International Journal of Minerals, Metallurgy, and Materials最新文献

筛选
英文 中文
Theoretical study on the morphology of cobalt nanoparticles modulated by alkali metal promoters 碱金属助催化剂调控钴纳米粒子形貌的理论研究
IF 2.232 2区 材料科学
International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-10-11 DOI: 10.1007/s12613-023-2634-5
Xiaobin Geng, Hui Yang, Wenping Guo, Xiaotong Liu, Tao Yang, Jinjia Liu
{"title":"Theoretical study on the morphology of cobalt nanoparticles modulated by alkali metal promoters","authors":"Xiaobin Geng,&nbsp;Hui Yang,&nbsp;Wenping Guo,&nbsp;Xiaotong Liu,&nbsp;Tao Yang,&nbsp;Jinjia Liu","doi":"10.1007/s12613-023-2634-5","DOIUrl":"10.1007/s12613-023-2634-5","url":null,"abstract":"<div><p>Cobalt nanoparticles (NPs) catalysts are extensively used in heterogeneous catalytic reactions, and the addition of alkali metal promoters is a common method to modulate the catalytic performance because the catalyst’s surface structures and morphologies are sensitive to the addition of promoters. However, the underlying modulation trend remains unclear. Herein, the adsorption of alkali metal promoters (Na and K) on the surfaces of face-centered-cubic (FCC) and hexagonal-closest packed (HCP) polymorphous cobalt was systematically investigated using density functional theory. Furthermore, the effect of alkali promoters on surface energies and nanoparticle morphologies was revealed on the basis of Wulff theory. For FCC-Co, the exposed area of the (111) facet in the nanoparticle increases with the adsorption coverage of alkali metal oxide. Meanwhile, the (311), (110), and (100) facets would disappear under the higher adsorption coverage of alkali metals. For HCP-Co, the Wulff morphology is dominated by the (0001) and (<span>(10bar 11)</span>) facets and is independent of the alkali metal adsorption coverage. This work provides insights into morphology modulation by alkali metal promoters for the rational design and synthesis of cobalt-based nanomaterials with desired facets and morphologies.</p></div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 10","pages":"2006 - 2013"},"PeriodicalIF":2.232,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s12613-023-2634-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41229141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Propylamine hydrobromide passivated tin-based perovskites to efficient solar cells 氢溴酸丙胺钝化锡基钙钛矿制备高效太阳能电池
IF 2.232 2区 材料科学
International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-10-11 DOI: 10.1007/s12613-023-2604-y
Xiaomeng Li, Pengcheng Jia, Fanwen Meng, Xingyu Zhang, Yang Tang, Bo Song, Chang Gao, Liang Qin, Feng Teng, Yanbing Hou
{"title":"Propylamine hydrobromide passivated tin-based perovskites to efficient solar cells","authors":"Xiaomeng Li,&nbsp;Pengcheng Jia,&nbsp;Fanwen Meng,&nbsp;Xingyu Zhang,&nbsp;Yang Tang,&nbsp;Bo Song,&nbsp;Chang Gao,&nbsp;Liang Qin,&nbsp;Feng Teng,&nbsp;Yanbing Hou","doi":"10.1007/s12613-023-2604-y","DOIUrl":"10.1007/s12613-023-2604-y","url":null,"abstract":"<div><p>The development of tin-based devices with low toxicity is critical for the commercial viability of perovskite solar cells. However, because tin halide is a stronger Lewis acid, its crystallization rate is extremely fast, resulting in the formation of numerous defects that affect the device performance of tin-based perovskite solar cells. Herein, propylamine hydrobromide (PABr) was added to the perovskite precursor solution as an additive to passivate defects and fabricate more uniform and dense perovskite films. Because propylamine cations are too large to enter the perovskite lattices, they only exist at the grain boundary to passivate surface defects and promote crystal growth in a preferred orientation. The PABr additive raises the average short-circuit current density from 19.45 to 25.47 mA·cm<sup>−2</sup> by reducing carrier recombination induced by defects. Furthermore, the device’s long-term illumination stability is improved after optimization, and the hysteresis effect is negligible. The addition of PABr results in a power conversion efficiency of 9.35%.</p></div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 10","pages":"1965 - 1972"},"PeriodicalIF":2.232,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41229122","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Corrosion engineering on AlCoCrFeNi high-entropy alloys toward highly efficient electrocatalysts for the oxygen evolution of alkaline seawater AlCoCrFeNi高熵合金对碱性海水析氧高效电催化剂的腐蚀工程
