发布求助
文献互助 智能选刊 最新文献

Chemistry - A European Journal最新文献

筛选
英文 中文
CoFe Hydroxide Nanopheres for Enhanced Alkaline Splitting and Seawater Oxidation:Anion Doping Effects of Fluorine and Carbonate. 用于增强碱性拆分和海水氧化的氢氧化钴铁纳米粒子：氟和碳酸盐的阴离子掺杂效应。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-17 DOI: 10.1002/chem.202403628
Tingting Zheng, Junyu Shi, Dandan Wang, Yulin Min, Qunjie Xu, Qiaoxia Li
{"title":"CoFe Hydroxide Nanopheres for Enhanced Alkaline Splitting and Seawater Oxidation:Anion Doping Effects of Fluorine and Carbonate.","authors":"Tingting Zheng, Junyu Shi, Dandan Wang, Yulin Min, Qunjie Xu, Qiaoxia Li","doi":"10.1002/chem.202403628","DOIUrl":"https://doi.org/10.1002/chem.202403628","url":null,"abstract":"<p><p>Green hydrogen production can be achieved through electrolysis of fresh water or the use of renewable energy to electrolyze seawater. However, due to the low activity and poor stability of oxygen evolution reaction catalysts, direct electrolysis of alkaline seawater faces significant challenges. Herein, The catalyst F-CoFe(OH)-CO3/NF with three-dimensional nanosphere structure was prepared, The introduction of CO32- into the intermediate layer of CoFe Hydroxide improves the corrosion resistance of alkaline electrolyte and the doping of F- is to design three-dimensional layered nanostructures, increase the active site, and accelerate the diffusion of the electrolyte. By in situ Raman analysis, partial oxidation of CoFe hydroxide to CoFe (oxy)hydroxide as the active center can accelerating the adsorption of oxygen-related intermediates. In 1M KOH, it requires overpotentials of 210 mV and 251mV to drive current densities of 10 and 100 mA cm-2, respectively. And it remained stable at the current density of 100 mA cm-2 for 120 h in 1M KOH.  F-CoFe(OH)-CO3/NF can also catalyzes the decomposition of electrolytic seawater. Compared with hydroxide, anion-doped carbonate hydroxide is more efficient and stable in electrolyte solution, which is of great importance for the development of a new stable electrocatalyst for water decomposition.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403628"},"PeriodicalIF":3.9,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142646132","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Towards Designer Photocatalysts: Structure-Property Relationships in 2,6-Diaryl-pyryliums. 实现设计光催化剂：2,6-Diaryl-pyryliums 的结构-性能关系。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-17 DOI: 10.1002/chem.202403543
Jenna Konzal, McKenna Murley, Alaina Wolter, Lazlo Camou, Alex Oberbroeckling, Madilyn Dekker, Gillianne Wagner, Kate Jennejohn, Madison Peters, Natalie Hayes, Cory Franklin, Sydney Tobin, Elizabeth Collier, Ian MacKenzie
{"title":"Towards Designer Photocatalysts: Structure-Property Relationships in 2,6-Diaryl-pyryliums.","authors":"Jenna Konzal, McKenna Murley, Alaina Wolter, Lazlo Camou, Alex Oberbroeckling, Madilyn Dekker, Gillianne Wagner, Kate Jennejohn, Madison Peters, Natalie Hayes, Cory Franklin, Sydney Tobin, Elizabeth Collier, Ian MacKenzie","doi":"10.1002/chem.202403543","DOIUrl":"https://doi.org/10.1002/chem.202403543","url":null,"abstract":"<p><p>Fully organic photocatalyst systems are highly attractive, not merely because they are transition-metal free, but more importantly due to their unique and often potent reactivity. A detailed understanding of the various redox states, both ground and excited state, and specifically what structural parameters control them is therefore crucial for harnessing the full potential of these systems in organic synthesis. However, unlike their organometallic counterparts, detailed structure-property relationships for organic photocatalysts are largely absent from the literature. In this study, we demonstrate linear free-energy relationships across a range of key photophysical and electrochemical properties of 2,6-diarylpyryliums. Electronic absorption and emission maxima can be carefully tuned over the ranges of 83 nm and 102 nm respectively. Intramolecular charge transfer (ICT) interactions were revealed in cases of substitution with polarizable heavy-atoms. A strong linear dependence of ground state reduction potentials on substituent electronics was observed. Notably, the excited state reduction potential, E*red, could be controlled over a range of nearly 1000 mV. Systematic errors in computational modeling of ground and excited state redox potentials were identified and corrected. We believe the quantitative structure-property relationships identified here provide foundational tools for rational and predictive organic photocatalyst design.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403543"},"PeriodicalIF":3.9,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142646151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Morphological Evolution of Metal-Organic Frameworks into Hedrite, Sheaf and Spherulite Superstructures with Localized Different Coloration. 金属有机框架的形态演变：赫德岩、叶片岩和球粒岩上层结构的局部不同着色。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-17 DOI: 10.1002/chem.202403577
