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Integrated pretreatment and fermentation strategies for L-lactic acid production from brewers' spent grain using native Streptococcus infantarius and Bacillus coagulans 利用天然婴儿链球菌和凝固芽孢杆菌对啤酒废粮进行预处理和发酵生产l -乳酸
IF 2.7 4区 生物学
Journal of chemical technology and biotechnology Pub Date : 2026-08-03 Epub Date: 2026-06-03 DOI: 10.1002/jctb.70212
Mónica Olvera, Carmen G. Hernández-Valencia, Carmina Montiel, Agata Olszewska-Widdrat, Joachim Venus, Miquel Gimeno
{"title":"Integrated pretreatment and fermentation strategies for L-lactic acid production from brewers' spent grain using native Streptococcus infantarius and Bacillus coagulans","authors":"Mónica Olvera,&nbsp;Carmen G. Hernández-Valencia,&nbsp;Carmina Montiel,&nbsp;Agata Olszewska-Widdrat,&nbsp;Joachim Venus,&nbsp;Miquel Gimeno","doi":"10.1002/jctb.70212","DOIUrl":"https://doi.org/10.1002/jctb.70212","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Brewers' spent grain (BSG) is an abundant lignocellulosic byproduct of the brewing industry with strong potential as a renewable substrate for biotechnological production of lactic acid (LA). This study evaluated integrated pretreatment, enzymatic hydrolysis, and fermentation strategies to enable efficient production of optically pure L-lactic acid (L-LA) from BSG using native <i>Streptococcus infantarius</i> and thermophilic <i>Bacillus coagulans</i> strains.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>Thermal, thermal/acid, and thermal/alkaline pretreatments were applied to BSG samples from two origins, followed by enzymatic saccharification using commercial cellulolytic and hemicellulolytic enzymes. Thermal/acid pretreatment was the most effective strategy, promoting extensive disruption of the lignocellulosic matrix and enhanced release of fermentable sugars while maintaining inhibitor concentrations compatible with microbial fermentation. <i>S. infantarius</i> showed limited sugar utilization and relatively low LA productivity under alkaline conditions. In contrast, <i>B. coagulans</i> strains efficiently co-fermented hexose and pentose sugars from BSG hydrolysates, achieving L-LA yields up to 0.82 g g<sup>−1</sup>, volumetric productivities up to 0.74 g L<sup>−1</sup> h<sup>−1</sup>, and optical purities exceeding 99%, even in the presence of pretreatment-derived inhibitors.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>The combination of thermal/acid pretreatment and metabolically robust <i>B. coagulans</i> strains enables the sustainable conversion of BSG into high-value optically pure L-LA. These findings support the valorization of brewing byproducts within integrated biorefinery and circular bioeconomy frameworks. © 2026 The Author(s). <i>Journal of Chemical Technology and Biotechnology</i> published by John Wiley &amp; Sons Ltd on behalf of Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"101 9","pages":"1869-1876"},"PeriodicalIF":2.7,"publicationDate":"2026-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jctb.70212","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148662402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of polyaniline/TiO2 nanocomposites: effects of acid and aniline concentrations on material properties and photocatalytic performance for sulfamethoxazole degradation 聚苯胺/TiO2纳米复合材料的合成:酸和苯胺浓度对材料性能及降解磺胺甲恶唑光催化性能的影响
IF 2.7 4区 生物学
Journal of chemical technology and biotechnology Pub Date : 2026-08-03 Epub Date: 2026-06-17 DOI: 10.1002/jctb.70218
Vanessa Mendonça Mendes Vargas, Susan Leonora Antunes, Carla Dalmolin, Sérgio Henrique Pezzin
{"title":"Synthesis of polyaniline/TiO2 nanocomposites: effects of acid and aniline concentrations on material properties and photocatalytic performance for sulfamethoxazole degradation","authors":"Vanessa Mendonça Mendes Vargas,&nbsp;Susan Leonora Antunes,&nbsp;Carla Dalmolin,&nbsp;Sérgio Henrique Pezzin","doi":"10.1002/jctb.70218","DOIUrl":"https://doi.org/10.1002/jctb.70218","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>This work investigated the synthesis of TiO<sub>2</sub>-P25/polyaniline (PANI) nanocomposites, denoted as PANI– TiO<sub>2</sub>, <i>via</i> chemical oxidative polymerization under different aniline:H<sup>+</sup> molar ratios, and evaluated their performance in heterogeneous photocatalysis (HP). Although this parameter is directly related to PANI properties, it has been insufficiently explored in the literature. Therefore, the aniline concentration was fixed while two conventional HCl concentrations (0.1 and 1.0 mol L<sup>−1</sup>) were employed.