IF 2.232 2区 材料科学
International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-10-11 DOI: 10.1007/s12613-023-2624-7
Zhibin Chen, Kang Huang, Bowei Zhang, Jiuyang Xia, Junsheng Wu, Zequn Zhang, Yizhong Huang
{"title":"Corrosion engineering on AlCoCrFeNi high-entropy alloys toward highly efficient electrocatalysts for the oxygen evolution of alkaline seawater","authors":"Zhibin Chen,&nbsp;Kang Huang,&nbsp;Bowei Zhang,&nbsp;Jiuyang Xia,&nbsp;Junsheng Wu,&nbsp;Zequn Zhang,&nbsp;Yizhong Huang","doi":"10.1007/s12613-023-2624-7","DOIUrl":"10.1007/s12613-023-2624-7","url":null,"abstract":"<div><p>Seawater splitting is a prospective approach to yield renewable and sustainable hydrogen energy. Complex preparation processes and poor repeatability are currently considered to be an insuperable impediment to the promotion of the large-scale production and application of electrocatalysts. Avoiding the use of intricate instruments, corrosion engineering is an intriguing strategy to reduce the cost and presents considerable potential for electrodes with catalytic performance. An anode comprising quinary AlCoCrFeNi layered double hydroxides uniformly decorated on an AlCoCrFeNi high-entropy alloy is proposed in this paper via a one-step corrosion engineering method, which directly serves as a remarkably active catalyst for boosting the oxygen evolution reaction (OER) in alkaline seawater. Notably, the best-performing catalyst exhibited oxygen evolution reaction activity with overpotential values of 272.3 and 332 mV to achieve the current densities of 10 and 100 mA·cm<sup>−2</sup>, respectively. The failure mechanism of the obtained catalyst was identified for advancing the development of multicomponent catalysts.</p></div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 10","pages":"1922 - 1932"},"PeriodicalIF":2.232,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41229147","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
High-performance triboelectric nanogenerator based on ZrB2/polydimethylsiloxane for metal corrosion protection 基于ZrB2/聚二甲基硅氧烷的高性能金属防腐摩擦电纳米发电机
IF 2.232 2区 材料科学
International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-10-11 DOI: 10.1007/s12613-023-2626-5
Xiucai Wang, Naijian Hu, Jia Yang, Jianwen Chen, Xinmei Yu, Wenbo Zhu, Chaochao Zhao, Ting Wang, Min Chen
{"title":"High-performance triboelectric nanogenerator based on ZrB2/polydimethylsiloxane for metal corrosion protection","authors":"Xiucai Wang,&nbsp;Naijian Hu,&nbsp;Jia Yang,&nbsp;Jianwen Chen,&nbsp;Xinmei Yu,&nbsp;Wenbo Zhu,&nbsp;Chaochao Zhao,&nbsp;Ting Wang,&nbsp;Min Chen","doi":"10.1007/s12613-023-2626-5","DOIUrl":"10.1007/s12613-023-2626-5","url":null,"abstract":"<div><p>Metal corrosion causes billions of dollars of economic losses yearly. As a smart and new energy-harvesting device, triboelectric nanogenerators (TENGs) can convert almost all mechanical energy into electricity, which leads to great prospects in metal corrosion prevention and cathodic protection. In this work, flexible TENGs were designed to use the energy harvested by flexible polydimethylsiloxane (PDMS) films with ZrB<sub>2</sub> nanoparticles and effectively improve the dielectric constant by incorporating ZrB<sub>2</sub>. The open-circuit voltage and short-circuit current were 264 V and 22.9 µA, respectively, and the power density of the TENGs reached 6 W·m<sup>−2</sup>. Furthermore, a self-powered anti-corrosion system was designed by the rectifier circuit integrated with TENGs, and the open-circuit potential (OCP) and Tafel curves showed that the system had an excellent anti-corrosion effect on carbon steel. Thus, the system has broad application prospects in fields such as metal cultural relics, ocean engineering, and industry.</p></div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 10","pages":"1957 - 1964"},"PeriodicalIF":2.232,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s12613-023-2626-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41229282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Synergically enhanced piezocatalysis performance of eco-friendly (K0.52Na0.48)NbO3 through ferroelectric polarization and defects 通过铁电极化和缺陷协同增强环保型(K0.52Na0.48)NbO3的压电催化性能
