ChemistrySelectPub Date : 2025-04-22DOI: 10.1002/slct.202500203
Nguyen Minh Hoa
{"title":"Influence of Sulfur Precursor Reactivity on Size-Controlled and Optical Properties of CdS Nanocrystals","authors":"Nguyen Minh Hoa","doi":"10.1002/slct.202500203","DOIUrl":"https://doi.org/10.1002/slct.202500203","url":null,"abstract":"<p>This study investigates the synthesis of cadmium sulfide (CdS) nanocrystals (NCs) using a hot-injection method, focusing on how sulfur precursor reactivity, controlled by its preparation temperature, influences the final nanomaterial properties. The sulfur precursor was prepared at three temperatures (120, 140, and 180 °C) to modulate its reactivity. Transmission electron microscopy, UV–vis spectroscopy, and photoluminescence spectroscopy were employed to characterize the size, morphology, and optical properties of the resulting CdS NCs. We found a clear correlation between the sulfur precursor preparation temperature and the CdS nanocrystal properties. The precursor prepared at 140 °C resulted in the most homogeneous growth, leading to the smallest size distribution and highest quality NCs, as evidenced by the higher PL intensity. The precursor prepared at 180 °C resulted in a faster growth rate, ultimately leading to larger NCs with inhomogeneous morphologies, while the 120 °C precursor exhibited the slowest growth rate, producing larger particles with a wider size distribution. These findings underscore the significant role of sulfur precursor preparation temperature in controlling the final CdS nanocrystal material properties, offering valuable insights for the tailored synthesis of high-quality CdS nanomaterials for diverse applications.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 16","pages":""},"PeriodicalIF":1.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143857071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemistrySelectPub Date : 2025-04-22DOI: 10.1002/slct.202500904
Dinesh P. Shinde, Yogesh A. Pathak, Aparna T. Mane, Dattatray H. Bobade, Gajanan M. Hingangavkar, Shaukat L. Tamboli, Sanjeev D. Chavan
{"title":"Unravelling the Role of Synthesis Temperature in δ-MnO2 Nanosphere Formation for High-Performance Supercapacitors","authors":"Dinesh P. Shinde, Yogesh A. Pathak, Aparna T. Mane, Dattatray H. Bobade, Gajanan M. Hingangavkar, Shaukat L. Tamboli, Sanjeev D. Chavan","doi":"10.1002/slct.202500904","DOIUrl":"https://doi.org/10.1002/slct.202500904","url":null,"abstract":"<p>In the present research work, reported a role of controlled temperature for the synthesis of the 2D layered structure of the δ-MnO<sub>2</sub> nanospheres, for high capacitance, were synthesized using the simple, facile hydrothermal method. The temperature taken for the synthesis of δ-MnO<sub>2</sub> as 140, 160, and 180 °C. The highest specific capacitance 525.93 F g<sup>−1</sup> in 1 <span>m</span> Na<sub>2</sub>SO<sub>4</sub> electrolyte for 5 mV s<sup>−1</sup> scan rate was observed for the sample prepared at a temperature 180 °C. The symmetric δ-MnO<sub>2</sub> supercapacitor device was fabricated using a liquid-state assembly process, with EIS confirmed low charge transfer resistance and excellent cycling stability. From XRD studies, confirmed that the synthesized material is δ-MnO<sub>2</sub> with crystalline size increases from 10 to 16 nm as the temperature increases. FESEM confirmed that the prepared sample is of nanosphere like morphology, and the average grain size decreases from 700 to 300 nm as the temperature increases. EDAX analysis reveals that the prepared sample only contains Mn and O there is no any impurity present. Advantageously, the water contact angle of the prepared electrode is hydrophilic in nature. The Raman and FTIR spectroscopy investigated the chemical structure and functional groups present in δ-MnO<sub>2</sub>. The oxidation states of Mn and O are analysed using XPS.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 16","pages":""},"PeriodicalIF":1.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemistrySelectPub Date : 2025-04-22DOI: 10.1002/slct.202500121