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>Significant differences were observed in both PANI and PANI–TiO<sub>2</sub> synthesized under distinct aniline:H<sup>+</sup> ratios. Spectroscopic characterization revealed that PANI synthesized in 0.1 mol L<sup>−1</sup> HCl exhibited more oligomeric structures, lower oxidation degree, and reduced electrical conductivity. The incorporation of TiO<sub>2</sub>-P25 promoted stabilization of quinoid segments in PANI, induced a core–shell morphology, and shortened the synthesis time. The composites synthesized in 1.0 mol L<sup>−1</sup> HCl exhibited improved dispersion in water, an important characteristic for HP applications. Photocatalytic experiments demonstrated that TiO<sub>2</sub>-P25, a benchmark and challenging catalyst for visible-light sensitization, exhibited photosensitization by PANI under both visible and UV irradiation. Under visible-light irradiation, the TP20HA sample, synthesized in 1.0 mol L<sup>−1</sup> HCl, achieved approximately 35% sulfamethoxazole (antibiotic) removal after 120 min. Under UV irradiation, the same sample exhibited an apparent rate constant approximately 18% higher than that of TiO<sub>2</sub>-P25.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>The photosensitization of TiO<sub>2</sub>-P25 depended on nanocomposite characteristics and HP experimental parameters, including the spectral range of incident radiation, color, and pH of the contaminant solution. The results demonstrated that the aniline:H<sup>+</sup> ratio strongly influenced the physicochemical properties and photocatalytic performance of the obtained materials. © 2026 The Author(s). <i>Journal of Chemical Technology and Biotechnology</i> published by John Wiley &amp; Sons Ltd on behalf of Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"101 9","pages":"1906-1923"},"PeriodicalIF":2.7,"publicationDate":"2026-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jctb.70218","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148662587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comprehensive review of nitrogen-doped porous carbon materials for CO2 capture: synthesis techniques, computational modelling, machine learning and future perspectives 二氧化碳捕获用氮掺杂多孔碳材料的综合综述:合成技术、计算建模、机器学习和未来展望
IF 2.7 4区 生物学
Journal of chemical technology and biotechnology Pub Date : 2026-08-03 Epub Date: 2026-06-22 DOI: 10.1002/jctb.70213
Shajaratuldur Ismail, Farihahusnah Hussin, Zong Yang Kong, Mohamed Kheireddine Aroua
{"title":"Comprehensive review of nitrogen-doped porous carbon materials for CO2 capture: synthesis techniques, computational modelling, machine learning and future perspectives","authors":"Shajaratuldur Ismail,&nbsp;Farihahusnah Hussin,&nbsp;Zong Yang Kong,&nbsp;Mohamed Kheireddine Aroua","doi":"10.1002/jctb.70213","DOIUrl":"https://doi.org/10.1002/jctb.70213","url":null,"abstract":"<p>Nitrogen-doped porous carbons have emerged as promising and cost-effective adsorbents for carbon dioxide (CO<sub>2</sub>) capture owing to their tuneable pore structures, varied nitrogen functionalities, and compatibility with sustainable precursors. This review provides a comprehensive overview of precursor types and synthesis strategies, including pyrolysis, chemical activation, template-assisted, hydrothermal, plasma, and microwave-assisted methods, and examines the effects of these approaches on the structural and surface properties of the materials. The role of nitrogen doping in enhancing CO<sub>2</sub> adsorption capacity, selectivity, and interaction mechanisms is critically assessed. Emphasis is placed on identifying active sites and understanding the contributions of pyridinic, pyrrolic, and graphitic nitrogen under various conditions. The discussion includes stability, regeneration behaviour, and comparisons with conventional adsorbents to assess their practical applicability. The review further integrates computational and data-driven approaches. Density functional theory studies offer atomistic