International Journal of Phytoremediation最新文献

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Advanced treatment of tannery effluent from Fez City (Morocco) using a sequence of aerobic and sono-photo-Fenton processes. 采用一系列好氧和声纳-光-芬顿工艺对摩洛哥非斯市制革厂废水进行深度处理。
IF 3.4 4区 环境科学与生态学
International Journal of Phytoremediation Pub Date : 2025-05-07 DOI: 10.1080/15226514.2025.2499721
Oumaima Bahammou, Imane El Mrabet, Zineb Chaouki, Mostafa Nawdali, Karim Tanji, Jamel Bouaziz, Fouad Khalil, Mourad Benzina, Corinne Ferronato, Frederic C Meunier, Hicham Zaitan
{"title":"Advanced treatment of tannery effluent from Fez City (Morocco) using a sequence of aerobic and sono-photo-Fenton processes.","authors":"Oumaima Bahammou, Imane El Mrabet, Zineb Chaouki, Mostafa Nawdali, Karim Tanji, Jamel Bouaziz, Fouad Khalil, Mourad Benzina, Corinne Ferronato, Frederic C Meunier, Hicham Zaitan","doi":"10.1080/15226514.2025.2499721","DOIUrl":"https://doi.org/10.1080/15226514.2025.2499721","url":null,"abstract":"<p><p>This work aims to purify real tannery wastewater (TWW) after a physicochemical characterization. A pretreatment using air stripping (aerobic pretreatment; AP) was first applied and compared to anaerobic pretreatment (ANP). The COD and BOD<sub>5</sub> were highly removed by AP, reaching 86% and 88% compared to ANP, which only achieved 48% and 55%, respectively. Following the AP, the sono-photo-Fenton (SPF) process was applied as post-treatment. The optimal conditions pH = 3, [H<sub>2</sub>O<sub>2</sub>] = 1834 mg/L, and [Fe<sup>2+</sup>] = 1281 mg/L improved the COD, color and BOD<sub>5</sub> removal of 96%, 98%, and 98%, respectively. Turbidity, N-NO<sub>3</sub><sup>-</sup>, and N-NO<sub>2</sub><sup>-</sup> were completely removed (100%) by the combined processes (AP+SPF), while Cr, Cl<sup>-</sup>, and N-NH<sub>4</sub><sup>+</sup> were reduced to 99%, 97%, and 99%, respectively. Finally, phytotoxicity tests were performed to confirm the efficiency of the sequential processes. The highest germination percentage, germination rate index, and seedling vigor index for the grains <i>wheat</i> and <i>Medicago sativa</i> were observed using the TWW treated by the AP+SPF, followed by those treated by AP alone. In contrast, no germination indicators were noticed in raw TWW. These findings highlight the significant purification effectiveness of the sequential processes of AP and SPF post-treatment, which suggests the potential use of this combination for the efficient treatment of real liquid effluents.</p>","PeriodicalId":14235,"journal":{"name":"International Journal of Phytoremediation","volume":" ","pages":"1-14"},"PeriodicalIF":3.4,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144010136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of cropping rotation and straw management on Cd accumulation in rice (Oryza sativa L.): a perspective from the rape (Brassica campestris)-rice system. 轮作和秸秆管理对水稻Cd积累的影响——以油菜-水稻系统为例
IF 3.4 4区 环境科学与生态学
International Journal of Phytoremediation Pub Date : 2025-05-07 DOI: 10.1080/15226514.2025.2499120
Yuhui Zeng, Changsong Huang, Beibei Tian, Li Li, Xufeng Luo, Zhong Hu, Huihui Du, Xiao Deng, Yang Yang, Qingru Zeng, Si Luo
{"title":"Influence of cropping rotation and straw management on Cd accumulation in rice (<i>Oryza sativa</i> L.): a perspective from the rape (<i>Brassica campestris</i>)-rice system.","authors":"Yuhui Zeng, Changsong Huang, Beibei Tian, Li Li, Xufeng Luo, Zhong Hu, Huihui Du, Xiao Deng, Yang Yang, Qingru Zeng, Si Luo","doi":"10.1080/15226514.2025.2499120","DOIUrl":"https://doi.org/10.1080/15226514.2025.2499120","url":null,"abstract":"<p><p>Cadmium (Cd) contamination is a major concern due to its toxicity and bioaccumulation in crops. The study researched the impact of rape (<i>Brassica campestris</i>) cultivation