Chinese Journal of Chemistry最新文献

{"title":"Precursor-Mediated Direct Growth of Defect-Rich Hierarchical Nanocarbons for Electrocatalytic Hydrogen Peroxide Production†","authors":"Xiaoting Sun,&nbsp;Tiantian Lu,&nbsp;Jialei Chen,&nbsp;Youzeng Li,&nbsp;Shan Chen,&nbsp;Xuelong Liao,&nbsp;Ying Liu,&nbsp;Runyu Lv,&nbsp;Huan Wang","doi":"10.1002/cjoc.202400455","DOIUrl":"10.1002/cjoc.202400455","url":null,"abstract":"<div>\u0000 \u0000 <p>Carbon-based nanomaterials show great potential in selective electrochemical oxygen reduction reaction (ORR) through two-electron (2e⁻) pathway for H₂O₂ production, which provides an eco-friendly alternative to industrial energy-intensive anthraquinone process. However, it still remains challenging to directly construct topological defects, which makes it difficult to study the working mechanism on 2e^– ORR. Herein, we propose a precursor-mediated chemical vapor deposition (CVD) approach for direct growth of topological defect-rich hierarchical nanocarbons. Boric acid (H₃BO₃) is introduced into the precursor for disturbing the nucleation and growth through decomposing B-containing species, which can <i>in situ</i> induce the formation of pentagon defects. The topological defect is found to be capable of introducing lattice strain, which can modify the electronic structure of nanocarbons and promote the key intermediate (*OOH) formation, thus greatly enhancing the 2e^– ORR performance. Experimentally, the 2e^– ORR selectivity shows a positive correlation to the topological defect density, where the average H₂O₂ selectivity reaches above 90% over a wide potential range with optimized concentration of H₃BO₃ as mediator. Moreover, in a flow cell, the hierarchical nanocarbons achieve a high H₂O₂ production rate of 998 mmol·g_catalyst⁻¹·h⁻¹ over 20 h of continuous electrocatalysis with stable current density (&gt;100 mA·cm^–2) and Faradaic efficiency (&gt; 90%). This work provides a straightforward method for the synthesis of active metal-free carbon-based catalyst for sustainable H₂O₂ production.</p>\u0000 <p>\u0000 </p>\u0000 </div>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"42 23","pages":"3113-3121"},"PeriodicalIF":5.5,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Formate-Mediated Synthesis of β-Hydroxysulfides from Olefins and Thiosulfonates via EDA Complex Strategy under Visible Light Irradiation in Air","authors":"Qing Shen,&nbsp;Xiaoyan Peng,&nbsp;Jiahong Sui,&nbsp;Min Peng,&nbsp;Xiangwei Liu,&nbsp;Hezhong Jiang,&nbsp;Rui Tan,&nbsp;Min Zhou,&nbsp;Jiahong Li","doi":"10.1002/cjoc.202400530","DOIUrl":"10.1002/cjoc.202400530","url":null,"abstract":"<div>\u0000 \u0000 <p>A visible-light-induced and efficient one-pot synthesis of <i>β</i>-hydroxysulfides from olefins, thiosulfonates and HCOOCs using an EDA complex strategy under air atmosphere at room temperature has been disclosed. A plausible radical involved mechanism is proposed. During the reaction process, formates play a crucial role: first, as donors in the EDA complex; second, as providers of the hydrogen source; and third, by generating CO₂^•– to reduce peroxide intermediates, leading to the formation of <i>β</i>-hydroxysulfides. In contrast to the previously reported thiol-oxygen co-oxidation reactions, this simple and sustainable approach features mild reaction conditions, operational simplicity, odorless and excellent functional group tolerance.