insights into potential energy of CO<sub>2</sub> surface interactions, while machine learning (ML) models facilitate the mapping of structure performance relationships and the prediction of adsorption capacity based by analysing key input such as micropore volume, Brunauer–Emmett–Teller surface area, and nitrogen speciation. Key challenges are also addressed, including lack of data, inconsistent datasets from the literature, and limited experimental validation of ML predictions. Despite significant progress, challenges remain in scaling synthesis methods, improving long-term stability under realistic conditions, and optimising nitrogen functionalities. The integration of experimental, theoretical, and ML approaches offers strong potential to accelerate the design and development of nitrogen-doped porous carbons for practical CO<sub>2</sub> capture applications. © 2026 Society of Chemical Industry (SCI).</p>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"101 9","pages":"1661-1694"},"PeriodicalIF":2.7,"publicationDate":"2026-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148662594","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photocatalytic degradation of Congo red dye using N and S doped rGO/NiFe2O4 heterogeneous nanocomposite under visible light N和S掺杂rGO/NiFe2O4非均相纳米复合材料在可见光下光催化降解刚果红染料
IF 2.7 4区 生物学
Journal of chemical technology and biotechnology Pub Date : 2026-08-03 Epub Date: 2026-06-20 DOI: 10.1002/jctb.70143
Maryam Nazari Aliabadi, Ali Oji Moghanlou, Zohreh Doroudi, Mohammad Reza Allah Gholi Ghasri, Jamshid Najafpour
{"title":"Photocatalytic degradation of Congo red dye using N and S doped rGO/NiFe2O4 heterogeneous nanocomposite under visible light","authors":"Maryam Nazari Aliabadi,&nbsp;Ali Oji Moghanlou,&nbsp;Zohreh Doroudi,&nbsp;Mohammad Reza Allah Gholi Ghasri,&nbsp;Jamshid Najafpour","doi":"10.1002/jctb.70143","DOIUrl":"https://doi.org/10.1002/jctb.70143","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>This study reports the design and fabrication of a series of heterogeneous N,S-rGO/NiFe<sub>2</sub>O<sub>4</sub>-X% nanocomposites, where X represents the weight percentage of NiFe<sub>2</sub>O<sub>4</sub>. Nitrogen and sulfur dopants were deliberately introduced into the graphene oxide framework, followed by the concurrent anchoring of NiFe<sub>2</sub>O<sub>4</sub> nanoparticles within the graphene oxide layers through a controlled hydrothermal approach. The structure, morphology, optical characteristics, and photocatalytic activity of the nanocomposites were precisely characterized using XRD, XPS, FTIR, Raman spectroscopy, FESEM, TEM, EDAX, elemental mapping, DRS, BET, PL, and EIS, which collectively validated the successful integration of the designed components.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>The results confirmed the effective reduction of graphene oxide and the successful incorporation of NiFe<sub>2</sub>O<sub>4</sub> nanoparticles between the reduced graphene oxide layers. For the first time, the photocatalytic activity of these engineered nanocomposites was exclusively evaluated for the chemical degradation of Congo red dye, selected as a model organic pollutant, under visible irradiation, yielding successful outcomes.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>Our study demonstrated the outstanding photocatalytic activity of the N,S-rGO/NiFe<sub>2</sub>O<sub>4</sub> heterostructured nanocomposite. Among the prepared samples, the N,S-rGO/NiFe<sub>2</sub>O<sub>4</sub>–30% nanocomposite demonstrated an outstanding degradation efficiency of 91.45% for a 10 mg/L solution within 1 h under visible-light irradiation. Furthermore, the material exhibited remarkable structural stability and reusability, maintaining its catalytic performance without any measurable loss in activity or mass even after 12 consecutive cycles. These findings establish the novelty of this research work and highlight the significant potential of the synthesized N,S-rGO/NiFe<sub>2</sub>O<sub>4</sub> nanocomposites as durable and recyclable photocatalysts for environmental remediation applications. © 2026 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"101 9","pages":"1710-1728"},"PeriodicalIF":2.7,"publicationDate":"2026-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148662777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyurethane biocarrier drives simultaneous nitrification–denitrification and phosphorus removal in IFAS by enriching Pseudomonas and Aeromonas 聚氨酯生物载体通过富集假单胞菌和气单胞菌来驱动IFAS的硝化反硝化和除磷
