Wai Siong Chai , Awais Ali Aslam , Xinyang Li , Tao Wu , Cheng Heng Pang
{"title":"Surface-engineered biochar: Recent advances in modification strategies for environmental remediation and energy applications","authors":"Wai Siong Chai , Awais Ali Aslam , Xinyang Li , Tao Wu , Cheng Heng Pang","doi":"10.1016/j.jece.2025.117951","DOIUrl":"10.1016/j.jece.2025.117951","url":null,"abstract":"<div><div>In recent years, biochar has surfaced as an intriguing biosourced substance capable of tackling worldwide issues in energy, agriculture, biomedicine, and environmental sectors. Nonetheless, the effectiveness of biochar relies on the precise adjustment of its surface chemical properties to fulfill specific roles. This review offers an extensive summary of biochar production techniques, highlighting the thermochemical conversion of biomass and the crucial influence of precursor choice and process conditions on biochar characteristics. Furthermore, we investigate sophisticated surface alteration methods, such as chemical activation, physical activation, and functionalization with silane coupling agents, titanates, diazonium salts, and nitrogen-derived compounds. Recent progress in biochar engineering, especially the developments made in the past years, is summarized and linked to their uses in pollutant adsorption, water treatment, catalysis, energy storage, and soil remediation. This review emphasizes the promise of surface-engineered biochar as a sustainable answer to urgent global challenges by exploring the connection between functionalization methods and final uses.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117951"},"PeriodicalIF":7.4,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144632673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuntao Kang , Hongxiang Xu , Hongguang Xu , Yijun Cao , Xin Sun , Lin Ma , Jingzheng Wang , Jiahua Cui , Jiushuai Deng
{"title":"Advances in interfacial conditioning in phosphate ore flotation: A comprehensive review","authors":"Yuntao Kang , Hongxiang Xu , Hongguang Xu , Yijun Cao , Xin Sun , Lin Ma , Jingzheng Wang , Jiahua Cui , Jiushuai Deng","doi":"10.1016/j.jece.2025.117942","DOIUrl":"10.1016/j.jece.2025.117942","url":null,"abstract":"<div><div>Given the gradual depletion of high-grade phosphorite deposits, enhancing the performance indicators of phosphorite flotation separation using froth flotation becomes critical. Although some studies on interfacial regulation of phosphate ore flotation have been conducted, there are still few systematic reviews on the subject, leaving our understanding of the challenges of flotation interfaces, the regulation system, and related mechanisms unclear. The development and industrialization of phosphate ore flotation technology have long faced the following challenges: interference from calcium-bearing minerals and fine-grained minerals, the influence of unavoidable ions, and complex pulp interface issues caused by insufficient selectivity of flotation reagents. A comprehensive investigation of the current research status in phosphate ore flotation is conducted, addressing five main aspects: mineral properties of apatite and its gangue minerals, interfacial regulation of mineral interactions, interfacial regulation of unavoidable metal ions, interfacial regulation of flotation reagents, and progress in flotation process research.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117942"},"PeriodicalIF":7.4,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144587686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Toon Van Vaerenbergh, Kseniia Vikanova, Xian Wu, Jonathan Van Waeyenberg, Brent Smeyers, Hendrik van Leuven, Bert Sels
{"title":"Hydrogen production from plastics: A comprehensive review of thermochemical pathways, process optimization and sustainability insights","authors":"Toon Van Vaerenbergh, Kseniia Vikanova, Xian Wu, Jonathan Van Waeyenberg, Brent Smeyers, Hendrik van Leuven, Bert Sels","doi":"10.1016/j.jece.2025.117929","DOIUrl":"10.1016/j.jece.2025.117929","url":null,"abstract":"<div><div>Plastic waste accumulation has become a major environmental challenge, prompting interest in advanced recycling technologies that can recover value from non-recyclable streams. Among these, thermochemical processes for hydrogen production offer a compelling route for both waste management of heavily contaminated streams and clean energy generation. This review provides a comprehensive overview of hydrogen production from plastic waste through catalytic gasification, pyrolysis-reforming, and pyrolysis-chemical vapor deposition. Following an overview of these thermochemical routes, the review examines how process parameters - such as plastic feedstock, catalyst type, reactor configuration, temperature, and oxidant input- affect hydrogen yield and co-product formation. Further, environmental and techno-economic assessments are discussed to evaluate the feasibility and scalability of each approach. By consolidating current advances and identifying key research gaps, this work aims to guide future developments toward viable and sustainable hydrogen production from plastic waste.