</p>\u0000 <p>\u0000 </p>\u0000 </div>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"42 23","pages":"3129-3134"},"PeriodicalIF":5.5,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Deracemization of Sulfoxides Combining Electrocatalysis and Biocatalysis","authors":"Xinyu Duan,&nbsp;Dong Cui,&nbsp;Mengdi Wang,&nbsp;Yifan Tian,&nbsp;Jianan Shi,&nbsp;Yixue Wu,&nbsp;Shuang Liu,&nbsp;Zejie Zhu,&nbsp;Jian Xu","doi":"10.1002/cjoc.202400567","DOIUrl":"10.1002/cjoc.202400567","url":null,"abstract":"<div>\u0000 \u0000 <p>The concurrent implementation of cascade reactions that combine biocatalysis and chemocatalysis is a challenging undertaking. Electrocatalysis provides versatile catalytic abilities and allows for mild reaction conditions, offering the potential for designing concurrent chemoenzymatic cascade reactions. The research on bioelectrocatalysis has primarily concentrated on utilizing electrocatalysis to achieve cofactor regeneration of enzymes. In contrast with previous reports, herein, we developed a deracemization strategy involving the concurrent combination of biocatalytic reduction and anodic oxidation in an undivided cell to achieve chiral sulfoxides, demonstrating the good compatibility. We anticipate this study will offer an alternative pathway for the design of the cascade reaction combined with electrocatalysis and biocatalysis.</p>\u0000 <p>\u0000 </p>\u0000 </div>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"42 23","pages":"3107-3112"},"PeriodicalIF":5.5,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Photo-Excited Switching and Enhancement of Dielectric Properties in Two-Dimensional Double Perovskite Phase Transition Thin Films","authors":"Linjie Wei,&nbsp;Yi Liu,&nbsp;Tian Yang,&nbsp;Hao Rong,&nbsp;Xianmei Zhao,&nbsp;Jingtian Zhang,&nbsp;Junhua Luo,&nbsp;Zhihua Sun","doi":"10.1002/cjoc.202400529","DOIUrl":"10.1002/cjoc.202400529","url":null,"abstract":"<div>\u0000 \u0000 <p>Optical controlling of solid-sate electric properties is emerging as a non-contact and nondestructive avenue to optimize the physical properties of electronic and optoelectronic devices. In term of strong light-material coupling, two-dimensional (2D) double perovskites hold great prospects to create photo-dielectric activities for high-performance device applications. Here, we have achieved the photo-excited switching and enhancement of dielectric properties in the orientational thin films of a 2D double perovskite, (C₄H₁₂N)₄AgBiI₈ (<b>1</b>, where C₄H₉NH₃⁺ is isobutylammonium). It undergoes a structural phase transition at 384 K (<i>T</i>_c), triggered by the dynamic ordering of organic cations and tilting motion of isometallic perovskite sheets. Most notably, the orientational thin films of <b>1</b> are extremely sensitive to light illumination, of which the dielectric constants can be facilely photo-switched between the low- and high-states. During this photo-switching process, the dielectric constants are enhanced with a magnitude up to ~350% under 405 nm, far beyond most of the inorganic phase transition counterparts. In addition, this photo-excited switching and enhancement of dielectric response exhibits an operational stability with superior anti-fatigue characteristics. Our work opens up a potential avenue for assembling high-performance optoelectronic devices with the controllable physical properties.</p>\u0000 <p>\u0000 </p>\u0000 </div>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"42 23","pages":"3122-3128"},"PeriodicalIF":5.5,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142195546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Borane-Catalyzed Asymmetric Reduction of 2-Alkylpyridines†","authors":"Heng Luo,&nbsp;Zhao-Ying Yang,&nbsp;Ming Zhang,&nbsp;Xiao-Chen Wang","doi":"10.1002/cjoc.202400671","DOIUrl":"10.1002/cjoc.202400671","url":null,"abstract":"<div>\u0000 \u0000 <p>Herein, a method for the enantioselective reduction of unprotected 2-alkylpyridines is reported for the first time. By using pinacolborane and an amide as reducing agents, a large number of 2-alkylpiperidines were synthesized with high yields and excellent enantioselectivities via a cascade process involving 1,4-hydroboration and subsequent transfer hydrogenation. The resulting products can be easily converted to natural alkaloids.