International Journal of Minerals, Metallurgy, and Materials最新文献_第10页

Homogeneous distributed natural pyrite-derived composite induced by modified graphite as high-performance lithium-ion batteries anode 改性石墨诱导均匀分布的天然黄铁矿衍生复合材料作为高性能锂离子电池负极

IF 2.232 2区材料科学

International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-05-13 DOI: 10.1007/s12613-023-2598-5

Juan Yu, Yinbo Wei, Bicheng Meng, Jiaxin Peng, Kai Yang, Tianxing Chen, Naixing Yang, Xiuyun Chuan

{"title":"Homogeneous distributed natural pyrite-derived composite induced by modified graphite as high-performance lithium-ion batteries anode","authors":"Juan Yu, Yinbo Wei, Bicheng Meng, Jiaxin Peng, Kai Yang, Tianxing Chen, Naixing Yang, Xiuyun Chuan","doi":"10.1007/s12613-023-2598-5","DOIUrl":"10.1007/s12613-023-2598-5","url":null,"abstract":"<div>Natural minerals-based energy materials have attracted enormous attention because of the advantages of good materials consistency, high production, environmental friendliness, and low cost. The uniform distribution of grains can effectively inhibit the aggregation of active materials, improving lithium storage performance. In this work, natural graphite is modified by polyvinylpyrrolidone to obtain modified graphite with reduced size and better dispersion. Natural pyrite composite polyvinylpyrrolidone-modified graphite (pyrite/PG) material with uniform particle distribution is obtained by the ball milling process. The subsequent calcination process converts pyrite/PG into Fe1−xS compounded with polyvinylpyrrolidone-modified graphite (Fe1−xS/PG). The homogeneous grain distributions of active material can facilitate the faster transfer of electrons and promote the efficient utilization of active materials. The as-prepared Fe1−xS/PG electrode exhibits a remarkably reversible specific capacity of 613.0 mAh·g−1 at 0.2 A·g−1 after 80 cycles and an excellent rate capability of 523.0 mAh·g−1 at 5 A·g−1. Even at a higher current density of 10 A·g−1, it can deliver a specific capacity of 348.0 mAh·g−1. Moreover, the dominant pseudocapacitance in redox reactions accounts for the impressive rate and cycling stability. This work provides a low-cost and facile method to fabricate natural mineral-based anode materials and apprise readers about the impact of uniform particle distribution on lithium storage performance.</div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 7","pages":"1353 - 1362"},"PeriodicalIF":2.232,"publicationDate":"2023-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4842502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microwave absorption and thermal properties of coral-like SiC aerogel composites prepared by water glass as a silicon source 以水玻璃为硅源制备的珊瑚状碳化硅气凝胶复合材料的微波吸收和热性能

IF 2.232 2区材料科学

International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-05-13 DOI: 10.1007/s12613-023-2605-x

Xinyuan Zhang, Chenkang Xia, Weihai Liu, Mingyuan Hao, Yang Miao, Feng Gao

{"title":"Microwave absorption and thermal properties of coral-like SiC aerogel composites prepared by water glass as a silicon source","authors":"Xinyuan Zhang, Chenkang Xia, Weihai Liu, Mingyuan Hao, Yang Miao, Feng Gao","doi":"10.1007/s12613-023-2605-x","DOIUrl":"10.1007/s12613-023-2605-x","url":null,"abstract":"<div>As a heat-resistant wave-absorbing material, silicon carbide (SiC) aerogel has become a research hotspot at present. However, the most common silicon sources are organosilanes, which are costly and toxic. In this work, SiC aerogels were successfully prepared by using water glass as the silicon source. Specifically, the microstructure and chemical composition of SiC aerogels were controlled by adjusting the Si to C molar ratio during the sol–gel process, and the effect on SiC aerogel microwave absorption properties was investigated. The SiC aerogels prepared with Si:C molar ratio of 1:1 have an effective electromagnetic wave absorption capacity, with a minimum reflection loss value of −46.30 dB at 12.88 GHz and an effective frequency bandwidth of 4.02 GHz. They also have good physical properties, such as the density of 0.0444 g/cm3, the thermal conductivity of 0.0621 W/(m·K), and the specific surface area of 1099 m2/g. These lightweight composites with microwave-absorbing properties and low thermal conductivity can be used as thermal protection materials for space shuttles and reusable carriers.</div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 7","pages":"1375 - 1387"},"PeriodicalIF":2.232,"publicationDate":"2023-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4548360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Surface metal-matrix composites based on AZ91 magnesium alloy via friction stir processing: A review 搅拌摩擦法制备AZ91镁合金表面金属基复合材料研究进展