and influence of straw management on Cd accumulation in rice (<i>Oryza sativa</i> L.) under rape-rice rotation system. Field experiments were set in moderately Cd-contaminated farmlands, with treatments including rape-rice rotation with straw removal (NR), rape-rice rotation with straw return (RR), and single cropping rice (SR). In contrast with SR, the NR effectively reduced 6.67-19.59% soil available Cd and the 37.18-39.10% rice grains Cd accumulation during 3 years. Compared with the RR, SR significantly decreased 17.17-27.78% soil available Cd concentrations and 33.30-53.84% rice grain Cd accumulation. Soil physical and chemical properties were influenced by rape cultivation and straw return, further affecting Cd mobility. This study underscores that rape-rice rotation with straw removal can be an effective tactic for reducing the Cd contamination in rice grains and improve soil environment. This research provides critical insights into sustainable agricultural practices for Cd-contaminated soils, offering practical solutions for mitigating Cd risk in rice, while highlighting the importance of straw management in crop rotations.</p>","PeriodicalId":14235,"journal":{"name":"International Journal of Phytoremediation","volume":" ","pages":"1-13"},"PeriodicalIF":3.4,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143966028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mitigating toxicity of arsenic in sunflower (Helianthus annuus L.) with phosphate rock and farmyard manure using contrasting soil textures. 磷矿和农家肥对向日葵砷毒性的缓解作用。
IF 3.4 4区 环境科学与生态学
International Journal of Phytoremediation Pub Date : 2025-05-02 DOI: 10.1080/15226514.2025.2493855
Muhammad Awais Piracha, Muhammad Ashraf, Rizwana Kausar, Muhammad Asif, Ali Raza Siddiqui, Syed Ayyaz Javed, Abid Niaz, Zafar Abbas, Shabana Nazeer
{"title":"Mitigating toxicity of arsenic in sunflower (<i>Helianthus annuus</i> L.) with phosphate rock and farmyard manure using contrasting soil textures.","authors":"Muhammad Awais Piracha, Muhammad Ashraf, Rizwana Kausar, Muhammad Asif, Ali Raza Siddiqui, Syed Ayyaz Javed, Abid Niaz, Zafar Abbas, Shabana Nazeer","doi":"10.1080/15226514.2025.2493855","DOIUrl":"https://doi.org/10.1080/15226514.2025.2493855","url":null,"abstract":"<p><p>Arsenic (As) immobilization in soil using inorganic/organic amendments may improve the productivity of As<b>-</b>contaminated soils. However, the degree of immobilization may vary depending on soil texture, phosphorus and organic matter content. A pot study was designed to investigate the effect of phosphate rock (PR) and farmyard manure (FYM) on As solubility in three soil types (sand, loam and clay), its transfer to plant parts and the resultant impact on physiology and achene yield of <i>Helianthus annuus</i> L. under alkaline calcareous condition. Plants were treated with As (60 and 120 mg kg<sup>-1</sup> soil), PR (5 and 20 g kg<sup>-1</sup> soil) and FYM (5 and 20% w/w) with a control. After sixteen weeks of growth period, results showed that As solubility decreased by 22.07-44.85% and 21.33-36.35% in sand, 17.55-45.80% and 30.83-45.98% in loam, while 22.81-36.89% and 20.92-42.41% in clay soils at As<b>-</b>60 and As<b>-</b>120, respectively with varied PR+FYM combinations compared to control. Integrated PR+FYM application restricted As movement from soil to plant, reducing achene As concentration by 22.22-41.26%, 26.08-43.47%, and 25.80-45.16% in sand, loam and clay soils, respectively, at As<b>-</b>120 compared to without PR+FYM. Thus, integrated PR+FYM application could be recommended to enhance the productivity of As<b>-</b>contaminated marginal lands by sunflower cultivation.</p>","PeriodicalId":14235,"journal":{"name":"International Journal of Phytoremediation","volume":" ","pages":"1-13"},"PeriodicalIF":3.4,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144015598","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparison of two hybrid constructed wetland configurations for dairy wastewater treatment. 两种混合式人工湿地处理乳制品废水的比较。