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117929"},"PeriodicalIF":7.4,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144595810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Practice and challenges for beneficial use of municipal solid waste incineration bottom ash in China","authors":"Huihuang Zou , Pinjing He , Fan Lü , Hua Zhang","doi":"10.1016/j.jece.2025.117923","DOIUrl":"10.1016/j.jece.2025.117923","url":null,"abstract":"<div><div>Municipal solid waste incineration bottom ash (MSWIBA) is a major by-product of incineration and has been classified as non-hazardous waste in most countries. Owing to its mineral composition being similar to that of natural aggregates, MSWIBA has attracted increasing attention for use in construction materials such as road subbase and cement-based products. However, concerns remain about its environmental risks due to the potential release of heavy metals and soluble salts during long-term field applications. This review critically examines the current status of MSWIBA management in China, including generation, physicochemical characteristics, and national regulatory frameworks. Comparative insights are provided based on international practices, highlighting differences in pretreatment technologies, utilization pathways, and environmental standards. The review identifies several key challenges in China, such as decentralized management, lack of long-term risk assessment, and absence of enforceable standards. Drawing on global experience, the paper proposes policy and technical recommendations to support safe and efficient reuse of MSWIBA, contributing to the development of a circular economy and China’s “Zero-Waste City” initiative.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117923"},"PeriodicalIF":7.4,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144581239","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Amorphous metal-organic frameworks: From synthesis strategies to emerging applications","authors":"Hossein Molavi","doi":"10.1016/j.jece.2025.117890","DOIUrl":"10.1016/j.jece.2025.117890","url":null,"abstract":"<div><div>Amorphous metal-organic frameworks (AmMOFs) have emerged as alternatives to their crystalline counterparts due to their unique structures, diverse properties, and wide applications. AmMOFs usually combine the advantages of crystalline MOFs (CrMOFs) including high surface area, exceptional chemical and thermal stabilities, chemical functionalities, and tunable pore sizes/shapes, with the emerging properties of amorphous counterparts including the absence of grain boundaries, abundant defects and active sites, isotropy, high flexibility, and enhanced mechanical robustness. Although the number of reports on AmMOFs is much lower than those on CrMOFs, in some examples they exhibit improved properties and have also attracted increasing attention in the recent years, thereby they will possess great potential in the future technologies. This review aims to highlight the recent progress of AmMOFs in synthesis methods, structure-property relationships, and emerging applications. In this regard, we highlight the superiority of AmMFs compared to their crystalline counterparts, then describe two primary approaches for preparing AmMOFs including: 1) top-down: amorphization of pre-synthesized CrMOFs via different treatment methods, and 2) bottom-up: direct synthesis of AmMOFs. Additionally, we highlight the recent progress of AmMOFs in different fields including biomedical, catalysis/photocatalysis, energy storage and conversion, chemical sensing, gas adsorption and separation, and water/wastewater treatment applications.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117890"},"PeriodicalIF":7.4,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144595390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Longfei Liu , Jiayi Ding , Chenhao Zhao , Wan Yang , Ahmed Mosa , Hailong Wang , Nanthi Bolan , Chengliang Li , Yao Huang , Xiaozhi Wang , Shengsen Wang , Jörg Rinklebe