IF 2.7 4区 生物学
Journal of chemical technology and biotechnology Pub Date : 2026-08-03 Epub Date: 2026-05-26 DOI: 10.1002/jctb.70202
Hao Wang, Xiaowei Song, Jiayu Liu, Xiaohao Wang
{"title":"Polyurethane biocarrier drives simultaneous nitrification–denitrification and phosphorus removal in IFAS by enriching Pseudomonas and Aeromonas","authors":"Hao Wang,&nbsp;Xiaowei Song,&nbsp;Jiayu Liu,&nbsp;Xiaohao Wang","doi":"10.1002/jctb.70202","DOIUrl":"https://doi.org/10.1002/jctb.70202","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>The effective removal of nitrogen and phosphorus from municipal wastewater with low carbon-to-nitrogen ratios remains a significant challenge for conventional biological processes. This study aimed to evaluate the enhancement of nutrient removal using an integrated fixed-film activated sludge (IFAS) equipped with a commercial polyurethane biocarrier (PUB) and to elucidate the underlying microbial mechanisms.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>A field-scale anaerobic–anoxic–oxic system (48 m<sup>3</sup> d<sup>−1</sup>) was operated for 190 days, with 20% PUB added to the aerobic zone for the final 130 days. The addition of PUB significantly improved system performance, increasing the total nitrogen removal efficiency from 50.4% to 69.5% and enhancing the stability of phosphorus removal. Microbial analysis revealed the unique enrichment of key genera such as <i>Pseudomonas</i> and <i>Aeromonas</i> on the PUB biofilm. Functional gene sequencing demonstrated that nitrogen removal was achieved through a synergistic effect between conventional nitrification–denitrification and simultaneous nitrification–denitrification (SND) pathways. The porous structure of PUB promoted robust biofilm development with abundant extracellular polymeric substances.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>The PUB created a favorable microenvironment that selectively enriched functional microorganisms, enabling efficient simultaneous nitrogen and phosphorus removal, particularly via SND. These findings provide crucial mechanistic insights into PUB-enhanced systems and support their practical application for upgrading wastewater treatment plants to achieve stricter nutrient discharge standards. © 2026 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"101 9","pages":"1780-1789"},"PeriodicalIF":2.7,"publicationDate":"2026-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148662820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Data-driven insights into photocatalytic dye degradation: Ensemble learning and SHAP-based mechanistic interpretation 数据驱动的见解光催化染料降解:集合学习和基于shap的机制解释
IF 2.7 4区 生物学
Journal of chemical technology and biotechnology Pub Date : 2026-08-03 Epub Date: 2026-06-10 DOI: 10.1002/jctb.70207
Muhammad Tahir Amin
{"title":"Data-driven insights into photocatalytic dye degradation: Ensemble learning and SHAP-based mechanistic interpretation","authors":"Muhammad Tahir Amin","doi":"10.1002/jctb.70207","DOIUrl":"https://doi.org/10.1002/jctb.70207","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Photocatalytic dye degradation remains difficult to predict because performance depends on a complex interplay among catalyst composition, electronic structure, and operating conditions, while the available literature is often inconsistent in experimental design and reporting. In this study, a literature curated dataset containing photocatalytic degradation experiments from 305 studies was systematically analyzed using interpretable machine learning to reveal quantitative structure–activity relationships. The dataset integrates compositional descriptors including photocatalyst type, active metal, and support materials, with physicochemical and operational variables such as bandgap, surface area, catalyst dosage, reaction time, dye concentration, and solution volume.