Naveen Malik, Linda J W Shimon, Lothar Houben, Anna Kossoy, Iddo Pinkas, Ifat Kaplan-Ashiri, Tatyana Bendikov, Michal Lahav, Milko Erik van der Boom
{"title":"Morphological Evolution of Metal-Organic Frameworks into Hedrite, Sheaf and Spherulite Superstructures with Localized Different Coloration.","authors":"Naveen Malik, Linda J W Shimon, Lothar Houben, Anna Kossoy, Iddo Pinkas, Ifat Kaplan-Ashiri, Tatyana Bendikov, Michal Lahav, Milko Erik van der Boom","doi":"10.1002/chem.202403577","DOIUrl":"https://doi.org/10.1002/chem.202403577","url":null,"abstract":"<p><p>The branched metal-organic frameworks (MOFs) are the first superstructures of this kind, and the growth mechanism may explain crystal shapes of other materials. The mechanism of the formation of fascinating structures having a hedrite, sheaf or spherulite appearance are detailed. The branching can be controlled, resulting in crystals that either exhibit multiple generations of branching or a single generation. These structures might result from an increasing number of defects on fast-grown rods. As the basal facets become less reactive, material is added to the prism facets, leading to secondary nucleation and triangular branches. These triangular structures are connected to the rod surface, growing longer than the central rod. Electron diffraction analyses show that the sheafs are polycrystalline structures with their fantails consisting of single-crystalline nanorods deviating gradually from each-other in their orientation. The crystallographic structure formed from achiral components consists of helical channels with opposite handedness. The accessibility of the nanochannels and the porosity of the superstructures are demonstrated by chromophore diffusion into the channels. The confinement and alignment of the chromophores inside the channels resulted in polarized-light dependent coloration of the crystals; the polycrystallinity generated areas having different optical properties.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403577"},"PeriodicalIF":3.9,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142646137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cover Feature: Formation and Stability of Benzylic Amide [2]- and [3]Rotaxanes: An Intercomponent Interactions Study (Chem. Eur. J. 64/2024) 封面专题：苄基酰胺 [2]- 和 [3]Rotaxanes 的形成和稳定性：成分间相互作用研究》（《欧洲化学杂志》64/2024）
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-16 DOI: 10.1002/chem.202486403
Tainára Orlando, Gustavo Henrique Weimer, Paulo Roberto dos Santos Salbego, Alberto Martinez-Cuezva, Jose Berna, Marcos Antonio Pinto Martins
{"title":"Cover Feature: Formation and Stability of Benzylic Amide [2]- and [3]Rotaxanes: An Intercomponent Interactions Study (Chem. Eur. J. 64/2024)","authors":"Tainára Orlando,&nbsp;Gustavo Henrique Weimer,&nbsp;Paulo Roberto dos Santos Salbego,&nbsp;Alberto Martinez-Cuezva,&nbsp;Jose Berna,&nbsp;Marcos Antonio Pinto Martins","doi":"10.1002/chem.202486403","DOIUrl":"https://doi.org/10.1002/chem.202486403","url":null,"abstract":"<p><b>The stability and formation of [2]- or [3]rotaxanes</b> are influenced by minor alterations in the thread structure. The Cover Feature depicts scientists observing the molecular structures, symbolizing the exploration of intercomponent interactions in rotaxane molecules. It has been found that introducing a second macrocycle slightly reduced the stabilization energy between the thread and the first macrocycle but significantly enhanced the overall stabilization energy of the [3]rotaxane. More information can be found in the Research Article by T. Orlando and co-workers (DOI: 10.1002/chem.202403276).\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":"30 64","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202486403","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: IPr*F – Highly Hindered, Fluorinated N-Heterocyclic Carbenes (Chem. Eur. J. 64/2024) 封面：IPr*F - 高度受阻的氟化 N-杂环烯（《欧洲化学杂志》第 64/2024 期）
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-16 DOI: 10.1002/chem.202486401
Greta Utecht-Jarzyńska, Shicheng Shi, Pengcheng Gao, Szymon Jarzyński, Md. Mahbubur Rahman, Roger Lalancette, Roman Szostak, Michal Szostak