{"title":"Mechanistic insights into the adsorptive removal of PFOA and PFOS using microbubbles and nanobubbles: A review","authors":"Longfei Liu , Jiayi Ding , Chenhao Zhao , Wan Yang , Ahmed Mosa , Hailong Wang , Nanthi Bolan , Chengliang Li , Yao Huang , Xiaozhi Wang , Shengsen Wang , Jörg Rinklebe","doi":"10.1016/j.jece.2025.117832","DOIUrl":"10.1016/j.jece.2025.117832","url":null,"abstract":"<div><div>Perfluoro- or polyfluoroalkyl substances (PFASs) have attracted research attention due to their high concentrations and severe ecotoxicity in the environment. The distinctive attributes of adsorption support its wide-scale application in the remediation of contaminants including PFASs. Previous studies mainly focused on the exploration and development of adsorbent materials, evaluating the removal of PFASs with different chain lengths, or assessing the impact of environmental factors on PFASs removal. However, the role of microbubbles (MBs) or nanobubbles (NBs), a commonly present but easily overlooked substance in natural media, in the PFASs adsorption has not been systematically summarized. Therefore, in this review, we introduce the importance of MBs/NBs in PFASs (particularly PFOA and PFOS) adsorption, by analyzing their characteristics related to adsorption. MBs/NBs can effectively remove PFASs by enriching at the interface and prolonging the retention time. The theoretical calculations of molecular dynamics and Gibbs free energy on the adsorption behavior of PFOS/PFOS with the participation of MBs/NBs were systematically analyzed. The hydrophobicity of PFOS, which is greater than that of PFOA, leads to stronger adsorption of PFOS by MBs. Environmental factors mainly affect the stability and surface properties of MBs/NBs, as well as the hydrophobicity of PFOA/PFOS, to alter the adsorption behavior of PFOA/PFOS mediated by MBs/NBs. Furthermore, the adsorption mechanisms of PFOA/PFOS on MBs/NBs were summarized, with electrostatic and hydrophobic interactions dominating this behavior. This review offers an enhanced and comprehensive insight into the adsorption of PFASs in water. Furthermore, it facilitates a more profound evaluation of the significant role played by MBs/NBs in the adsorptive elimination of PFASs from aquatic system.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117832"},"PeriodicalIF":7.4,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144549368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Amanda F. Gouveia , Geovânia C. de Assis , Lara K. Ribeiro , Lucia H. Mascaro , Monica Calatayud , Antonio C.S.C. Teixeira
{"title":"Heterogeneous photocatalysis as an efficient process for degrading MPs/NPs in aqueous media: A systematic review","authors":"Amanda F. Gouveia , Geovânia C. de Assis , Lara K. Ribeiro , Lucia H. Mascaro , Monica Calatayud , Antonio C.S.C. Teixeira","doi":"10.1016/j.jece.2025.117878","DOIUrl":"10.1016/j.jece.2025.117878","url":null,"abstract":"<div><div>Plastic waste has become one of the most pressing environmental issues due to the resistance of these materials to natural degradation. Over time, they break down into microplastics (MPs) and nanoplastics (NPs), posing a serious problem, especially in water pollution, and can have significant impacts on the quality of human, animal, and plant life. Several emerging strategies are being explored to combat this pollution, with the emergence of semiconductors as effective and sustainable heterogeneous photocatalysts for degrading MPs/NPs. The strategy is promising for tackling this social and environmental challenge. Therefore, this review begins by addressing the systemic issue of MPs/NPs in aquatic environments, emphasizing their occurrence, effects and degradation processes. It then outlines the application of heterogeneous photocatalysis for the degradation of MPs and NPs. In addition, we present some significant recent research into the upcycling approach, which involves transforming plastic waste into chemical inputs with high added value. We then explore the current limitations and future challenges in advancing this field of study.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117878"},"PeriodicalIF":7.4,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144581240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sikandar Aftab , Ganesh Koyyada , Ghazanfar Nazir , Awais Khalid , Mohammed A. Assiri , Najaf Rubab , Jae Hong Kim