IF 2.232 2区材料科学

International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-05-13 DOI: 10.1007/s12613-022-2589-y

Hamed Mirzadeh

{"title":"Surface metal-matrix composites based on AZ91 magnesium alloy via friction stir processing: A review","authors":"Hamed Mirzadeh","doi":"10.1007/s12613-022-2589-y","DOIUrl":"10.1007/s12613-022-2589-y","url":null,"abstract":"<div>This monograph presents an overview of friction stir processing (FSP) of surface metal-matrix composites (MMCs) using the AZ91 magnesium alloy. The reported results in relation to various reinforcing particles, including silicon carbide (SiC), alumina (Al2O3), quartz (SiO2), boron carbide (B4C), titanium carbide (TiC), carbon fiber, hydroxyapatite (HA), in-situ formed phases, and hybrid reinforcements are summarized. AZ91 composite fabricating methods based on FSP are explained, including groove filling (grooving), drilled hole filling, sandwich method, stir casting followed by FSP, and formation of in-situ particles. The effects of introducing second-phase particles and FSP process parameters (e.g., tool rotation rate, traverse speed, and the number of passes) on the microstructural modification, grain refinement, homogeneity in the distribution of particles, inhibition of grain growth, mechanical properties, strength–ductility trade-off, wear/tribological behavior, and corrosion resistance are discussed. Finally, useful suggestions for future work are proposed, including focusing on the superplasticity and superplastic forming, metal additive manufacturing processes based on friction stir engineering (such as additive friction stir deposition), direct FSP, stationary shoulder FSP, correlation of the dynamic recrystallization (DRX) grain size with the Zener–Hollomon parameter similar to hot deformation studies, process parameters (such as the particle volume fraction and external cooling), and common reinforcing phases such as zirconia (ZrO2) and carbon nanotubes (CNTs).</div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 7","pages":"1278 - 1296"},"PeriodicalIF":2.232,"publicationDate":"2023-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4550167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 8

Effect of dissolved components of malachite and calcite on surface properties and flotation behavior 孔雀石和方解石的溶解组分对表面性质和浮选行为的影响

IF 2.232 2区材料科学

International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-05-13 DOI: 10.1007/s12613-023-2606-9

Zhihao Shen, Shuming Wen, Han Wang, Yongchao Miao, Xiao Wang, Shengbing Meng, Qicheng Feng

{"title":"Effect of dissolved components of malachite and calcite on surface properties and flotation behavior","authors":"Zhihao Shen, Shuming Wen, Han Wang, Yongchao Miao, Xiao Wang, Shengbing Meng, Qicheng Feng","doi":"10.1007/s12613-023-2606-9","DOIUrl":"10.1007/s12613-023-2606-9","url":null,"abstract":"<div>In general, malachite is recovered via sulfidization–xanthate flotation, although many unsatisfactory flotation indexes are frequently obtained as a result of the presence of associated calcite. This phenomenon occurs because the dissolved components of malachite and calcite affect the flotation behavior of both minerals. In this study, the effect of the dissolved components derived from malachite and calcite on the flotation behavior and surface characteristics of both minerals was investigated. Flotation tests indicated that malachite recovery decreased when the calcite supernatant was introduced, while the presence of the malachite supernatant increased the recovery of calcite. Dissolution and adsorption tests, along with zeta potential measurements, X-ray photoelectron spectroscopy, Fourier transform infrared spectrometry, and time-of-flight secondary ion mass spectrometry demonstrated that the Ca species in the calcite supernatant were adsorbed on the malachite surface, which hindered the interaction of Na2S with malachite, thereby resulting in the insufficient adsorption of sodium isoamyl xanthate (NaIX) on the surface of malachite. By contrast, the Cu species in the malachite supernatant were adsorbed on the calcite surface, and they provided active sites for the subsequent adsorption of Na2S and NaIX.</div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 7","pages":"1297 - 1309"},"PeriodicalIF":2.232,"publicationDate":"2023-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4552185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 16

Coordination states of metal ions in molten salts and their characterization methods 熔盐中金属离子的配位态及其表征方法

IF 2.232 2区材料科学

International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-05-13 DOI: 10.1007/s12613-023-2608-7

