.2025.107673","url":null,"abstract":"<div><div>The <em>Brassicaceae</em> family is one of the most widely consumed plant groups, with increasing popularity for its microgreens and germinated seeds. However, comprehensive nutritional data on these stages of plant development remain limited. To address this gap, we analyzed and compared the nutritional compositions of three <em>Brassicaceae</em> cultivars—red cabbage, kaiware daikon, and broccoli—at the microgreen and germinated seed stages. We hypothesized that, in comparison to their antecedents, microgreens would have higher concentrations of nutrients and bioactive molecules. Rather, our results show that microgreens have a wide range of very high micronutrient concentrations, while germinated seeds have significantly greater macronutrients, glucosinolates, and minerals. Our study provides a reference index for future research, particularly in the biofortification of microgreens through the use of various growing media and elicitors. These findings not only deepen the understanding of the nutritional potential of <em>Brassicaceae</em> cultivars but also highlight the distinct contributions of both microgreens and germinated seeds to human nutrition. This knowledge is essential for consumers, growers, and researchers to optimize the health benefits of these plant stages.</div></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":"144 ","pages":"Article 107673"},"PeriodicalIF":4.0,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143883114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Method development for quantification of iodine in food for special medical purposes (FSMP) after microextraction by Bi-SBA-15 based matrix solid-phase dispersion Bi-SBA-15基基质固相分散微萃取法测定特殊医用食品中碘含量方法的建立
IF 4 2区 农林科学
Journal of Food Composition and Analysis Pub Date : 2025-04-22 DOI: 10.1016/j.jfca.2025.107674
Baorui Li, Jingya Qin, Qian Li, Xiuxiu Wang, Aizhen Zong, Fangling Du, Tongcheng Xu
{"title":"Method development for quantification of iodine in food for special medical purposes (FSMP) after microextraction by Bi-SBA-15 based matrix solid-phase dispersion","authors":"Baorui Li,&nbsp;Jingya Qin,&nbsp;Qian Li,&nbsp;Xiuxiu Wang,&nbsp;Aizhen Zong,&nbsp;Fangling Du,&nbsp;Tongcheng Xu","doi":"10.1016/j.jfca.2025.107674","DOIUrl":"10.1016/j.jfca.2025.107674","url":null,"abstract":"<div><div>In this study, bismuth (Bi)-embedded SBA-15 mesoporous silica was synthesized, characterized and used as adsorbent for matrix solid phase dispersion (MSPD) of iodine in whole nutritional formula foods, subsequently determined by inductively coupled plasma mass spectrometry (ICP-MS). The experimental conditions for the MSPD were firstly investigated, utilizing a mass ratio of sample to Bi-SBA-15 at 3:3, with 200 mM [C12mim]Br as the elution solvent and a grinding time of 2 min. Meanwhile, interference studies revealed that the presence of cations (K<sup>+</sup>, Na<sup>+</sup>, Ca<sup>2+</sup>) could significantly decrease the analytical signal, prompting the implementation of a cation-exchange procedure. Under optimum experimental conditions, analytical performance of Bi-SBA-15 based MSPD-ICP-MS for iodine detection was evaluated in terms of limit of detection (LOD) and limit of quantification (LOQ), which was 0.03 μg/kg and 0.21 μg/kg respectively. To evaluate the accuracy and applicability of this method, a recovery study was conducted on commercial foods for special medical purposes (FSMP), with recoveries ranging from 95.5 % to 106 %. Therefore, the application of SBA-15 based matrix solid-phase dispersion would attract significant attention for separation and preconcentration of total iodine in complex food samples such as foods for special medical purposes (FSMP).</div></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":"144 ","pages":"Article 107674"},"PeriodicalIF":4.0,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143869780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Immobilisation of esterase purified from mung bean (Vigna radiata L. Wilczek) onto chitosan/glutaraldehyde/glycine and its application in bi-enzyme colorimetric assay for dichlorvos detection 壳聚糖/戊二醛/甘氨酸固定化绿豆酯酶及其在双酶比色法检测敌敌畏中的应用
IF 4 2区 农林科学
Journal of Food Composition and Analysis Pub Date : 2025-04-22 DOI: 10.1016/j.jfca.2025.107665
Jue Li , Hao Liu , Mahila Ablikm , Haoran Yuan , Huiqin Liu , Qingfeng He
{"title":"Immobilisation of esterase purified from mung bean (Vigna radiata L. Wilczek) onto chitosan/glutaraldehyde/glycine and its application in bi-enzyme colorimetric assay for dichlorvos detection","authors":"Jue Li ,&nbsp;Hao Liu ,&nbsp;Mahila Ablikm ,&nbsp;Haoran Yuan ,&nbsp;Huiqin Liu ,&nbsp;Qingfeng He","doi":"10.1016/j.jfca.2025.107665","DOIUrl":"10.1016/j.jfca.2025.107665","url":null,"abstract":"<div><div>Reliable methods for detecting organophosphorus pesticides (OPs) are urgently demanded to guarantee food safety. Herein, a purified alpha-naphthyl acetate esterase from mung bean (mANAE) was prepared and successfully immobilized on the functionalized chitosan (CTS)-glutaraldehyde(GA)-glycine(Gly). Superior to free enzymes, the immobilized enzyme exhibited more excellent surface morphology characteristics, pH and temperature stability, higher affinity to α-naphthol acetate (1-NA). Furthermore, a new colorimetric method was firstly developed by using the immobilized mANAE (I-mANAE) and hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>)/horse radish peroxidase (HRP)/3,3′,5,5′-tetramethylbenzidine (TMB) color system. This method gives an associated response of inhibition ratio that is linearly proportional to the concentrations (10–100 ng/mL) of dichlorvos (DDVP), with a low limit of detection (1.32 ng/mL). Moreover, the performance of the method was challenged for DDVP detection in real agricultural products (cabbage, tomato and jujube) with excellent recoveries. The results indicated the advantages of the constructed method (strong stability, low cost, high sensitivity, ease of visual identification), which provide a promising alternative for the screening of OPs in foods.</div></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":"144 ","pages":"Article 107665"},"PeriodicalIF":4.0,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143873929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development and feasibility of a 24-hour recall software to characterize the Chilean diet 24小时召回软件的开发和可行性,以表征智利饮食