</p>\u0000 <p>\u0000 </p>\u0000 </div>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"42 23","pages":"3088-3092"},"PeriodicalIF":5.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141929090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of Three-Dimensional Chiral Covalent Organic Frameworks Using Surfactant as Inducer in Water","authors":"Meiying Huang,&nbsp;Zhipeng Zhou,&nbsp;Xin Dong,&nbsp;Yuyao Li,&nbsp;Yonghang Yang,&nbsp;Changye Zhan,&nbsp;Jiaxing Lu,&nbsp;Xiaoshu Wei,&nbsp;Yuexian Hong,&nbsp;Weiqi Cheng,&nbsp;Wei Liu,&nbsp;Zhongke Yuan,&nbsp;Xudong Chen,&nbsp;Zhikun Zheng","doi":"10.1002/cjoc.202400552","DOIUrl":"10.1002/cjoc.202400552","url":null,"abstract":"<div>\u0000 \u0000 <p>Chiral covalent organic frameworks (COFs) have shown promising applications in asymmetric catalysis, enantiomer separation and chiral recognition due to their tunable structures and permanent porosity. Currently, synthesis of chiral COFs mainly relies on direct- synthesis method which requires asymmetric monomers to polymerize and crystallize with symmetric monomers and post-synthesis method which has been greatly limited to having complete reactions with the micro-/meso-sized pores of COFs. Recently, the synthesis of two-dimensional COFs by covalent replacement of chiral competitor has been reported. Herein, we present the synthesis of three types of 3D COFs with tunable chirality using chiral amino acid derivative surfactant as inducer in water under ambient conditions. The hydrogen bonds and electrostatic interactions between amino acid derivative surfactant and monomers as well as their precursors facilitate the transfer of the chirality.</p>\u0000 <p>\u0000 </p>\u0000 </div>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"42 23","pages":"3093-3098"},"PeriodicalIF":5.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141935585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A GSH-Responsive Immune-Stimulating Polypeptide Hydrogel Loaded with Chemotherapeutics, IDO Inhibitor and Immune Checkpoint Blocking Antibody for Enhanced Anti-Tumor Chemo-Immunotherapy","authors":"Junfeng Ding,&nbsp;Tianran Wang,&nbsp;Yan Rong,&nbsp;Chaoliang He,&nbsp;Xuesi Chen","doi":"10.1002/cjoc.202400475","DOIUrl":"10.1002/cjoc.202400475","url":null,"abstract":"<div>\u0000 \u0000 <p>Due to the immunosuppressive tumor microenvironment (TME), T cells are usually inactivated and tend to differentiate into regulatory T cells (Tregs) in the tumor tissues, which seriously hinders the anti-tumor efficiency of immunotherapy. In this study, an immune-stimulating polypeptide hydrogel conjugated with an indoleamine-2,3-dioxygenase (IDO) inhibitor, 1-methyl-<i>D</i>-tryptophan (D1MT), through a glutathione (GSH)-responsive spacer was developed as an immunotherapy platform capable of regulating the TME. A combined immunotherapy system was further constructed through encapsulating doxorubicin (Dox) and immune checkpoint blocking antibody targeting programmed cell death protein 1 (aPD-1) in the hydrogel. Dox released from the hydrogel could cause the immunogenic cell death (ICD) of tumor cells and induce the maturation of antigen presenting cells (APCs). After intratumoral injection, the multiple agent-loaded hydrogel elicited effective anti-tumor immunity in mice bearing B16F10 melanoma. Moreover, compared with the control hydrogel without D1MT, the immune-stimulating hydrogel showed better efficiency in improving the immunosuppressive TME with increased number of activated T cells and reduced number of Tregs. Therefore, the immune-stimulating hydrogel has great potential as a stimuli-responsive platform for regulating suppressive TME and enhanced anti-tumor chemo-immunotherapy.