IF 3.4 4区 环境科学与生态学
International Journal of Phytoremediation Pub Date : 2025-05-02 DOI: 10.1080/15226514.2025.2495765
Emanuel Nocetti, Hernán Ricardo Hadad, María Alejandra Maine
{"title":"Comparison of two hybrid constructed wetland configurations for dairy wastewater treatment.","authors":"Emanuel Nocetti, Hernán Ricardo Hadad, María Alejandra Maine","doi":"10.1080/15226514.2025.2495765","DOIUrl":"https://doi.org/10.1080/15226514.2025.2495765","url":null,"abstract":"<p><p>The aim was to evaluate the performance of two hybrid constructed wetlands (HCW) for the treatment of a dairy wastewater at pilot-scale. The HCW1 was composed of vertical flow (VF) and horizontal subsurface flow (HSSF) wetland units while the HCW2 of VF and free water surface (FWS) wetland units. Wastewater, plants, and sediment samples were collected to evaluate the removal efficiency and nutrient accumulation in plant tissues and sediment. Kinetics were evaluated using the volumetric removal rate (<i>k</i>). COD and BOD decrease was significantly higher in HCW1 than in HCW2, due to chemical oxidation prevails in the VF stages and biological processes in the second stage of HCW1, leading to organic matter removal. Total nitrogen (TN) removal was comparable in the two HCW configurations. Nitrogen compounds interconversions were favored in HCW1 due to HSSF wetland conditions and higher plant biomass values in VF stages than in HCW2. Phosphorus removal was favored in FWS. <i>k</i> values showed that HCW1 was kinetically favored. The main strengths of the HSSF wetland were Org-N and NO<sub>3</sub><sup>-</sup>-N removals, but the weakness was NH<sub>4</sub><sup>+</sup>-N removal under limited nitrification conditions. The HCW1 was efficient for nitrogen interconversions, leading to higher removal efficiencies than HCW2.</p>","PeriodicalId":14235,"journal":{"name":"International Journal of Phytoremediation","volume":" ","pages":"1-13"},"PeriodicalIF":3.4,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144010114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of glycine betaine loaded chitosan nanoparticles mitigates lead toxicity and promotes plant growth in wheat. 甘氨酸甜菜碱负载壳聚糖纳米颗粒减轻小麦铅毒性,促进植物生长。
IF 3.4 4区 环境科学与生态学
International Journal of Phytoremediation Pub Date : 2025-04-30 DOI: 10.1080/15226514.2025.2497900
Zahra Jabeen, Shanza Javaid, Shaziqa Javaid, Ghulam Abbas, Sidra Rehman, Amjad Farooq
{"title":"Application of glycine betaine loaded chitosan nanoparticles mitigates lead toxicity and promotes plant growth in wheat.","authors":"Zahra Jabeen, Shanza Javaid, Shaziqa Javaid, Ghulam Abbas, Sidra Rehman, Amjad Farooq","doi":"10.1080/15226514.2025.2497900","DOIUrl":"https://doi.org/10.1080/15226514.2025.2497900","url":null,"abstract":"<p><p>In recent years, heavy metal toxicity has become a major threat to all living organisms due to the increase in human population and anthropogenic activities. Among heavy metals, lead (Pb) is regarded as a highly toxic pollutant for wheat. A hydroponic experiment was performed to examine the potential of exogenously applied glycine betaine loaded chitosan nanoparticles (NPs) (0.04%) in mitigating Pb phyto-toxicity in wheat. Under Pb stress (2 mM Pb), plant height, pigment contents were decreased and Pb accumulation was enhanced both in roots and shoots of plants. Moreover, the application of NPs decreased Pb accumulation and increased plant growth, pigment contents, soluble sugars, proline, and glycine betaine contents, Additionally, it enhanced the activities of antioxidative enzymes such as super dismutase (SOD), catalase (CAT), and ascorbate peroxidase (APX) by 78%, 12%, and 36% in shoots, and 82%, 14%, and 40% in roots, respectively relative to plants under Pb stress alone. These findings suggest that the exogenous application of glycine- betaine loaded chitosan NPs is highly effective in mitigation of phytotoxicity of Pb in wheat grown under Pb contamination.