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>Among the evaluated models, ensemble methods, particularly Random Forest, achieved the best predictive performance (<i>R</i><sup>2</sup> ≈ 0.63, MAE ≈ 0.01), indicating a strong ability to capture nonlinear dependencies within heterogeneous literature data. Feature importance analysis and SHapley Additive exPlanations consistently identified reaction time, photocatalyst composition, and active-metal species as the dominant predictors of degradation efficiency. Bandgap energy and surface area showed secondary but mechanistically meaningful contributions. The model also reproduced key kinetic behaviors reported experimentally, including saturation trends with irradiation time and the nonlinear influence of bandgap on degradation performance.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>Despite limitations arising from literature heterogeneity and missing experimental descriptors, the results demonstrate that interpretable machine learning can convert fragmented experimental data into predictive and mechanistically meaningful insights. This framework provides a practical bases for the data-driven design and optimization of next-generation photocatalysts, while also underscoring the importance of more standardized experimental reporting to improve model reliability, reproducibility, and transferability. © 2026 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"101 9","pages":"1813-1829"},"PeriodicalIF":2.7,"publicationDate":"2026-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148662212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Data-driven insights into photocatalytic dye degradation: Ensemble learning and SHAP-based mechanistic interpretation 数据驱动的见解光催化染料降解:集合学习和基于shap的机制解释
IF 2.7 4区 生物学
Journal of chemical technology and biotechnology Pub Date : 2026-08-03 Epub Date: 2026-06-10 DOI: 10.1002/jctb.70207
Muhammad Tahir Amin
{"title":"Data-driven insights into photocatalytic dye degradation: Ensemble learning and SHAP-based mechanistic interpretation","authors":"Muhammad Tahir Amin","doi":"10.1002/jctb.70207","DOIUrl":"https://doi.org/10.1002/jctb.70207","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Photocatalytic dye degradation remains difficult to predict because performance depends on a complex interplay among catalyst composition, electronic structure, and operating conditions, while the available literature is often inconsistent in experimental design and reporting. In this study, a literature curated dataset containing photocatalytic degradation experiments from 305 studies was systematically analyzed using interpretable machine learning to reveal quantitative structure–activity relationships. The dataset integrates compositional descriptors including photocatalyst type, active metal, and support materials, with physicochemical and operational variables such as bandgap, surface area, catalyst dosage, reaction time, dye concentration, and solution volume.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>Among the evaluated models, ensemble methods, particularly Random Forest, achieved the best predictive performance (<i>R</i><sup>2</sup> ≈ 0.63, MAE ≈ 0.01), indicating a strong ability to capture nonlinear dependencies within heterogeneous literature data. Feature importance analysis and SHapley Additive exPlanations consistently identified reaction time, photocatalyst composition, and active-metal species as the dominant predictors of degradation efficiency. Bandgap energy and surface area showed secondary but mechanistically meaningful contributions. The model also reproduced key kinetic behaviors reported experimentally, including saturation trends with irradiation time and the nonlinear influence of bandgap on degradation performance.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>Despite limitations arising from literature heterogeneity and missing experimental descriptors, the results demonstrate that interpretable machine learning can convert fragmented experimental data into predictive and mechanistically meaningful insights. This framework provides a practical bases for the data-driven design and optimization of next-generation photocatalysts, while also underscoring the importance of more standardized experimental reporting to improve model reliability, reproducibility, and transferability. © 2026 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"101 9","pages":"1813-1829"},"PeriodicalIF":2.7,"publicationDate":"2026-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148662213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Roles of soil-inherent Fe minerals in bisphenol: A degradation by biochar/persulfate 土壤固有铁矿物在双酚中的作用:生物炭/过硫酸盐降解