IF 4 2区 农林科学
Journal of Food Composition and Analysis Pub Date : 2025-04-22 DOI: 10.1016/j.jfca.2025.107660
Maria F. Mujica-Coopman , Angela Martínez-Arroyo , Natalia Rebolledo , Daiana Quintiliano-Scarpelli , Marcela Reyes
{"title":"Development and feasibility of a 24-hour recall software to characterize the Chilean diet","authors":"Maria F. Mujica-Coopman ,&nbsp;Angela Martínez-Arroyo ,&nbsp;Natalia Rebolledo ,&nbsp;Daiana Quintiliano-Scarpelli ,&nbsp;Marcela Reyes","doi":"10.1016/j.jfca.2025.107660","DOIUrl":"10.1016/j.jfca.2025.107660","url":null,"abstract":"<div><div>Dietary assessment is critical for tracking nutritional improvements, especially among vulnerable groups. However, the availability of local software to collect dietary information using a standardized approach is limited. We documented the development of the 24-hour recall software (SER-24H) designed to collect locally based information on dietary intake and food habits, and 2) the experience of its use. The SER-24H collects dietary intake information from participants in Chilean cohorts. The development of the SER-24H involved: 1) organizing the food and recipe database, 2) linking foods to nutrient content databases, and 3) converting to portion sizes. In addition, a pilot study was conducted with Chilean dietitians (n = 73) to explore their experience of using the SER-24H. The SER-24H contains &gt; 7000 food items and &gt; 1400 culturally based recipes. Benefits of using the SER-24H include the availability of locally relevant foods, estimation of food intake for each meal and nutrient sources. Dietitians found the SER-24H easy to use and useful. However, registering new foods was a challenge. Our work showed that developing locally based dietary intake software is feasible, but not without challenges. Given the current epidemic of diet-related chronic non-communicable diseases, the development of this type of data collection tool is imperative.</div></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":"144 ","pages":"Article 107660"},"PeriodicalIF":4.0,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143883113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Co-doped Bi2MoO6 lattice distortion strategy-based photoelectrochemical sensors for highly sensitive detection of profenofos residues in milk and cabbage 基于共掺杂Bi2MoO6晶格畸变策略的电化学传感器用于高灵敏度检测牛奶和卷心菜中丙诺威残留量
IF 4 2区 农林科学
Journal of Food Composition and Analysis Pub Date : 2025-04-22 DOI: 10.1016/j.jfca.2025.107675
Jia Wei , Yi Zhang , Wangui Peng , Weihong Huang , Yunfei Cao , Wenming Yang , Wanzhen Xu
{"title":"Co-doped Bi2MoO6 lattice distortion strategy-based photoelectrochemical sensors for highly sensitive detection of profenofos residues in milk and cabbage","authors":"Jia Wei ,&nbsp;Yi Zhang ,&nbsp;Wangui Peng ,&nbsp;Weihong Huang ,&nbsp;Yunfei Cao ,&nbsp;Wenming Yang ,&nbsp;Wanzhen Xu","doi":"10.1016/j.jfca.2025.107675","DOIUrl":"10.1016/j.jfca.2025.107675","url":null,"abstract":"<div><div>Pesticide residues in food pose significant risks to human health, necessitating accurate monitoring methods. To address this, a lattice distortion strategy-based highly sensitive photoelectrochemical (PEC) sensor was developed for profenofos (PFF) detection. Substitution of Bi<sup>3 +</sup> with Co<sup>2+</sup> in the Bi<sub>2</sub>MoO<sub>6</sub> lattice induced enhanced lattice distortions and oxygen vacancies, reducing the bandgap and dramatically improving visible-light absorption and charge transfer efficiency. These modifications synergistically boosted PEC performance, with 4 % Co-doped Bi<sub>2</sub>MoO<sub>6</sub> achieving optimal results, including a reduced narrowed bandgap (2.28 eV) and a significantly enhanced photocurrent density compared to pristine Bi<sub>2</sub>MoO<sub>6</sub>. The sensor exhibited a broad linear detection range (0.5 mg L<sup>−1</sup> to 0.01 ng L<sup>−1</sup>) and an ultralow detection limit of 3.3 pg L<sup>−1</sup>, demonstrating excellent sensitivity and selectivity in real food samples. This work presents an innovative efficient, non-toxic, and eco-friendly tool for pesticide residue detection, paving new avenues for food safety monitoring and public health protection.</div></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":"144 ","pages":"Article 107675"},"PeriodicalIF":4.0,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143864265","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Detection of Salmonella in food by SG4MB/SRCA based colorimetric biosensor 基于SG4MB/SRCA的比色生物传感器检测食品中沙门氏菌
IF 4 2区 农林科学
Journal of Food Composition and Analysis Pub Date : 2025-04-22 DOI: 10.1016/j.jfca.2025.107677
Xiaoxuan Wang , Yunzhe Zhang , Hui Di , Congyan Qi , Hui Xu , Xin Lu , Guoqiang Shi , Shumei Cheng , Wei Zhang
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