</p>","PeriodicalId":14235,"journal":{"name":"International Journal of Phytoremediation","volume":" ","pages":"1-12"},"PeriodicalIF":3.4,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144019684","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Combination of magnesium and iron nanoparticles with biochar mitigated salt toxicity and altered antioxidant activity and essential oil production of chamomile. 镁和铁纳米颗粒与生物炭的结合减轻了盐毒性,改变了洋甘菊的抗氧化活性和精油产量。
IF 3.4 4区 环境科学与生态学
International Journal of Phytoremediation Pub Date : 2025-04-30 DOI: 10.1080/15226514.2025.2497899
Kazem Ghassemi-Golezani, Roghayeh Solhi-Khajehmarjan
{"title":"Combination of magnesium and iron nanoparticles with biochar mitigated salt toxicity and altered antioxidant activity and essential oil production of chamomile.","authors":"Kazem Ghassemi-Golezani, Roghayeh Solhi-Khajehmarjan","doi":"10.1080/15226514.2025.2497899","DOIUrl":"https://doi.org/10.1080/15226514.2025.2497899","url":null,"abstract":"<p><p>This research was conducted in a greenhouse to examine the effects of solid biochar (25 g kg<sup>-1</sup> soil), and biochar-based nanoparticles of magnesium (BNP-MgO), iron (BNP-Fe<sub>3</sub>O<sub>4</sub>), and magnesium + iron (BNP-MgO + BNP-Fe<sub>3</sub>O<sub>4</sub>) in comparison with control (soil) on German chamomile (<i>Matricaria chamomilla</i> L.) under salinity levels (0.9, 6, and 12 dS m<sup>-1</sup> as non-saline treatment and moderate and high salinities, respectively). Salinity increased sodium uptake, generation of reactive oxygen species and enzymatic and non-enzymatic antioxidant activities, leading to a reduction in leaf nutrients and pigments, and organs masses. High salinity significantly decreased the essential oil percentage and yield. However, solid and especially enriched biochars with BNP-MgO, BNP-Fe<sub>3</sub>O<sub>4</sub>, and their combined form reduced hydrogen peroxide and consequently enzymatic and non-enzymatic antioxidant activities under saline conditions. The BNP-MgO was the best treatment for enhancing leaf pigments, and the BNP-Fe<sub>3</sub>O<sub>4</sub> was generally the best choice for improving organs masses and essential oil percentage and yield of chamomile under salinity. Therefore, solid and especially enriched biochars, due to their excellent physicochemical properties, were suggested as the suitable soil amendments to mitigate salt toxicity and improve the growth and essential oil production of medicinal plants in the greenhouse and field cultivations.</p>","PeriodicalId":14235,"journal":{"name":"International Journal of Phytoremediation","volume":" ","pages":"1-12"},"PeriodicalIF":3.4,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144010109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring the phytostabilization potential of ryegrass (Lolium perenne L.) upon synergistic application of Cd-tolerant Pseudomonas fluorescens and organic amendments. 探讨耐cd荧光假单胞菌和有机改性剂协同应用对黑麦草植物稳定性的影响。
IF 3.4 4区 环境科学与生态学
International Journal of Phytoremediation Pub Date : 2025-04-29 DOI: 10.1080/15226514.2025.2494700
Muhammad Babar Khan, Saira Sulaman, Muhammad Shabaan, Arooj Fatima, Ashir Hameed, Usman Zulfiqar, Rehmat Kabir, Khaloud Mohammed Alarjani, Reem A Aljeidi
