Journal of forensic sciences最新文献

A preliminary study of the manufacturing of breech faces 后端面制造的初步研究。

IF 1.5 4区医学

Journal of forensic sciences Pub Date : 2024-10-14 DOI: 10.1111/1556-4029.15626

Veronica L. Franklin MS, Keith B. Morris PhD

{"title":"A preliminary study of the manufacturing of breech faces","authors":"Veronica L. Franklin MS, Keith B. Morris PhD","doi":"10.1111/1556-4029.15626","DOIUrl":"10.1111/1556-4029.15626","url":null,"abstract":"Firearm examiners may face challenges with subclass characteristics. Subclass characteristics have the potential to be confused with individual characteristics if a careful analysis for the presence of subclass characteristics is not performed. Several case studies are reported in the literature that discuss the presence of subclass characteristics and advise firearm examiners to disregard these characteristics for identification purposes. As far as can be determined, no fundamental study has been performed that explores the various methods used in firearm manufacturing and assess the potential of subclass characteristics being produced. In this study broaching, plunge milling, and lathe turning were used to produce consecutively manufactured breech faces for a Thompson/Center® (T/C®) Contender® G2 pistol. The breech faces were finished by tumbling or glass bead blasting. The 3D topographical scans of the breech faces were collected using a confocal microscope and then compared using the National Institute of Standards and Technology (NIST) congruent matching cells (CMC) algorithm. The results of this study demonstrated the presence of subclass characteristics after manufacturing by broaching and plunge milling. Lathe turning did not produce any subclass characteristics. ANOVA and Kruskal–Wallis H tests were used to determine significant differences between finishing methods within each manufacturing method. Significant differences were found in glass bead blasting versus tumbling and glass bead blasting versus no finish. No significant differences were found in no finish versus tumbling.","PeriodicalId":15743,"journal":{"name":"Journal of forensic sciences","volume":"69 6","pages":"2041-2053"},"PeriodicalIF":1.5,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/1556-4029.15626","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142484299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The application of GIS technology in building a multivariate taphonomic profile for improving PMI estimations in Greece 应用地理信息系统（GIS）技术建立多变量岩相剖面图，以改进希腊的 PMI 估算。

IF 1.5 4区医学

Journal of forensic sciences Pub Date : 2024-10-11 DOI: 10.1111/1556-4029.15634

Christina Karydi MSc, Ioannis Montesantos MSc, Konstantinos Moraitis PhD

{"title":"The application of GIS technology in building a multivariate taphonomic profile for improving PMI estimations in Greece","authors":"Christina Karydi MSc, Ioannis Montesantos MSc, Konstantinos Moraitis PhD","doi":"10.1111/1556-4029.15634","DOIUrl":"10.1111/1556-4029.15634","url":null,"abstract":"Environmental conditions highly affect decomposition rates and therefore a forensic practitioner should consider context-specific information when estimating the post mortem interval (PMI). Traditional methods of collecting environmental data, however, are time-consuming and often impractical for large-scale studies or routine forensic investigations. This study developed an automated computer method by employing the technology of geographic information systems (GIS) and Python programming language to provide contextual information for bodies found outdoors in Greece. The generated coding script underwent testing on 95 bodies in various stages of decomposition, which were examined between the years 1999 and 2022 at the National and Kapodistrian University of Athens and the Forensic Medical Service of Thessaloniki. Using ArcGIS Pro software and publicly available online data, a multilayer map was developed. Individual layers included high-resolution aerial images and data on the European Nature Information System ecosystem type, the Köppen–Geiger climatic type, the population density, the elevation, and the slope. Additionally, 99 national weather stations and their corresponding meteorological data were integrated. By leveraging the geographical coordinates of the recovery site of each case and information about the decedent's disappearance and recovery dates, this script automatically generates details from each of the above layers. Additionally, it calculates the accumulated degree days (ADD) and accumulated humidity days (AHD) values by extracting data from the nearest weather station. The GIS-based approach enables rapid, objective, and reproducible taphonomic profile construction, which can greatly improve the reliability of PMI estimations. By utilizing this method, forensic practitioners can accurately evaluate environmental effects on decomposition, thus standardizing taphonomic profiling globally.","PeriodicalId":15743,"journal":{"name":"Journal of forensic sciences","volume":"69 6","pages":"2258-2269"},"PeriodicalIF":1.5,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/1556-4029.15634","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142402509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Determining the sequence of intersecting lines formed by laser printer toner and seal ink based on confocal Raman spectroscopy 基于共焦拉曼光谱确定激光打印机墨粉和密封墨水形成的相交线序列。

