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Reactor design and process optimization in chemical looping combustion: Insights into fuel types, oxygen carriers, and process design 化学环燃烧中的反应器设计和工艺优化:洞察燃料类型、氧载体和工艺设计
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-04-08 DOI: 10.1016/j.jece.2025.116561
Raghvendra Kumar Gupta , Krish Jain , Hari Govind , Natarajan Rajamohan , Iyman Abrar
{"title":"Reactor design and process optimization in chemical looping combustion: Insights into fuel types, oxygen carriers, and process design","authors":"Raghvendra Kumar Gupta ,&nbsp;Krish Jain ,&nbsp;Hari Govind ,&nbsp;Natarajan Rajamohan ,&nbsp;Iyman Abrar","doi":"10.1016/j.jece.2025.116561","DOIUrl":"10.1016/j.jece.2025.116561","url":null,"abstract":"<div><div>Chemical looping combustion (CLC) is a novel technique developed for inherent carbon capture and storage (CCS). CLC utilizes an oxygen carrier (OC) to transport oxygen to the fuel for combustion, hence making the process oxy-fuel combustion. This article aims to review the process of CLC in terms of improving carbon capture efficiency and fuel conversion by studying the reaction mechanism, effect of temperature and pressure, and the effect of reactivity of OC towards fuel. The applications of several reactors, including fluidized bed reactor, have been discussed with reference to the operating conditions employed. The quantitative findings reported in various studies proved the efficient performance of copper based carriers achieving efficiency as high as 93 % when the gasification temperature was 930°C. Fuel conversion efficiencies reach 89–93.5 % for solid fuels like pine sawdust with Cu-based carriers, and up to 100 % for liquid fuels like glycerin and propane using metallic and nickel-based oxygen carriers, respectively. Carbon capture efficiencies vary, with pet coke achieving 97 % using ilmenite and Mn-based carriers.The energy duty for CLC is estimated at 0.3 GJ/tCO₂, with studies showing a 6 % reduction in CAPEX and a 14 % drop in OPEX compared to amine-based absorption. Future scope and challenges to be addressed in the chemical looping studies are identified.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 3","pages":"Article 116561"},"PeriodicalIF":7.4,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143820488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Plastic pollutants: From wastes to fuels and high-value chemicals 塑料污染物:从废物到燃料和高价值化学品
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-04-08 DOI: 10.1016/j.jece.2025.116562
Komal Poonia , Duc Anh Dinh , Pardeep Singh , Tansir Ahamad , Sourbh Thakur , Pankaj Raizada , Huy Hoang Phan Quang , Aftab Aslam Parwaz Khan , Van-Huy Nguyen
{"title":"Plastic pollutants: From wastes to fuels and high-value chemicals","authors":"Komal Poonia ,&nbsp;Duc Anh Dinh ,&nbsp;Pardeep Singh ,&nbsp;Tansir Ahamad ,&nbsp;Sourbh Thakur ,&nbsp;Pankaj Raizada ,&nbsp;Huy Hoang Phan Quang ,&nbsp;Aftab Aslam Parwaz Khan ,&nbsp;Van-Huy Nguyen","doi":"10.1016/j.jece.2025.116562","DOIUrl":"10.1016/j.jece.2025.116562","url":null,"abstract":"<div><div>Every year, a large number of plastic products are used extensively and discarded worldwide, causing severe plastic pollution that contaminates the soil, air, and water supplies. While solar energy can help in the sustainable degradation of plastics, the process takes time and releases harmful chemicals that contaminate the food and water cycles. This review examines existing conventional methods and emerging processes for solar-driven catalytic plastic degradation. Conventional methods, such as pyrolysis, catalytic cracking, hydrogenolysis, and electrocatalysis, are discussed, focusing on the requirement for a more sustainable approach. In particular, this review highlights how the catalytic potential can be enhanced by activating chemical bonds to yield value-added products by photocatalytic upcycling under moderate circumstances. Photocatalytic upcycling, as a sustainable approach, has been explored for hydrogen production and the production of value-added chemicals using the waste plastic substrate, signifying “treasure from trash”. The key obstacles to the uptake and expansion of these technologies are identified, along with recommendations for future research directions to improve the effectiveness of upcycling techniques.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 3","pages":"Article 116562"},"PeriodicalIF":7.4,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143820491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical Sensors for Monitoring Water Quality: Recent Advances in Graphene Quantum Dot-based Materials for the Detection of Toxic Heavy Metal Ions Cd(II), Pb(II) and Hg(II) with their Mechanistic Aspects 用于监测水质的电化学传感器:用于检测有毒重金属离子Cd(II)、Pb(II)和Hg(II)的石墨烯量子点材料及其机理的最新进展