{"title":"Front Cover: IPr*F – Highly Hindered, Fluorinated N-Heterocyclic Carbenes (Chem. Eur. J. 64/2024)","authors":"Greta Utecht-Jarzyńska,&nbsp;Shicheng Shi,&nbsp;Pengcheng Gao,&nbsp;Szymon Jarzyński,&nbsp;Md. Mahbubur Rahman,&nbsp;Roger Lalancette,&nbsp;Roman Szostak,&nbsp;Michal Szostak","doi":"10.1002/chem.202486401","DOIUrl":"https://doi.org/10.1002/chem.202486401","url":null,"abstract":"<p><b>Fluorine considered as</b> <i><b>magic element</b></i> strongly affects the chemical, physical and biological properties of molecules. Simultaneously, sterically hindered N-heterocyclic carbenes (NHCs) have received major interest due to the high stabilization of the reactive metal centers. In their Research Article (DOI: 10.1002/chem.202402847), G. Utecht-Jarzyńska, M. Szostak and co-workers report a new class of fluorinated, sterically hindered NHCs characterized by unique steric and electronic properties. An efficient, one-pot synthesis of IPr*<sup>F</sup> ligands is presented, enabling broad access to fluorinated ligands for academic and industrial researchers. Image created in cooperation with Katarzyna Rózga.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":"30 64","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202486401","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cover Feature: Chirality at Metal in a Linear [Ag(NHC)2]+ Complex: Stereogenic C−Ag−C Axis, Atropisomerism and Role of π-π Interactions (Chem. Eur. J. 64/2024) 封面专题：线性[Ag(NHC)2]+配合物的金属手性：立体C-Ag-C轴、异构性和π-π相互作用的作用（《欧洲化学杂志》64/2024）
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-16 DOI: 10.1002/chem.202486404
Alvaro Polo, Lara Gutiérrez Merino, Ricardo Rodríguez, Pablo J. Sanz Miguel
{"title":"Cover Feature: Chirality at Metal in a Linear [Ag(NHC)2]+ Complex: Stereogenic C−Ag−C Axis, Atropisomerism and Role of π-π Interactions (Chem. Eur. J. 64/2024)","authors":"Alvaro Polo,&nbsp;Lara Gutiérrez Merino,&nbsp;Ricardo Rodríguez,&nbsp;Pablo J. Sanz Miguel","doi":"10.1002/chem.202486404","DOIUrl":"https://doi.org/10.1002/chem.202486404","url":null,"abstract":"<p><b>A pioneering example of linear chirality-at-metal</b>: The concept of metal-centered chirality is no longer limited to octahedral, tetrahedral and square-planar geometries. Our design induces the formation of a stereogenic C−Ag−C axis as a consequence of atropisomerism. More importantly, π–π interactions, both in solution and the solid state, are crucial in preserving the chiral information. More information can be found in the Research Article by P. J. Sanz Miguel and co-workers (DOI: 10.1002/chem.202403239).\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":"30 64","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202486404","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cover Feature: Isonitrile Photochemistry: A Functional Group Class Coming in from the Cold (Chem. Eur. J. 64/2024) 封面特写：异腈光化学：从寒冷中走来的一类官能团（《欧洲化学杂志》第 64/2024 期）
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-16 DOI: 10.1002/chem.202486402
Mariateresa Giustiniano
{"title":"Cover Feature: Isonitrile Photochemistry: A Functional Group Class Coming in from the Cold (Chem. Eur. J. 64/2024)","authors":"Mariateresa Giustiniano","doi":"10.1002/chem.202486402","DOIUrl":"https://doi.org/10.1002/chem.202486402","url":null,"abstract":"<p><b>Despite being an important class of compounds</b> with broad applications in organic synthesis, isonitriles have often been neglected due to concerns about their unpleasant odor, stability, and toxicity. Recently, the potential to exploit their stereoelectronic properties in light-triggered synthetic methods leading to unique reactivity patterns has sparked renewed interest, allowing them to come in from the cold. More information can be found in the Concept by M. Giustiniano (DOI: 10.1002/chem.202402350). Artwork created by Gennaro Maddaloni.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":"30 64","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202486402","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142665974","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fluorescent Coating through Melanisation of Merocyanine Based on Catechol Chemistry. 基于儿茶酚化学的梅洛菁黑色化荧光涂层。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-15 DOI: 10.1002/chem.202403294
Belén Alonso, Claus Samuelsen Lucea, Claudia Domini, Gabriel Radivoy, Juan Mancebo-Aracil, Fabiana Nador