IF 1.5 4区医学

Journal of forensic sciences Pub Date : 2024-09-24 DOI: 10.1111/1556-4029.15632

Shuo Liu MSc, Yaqi Yang MSc, Yi Zhang MSc, Bing Li PhD

{"title":"Determining the sequence of intersecting lines formed by laser printer toner and seal ink based on confocal Raman spectroscopy","authors":"Shuo Liu MSc, Yaqi Yang MSc, Yi Zhang MSc, Bing Li PhD","doi":"10.1111/1556-4029.15632","DOIUrl":"10.1111/1556-4029.15632","url":null,"abstract":"In the field of questioned document examination, determining the sequence of intersecting lines is still a technical challenge. This study aims to validate whether confocal Raman spectroscopy can determine the sequence of intersecting lines created by laser prints toner and seal ink through empirical research. The study collected 110 varieties of seal ink and 1074 test pages from 66 models of laser printers available in the Chinese market. Based on the Raman spectral characteristics of the seal ink and the microscopic morphology of the toner, 13 types of seal ink and three types of laser printers were selected for further analysis, producing 78 representative samples of intersecting lines. Confocal Raman spectroscopy was applied to the examination of these samples using a point-scanning mode for enhanced accuracy and efficiency. The experimental results demonstrate that confocal Raman spectroscopy can non-destructively and quickly examine the sequence of intersecting lines produced by laser printer toner and seal ink. Variations in toner forms result in differing levels of difficulty in resolving intersection problems, with the sequence of intersecting lines from toner-dense laser printers being the easiest to ascertain. In contrast, those from printers with porous and dispersed toner present a more significant challenge in examination. This study can be corroborated with other methods proposed, and more significantly, it lays the groundwork for addressing intersection problems related to other printing or writing instruments.","PeriodicalId":15743,"journal":{"name":"Journal of forensic sciences","volume":"69 6","pages":"2148-2158"},"PeriodicalIF":1.5,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142309497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Emergence of semi-synthetic cannabinoids in cannabis products seized in Eastern Denmark over a 6-year period 丹麦东部 6 年间缉获的大麻产品中出现的半合成大麻素。

IF 1.5 4区医学

Journal of forensic sciences Pub Date : 2024-09-20 DOI: 10.1111/1556-4029.15631

Christian Falck Jørgensen MSc, Brian Schou Rasmussen PhD, Kristian Linnet MD, DMSc, Ragnar Thomsen PhD

{"title":"Emergence of semi-synthetic cannabinoids in cannabis products seized in Eastern Denmark over a 6-year period","authors":"Christian Falck Jørgensen MSc, Brian Schou Rasmussen PhD, Kristian Linnet MD, DMSc, Ragnar Thomsen PhD","doi":"10.1111/1556-4029.15631","DOIUrl":"10.1111/1556-4029.15631","url":null,"abstract":"Semi-synthetic cannabinoids (SSCs) are derivatives of phytocannabinoids with slight chemical modifications. SSCs have appeared as legal alternatives to tetrahydrocannabinol (Δ9-THC) in recent years. This study investigates the prevalence of SSCs in seized drug samples from Danish police and custom authorities seized in Eastern Denmark in the period 2018–2023. Screening data obtained by gas chromatography–mass spectrometry (GC–MS) were reprocessed to enable detection of SSCs. Seized drug samples were categorized into six types of formulations. Δ8-THC was the first SSC observed and appeared in 2019 followed by hexahydrocannabinol (HHC), tetrahydrocannabidiol (H4-CBD), hexahydrocannabinol acetate (HHC-O-Acetate), hexahydrocannabiphorol (HHCP) and tetrahydrocannabiphorol (Δ9-THCP). Only one sample positive for SSCs was observed before the third quarter of 2021, with positive samples increasing from third quarter of 2022. Over the study period, a total of 15% (n = 216) of seized cannabis products were positive for SSCs. HHC was the most frequently identified SSC and found in 10% (n = 137) of samples, followed by H4-CBD at 4% (n = 53), Δ8-THC at 3% (n = 44), and HHC-O-Acetate, HHCP, and THCP each at 1% (n = 10–20). SSCs appeared in 56% of E-cigarette products, 20% of hashish, 17% of concentrates, 10% of edibles, and 10% of plant materials. In conclusion, SSCs represent a new type of cannabinoids with a rapidly growing popularity and with specific compounds dominating at different periods. Some of the observed trends were likely influenced by the scheduling of HHC in May of 2023 in Denmark.","PeriodicalId":15743,"journal":{"name":"Journal of forensic sciences","volume":"69 6","pages":"2009-2017"},"PeriodicalIF":1.5,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/1556-4029.15631","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142304962","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cutting edge document examination: The physical fit of machine-cut edges of paper 切边文件检查：纸张机切边缘的物理配合。