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-04-07 DOI: 10.1016/j.jece.2025.116545
S. Saisree, Arya S. Nair, Elsa Dais, K.Y Sandhya
{"title":"Electrochemical Sensors for Monitoring Water Quality: Recent Advances in Graphene Quantum Dot-based Materials for the Detection of Toxic Heavy Metal Ions Cd(II), Pb(II) and Hg(II) with their Mechanistic Aspects","authors":"S. Saisree,&nbsp;Arya S. Nair,&nbsp;Elsa Dais,&nbsp;K.Y Sandhya","doi":"10.1016/j.jece.2025.116545","DOIUrl":"10.1016/j.jece.2025.116545","url":null,"abstract":"<div><div>In this review, we discuss the current state of the art of electrochemical (EC) sensors based on graphene quantum dot (GQD)-based materials for the detection of heavy metal ions (HMIs), Cd(II), Pb(II), and Hg(II). The majority of the water sources are polluted with HMIs according to WHO, and UNEP. Because of its widespread nature and high toxicity even at very low concentrations and bio accumulative properties, it is imperative to monitor and measure the concentrations of the HMIs in water sources for a safe and healthy environment. Among other HMIs, Cd(II), Pb(II), and Hg(II) bagged much attention in the research field due to its high toxicity, environmental persistence, and significant health hazards, even at trace levels and hence they are listed in the top ten highly toxic species by WHO. Thus, the EC Sensing of Cd(II), Pb(II), and Hg(II) become more prevalent in water quality monitoring. Herein, we discuss the recent advances in GQD-based EC sensors for HMIs with focus on the sensors for Cd(II), Pb(II), and Hg(II). We have further conceptualized the mechanism involved in the EC sensing. In brief, this review, we started off by emphasizing the necessity of water quality monitoring, followed by the significance of employing EC sensing in water quality assessment and the available GQD sensors in the detection of Cd(II), Pb(II), and Hg(II). The review is concluded with a detailed and critical analysis of the mechanism involved in the EC sensing process and its future perspectives.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 3","pages":"Article 116545"},"PeriodicalIF":7.4,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143800651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review of the metabolic response of the anammox process to biochar carriers: Performance impacts and mechanisms Anammox 过程对生物炭载体的新陈代谢反应综述:性能影响和机制
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-04-07 DOI: 10.1016/j.jece.2025.116536
Menghan Wang , Jiajia Xu , Chenyu Xia , Weihua Li
{"title":"A review of the metabolic response of the anammox process to biochar carriers: Performance impacts and mechanisms","authors":"Menghan Wang ,&nbsp;Jiajia Xu ,&nbsp;Chenyu Xia ,&nbsp;Weihua Li","doi":"10.1016/j.jece.2025.116536","DOIUrl":"10.1016/j.jece.2025.116536","url":null,"abstract":"<div><div>Anaerobic ammonium oxidation (Anammox), as an efficient biological nitrogen removal process, has been engineered and applied in the field of side-stream wastewater. Inhibition of nitrite-oxidizing bacteria (NOB) and lack of biomass for anaerobic ammonia oxidation are the core barriers to the scale-up of mainstream PN-A technology. In recent years, biochar has shown broad application prospects in the mainstream anammox field due to its unique ability to reduce nitrates. This review systematically summarizes the role of biochar carriers under different feedstocks and production conditions for the promotion of nitrogen removal performance in anammox reactors and the effective mitigation of pollutant inhibition, and further analyzes the possible mechanisms of action involved in terms of metabolic changes at the microbial molecular level. The structure of biochar optimizes the survival environment of anaerobic ammonium oxidation bacteria (AnAOB), promotes the activity and gene expression of functional bacteria, and synergizes with partial denitrification and anaerobic ammonia oxidation to achieve the degradation of nitrate and the stable supply of nitrite, which enhances the efficiency of anammox for nitrogen removal. In addition, the potential risks of biochar to the environment are summarized, and risk aversion measures are given to promote the anammox reaction and promote the friendly development of the environment. This indicates that the future biochar anammox process can be carried out in the direction of research on biochar harmlessness, compositing and modification strategies, to provide a theoretical basis for biochar in the mainstream anammox.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 3","pages":"Article 116536"},"PeriodicalIF":7.4,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143817774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review on conductive polymers-modified TiO2 photocatalyst for environmental remediation 导电聚合物修饰TiO2光催化剂在环境修复中的研究进展