{"title":"Exploring the phytostabilization potential of ryegrass (<i>Lolium perenne</i> L.) upon synergistic application of Cd-tolerant <i>Pseudomonas fluorescens</i> and organic amendments.","authors":"Muhammad Babar Khan, Saira Sulaman, Muhammad Shabaan, Arooj Fatima, Ashir Hameed, Usman Zulfiqar, Rehmat Kabir, Khaloud Mohammed Alarjani, Reem A Aljeidi","doi":"10.1080/15226514.2025.2494700","DOIUrl":"https://doi.org/10.1080/15226514.2025.2494700","url":null,"abstract":"<p><p>Soil Cd contamination limits plant productivity by affecting their key functions and reducing yields. In-situ immobilization of heavy metals (HMs) can achieve 'green' and 'sustainable' ways of HM remediation owing to its lower life cycle environmental footprints. This study explored the effects of Cd-resistant <i>P. fluorescens</i> and OAs such as rice straw, wheat straw and cow dung (1% w/w) on the Cd tolerance of ryegrass under Cd contamination (2.2 mg kg<sup>-1</sup>). In our findings, Cd exposure reduced plant height (22%), root length (38%), chlorophyll 'a' and 'b' (36 and 38%), and relative water content (32%) in uninoculated plants. However, combined use of <i>P. fluorescens</i> and OAs mitigated these effects by immobilizing Cd in soil, with a 56% increase in residual Cd and higher Cd retention in roots and shoots (77 and 87%). Co-application enhanced plant height (96%), root length (158%), chlorophyll content (90 and 98%), relative water content (168%), flavonoids and phenols (151 and 68%) and NPK uptake (104, 73 and 71%) as compared to uninoculated control. Integration of <i>P. fluorescens</i> and OAs not only reduced Cd uptake but also improved growth and yield. Thus, this approach mitigates Cd stress in ryegrass, improving growth and physiology by reducing Cd uptake.</p>","PeriodicalId":14235,"journal":{"name":"International Journal of Phytoremediation","volume":" ","pages":"1-15"},"PeriodicalIF":3.4,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143980478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Screening of chili cultivars with low cadmium accumulation and analysis of their physiological properties of tolerance. 低镉积累辣椒品种筛选及耐镉生理特性分析。
IF 3.4 4区 环境科学与生态学
International Journal of Phytoremediation Pub Date : 2025-04-28 DOI: 10.1080/15226514.2025.2496412
Yating Zhang, Shuhe Wei, Jibao Jia, Jie Zhan, Li Zhan, Brett H Robinson, Lidia Skuza, Jianming Xue, Huiping Dai, Lingjiang Kou, Chao Zhang, Kaimei Huang
{"title":"Screening of chili cultivars with low cadmium accumulation and analysis of their physiological properties of tolerance.","authors":"Yating Zhang, Shuhe Wei, Jibao Jia, Jie Zhan, Li Zhan, Brett H Robinson, Lidia Skuza, Jianming Xue, Huiping Dai, Lingjiang Kou, Chao Zhang, Kaimei Huang","doi":"10.1080/15226514.2025.2496412","DOIUrl":"https://doi.org/10.1080/15226514.2025.2496412","url":null,"abstract":"<p><p>Chili (<i>Capsicum annuum</i> L.) is a widely eaten condiment that may accumulate the toxic element cadmium (Cd) from environments, thus presenting a human health risk. This experiment aimed to identify cultivars with low Cd-uptake characteristics that could be used to produce safe spicy food in Cd-contaminated soil. Five chili cultivars responses to Cd exposure in soils with 0.18 mg kg<sup>-1</sup> (CK), 2.88 mg kg<sup>-1</sup> (T1), 7.69 mg kg<sup>-1</sup> (T2), 16.72 mg kg<sup>-1</sup> (T3), and 33.46 mg kg<sup>-1</sup> (T4) in a greenhouse were compared. The results showed that Cd concentration in roots, shoots, and fruits of the cultivar Bolafengxiang was the lowest. Additionally, its biomass was not reduced compared to the CK, and both the enrichment factor (EF) and translocation factor (TF) were all lower than 1. Notably, under soil Cd concentrations of 2.88 mg kg<sup>-1</sup>, the Cd content in the fruits of Bolafengxiang was 0.07 mg kg<sup>-1</sup>, which is below the safety standard limit (0.1 mg kg<sup>-1</sup>) for \"Green Food Chili Products.