IF 2.232 2区 材料科学
International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-10-11 DOI: 10.1007/s12613-023-2671-0
Min Zhou, Laijun Liang, Dingze Lu, Xiaomei Lu, Zheng Wang, Fengzhen Huang, Pengfei Cheng, Dongdong Liu, Mengqi Tian, Qiuping Wang, Yunjie Zhang
{"title":"Synergically enhanced piezocatalysis performance of eco-friendly (K0.52Na0.48)NbO3 through ferroelectric polarization and defects","authors":"Min Zhou,&nbsp;Laijun Liang,&nbsp;Dingze Lu,&nbsp;Xiaomei Lu,&nbsp;Zheng Wang,&nbsp;Fengzhen Huang,&nbsp;Pengfei Cheng,&nbsp;Dongdong Liu,&nbsp;Mengqi Tian,&nbsp;Qiuping Wang,&nbsp;Yunjie Zhang","doi":"10.1007/s12613-023-2671-0","DOIUrl":"10.1007/s12613-023-2671-0","url":null,"abstract":"<div><p>Piezocatalysis has attracted unprecedented research interest as a newly emerging catalysis technology. However, the inherent insulating property of ferroelectric materials ultimately leads to the poor vibration–electricity conversion ability. Herein, this work reports the (K<sub>0.52</sub>Na<sub>0.48</sub>)NbO<sub>3</sub> ferroelectric ceramics (KNNFC<i>x</i>), for which the FeCo modification strategy is proposed. The substitution of the moderate amount of FeCo (<i>x</i> = 0.015) at Nb site not only optimizes ferroelectricity but also produces beneficial defects, notably increasing Rhodamine B water purification efficiency to 95%. The pinning effect of monovalent oxygen vacancies on ferroelectric domains is responsible for the excellent ferroelectric polarization of KNNFC0.015 through the generation of an internal field to promote charge carriers separation and reduce non-radiative recombination. Importantly, the accompanying electron carriers can easily move to the material surface and participate in redox reactions because they have low activation energy. Therefore, ferroelectric polarization and defects play synergetic roles in enhancing piezocatalytic performance.</p></div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 10","pages":"2044 - 2054"},"PeriodicalIF":2.232,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s12613-023-2671-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41229285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Speeding up the prediction of C–O cleavage through bond valence and charge on iron carbides 通过碳化物上的键价和电荷加速C–O解理的预测
IF 2.232 2区 材料科学
International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-10-11 DOI: 10.1007/s12613-023-2612-y
Yurong He, Kuan Lu, Jinjia Liu, Xinhua Gao, Xiaotong Liu, Yongwang Li, Chunfang Huo, James P. Lewis, Xiaodong Wen, Ning Li
{"title":"Speeding up the prediction of C–O cleavage through bond valence and charge on iron carbides","authors":"Yurong He,&nbsp;Kuan Lu,&nbsp;Jinjia Liu,&nbsp;Xinhua Gao,&nbsp;Xiaotong Liu,&nbsp;Yongwang Li,&nbsp;Chunfang Huo,&nbsp;James P. Lewis,&nbsp;Xiaodong Wen,&nbsp;Ning Li","doi":"10.1007/s12613-023-2612-y","DOIUrl":"10.1007/s12613-023-2612-y","url":null,"abstract":"<div><p>The activation of CO on iron-based materials is a key elementary reaction for many chemical processes. We investigate CO adsorption and dissociation on a series of Fe, Fe<sub>3</sub>C, Fe<sub>5</sub>C<sub>2</sub>, and Fe<sub>2</sub>C catalysts through density functional theory calculations. We detect dramatically different performances for CO adsorption and activation on diverse surfaces and sites. The activation of CO is dependent on the local coordination of the molecule to the surface and on the bulk phase of the underlying catalyst. The bulk properties and the different local bonding environments lead to varying interactions between the adsorbed CO and the surface and thus yielding different activation levels of the C–O bond. We also examine the prediction of CO adsorption on different types of Fe-based catalysts by machine learning through linear regression models. We combine the features originating from surfaces and bulk phases to enhance the prediction of the activation energies and perform eight different linear regressions utilizing the feature engineering of polynomial representations. Among them, a ridge linear regression model with 2nd-degree polynomial feature generation predicted the best CO activation energy with a mean absolute error of 0.269 eV.