IF 1.5 4区医学

Journal of forensic sciences Pub Date : 2024-09-20 DOI: 10.1111/1556-4029.15630

Nicola R. Musgrave BSc, MSc, Oliver T. S. Thorne BSc, Alix J. Howells BSc, MSc

{"title":"Cutting edge document examination: The physical fit of machine-cut edges of paper","authors":"Nicola R. Musgrave BSc, MSc, Oliver T. S. Thorne BSc, Alix J. Howells BSc, MSc","doi":"10.1111/1556-4029.15630","DOIUrl":"10.1111/1556-4029.15630","url":null,"abstract":"This technical note describes in detail a method for associating individual sheets of blank A4 white paper from the same ream by the physical fit of machine-cut edges. A large-scale laboratory trial involving ~700 sheets of paper from 24 different reams (plus one spoiled sample), and more than 20,000 potential physical fits, correctly associated and sequenced 219 pairs of sheets together with a 100% empirical success rate and no false associations. The edge profile of each short machine-cut end of a sheet of A4 paper allows us to physically fit sheets of paper from the same ream to each other and use this to predict the sequence of sheets in a set of documents. In a real-life scenario, it may now be possible to detect the substitution or addition of a sheet in a multipage document, link documents from different sources to each other or to a common source of paper (e.g. to paper from a seized printer or from an accused's address) or to date documents. The study provides data for the application of this method in forensic casework and supports the practitioner when forming conclusions in this type of case.","PeriodicalId":15743,"journal":{"name":"Journal of forensic sciences","volume":"69 6","pages":"2290-2301"},"PeriodicalIF":1.5,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142304961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The effect of insect excretions/secretions and decomposition fluid on DNA quantity and quality in human bloodstains 昆虫排泄物/分泌物和分解液对人类血迹中 DNA 数量和质量的影响

IF 1.5 4区医学

Journal of forensic sciences Pub Date : 2024-09-20 DOI: 10.1111/1556-4029.15597

Maggie Murphy BFSc (Hons), Michelle Harvey PhD, Roland A. H. van Oorschot PhD, Annalisa Durdle PhD

{"title":"The effect of insect excretions/secretions and decomposition fluid on DNA quantity and quality in human bloodstains","authors":"Maggie Murphy BFSc (Hons), Michelle Harvey PhD, Roland A. H. van Oorschot PhD, Annalisa Durdle PhD","doi":"10.1111/1556-4029.15597","DOIUrl":"10.1111/1556-4029.15597","url":null,"abstract":"The larval excretions/secretions (ES) of blowflies contain proteolytic enzymes and bacteria that assist with tissue breakdown. Decomposition fluid (DF) contains organic and inorganic waste products from cell death. This study investigated if human DNA recovery from blood was impacted by exposure to ES and DF over time. Lucilia sericata ES were collected daily from 50 larvae, and all available DF was collected from two fetal piglets left to decompose for 2 weeks. Daily for 3–5 days, 28 μL-30 μL of ES, DF, or a 1:1 mixture of the fluids was added to 30 μL of blood on cotton. Three bloodstains per treatment were sampled every 12 h up to 3 days and at 1 and 2 weeks after initial addition of fluid. No PCR inhibition was detected, but DNA degradation increased over time, primarily in samples exposed to ES and ES/DF mixtures. The amount of DNA recovered decreased over time, but generally more DNA was recovered from DF samples than other samples. Full profiles, or partial profiles suitable for routine database searching (14–39 alleles), were generated from all DF and ES samples and at least one mixture sample at all timepoints. Partial profiles of between 1 and 13 alleles were obtained from all other mixture samples, except one mixture sample which generated no profile. These findings indicate bloodstain evidence recovered from maggot-infested and/or decomposing bodies may generate forensically useful DNA evidence and should be analyzed as quickly as possible after collection or stored appropriately to prevent further degradation.","PeriodicalId":15743,"journal":{"name":"Journal of forensic sciences","volume":"69 6","pages":"2082-2090"},"PeriodicalIF":1.5,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/1556-4029.15597","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142304965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Barbie drug identification: Not a child's play 芭比娃娃毒品鉴定：不是儿戏