Dr. Diana C. Pinilla Peña, Dr. Laura I. Rossi
{"title":"Native α- and β-Cyclodextrin Cobalt Complexes as Catalysts in Sulfoxidation Reaction","authors":"Dr. Diana C. Pinilla Peña, Dr. Laura I. Rossi","doi":"10.1002/slct.202500121","DOIUrl":"https://doi.org/10.1002/slct.202500121","url":null,"abstract":"<p>Four complexes were synthesised between bromide cobalt salt and native α- and β-cyclodextrins using dichloromethane or ethyl acetate as solvents. These were characterised by techniques such as IR, TGA and UV–vis diffuse reflectance. These complexes were used as catalysts in the sulfoxidation reaction, being β-CD/CoBr<sub>2(DCM)</sub> is the more efficient complex. The reaction conditions studied yielded good results with high chemoselectivity, as the aldehyde and sulfoxide functional groups were not oxidized under these conditions. The evaluation using green chemistry parameters showed good results. The use of EtOAc, a green solvent, in the synthesis of the complexes is highlighted.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 16","pages":""},"PeriodicalIF":1.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemistrySelectPub Date : 2025-04-22DOI: 10.1002/slct.202404941
Varnakumar Gayathri, R.T. Birla Sheyara, M. Satheeshkumar, Suresh Prem, Dr. Niraikulam Ayyadurai, Dr. Nitin P. Lobo, Dr. Debasis Samanta
{"title":"Click-Chemistry Based Functionalization of Biomolecules and Biopolymers Using a Thermo-Responsive Smart Catalyst","authors":"Varnakumar Gayathri, R.T. Birla Sheyara, M. Satheeshkumar, Suresh Prem, Dr. Niraikulam Ayyadurai, Dr. Nitin P. Lobo, Dr. Debasis Samanta","doi":"10.1002/slct.202404941","DOIUrl":"https://doi.org/10.1002/slct.202404941","url":null,"abstract":"<p>In this paper, we report the convenient application of the Click reaction to collagen and bovine serum albumin (BSA) using a thermoresponsive catalyst we recently developed. The catalyst's thermoresponsive nature allows for its facile removal from the reaction medium by simply raising the temperature. The Click reaction was performed in aqueous solution and on surfaces using a self-assembled monolayer formation technique after appropriate functionalization of the collagen or BSA. Successful functionalization and Click reactions were confirmed through analysis by XPS, solid-state NMR spectroscopy (¹<sup>3</sup>C, ¹⁵N, and <sup>2</sup>⁹Si), IR spectroscopy, and microscopy. For instance, the characteristic azide signal in FTIR and the <sup>2</sup>⁹Si solid-state NMR spectrum confirmed the initial functionalization step. XPS, solid-state NMR, and microscopy validated the Click reaction on both BSA and collagen. Notably, the ¹⁵N solid-state NMR data provided compelling evidence of triazole formation after the Click reaction.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 16","pages":""},"PeriodicalIF":1.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemistrySelectPub Date : 2025-04-22DOI: 10.1002/slct.202406191
Gamze Demirel, Emine Incilay Torunoğlu, Erdi Can Aytar, Zeynep Betul Sarı, Muhammet Emin Sarı, Alper Durmaz
{"title":"Antioxidant Potential, Selective Cytotoxicity, and Molecular Docking Insights of Maresia nana Methanol Extract against A549 Cancer Cells","authors":"Gamze Demirel, Emine Incilay Torunoğlu, Erdi Can Aytar, Zeynep Betul Sarı, Muhammet Emin Sarı, Alper Durmaz","doi":"10.1002/slct.202406191","DOIUrl":"https://doi.org/10.1002/slct.202406191","url":null,"abstract":"<p>In this study, the antioxidant activity, phenolic content, and cytotoxicity of the above-ground parts of <i>Maresia nana</i> were evaluated using various assays. Antioxidant activity was assessed using the DPPH radical scavenging test, yielding an