</p></div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 10","pages":"2014 - 2024"},"PeriodicalIF":2.232,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41229145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Metal-organic framework derived NiFe2O4/FeNi3@C composite for efficient electrocatalytic oxygen evolution reaction 金属有机骨架衍生的NiFe2O4/FeNi3@C高效电催化析氧反应的复合材料
IF 2.232 2区 材料科学
International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-10-11 DOI: 10.1007/s12613-023-2721-7
Fangna Dai, Zhifei Wang, Huakai Xu, Chuanhai Jiang, Yuguo Ouyang, Chunyu Lu, Yuan Jing, Shiwei Yao, Xiaofei Wei
{"title":"Metal-organic framework derived NiFe2O4/FeNi3@C composite for efficient electrocatalytic oxygen evolution reaction","authors":"Fangna Dai,&nbsp;Zhifei Wang,&nbsp;Huakai Xu,&nbsp;Chuanhai Jiang,&nbsp;Yuguo Ouyang,&nbsp;Chunyu Lu,&nbsp;Yuan Jing,&nbsp;Shiwei Yao,&nbsp;Xiaofei Wei","doi":"10.1007/s12613-023-2721-7","DOIUrl":"10.1007/s12613-023-2721-7","url":null,"abstract":"<div><p>Reducing the cost and improving the electrocatalytic activity are the key to developing high efficiency electrocatalysts for oxygen evolution reaction (OER). Here, bimetallic NiFe-based metal-organic framework (MOF) was prepared by solvothermal method, and then used as precursor to prepare NiFe-based MOF-derived materials by pyrolysis. The effects of different metal ratios and pyrolysis temperatures on the sample structure and OER electrocatalytic performance were investigated and compared. The experimental results showed that when the metal molar ratio was Fe: Ni = 1:5 and the pyrolysis temperature was 450°C, the sample (FeNi<sub>5</sub>-MOF-450) exhibits a composite structure of NiFe<sub>2</sub>O<sub>4</sub>/FeNi<sub>3</sub>/C and owns the superior electrocatalytic activity in OER. When the current density is 100 mA·cm<sup>−2</sup>, the overpotential of the sample was 377 mV with Tafel slope of 56.2 mV·dec<sup>−1</sup>, which indicates that FeNi<sub>5</sub>-MOF-450 exhibits superior electrocatalytic performance than the commercial RuO<sub>2</sub>. Moreover, the long-term stability of FeNi<sub>5</sub>-MOF-450 further promotes its development in OER. This work demonstrated that the regulatory methods such as component optimization can effectively improve the OER catalytic performance of NiFe-based MOF-derived materials.</p></div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 10","pages":"1914 - 1921"},"PeriodicalIF":2.232,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41229281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
A gel polymer electrolyte with IL@UiO-66-NH2 as fillers for high-performance all-solid-state lithium metal batteries 凝胶聚合物电解质IL@UiO-66-NH2作为高性能全固态锂金属电池的填料
IF 2.232 2区 材料科学
International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-10-11 DOI: 10.1007/s12613-023-2639-0
Tao Wei, Qi Zhang, Sijia Wang, Mengting Wang, Ye Liu, Cheng Sun, Yanyan Zhou, Qing Huang, Xiangyun Qiu, Fang Tian
{"title":"A gel polymer electrolyte with IL@UiO-66-NH2 as fillers for high-performance all-solid-state lithium metal batteries","authors":"Tao Wei,&nbsp;Qi Zhang,&nbsp;Sijia Wang,&nbsp;Mengting Wang,&nbsp;Ye Liu,&nbsp;Cheng Sun,&nbsp;Yanyan Zhou,&nbsp;Qing Huang,&nbsp;Xiangyun Qiu,&nbsp;Fang Tian","doi":"10.1007/s12613-023-2639-0","DOIUrl":"10.1007/s12613-023-2639-0","url":null,"abstract":"<div><p>All solid-state electrolytes have the advantages of good mechanical and thermal properties for safer energy storage, but their energy density has been limited by low ionic conductivity and large interfacial resistance caused by the poor Li<sup>+</sup> transport kinetics due to the solid–solid contacts between the electrodes and the solid-state electrolytes. Herein, a novel gel polymer electrolyte (UPP-5) composed of ionic liquid incorporated metal-organic frameworks nanoparticles (IL@MOFs) is designed, it exhibits satisfying electrochemical performances, consisting of an excellent electrochemical stability window (5.5 V) and an improved Li<sup>+</sup> transference number of 0.52. Moreover, the Li/UPP-5/LiFePO<sub>4</sub> full cells present an ultra-stable cycling performance at 0.2C for over 100 cycles almost without any decay in capacities. This study might provide new insight to create an effective Li<sup>+</sup> conductive network for the development of all-solid-state lithium-ion batteries.