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-04-06 DOI: 10.1016/j.jece.2025.116518
Kaipeng Sun , Chao Zhang , Chuanxi Yang , Xiaoning Wang , Ziheng Wan , Erling Zhao , Yihua Xiao , Weihua Zhao , Mingliang Ma , Dong Chen , Feng Dang , Changqing Liu , Weiliang Wang , Haofen Sun
{"title":"A review on conductive polymers-modified TiO2 photocatalyst for environmental remediation","authors":"Kaipeng Sun ,&nbsp;Chao Zhang ,&nbsp;Chuanxi Yang ,&nbsp;Xiaoning Wang ,&nbsp;Ziheng Wan ,&nbsp;Erling Zhao ,&nbsp;Yihua Xiao ,&nbsp;Weihua Zhao ,&nbsp;Mingliang Ma ,&nbsp;Dong Chen ,&nbsp;Feng Dang ,&nbsp;Changqing Liu ,&nbsp;Weiliang Wang ,&nbsp;Haofen Sun","doi":"10.1016/j.jece.2025.116518","DOIUrl":"10.1016/j.jece.2025.116518","url":null,"abstract":"<div><div>Titanium dioxide (TiO<sub>2</sub>) has garnered significant research interest in recent years for its application in the photocatalytic degradation of organic matter, owing to its affordability, high chemical stability, and environmental compatibility. However, TiO<sub>2</sub>’s wide band gap (3.0–3.2 eV) and low quantum efficiency (&lt; 20 %) hinder its photocatalytic performance. Conductive polymers (CPs), due to their high electrical conductivity and adjustable band gaps, can enhance the absorption of visible light by TiO<sub>2</sub> and inhibit the recombination of electron-hole pairs, providing a solution to address these limitations. As a result, CPs are widely employed to modify TiO<sub>2</sub>. This paper reviews the most commonly used CPs for TiO<sub>2</sub> modification, such as polyaniline (PANI), polypyrrole (PPy), and polythiophene (PTh), along with typical modification techniques. Studies the photocatalytic mechanism and the mechanism of enhanced photocatalytic activity of CPs-modified TiO<sub>2</sub>, highlighting the roles of photosensitization and the synergistic effects of CPs modification in enhancing photocatalytic efficiency. Discusses the application of CPs-modified TiO<sub>2</sub> in water treatment, and finally looks ahead to the opportunities and challenges faced by the research on CPs-modified TiO<sub>2</sub>.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 3","pages":"Article 116518"},"PeriodicalIF":7.4,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dendrimers as Versatile Platforms for Advanced Biosensor Development: A Review on Chemistry, Synthesis, and Performance Enhancements 树状大分子作为先进生物传感器开发的通用平台:化学、合成和性能增强的综述
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-04-05 DOI: 10.1016/j.jece.2025.116365
Fatemeh Aminian, Alireza Hemmati
{"title":"Dendrimers as Versatile Platforms for Advanced Biosensor Development: A Review on Chemistry, Synthesis, and Performance Enhancements","authors":"Fatemeh Aminian,&nbsp;Alireza Hemmati","doi":"10.1016/j.jece.2025.116365","DOIUrl":"10.1016/j.jece.2025.116365","url":null,"abstract":"<div><div>Dendrimers, with their unique branched, tree-like structures, have emerged as promising materials for enhancing the performance of biosensors. These macromolecules consist of a central core surrounded by several generations of branching units and peripheral functional groups. These structural elements contribute to their exceptional characteristics, including high surface area and a diverse array of functional groups. By integrating various bioreceptors with dendrimers, innovative nanobiosensors can effectively detect low concentrations of target analytes, overcoming the limitations of traditional biosensing technologies. This review discusses the chemistry and synthesis of dendrimers, including divergent and convergent methods, and explores various types of dendrimers such as polyamidoamine (PAMAM), Polypropylene imine (PPI), Poly-I-lysine (PLL), phosphorus dendrimers, and DNA dendrimers. Each type is discussed in terms of its chemical structure, properties, and potential applications. The mechanisms through which dendrimers amplify signal transduction, improve biomolecule immobilization and minimize non-specific adsorption are examined, which result in reduced background noises and enhanced detection sensitivity and selectivity. Furthermore, the potential of combining dendrimers with other nanomaterials, such as nanoparticles (NPs) and carbon-based materials, is considered to further enhance biosensor performance. This work underscores the potential of dendrimers to revolutionize biosensors, paving the way for future research and development in the sensing field.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 3","pages":"Article 116365"},"PeriodicalIF":7.4,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Vertical characteristics of bacterial community and the interaction of dissolved organic matter in sediments of a shallow lake, China 某浅湖沉积物中细菌群落垂直特征及溶解有机质相互作用