IC<sub>50</sub> value of 90.55 ± 11.14 mg mL<sup>−1</sup>. The total flavanol content of the extract was 0.41 ± 0.01 mg QE/g, the total flavonoid content was 29.26 ± 1.88 mg QE/g, and the total phenolic content was 29.76 ± 2.64 mg GAE/g, indicating significant antioxidant properties and richness in phytochemical compounds. Additionally, GC-MS analysis identified eight bioactive compounds in the methanol extract of <i>M. nana</i>. The extract demonstrated 58.50 ± 3.5% cytotoxicity in A549 cells at the highest dose, while it increased proliferation in HEK293 cells, indicating selective cytotoxicity toward cancer cells. Furthermore, the binding affinities and interactions of two small-molecule ligands, Acridin-1(2H)-one, 3,4-dihydro-3,3-dimethyl-9-propylamino- and Androsta-3,5-diene-3,17-diol diacetate, with the Ras protein were investigated. Acridin-1(2H)-one showed a binding energy of −5.1 kcal mol<sup>−1</sup>, while Androsta-3,5-diene-3,17-diol diacetate demonstrated a stronger binding affinity with a binding energy of −5.5 kcal mol<sup>−1</sup>. In conclusion, the <i>M. nana</i> extract's antioxidant and phenolic profiles support its potential health benefits, and its selective cytotoxic effects on cancer cells suggest its promise for cancer therapy. Additionally, the binding characteristics of the ligands provide valuable insights for future drug development strategies.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 16","pages":""},"PeriodicalIF":1.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143857125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Optimizing the Biosorption of Cadmium and Lead Ions on Agave Biomass Using Box–Behnken Response Methodology","authors":"Djamila Ikhou, Brahim Guezzen, Mohamed Kadari, Hanane Ziani, Saadia Lahreche, M'hamed Kaid, Didier Villemin","doi":"10.1002/slct.202405192","DOIUrl":"https://doi.org/10.1002/slct.202405192","url":null,"abstract":"<p>This research explored the potential of Agave leaf biomass (ALB) as a biosorbent for the removal of Pb(II) and Cd(II) ions from an aqueous solution. FT-IR, XRD, and SEM techniques were used to characterize the adsorbent biomass. A series of batch experiments at varying contact times, pH, adsorbent doses, initial metal concentrations, and salt concentrations were conducted. Box–Behnken design (BBD) was used for statistical analysis of the adsorption parameters for metal ion removal, modeled by response surface methodology (RSM). The proposed quadratic model was found to be suitable and highly significant for the experimental data, with predicted values < 0.05 for the adsorption efficiency, showing a strong agreement with the experimental results, confirming a significant regression coefficient at a 95% confidence interval (<i>R</i><sup>2</sup> = 0.9717 for Pb(II) and <i>R</i><sup>2</sup> = 0.9717 for Cd(II)). Salt concentration and initial metal ion concentration have a significant effect on the percentage removed. The optimum conditions of 0.8 and 0.2 mmol/L concentration and 0.18 and 0.17 g adsorbent dose at pH 3 and pH 6 can achieve a removal of 97.76% and 79.38% for Pb(II) and Cd(II) respectively. The adsorption mechanism confirmed that the Freundlich isotherm model provided the best fit due to its higher linear regression coefficient compared to other models (<i>R</i><sup>2</sup> = 0.97 for Pb(II) and <i>R</i><sup>2</sup> = 0.98 for Cd(II). The kinetic data of metal ion adsorption were well described by pseudo-second-order kinetics. The reusability of the adsorbent shows that it retains approximately 68.52% and 50.39% of its adsorption for Pb(II) and Cd(II), respectively, after seven successive adsorption–desorption cycles, suggesting that the studied adsorbent has a significant potential for industrial wastewater treatment applications.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 16","pages":""},"PeriodicalIF":1.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143856780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemistrySelectPub Date : 2025-04-22DOI: 10.1002/slct.202500909