IF 1.5 4区医学

Journal of forensic sciences Pub Date : 2024-09-20 DOI: 10.1111/1556-4029.15633

Marine Deville PhD, Corinne Charlier PhD

{"title":"Barbie drug identification: Not a child's play","authors":"Marine Deville PhD, Corinne Charlier PhD","doi":"10.1111/1556-4029.15633","DOIUrl":"10.1111/1556-4029.15633","url":null,"abstract":"Various samples—including two vials with a pharmaceutical appearance—were submitted to the laboratory for identification. The aim of this work was to describe the unique characteristics observed during the analysis of the powder contained in the vial. Samples were submitted to HPLC-DAD, UHPLC-TOF-MS, and/or UPLC-MS–MS analysis. The majority of the samples were easily identified as standard drugs of abuse. The main difficulty lay in identifying the powder in the vials. No match was found in the library through HPLC-DAD analysis. Fortunately, the vials were labeled as “Melanotan II”, although the UV spectrum was not available. Mass spectrometric analysis of melanotan II was challenging, as it is a small peptide with a molecular weight of 1024 Da, which is significantly heavier than classical drugs that the laboratory usually handles. As a result, mass spectrometer's parameters can be limited to detect masses up to 1000 Da. Additionally, melanotan II is multi-charged which is also unusual for compounds typically targeted in our daily work. Finally, the reference standard allowed us to confirm the identification with both instruments, and determine the purity of 30%. Melanotan II is not approved on the market due to safety concerns. It is used illegally mainly for tanning, explaining its nickname “Barbie drug”. To conclude, analysis of melanotan II was challenging as it is heavy and doubly charged. Moreover, its UV spectrum was initially not available in the literature. The difficulties faced by forensic scientists in detecting this drug may explain its popularity on the illicit market.","PeriodicalId":15743,"journal":{"name":"Journal of forensic sciences","volume":"69 6","pages":"2331-2338"},"PeriodicalIF":1.5,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142304960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

DentAge: Deep learning for automated age prediction using panoramic dental X-ray images DentAge：利用全景牙科 X 光图像进行自动年龄预测的深度学习。

IF 1.5 4区医学

Journal of forensic sciences Pub Date : 2024-09-18 DOI: 10.1111/1556-4029.15629

Žiga Bizjak PhD, Tina Robič DMD

{"title":"DentAge: Deep learning for automated age prediction using panoramic dental X-ray images","authors":"Žiga Bizjak PhD, Tina Robič DMD","doi":"10.1111/1556-4029.15629","DOIUrl":"10.1111/1556-4029.15629","url":null,"abstract":"Age estimation plays a crucial role in various fields, including forensic science and anthropology. This study aims to develop and validate DentAge, a deep-learning model for automated age prediction using panoramic dental X-ray images. DentAge was trained on a dataset comprising 21,007 panoramic dental X-ray images sourced from a private dental center in Slovenia. The dataset included subjects aged 4 to 97 years with various dental conditions. Transfer learning was employed, initializing the model with ImageNet weights and fine-tuning on the dental image dataset. The model was trained using stochastic gradient descent with momentum, and mean absolute error (MAE) served as the objective function. Across the test dataset, DentAge achieved an MAE of 3.12 years, demonstrating its efficacy in age prediction. Notably, the model performed well across different age groups, with MAEs ranging from 1.94 (age group [10–20]) to 13.40 years (age group [90–100]). Visual evaluation revealed factors contributing to prediction errors, including prosthetic restorations, tooth loss, and bone resorption. DentAge represents a significant advancement in automated age prediction within dentistry. The model's robust performance across diverse age groups and dental conditions underscores its potential utility in real-world scenarios. Our model will be accessible to the public for further adjustments and validation, ensuring DentAge's effectiveness and trustworthiness in practical scenarios.","PeriodicalId":15743,"journal":{"name":"Journal of forensic sciences","volume":"69 6","pages":"2069-2074"},"PeriodicalIF":1.5,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/1556-4029.15629","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142268993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Analysis of unique atypical screwdriver injuries 独特的非典型螺丝刀损伤分析