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-04-03 DOI: 10.1016/j.jece.2025.116415
Xihuan Wang , Weibo Zhang , Ang Liu , Zhong Jin , Yili Fan , Zeya Zhang , Chenglian Feng , Yingchen Bai
{"title":"Vertical characteristics of bacterial community and the interaction of dissolved organic matter in sediments of a shallow lake, China","authors":"Xihuan Wang ,&nbsp;Weibo Zhang ,&nbsp;Ang Liu ,&nbsp;Zhong Jin ,&nbsp;Yili Fan ,&nbsp;Zeya Zhang ,&nbsp;Chenglian Feng ,&nbsp;Yingchen Bai","doi":"10.1016/j.jece.2025.116415","DOIUrl":"10.1016/j.jece.2025.116415","url":null,"abstract":"<div><div>Bacteria and dissolved organic matter (DOM) play a pivotal role in the biogeochemical cycling of lake sediments. However, the vertical characteristics of bacterial communities in lake sediments and their interactions with DOM remain limited understood. This study focuses on the sediment bacteria of Liangzi Lake, identifying their community structure, key driving factors, and interactions with DOM along a vertical profile (0–120 cm). The dominant phyla in the shallow (0–36 cm), middle (36–72 cm), and deep (72–120 cm) sediments were identified as Chloroflexi and Actinobacterota, Firmicutes and Chloroflexi, and Proteobacteria and Firmicutes, respectively. Pb, Cd, Sb, As, TN (total nitrogen), and TC (total carbon) were the key driving factors of bacterial communities in shallow sediments, while C:N (the ratio of TC to TN), TS (total sulfur), and Cr played a dominant role in shaping bacterial communities in middle sediments. Based on co-occurrence network, shallow sediments showed the highest connectivity between bacterial communities and DOM components, followed by the deep and middle layers. Among them, Chloroflexi and Acidobacteriota exhibited significant interactions with fluorescent components, accounting for over 50 % of the total edges, with the strongest association observed with the tryptophan-like component. In addition, functional groups involved in the C cycle (83.03 %) were the most abundant, especially enriched in the shallow sediments. These results offer a support for understanding geo-microbiological processes and C storage in lacustrine sediment profiles.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 3","pages":"Article 116415"},"PeriodicalIF":7.4,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143800649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in microbubble-based separation technologies for microplastics removal from water 基于微泡的水中微塑料分离技术研究进展
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-04-03 DOI: 10.1016/j.jece.2025.116499
Kaiyu Zhou , Moslem Fattahi , Somasekhara Goud Sontti , Xuehua Zhang
{"title":"Advances in microbubble-based separation technologies for microplastics removal from water","authors":"Kaiyu Zhou ,&nbsp;Moslem Fattahi ,&nbsp;Somasekhara Goud Sontti ,&nbsp;Xuehua Zhang","doi":"10.1016/j.jece.2025.116499","DOIUrl":"10.1016/j.jece.2025.116499","url":null,"abstract":"<div><div>The widespread occurrence of microplastics (MPs) in aquatic environments has raised significant ecological concerns, particularly due to their interactions with coexisting pollutants and potential impact on aquatic ecosystems. Microbubble (MB) flotation has emerged as a low-cost, scalable solution, achieving removal efficiencies of 75–95 % for MPs (50–5000 µm) through tailored bubble size (10– 100 µm) and surface charge optimization. This review systematically examines the physicochemical properties of MPs, their role as pollutant carriers, and recent advancements in CFD-guided MB generation techniques, including the effects of MP aging and aquatic chemistry on separation performance. By synthesizing experimental and computational studies, we highlight how CFD modeling has uncovered critical mechanisms-such as turbulent flow regimes and bubble- MP collision probabilities-that enhance capture efficiency. Furthermore, we discuss innovations in pulsatile flow MB systems and surfactant-free stabilization strategies. This work identifies key gaps in CFD-MB integration, such as multiscale MP heterogeneity and biofilm interactions, and proposes adaptive modeling frameworks to address them. By bridging experimental insights with computational advances, this review summarizes the advantages and limitations of MB-enhanced MP separation and provides the perspective on potential applications after further improvements.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 3","pages":"Article 116499"},"PeriodicalIF":7.4,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143786033","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thin-film nanocomposite membranes for water treatment: Evolution, applications, challenges, and advancement strategies 水处理用薄膜纳米复合膜:发展、应用、挑战和发展策略