{"title":"Fluorescent Coating through Melanisation of Merocyanine Based on Catechol Chemistry.","authors":"Belén Alonso, Claus Samuelsen Lucea, Claudia Domini, Gabriel Radivoy, Juan Mancebo-Aracil, Fabiana Nador","doi":"10.1002/chem.202403294","DOIUrl":"10.1002/chem.202403294","url":null,"abstract":"<p><p>In this study, we present a novel approach for synthesising a merocyanine (MC) compound that integrates gallol and a near-infrared (NIR) fluorophore using a straightforward method. We conduct a comprehensive structural analysis to elucidate the specific roles of each functional group during monomer synthesis and their effects on the properties of both the spiropyran (SP) and MC forms, particularly their fluorescence. As a proof of concept, we explore the use of these compounds in formulating innovative fluorescent polymeric coatings by melanising catechol and gallol moieties on various substrates, including glass, a cupronickel coin, and an organic polymer. To our knowledge, this is the first report of a bioinspired approach utilizing the melanisation of a catechol and gallol moiety containing merocyanine.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403294"},"PeriodicalIF":3.9,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142613205","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Free Alcohol-Mediated Radical Alkynylation and Allylation of Unactivated C(sp3)-H Bonds. 游离醇介导的未活化 C（sp3）-H 键的自由基炔化和烯丙基化。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-15 DOI: 10.1002/chem.202403841
Zhu Cao, Yaohui Xu, Zhen Wu, Xinxin Wu, Chen Zhu
{"title":"Free Alcohol-Mediated Radical Alkynylation and Allylation of Unactivated C(sp<sup>3</sup>)-H Bonds.","authors":"Zhu Cao, Yaohui Xu, Zhen Wu, Xinxin Wu, Chen Zhu","doi":"10.1002/chem.202403841","DOIUrl":"10.1002/chem.202403841","url":null,"abstract":"<p><p>The daunting challenges in converting alcoholic O-H bonds with high bond-dissociation energy (BDE) to alkoxy radicals and harnessing those unruly reaction species largely limit exploiting free alcohols in C(sp<sup>3</sup>)-H functionalization. Herein we describe a novel radical alkynylation and allylation of unactivated C(sp<sup>3</sup>)-H bonds with unmodified aliphatic alcohols. The use of phenyliodine bis(trifluoroacetate) (PIFA) enables the formation of alkoxy radicals under mild photochemical conditions. α-Methyl styrene serves as a sacrificial-reagent that significantly improves the reaction outcomes. This transition-metal free protocol further features broad substrate scope, exclusive site-selectivity, high product diversity, and simple operation, supplying a robust manifold for C(sp<sup>3</sup>)-H functionalization using easily available aliphatic alcohols as feedstock.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403841"},"PeriodicalIF":3.9,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142637959","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ag-Catalyzed Cyclization-Intermolecular Sulfinyl Group Transfer Cascade Reactions Enabling Enantioselective Synthesis of 4-Sulfinylisoquinolines. 银催化的环化-分子间亚磺酰基转移级联反应实现了 4-亚磺酰基异喹啉的对映选择性合成。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-15 DOI: 10.1002/chem.202403866
Itaru Nakamura, Keiryo Kubota, Hiroki Tashiro, Yushiro Saito, Masahiro Terada
{"title":"Ag-Catalyzed Cyclization-Intermolecular Sulfinyl Group Transfer Cascade Reactions Enabling Enantioselective Synthesis of 4-Sulfinylisoquinolines.","authors":"Itaru Nakamura, Keiryo Kubota, Hiroki Tashiro, Yushiro Saito, Masahiro Terada","doi":"10.1002/chem.202403866","DOIUrl":"https://doi.org/10.1002/chem.202403866","url":null,"abstract":"<p><p>N-Sulfinylimines derived from ortho-alkynylbenzaldehydes were efficiently converted into the corresponding 4-sulfinylisoquinolines in good to excellent yields.  The reaction proceeds via cyclization followed by intermolecular migration of the sulfinyl group from the nitrogen atom to the silver-bound carbon of the resulting cyclized vinylsilver intermediate with the aid of either a counteranion or a nucleophilic species.  Moreover, the Ag-catalyzed reaction in the presence of quinidine acetate as a chiral nucleophilic cocatalyst yielded chiral isoquinolines with high enantioselectivities through a dynamic kinetic asymmetric transformation (DYKAT).</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403866"},"PeriodicalIF":3.9,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142637958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
首页 上一页 下一页 尾页
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整，为了账户安全，请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们：info@booksci.cn Book学术提供免费学术资源搜索服务，方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号：481959085
Book学术官方微信