\" This indicates its potential for low Cd accumulation. The above research indicates that selecting and cultivating low-Cd-accumulating chili cultivars is an effective approach to reduce Cd accumulation in edible parts, thereby ensuring agricultural food safety.</p>","PeriodicalId":14235,"journal":{"name":"International Journal of Phytoremediation","volume":" ","pages":"1-11"},"PeriodicalIF":3.4,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144003816","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorptive performance of sustainable biosorbent from Macadamia integrifoli shell powder for toxic methylene blue dye removal: desirability functions and dye uptake mechanism. 澳洲坚果壳粉末可持续生物吸附剂对有毒亚甲基蓝染料的吸附性能:可取功能和染料吸附机理。
IF 3.4 4区 环境科学与生态学
International Journal of Phytoremediation Pub Date : 2025-04-25 DOI: 10.1080/15226514.2025.2494697
Hasan M Agha, Ali H Jawad, Lee D Wilson, Zeid A ALOthman
{"title":"Adsorptive performance of sustainable biosorbent from <i>Macadamia integrifoli</i> shell powder for toxic methylene blue dye removal: desirability functions and dye uptake mechanism.","authors":"Hasan M Agha, Ali H Jawad, Lee D Wilson, Zeid A ALOthman","doi":"10.1080/15226514.2025.2494697","DOIUrl":"https://doi.org/10.1080/15226514.2025.2494697","url":null,"abstract":"<p><p>Herein, the potential of Macadamia integrifolia nutshell powder (MSP) as a sustainable, renewable, and cost-effective biosorbent for methylene blue (MB) dye was evaluated. The physicochemical properties of MSP were characterized <i>via</i> XRD, FTIR, FESEM-EDX, and pH<sub>pzc</sub> analysis. The biosorption process was optimized using the Box-Behnken design (RSM-BBD), to evaluate the influence of MSP dose (0.02-0.1 g/100 mL), contact time (20-300 min), and solution pH (4-10). The desirability function further refined and validated the BBD results, demonstrating that maximum MB removal (98.7%) was achieved at an MSP dose of 0.09 g/100 mL, contact time of 276.1 min, and solution pH of 8.7. Kinetic modeling indicated that MB biosorption onto MSP conformed to the pseudo-second order (PSO) model. The intraparticle diffusion (IPD) model supports a multi-step adsorption process, consisting of surface adsorption, gradual diffusion, and equilibrium stages. The adsorption equilibrium data were well described by the Langmuir and Freundlich isotherm models, confirming a combination of monolayer and multilayer adsorption profiles. The maximum adsorption capacity (<i>q<sub>max</sub></i>) of MSP was estimated to be 128.3 mg/g. The biosorption mechanism was attributed to hydrogen bonding, π-π interactions, electrostatic forces, and pore filling, as evidenced by spectroscopy and bioadsorbent morphology results. The reusability study demonstrated that MSP retained significant adsorption capacity over multiple cycles, highlighting its moderate recyclability. These findings establish MSP as a highly efficient, scalable, and environmentally sustainable bioadsorbent for MB dye removal, offering a practical solution for wastewater treatment applications and options for sustainable water management.</p>","PeriodicalId":14235,"journal":{"name":"International Journal of Phytoremediation","volume":" ","pages":"1-16"},"PeriodicalIF":3.4,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144012020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Silicon enhances the growth of nickel-stressed cabbage plants by reducing oxidative damage and strengthening root architecture. 硅通过减少氧化损伤和加强根构型来促进镍胁迫白菜植株的生长。
IF 3.4 4区 环境科学与生态学
International Journal of Phytoremediation Pub Date : 2025-04-21 DOI: 10.1080/15226514.2025.2494699
Rashad Mukhtar Balal, Muhammad Tauseef Jaffar, Syed Ayyaz Javed, Muhammad Zubair, Muhammad Ajmal Farhad, Hafiz Wasif Javaad, Muhammad Adnan Shahid, Waleed A A Alsakkaf, Hayssam M Ali
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