</p>\u0000 <p></p>\u0000 </div>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"42 23","pages":"2957-2969"},"PeriodicalIF":5.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141928889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Palladium-Catalyzed Direct B—H Oxygenation: Facile Synthesis of o-Carboranofuranones†","authors":"Chenyang Guo,&nbsp;Zaozao Qiu,&nbsp;Zuowei Xie","doi":"10.1002/cjoc.202400571","DOIUrl":"10.1002/cjoc.202400571","url":null,"abstract":"<div>\u0000 \u0000 <p>Recent advances in transition metal-catalyzed <i>o</i>-carborane B—H activation have led to the rapid development of various methodologies for cage boron functionalization. For catalytic cage B—H acyloxylation, intermolecular oxygenation gave products with different regioselectivities (B(3)-, B(4)-, and B(8,9)-selectivities). Herein, an efficient palladium-catalyzed direct cage B(4)–H oxygenation of <i>o</i>-carboranylacetic acids has been achieved, where the carboxylic group serves as not only a directing group, but also a coupling partner. A wide range of substituted <i>o</i>-carboranylacetic acids have been cyclized via the formation of B(4)−O bond to give the corresponding γ-lactones in modest to excellent yields. A Pd(IV) intermediate is proposed to be involved in the catalytic cycle. This work offers valuable references for the BH/OH dehydrocoupling reactions under mild conditions to produce carborane-featuring functional molecules.</p>\u0000 <p>\u0000 </p>\u0000 </div>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"42 23","pages":"3083-3087"},"PeriodicalIF":5.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141935586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sandwich-Type Single-Molecule Magnets Complexes of Er(III) with Ansa-Cyclooctatetraenyl Ligands†","authors":"You-Song Ding,&nbsp;Qi-Wei Chen,&nbsp;Jia-Qi Huang,&nbsp;Xiao-Fei Zhu,&nbsp;Zhiping Zheng","doi":"10.1002/cjoc.202400600","DOIUrl":"10.1002/cjoc.202400600","url":null,"abstract":"<div>\u0000 \u0000 <p>Many sandwich-type lanthanide complexes show extremely high energy barriers (<i>U</i>_eff) for the reversal of magnetization and high blocking temperatures, being the star molecules in the research area of single-molecule magnets. Herein, the preparation, structural determination, and magnetic property studies of two <i>ansa</i>-bridged Er-COT (COT = cyclooctatetraenyl dianion) complexes [KDME₂][Er((η⁸-COT-Si^Me2)₂O)] (<b>1</b>) and [KDME₂][Er((η⁸-COT-Si^<i>i</i>Pr2)₂O)]K[Er((η⁸-COT-Si^<i>i</i>Pr2)₂O)] (<b>2</b>) were reported. The Er(III) ions in both complexes are sandwiched by two COT rings which are <i>ansa</i>-bridged by a [Si-O-Si] group. Magnetic studies reveal both complexes display slow magnetic relaxations with comparable energy barriers (228(5) K for <b>1</b>, and 196(4) K for <b>2</b>) and blocking temperatures (10.5 K for both complexes). The difference in the relaxation times (<i>τ</i>) for the two complexes was studied in details: different molecular vibrations induced by the substituents are the main reason for <i>τ</i> for <b>1</b> being about 10 times longer than for <b>2</b> at the same temperature above 10 K, while the quantum tunnelling of magnetization relaxation time (<i>τ</i>_QTM) for <b>2</b> is about 10 times longer than for <b>1</b> below 8 K, probably owing to the different dipolar interactions. Further rearrangement of molecular network with such <i>ansa</i>-bridged SMMs is promising to design molecular magnetic materials with enhanced properties or new properties.</p>\u0000 <p>\u0000 </p>\u0000 </div>","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"42 23","pages":"3099-3106"},"PeriodicalIF":5.