</p></div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 10","pages":"1897 - 1905"},"PeriodicalIF":2.232,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s12613-023-2639-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41229146","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Editorial for special issue on renewable energy conversion, utilization and storage 可再生能源转换、利用和储存特刊编辑
IF 2.232 2区 材料科学
International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-10-11 DOI: 10.1007/s12613-023-2746-y
Qipeng Lu, Zhihong Du, Jie Wang, Wenbin Cao, Hailei Zhao
{"title":"Editorial for special issue on renewable energy conversion, utilization and storage","authors":"Qipeng Lu,&nbsp;Zhihong Du,&nbsp;Jie Wang,&nbsp;Wenbin Cao,&nbsp;Hailei Zhao","doi":"10.1007/s12613-023-2746-y","DOIUrl":"10.1007/s12613-023-2746-y","url":null,"abstract":"","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 10","pages":"1855 - 1858"},"PeriodicalIF":2.232,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41229123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Realizing high-performance Na3V2(PO4)2O2F cathode for sodium-ion batteries via Nb-doping Nb掺杂实现高性能钠离子电池Na3V2(PO4)2O2F阴极
IF 2.232 2区 材料科学
International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-10-11 DOI: 10.1007/s12613-023-2666-x
Jie Wang, Yifeng Yuan, Xianhui Rao, Min’an Yang, Doudou Wang, Ailing Zhang, Yan Chen, Zhaolin Li, Hailei Zhao
{"title":"Realizing high-performance Na3V2(PO4)2O2F cathode for sodium-ion batteries via Nb-doping","authors":"Jie Wang,&nbsp;Yifeng Yuan,&nbsp;Xianhui Rao,&nbsp;Min’an Yang,&nbsp;Doudou Wang,&nbsp;Ailing Zhang,&nbsp;Yan Chen,&nbsp;Zhaolin Li,&nbsp;Hailei Zhao","doi":"10.1007/s12613-023-2666-x","DOIUrl":"10.1007/s12613-023-2666-x","url":null,"abstract":"<div><p>Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub>O<sub>2</sub>F (NVPOF) has received considerable interest as a promising cathode material for sodium-ion batteries because of its high working voltage and good structural/thermal stability. However, the sluggish electrode reaction resulting from its low intrinsic electronic conductivity significantly restricts its electrochemical performance and thus its practical application. Herein, Nb-doped Na<sub>3</sub>V<sub>2−<i>x</i></sub>Nb<sub><i>x</i></sub>(PO<sub>4</sub>)<sub>2</sub>O<sub>2</sub>F/graphene (rGO) composites (<i>x</i> = 0, 0.05, 0.1) were prepared using a solvothermal method followed by calcination. Compared to the un-doped NVPOF/rGO, doping V-site with high-valence Nb element (Nb<sup>5+</sup>) (Na<sub>3</sub>V<sub>1.95</sub>Nb<sub>0.05</sub>(PO<sub>4</sub>)<sub>2</sub>O<sub>2</sub>F/rGO (NVN05POF/rGO)) can result in the generated V<sup>4+</sup>/V<sup>3+</sup> mixed-valence, ensuring the lower bandgap and thus the increased intrinsic electronic conductivity. Besides, the expanded lattice space favors the Na<sup>+</sup> migration. With the structure feature where NVN05POF particles are attached to the rGO sheets, the electrode reaction kinetics is further accelerated owing to the well-constructed electron conductive network. As a consequence, the as-prepared NVN05POF/rGO sample exhibits a high specific capacity of ∼72 mAh·g<sup>−1</sup> at 10C (capacity retention of 65.2% (vs. 0.5C)) and excellent long-term cycling stability with the capacity fading rate of ∼0.099% per cycle in 500 cycles at 5C.</p></div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 10","pages":"1859 - 1867"},"PeriodicalIF":2.232,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41229209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信