V. P. Madhurima, Kusum Kumari, P. K. Jain
{"title":"Synergistic Wastewater Detoxification Using h-BN and g-C3N4: Understanding the Photo-Assisted Charge Carrier Dynamics","authors":"V. P. Madhurima, Kusum Kumari, P. K. Jain","doi":"10.1002/slct.202500909","DOIUrl":"https://doi.org/10.1002/slct.202500909","url":null,"abstract":"<p>A hybrid material combining graphene-like hexagonal boron nitride (h-BN) and graphitic carbon nitride (g-C<sub>3</sub>N<sub>4</sub>), activated by visible light, was synthesized using a straightforward pyrolysis method. The hybrid structure was confirmed through various characterization techniques like XRD, SEM, and TEM, etc. Evaluations using rhodamine B (RhB) degradation under visible light revealed outstanding performance, with the hybrid photocatayst containing 0.5% h-BN in g-C<sub>3</sub>N<sub>4</sub> achieving nearly complete degradation within 60 min while the pristine g-C<sub>3</sub>N<sub>4</sub> showed 55% degradation under similar experimental conditions and the rate of degradation increased up to three times after the incorporation of h-BN. This exceptional performance was attributed to the efficient separation of photoinduced charge carriers. The hybrid's significant specific surface area facilitated ample surface-active sites for pollutant adsorption and degradation. Moreover, its stable structure and appropriate bandgap contributed to enhanced efficiency in pollutant removal. The study proposes a degradation mechanism based on these findings, marking a significant advancement in 2D/2D photocatalyst systems for both energy and environmental applications.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 16","pages":""},"PeriodicalIF":1.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemistrySelectPub Date : 2025-04-22DOI: 10.1002/slct.202500229
Shahid Iqbal, Amal M. Al-Mohaimeed, Mohammad Ashraf Hossain, Mohamed Soliman Elshikh, Rashid Iqbal, Lala Gurbanova, Md Rezaul Karim, Muhammad Jamshaid
{"title":"Hyaluronic Acid-Mediated Ge0.5Fe2.5O4 Nanoparticles: In Relation to Photocatalytic Performance for Organic Dye Degradation","authors":"Shahid Iqbal, Amal M. Al-Mohaimeed, Mohammad Ashraf Hossain, Mohamed Soliman Elshikh, Rashid Iqbal, Lala Gurbanova, Md Rezaul Karim, Muhammad Jamshaid","doi":"10.1002/slct.202500229","DOIUrl":"https://doi.org/10.1002/slct.202500229","url":null,"abstract":"<p>The present study reports the systematic synthesis, characterization, and photocatalytic evaluation of germanium-substituted iron oxide (Ge<sub>0.5</sub>Fe<sub>2.5</sub>O<sub>4</sub>) nanoparticles with varying concentrations of hyaluronic acid (HA). The synthesized nanoparticles were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and Brunauer–Emmett–Teller (BET) analysis. The XRD confirmed the formation of Ge<sub>0.5</sub>Fe<sub>2.5</sub>O<sub>4</sub> with a crystallite size of 19 nm. The FTIR and SEM analysis verified the successful incorporation of Ge and HA into the iron oxide lattice. BET analysis revealed increased porosity upon HA addition, indicating potential benefits for catalytic applications. The photocatalytic efficiency of the nanoparticles was assessed using methylene blue dye degradation as a model reaction. Surprisingly, pristine Ge<sub>0.5</sub>Fe<sub>2.5</sub>O<sub>4</sub> exhibited an impressive 89.11% degradation rate, greater than (6% and 12%) HA-modified Ge<sub>0.5</sub>Fe<sub>2.5</sub>O<sub>4</sub> photocatalysts. These findings highlight the complex interaction between surface chemistry, porosity, and catalytic activity.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 16","pages":""},"PeriodicalIF":1.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143857127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemistrySelectPub Date : 2025-04-22DOI: 10.1002/slct.202500414