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141926801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Metal-Decorated Porous Organic Polymers: Bridged the Gap between Organic and Inorganic Scaffolds†","authors":"Zhu Gao,&nbsp;Yufei Liu,&nbsp;Shaofei Wu,&nbsp;Juntao Tang,&nbsp;Kuanyu Yuan,&nbsp;Chunyue Pan,&nbsp;Guipeng Yu","doi":"10.1002/cjoc.202400386","DOIUrl":"10.1002/cjoc.202400386","url":null,"abstract":"&lt;div&gt;\u0000 \u0000 &lt;section&gt;\u0000 \u0000 &lt;h3&gt; Comprehensive Summary&lt;/h3&gt;\u0000 \u0000 &lt;p&gt;Advanced functionalization-decorated porous organic polymers (POPs) are emerging as a prominent research focus, spanning from their construction to applications in gas storage and separation, catalysis, energy storage, electrochemistry, and other areas. Furthermore, the inherent organic nature, tailored pore structures, and adjustable chemical components of POPs offer a versatile platform for the incorporation of various metal active sites. Meticulously designed molecular building blocks can serve as organic ligands uniformly distributed throughout POPs, leading to the effective isolation of inorganic metal active sites at the molecular level. In this manner, POPs containing active metal centers bridge the gap between organic and inorganic scaffolds. This review aims to provide an overview of recent research progress on metal-decorated POPs, focusing on strategies for incorporating metal active sites into POPs and their applications in adsorption, separation, catalysis, and photoelectrochemistry. Finally, current challenges and future prospects are discussed for further research.&lt;/p&gt;\u0000 \u0000 &lt;p&gt;\u0000 &lt;/p&gt;\u0000 &lt;/section&gt;\u0000 \u0000 &lt;section&gt;\u0000 \u0000 &lt;h3&gt; Key Scientists&lt;/h3&gt;\u0000 \u0000 &lt;p&gt;Advanced functionalized porous organic polymers have become a new research hotspot, ranging from their construction to their use in gas storage and separation, catalysis, energy storage, electrochemistry, and other applications. In 2002, the McKeown group was the first to report phthalocyanine-based MPOPs with permanent porosity and a moderate surface area. In 2010, the Yu group prepared nanoporous polyporphyrin materials P(Fe-TTPP) from the metallated porphyrin with functionalized thiophenyl groups by the FeCl&lt;sub&gt;3&lt;/sub&gt; catalyzed oxidation couple reaction showing the surface area of 1522 m&lt;sup&gt;2&lt;/sup&gt;·g&lt;sup&gt;–1&lt;/sup&gt;. Subsequently, in 2013, the Deng group was the first to use metalated salens as the original building blocks for preparing MPOPs. The Morin group was the first to produce a series of ferrocene-based nanoporous frameworks via radical polymerization, with surface areas ranging from 385 to 899 m&lt;sup&gt;2&lt;/sup&gt;·g&lt;sup&gt;–1&lt;/sup&gt;. In 2016, the Han group synthesized two &lt;i&gt;N&lt;/i&gt;-pyridinylphenylcarbazole (PPC) ligands to produce a series of metalized polycarbazole networks. Recently, the Tan group reported a solvent-knitting hyper-cross-linking reaction to produce HUST-1, which contains a porphyrin unit. The porphyrin moiety provides a centered square-planar metal post-coordination site, resulting in the metalated HUST-1-Co, which exhibits high efficiency in the catalytic conversion of CO&lt;sub&gt;2&lt;/sub&gt;. Additionally, the Kegnæs group combined the decomposition of the palladium complex with an &lt;i&gt;in situ&lt;/i&gt; catalyzed polymerization reaction, enabling the confinement of nasc","PeriodicalId":151,"journal":{"name":"Chinese Journal of Chemistry","volume":"42 22","pages":"2902-2934"},"PeriodicalIF":5.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141928698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}