IF 2.7 4区 生物学
Journal of chemical technology and biotechnology Pub Date : 2026-08-03 Epub Date: 2026-06-02 DOI: 10.1002/jctb.70205
Weiliang Zhang, Xing Yi, Xiao Chen, Shaojun Jiang, Yuehong Shu
{"title":"Roles of soil-inherent Fe minerals in bisphenol: A degradation by biochar/persulfate","authors":"Weiliang Zhang,&nbsp;Xing Yi,&nbsp;Xiao Chen,&nbsp;Shaojun Jiang,&nbsp;Yuehong Shu","doi":"10.1002/jctb.70205","DOIUrl":"https://doi.org/10.1002/jctb.70205","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>The advanced oxidation processes based on biochar-activated persulfate (BC/PS-AOPs) have been proven to be efficient in remediation of organics polluted soils. However, the roles and mechanisms of inherent soil constituents, especially the Fe fraction, in BC/PS-AOPs remain poorly understood. In this study, we investigated bisphenol A (BPA) degradation by BC/PS under the effect of two Fe minerals (ilmenite and hematite) at 2% and 4%, also accounting for the presence of organic matter and Mn minerals.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>Both hematite and ilmenite exhibited significant enhancement in BPA degradation in BC/PS-AOPs, reaching 74.7% and 85.2% respectively, at 4% Fe. Although hematite alone weakly activates PS, the biochar promoted the conversion of Fe(III) in hematite to Fe(II) and then efficiently activated PS. Both free radical pathway (•OH) and non-free radical pathway (1O2 and electron transfer) were involved in BPA degradation in BC/PS/ilmenite and BC/PS/hematite systems. Meanwhile, for both systems with higher Fe content (4%), the electron transfer pathway contributed more in BPA oxidation, in which electrons transferred from BPA to Fe/BC-PS* complexes. The existence of organic matter, including biochar, could facilitate PS activation by Fe-OM formation and promote Fe(III)/Fe(II) cycle. Birnessite could further improve the Fe(III)/Fe(II) cycle in the BC/PS/hematite/birnessite system, enhancing BPA oxidation.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>This study provides new insights into the positive roles of soil-inherent Fe minerals in BC/PS system, and provides important data on the remediation of soils contaminated with organic pollutants through BC/PS-AOPs. © 2026 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"101 9","pages":"1729-1741"},"PeriodicalIF":2.7,"publicationDate":"2026-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148662333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lactic acid bacteria from Amazonian fruits: Isolation and evaluation of probiotic potential 亚马逊水果中的乳酸菌:益生菌潜力的分离与评价
IF 2.7 4区 生物学
Journal of chemical technology and biotechnology Pub Date : 2026-08-03 Epub Date: 2026-06-11 DOI: 10.1002/jctb.70216
Omar S Pillaca-Pullo, Ana M Ortiz-Saravia, Marjorie Mendoza-Quezada, André M Lopes, Adela I Huaman-Susanibar, Jorge Villacrés-Vallejo, Nelson Bautista-Cruz
{"title":"Lactic acid bacteria from Amazonian fruits: Isolation and evaluation of probiotic potential","authors":"Omar S Pillaca-Pullo,&nbsp;Ana M Ortiz-Saravia,&nbsp;Marjorie Mendoza-Quezada,&nbsp;André M Lopes,&nbsp;Adela I Huaman-Susanibar,&nbsp;Jorge Villacrés-Vallejo,&nbsp;Nelson Bautista-Cruz","doi":"10.1002/jctb.70216","DOIUrl":"https://doi.org/10.1002/jctb.70216","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Lactic acid bacteria (LAB) are a well-recognized group of probiotic microorganisms with proven health benefits and wide-ranging applications in food, pharmaceutical, and cosmetic industries. Although LAB have been extensively studied in fermented foods, their occurrence in plant-based environments, particularly in tropical fruits, remains poorly characterized. The Amazon biome, with its exceptional biodiversity and unique climatic conditions, offers an untapped reservoir of microbial diversity that could harbor novel probiotic strains. This study investigated three Amazonian fruits, such as <i>Genipa americana</i>, <i>Pouteria caimito</i> (domesticated fruits), and <i>Solanum mammosum</i> (native fruit) for the isolation and characterization of potentially probiotic LAB.