{"title":"Graphene-based biosensing platforms for early detection of Alzheimer's disease: Advances, mechanisms, and future directions","authors":"Sikandar Aftab , Ganesh Koyyada , Ghazanfar Nazir , Awais Khalid , Mohammed A. Assiri , Najaf Rubab , Jae Hong Kim","doi":"10.1016/j.jece.2025.117836","DOIUrl":"10.1016/j.jece.2025.117836","url":null,"abstract":"<div><div>Alzheimer's disease (AD), the most prevalent type of neurodegenerative dementia, is becoming a major global health concern because of its progressive nature and the lack of reliable early detection methods. The remarkable electrical, mechanical, and chemical properties of graphene and its derivatives have drawn interest recently as promising materials for biosensing applications. In this review, we highlight the latest developments in graphene-based biosensing platforms designed for the early detection of AD biomarkers, such as tau proteins, amyloid-β (Aβ) peptides, and associated neurotransmitters. The processes that enable graphene to detect these biomarkers with high sensitivity, selectivity, and biocompatibility are investigated. We review functionalization techniques, electrochemical, optical, and field-effect transduction types, and integration with wearable and microfluidic systems. We also discuss future directions for developing trustworthy, point-of-care diagnostic tools and address current issues like sensor stability, validation with real samples, and clinical applicability. The substantial potential of graphene-based biosensors to revolutionize early AD detection and enable prompt treatment is highlighted in this review.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117836"},"PeriodicalIF":7.4,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144549390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Application of cellulose-based flocculants in microalgae flocculation: A review","authors":"Guozhu Xiong, Guohua Dao, Wenping Xiang, Qin xian Yang, Ziyi Zhou, Xuejun Pan, Benqin Yang","doi":"10.1016/j.jece.2025.117857","DOIUrl":"10.1016/j.jece.2025.117857","url":null,"abstract":"<div><div>The development of green and sustainable flocculants is critical for addressing the global environmental challenge of harmful algal blooms (HABs) through algal water separation techniques. Cellulose-based flocculants have garnered significant attention due to their biodegradability, substantial potential for surface modification, natural abundance, and high flocculation efficiency. Currently, the application of cellulose in microalgae flocculation primarily involves native cellulose fibers and cellulose nanocrystals. The flocculation performance of cellulose-based flocculants can be effectively enhanced through etherification modification and graft copolymerization. However, microalgae species, culture media, flocculant properties, and environmental factors may influence flocculation efficiency, necessitating the selection of appropriate cellulose sources and modification methods for specific application scenarios. This review examines recent advancements in cellulose-based flocculants for microalgae flocculation, including their sources, preparation methods, flocculation mechanisms, modification techniques, and factors affecting efficiency. The potential value of cellulose-based flocculants and the key technical challenges they face are evaluated, with the aim of providing theoretical support for future research and advancing microalgae harvesting technologies using cellulose-based flocculants.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117857"},"PeriodicalIF":7.4,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144581238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Dual-functional materials (catalysts and adsorbents) as innovative and sustainable pathways toward combined healthcare (antibacterial, antifungal, antiviral, antioxidant, and anticancer properties) and water pollution remediation","authors":"Mozhdeh Meghdadian, Niyaz Mohammad Mahmoodi","doi":"10.1016/j.jece.2025.117718","DOIUrl":"10.1016/j.jece.2025.117718","url":null,"abstract":"<div><div>Cancer remains a significant global health concern despite recent advancements in medicine and pharmaceuticals. Also, water contamination caused by various microorganisms, including bacteria and industrial dyes, significantly contributes to cancer prevalence and microbial diseases among populations. This review focuses on multifunctional nanomaterials—particularly photocatalysts, adsorbents, and catalysts—that possess dual abilities in both healthcare (antibacterial, antifungal, antiviral, anti-corona virus, antioxidant, and anticancer) and environmental pollutant removal. The emergence of nanotechnology, especially through nanoparticles and metal-organic frameworks (MOFs), offers innovative strategies for addressing these two domains. These materials not only improve the effectiveness of cancer therapies but also serve as agents for water purification. The relevance and promise of these materials have stimulated growing academic interest in this interdisciplinary field.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"13 5","pages":"Article 117718"},"PeriodicalIF":7.4,"publicationDate":"2025-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144570913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}