Qianqian Ma, Yilin Wang, Zonglin Yi, Lijing Xie, Fangyuan Su, Guohua Sun, Gongling Hui, Wei Xie, Chengmeng Chen, Yaqin Hou
{"title":"Research on the Controlled Synthesis of Phenolic Resin-Based Carbon Microspheres and Their Sodium Storage Behavior","authors":"Qianqian Ma, Yilin Wang, Zonglin Yi, Lijing Xie, Fangyuan Su, Guohua Sun, Gongling Hui, Wei Xie, Chengmeng Chen, Yaqin Hou","doi":"10.1002/slct.202500414","DOIUrl":"https://doi.org/10.1002/slct.202500414","url":null,"abstract":"<p>Phenolic resin is considered a promising precursor for advanced hard carbon anodes in sodium-ion batteries (NIBs) due to its ease of design, structural stability, and high residual carbon yield. However, the practical application of hard carbon is affected by its closed-pore content and structure. Here, we achieve fine control over the cross-linking structure of phenolic resin precursors by adjusting the catalyst content in the system, followed by high-temperature carbonization to produce phenolic resin-based carbon microspheres with small sizes (2–4 µm), monodispersity, and a narrow spherical diameter distribution. Based on this, we deeply explore the intrinsic relationship between the microstructure of these resin-based carbon microspheres and their sodium storage performance in NIBs. This strategy can provide a feasible molecular cross-linking engineering approach for the development of closed pores in phenolic resin-based hard carbon to tune electrochemical properties such as the plateau region capacity.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 16","pages":""},"PeriodicalIF":1.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143861553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemistrySelectPub Date : 2025-04-22DOI: 10.1002/slct.202501499
Dinesh S Shinde, Aarzoo F Qazi, Harshal R Patil, Ritvika Shukla, Dr. Rajendra D Patil, Dr. Pawan Gupta
{"title":"Green and Tandem Synthesis of Heterocyclic α,α’-Dibromocycloamides and Their Target Predictions and ADMET Analysis","authors":"Dinesh S Shinde, Aarzoo F Qazi, Harshal R Patil, Ritvika Shukla, Dr. Rajendra D Patil, Dr. Pawan Gupta","doi":"10.1002/slct.202501499","DOIUrl":"https://doi.org/10.1002/slct.202501499","url":null,"abstract":"<p>Oxy-bromination of cyclic amines to corresponding α,α’-dibromocycloamide(s) using bromide-bromate couple in aqueous acetic acid and at 60 °C (oil bath) is presented in the current work. A various types of cyclic amines were successfully oxybrominated during this work. Separation of the desired product by filtration therefore avoiding need of column chromatography, use of bromide-bromate couple as safe and stable source of oxy-bromination agent, mild reaction conditions and so on are the merits of the present research method. In silico ADMET and target prediction studies indicated that novel α,α’-dibromocycloamides possess satisfactory pharmacokinetic and pharmacodynamic profiles. The identified therapeutic targets provided a foundation for developing optimized molecules targeting therapeutically significant classes. The HOMO-LUMO energy calculations of the molecules using DFT method showed that Mole 3 and Mole 4 exhibited low gap energy and demonstrated high reactivity. However, Mole 5, Mole 6, Mole 7 and Mole 9 were found with high gap energy, thereby producing less reactivity or high stability. The high reactive molecules could be potential lead molecules which can interact efficiently with the drug targets. However, further experimental studies (in vitro/in vivo) are necessary to gain deeper insights into the pharmacological activities of these compounds.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"10 16","pages":""},"PeriodicalIF":1.9,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143856786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}