IF 1.5 4区医学

Journal of forensic sciences Pub Date : 2024-09-17 DOI: 10.1111/1556-4029.15610

Francisco Reyes Albaladejo MS, Benjamin J. Soriano MD, Lorenzo Gitto MD

{"title":"Analysis of unique atypical screwdriver injuries","authors":"Francisco Reyes Albaladejo MS, Benjamin J. Soriano MD, Lorenzo Gitto MD","doi":"10.1111/1556-4029.15610","DOIUrl":"10.1111/1556-4029.15610","url":null,"abstract":"Fatalities caused by sharp and pointed instruments, especially screwdrivers, are not frequently observed in the United States. The shape of the screwdriver tip generally determines the resulting wounds that can range from linear, to rectangular or cross-shaped, often reflecting common screwdriver head shapes. Recognizing such patterns is crucial, as they can aid in identifying the potential weapon used in the crime. In the reported case, an adult male was found dead in his living room surrounded by a pool of blood, with multiple injuries. At autopsy, the pattern of penetration was consistent with that of a six-point star (Torx) screwdriver, which has never been reported as a deadly weapon in the literature before. A Torx screwdriver has a blunt head, resulting in hybrid injuries with both penetrating and blunt force features. Because of its rigid structure and narrow tip, a Torx screwdriver may forcefully penetrate the skin, soft tissues, and bone, causing severe injuries to the deep organs. The case highlights the importance for the forensic pathologist to examine and recognize atypical penetrating wounds for the identification and location of rare weapons. High-definition graphic documentation of the injuries allows thorough examination and comparison of injuries with potential weapons. When the weapon is not retrieved, detailed injury descriptions guide investigations toward searching for a screwdriver, improving the chances of identifying the weapon used to commit the crime.","PeriodicalId":15743,"journal":{"name":"Journal of forensic sciences","volume":"69 6","pages":"2302-2307"},"PeriodicalIF":1.5,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142255020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigation of isotopic linkages between raw materials and black powder 原材料与黑火药之间同位素联系的研究。

IF 1.5 4区医学

Journal of forensic sciences Pub Date : 2024-09-15 DOI: 10.1111/1556-4029.15615

Can Hu PhD, Yang Huang MSc, Hongcheng Mei PhD, Hongling Guo PhD, Ping Wang MSc, Yajun Li MSc, Xianhe Deng MSc, Jun Zhu PhD

{"title":"Investigation of isotopic linkages between raw materials and black powder","authors":"Can Hu PhD, Yang Huang MSc, Hongcheng Mei PhD, Hongling Guo PhD, Ping Wang MSc, Yajun Li MSc, Xianhe Deng MSc, Jun Zhu PhD","doi":"10.1111/1556-4029.15615","DOIUrl":"10.1111/1556-4029.15615","url":null,"abstract":"The stable isotope analysis of black powder (BP) is of great significance for its comparison and source inference. Previous studies have verified the feasibility of distinguishing different BP samples through stable isotopes. However, the impact of raw materials and synthesis processes on the stable isotopes of BP remains unclear. On the one hand, the raw materials of BP are widely sourced, and whether stable isotopes can distinguish different source materials remains to be studied. On the other hand, the synthesis of BP involves the physical mixing of raw materials, and whether this process leads to isotope fractionation also needs further investigation. To address these problems, stable isotope ratios of 27 charcoals, 15 potassium nitrates, 6 self-made and 10 commercial BP samples were analyzed. The results showed that the stable isotope ratios can be utilized to distinguish charcoals and potassium nitrates from different manufacturers and batches. No significant differences in the nitrogen and oxygen stable isotope ratios between the self-made BP and its raw materials were observed, indicating that the physical mixing process does not induce significant fractionation of stable isotopes. However, the carbon stable isotope ratios of charcoal increased (within 2SD) after being synthesized into BP. Due to the utilization of additives and variations in the synthesis process, the correlation between the stable isotope ratios of commercial BP and its raw materials was complex. The findings of this study provide a scientific reference for tracing the source of BP.","PeriodicalId":15743,"journal":{"name":"Journal of forensic sciences","volume":"69 6","pages":"2018-2027"},"PeriodicalIF":1.5,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142304963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0