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>From 72 total isolates, 06 strains obtained from <i>P. caimito</i> were non-hemolytic and selected for <i>in vitro</i> probiotic assessment. Molecular identification revealed that these isolates belonged to the genera <i>Lactobacillus</i>, <i>Pediococcus</i>, and <i>Lactiplantibacillus</i>. Among them, isolate POU-25 (<i>Lactiplantibacillus plantarum</i>) exhibited superior probiotic features, including tolerance to acid and bile salts, strong autoaggregation and coaggregation with pathogens, and high surface hydrophobicity, traits associated with gastrointestinal survival and host adhesion.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>These findings expand the current understanding of LAB diversity in Amazonian fruits and position <i>Lactiplantibacillus plantarum</i> POU-25 as a promising candidate for future use in functional foods and beverages. Moreover, its potential for the sustainable biosynthesis of value-added compounds, such as lactic acid, underscores its industrial relevance in the pharmaceutical and cosmetic sectors. © 2026 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"101 9","pages":"1891-1905"},"PeriodicalIF":2.7,"publicationDate":"2026-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148662448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyelectrolyte-Enhanced Ultrafiltration for Copper Ion Removal from Industrial Wastewater 聚电解质强化超滤法去除工业废水中的铜离子
IF 2.7 4区 生物学
Journal of chemical technology and biotechnology Pub Date : 2026-08-03 Epub Date: 2026-06-19 DOI: 10.1002/jctb.70220
Molka Nafti-Mateur, Mouna Jaouadi, Karima Horchani Naifer, Dorra Jellouli Ennigrou
{"title":"Polyelectrolyte-Enhanced Ultrafiltration for Copper Ion Removal from Industrial Wastewater","authors":"Molka Nafti-Mateur,&nbsp;Mouna Jaouadi,&nbsp;Karima Horchani Naifer,&nbsp;Dorra Jellouli Ennigrou","doi":"10.1002/jctb.70220","DOIUrl":"https://doi.org/10.1002/jctb.70220","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> BACKGROUND</h3>\u0000 \u0000 <p>Copper contamination in industrial effluents represents a significant environmental concern and restricts wastewater reuse. This study aims to evaluate the performance of polymer-enhanced ultrafiltration (PEUF) for copper removal from industrial wastewater generated by a Tunisian cable manufacturing plant, using water-soluble polyelectrolytes as complexing agents.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> RESULTS</h3>\u0000 \u0000 <p>Three polyelectrolytes poly(acrylic acid) (PAA), poly(sodium 4-styrenesulfonate) (PSS), and polyethylenimine (PEI) were investigated. Preliminary experiments using synthetic copper solutions assessed the effects of transmembrane pressure; pH, polymer concentration, and molecular weight on permeate flux and copper rejection. Conventional ultrafiltration showed poor copper retention (&lt;13%), whereas PEUF significantly enhanced removal through the formation of polymer–metal complexes retained by the membrane. Under optimal conditions (3 bar, pH 7, and polymer concentration of 1000 ppm), copper rejection reached 96% with PEI and 95% with PSS, while PAA exhibited lower performance due to increased membrane fouling. When applied to real industrial wastewater, copper removal efficiencies of approximately 91% and 87% were achieved with PEI and PSS, respectively. Significant reductions in suspended solids, turbidity and conductivity were also observed, with moderate chemical oxygen demand removal.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> CONCLUSION</h3>\u0000 \u0000 <p>The PEUF process demonstrates high efficiency for copper removal and enables compliance with the Tunisian discharge standard NT 106-02. These results highlight PEUF as a promising and effective technique for industrial wastewater treatment and reuse. © 2026 Society of Chemical Industry (SCI).</p>\u0000 </section>\u0000 </div>","PeriodicalId":15335,"journal":{"name":"Journal of chemical technology and biotechnology","volume":"101 9","pages":"1790-1800"},"PeriodicalIF":2.7,"publicationDate":"2026-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148662667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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