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-04-03 DOI: 10.1016/j.jece.2025.116392
Masoud Rahbari-Sisakht , Seyedsaman Mousavian , Mohammad Amin Ariana , Ahmad Fauzi Ismail
{"title":"Thin-film nanocomposite membranes for water treatment: Evolution, applications, challenges, and advancement strategies","authors":"Masoud Rahbari-Sisakht ,&nbsp;Seyedsaman Mousavian ,&nbsp;Mohammad Amin Ariana ,&nbsp;Ahmad Fauzi Ismail","doi":"10.1016/j.jece.2025.116392","DOIUrl":"10.1016/j.jece.2025.116392","url":null,"abstract":"<div><div>Thin-film nanocomposite (TFN) membranes have been one of the transformative innovations in membrane technology, addressing some of the critical challenges faced in water treatment, desalination, and gas separation. TFN membranes, by incorporating nanoparticles in the thin polyamide layer of traditional thin-film composite (TFC) membranes, exhibit enhanced permeability, selectivity, fouling resistance, and chemical stability. Improvements in the design of TFN membranes, in terms of their hydrophilic nanomaterials and porous fillers incorporated into the structure, bring about improved water flux and solute rejection, further enabling these membranes to be most effectively efficient in several filtration fields. More importantly, emerging new fabrication techniques allow for the dispersion of nanomaterials in a membrane matrix with great precisions, otherwise suffering from the problems related to nanoparticle aggregation and incompatibility. This review provides an in-depth analysis of the evolution, recent developments, and future perspectives of TFN membrane technology. It presents the ability of TFN membranes to give better performance in the field of reverse osmosis, forward osmosis, and nanofiltration and discusses the challenges in fabrication but also strategizes on ways of optimizing the performance. The review closes with prospects for the application of TFN membranes to address various water-energy challenges globally in a sustainable way.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 3","pages":"Article 116392"},"PeriodicalIF":7.4,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143768588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrogel materials in agriculture: A review 水凝胶材料在农业中的应用综述
IF 7.4 2区 工程技术
Journal of Environmental Chemical Engineering Pub Date : 2025-04-02 DOI: 10.1016/j.jece.2025.116385
Hanghang Wang , Guangfei Qu , Xinxin Liu , Minjie He , Chenyang Yin , Rui Xu
{"title":"Hydrogel materials in agriculture: A review","authors":"Hanghang Wang ,&nbsp;Guangfei Qu ,&nbsp;Xinxin Liu ,&nbsp;Minjie He ,&nbsp;Chenyang Yin ,&nbsp;Rui Xu","doi":"10.1016/j.jece.2025.116385","DOIUrl":"10.1016/j.jece.2025.116385","url":null,"abstract":"<div><div>Hydrogel, as a typical representative of functional materials, constructs a three-dimensional network structure through physical or chemical cross-linking of hydrophilic polymer chains, which are rich in hydrophilic groups such as hydroxyl (-OH), carboxyl (-COOH), and amino (-NH<sub>2</sub>) on the molecular chain and exhibit excellent high water absorption (water absorption multiplication rate of 10–20 times and up to more than 500 times after nanocomposite modification). Studies have shown that the modified hydrogel removes more than 95 % of heavy metal ions (e.g., Pb<sup>2</sup><sup>⁺</sup>, Cr<sup>3</sup><sup>⁺</sup>) and possesses pH and temperature responsive swelling behavior. In response to the pressing problems faced by global agriculture, such as water scarcity, low fertilizer utilization, and soil heavy metal pollution, hydrogels show great potential for application in precision controlled release of fertilizers, water and moisture conservation, and pollution remediation. In this paper, we systematically review the performance characteristics of hydrogel, optimization strategies, and preparation methods, focusing on its innovative applications in agriculture and mechanistic role based on the environmental response mechanism to achieve the synergistic management of nutrients, water, and pollutants, which provides significant technological support for the development of sustainable agriculture.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 3","pages":"Article 116385"},"PeriodicalIF":7.4,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143817776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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