Xin Song, Shaolong Li, Shanshan Liu, Yong Fan, Jilin He, Jianxun Song

{"title":"Coordination states of metal ions in molten salts and their characterization methods","authors":"Xin Song, Shaolong Li, Shanshan Liu, Yong Fan, Jilin He, Jianxun Song","doi":"10.1007/s12613-023-2608-7","DOIUrl":"10.1007/s12613-023-2608-7","url":null,"abstract":"<div>The macroscopic characteristics of molten salts are governed by their microstructures. Research on the structures of molten salts provides the foundation for a full understanding of the physicochemical properties of molten salts as well as a deeper analysis of the microscopic electrolysis process in molten salts. Information about the microstructure of matter can be obtained with the help of several speculative and experimental procedures. In this review, the advantages and disadvantages of the various test procedures used to determine the microstructures of molten salts are compared. The typical coordination configurations of metal ions in molten salt systems are also summarized. Furthermore, the impact of temperature, anions, cations, and metal oxides (O2−) on the structures of molten salts is discussed in detail. The accuracy and completeness of the information on molten salt structures need to be investigated by the integration of multiple methods and interdisciplinary fields. Information on the microstructure and coordination of molten salts deepens the understanding of the elementary elements of the microstructure of matter. This paper, which is based on the review of the coordination states of metal ions in molten salts, is hoped to inspire researchers to explore the inter-relationship between the microstructure and macroscopic properties of materials.</div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 7","pages":"1261 - 1277"},"PeriodicalIF":2.232,"publicationDate":"2023-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4548746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Influence of band microstructure on carbide precipitation behavior and toughness of 1 GPa-grade ultra-heavy gauge low-alloy steel 带状组织对1gpa级特重规低合金钢碳化物析出行为及韧性的影响

IF 2.232 2区材料科学

International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-05-13 DOI: 10.1007/s12613-023-2597-6

Peng Han, Zhipeng Liu, Zhenjia Xie, Hua Wang, Yaohui Jin, Xuelin Wang, Chengjia Shang

{"title":"Influence of band microstructure on carbide precipitation behavior and toughness of 1 GPa-grade ultra-heavy gauge low-alloy steel","authors":"Peng Han, Zhipeng Liu, Zhenjia Xie, Hua Wang, Yaohui Jin, Xuelin Wang, Chengjia Shang","doi":"10.1007/s12613-023-2597-6","DOIUrl":"10.1007/s12613-023-2597-6","url":null,"abstract":"<div>This study investigated the influence of band microstructure induced by centerline segregation on carbide precipitation behavior and toughness in an 80 mm-thick 1 GPa low-carbon low-alloy steel plate. The quarter-thickness (1/4t) and half-thickness (1/2t) regions of the plate exhibited similar ductility and toughness after quenching. After tempering, the 1/4t region exhibited ∼50% and ∼25% enhancements in both the total elongation and low-temperature toughness at −40°C, respectively, without a decrease in yield strength, whereas the toughness of the 1/2t region decreased by ∼46°%. After quenching, both the 1/4t and 1/2t regions exhibited lower bainite and lath martensite concentrations, but only the 1/2t region exhibited microstructure bands. Moreover, the tempered 1/4t region featured uniformly dispersed short rod-like M23C6 carbides, and spherical MC precipitates with diameters of ∼20–100 nm and <20 nm, respectively. The uniformly dispersed nanosized M23C6 carbides and MC precipitates contributed to the balance of high strength and high toughness. The band microstructure of the tempered 1/2t region featured a high density of large needle-like M3C carbides. The length and width of the large M3C carbides were ∼200–500 nm and ∼20–50 nm, respectively. Fractography analysis revealed that the high density of large carbides led to delamination cleavage fracture, which significantly deteriorated toughness.</div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 7","pages":"1329 - 1337"},"PeriodicalIF":2.232,"publicationDate":"2023-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4552915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Dielectric loss enhancement induced by the microstructure of CoFe2O4 foam to realize broadband electromagnetic wave absorption 泡沫CoFe2O4微结构诱导介质损耗增强，实现宽带电磁波吸收

IF 2.232 2区材料科学

International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-05-13 DOI: 10.1007/s12613-023-2599-4

Bin Shi, Hongsheng Liang, Zijun Xie, Qing Chang, Hongjing Wu

{"title":"Dielectric loss enhancement induced by the microstructure of CoFe2O4 foam to realize broadband electromagnetic wave absorption","authors":"Bin Shi, Hongsheng Liang, Zijun Xie, Qing Chang, Hongjing Wu","doi":"10.1007/s12613-023-2599-4","DOIUrl":"10.1007/s12613-023-2599-4","url":null,"abstract":"<div>CoFe2O4 has been widely used for electromagnetic wave absorption owing to its high Snoek limit, high anisotropy, and suitable saturation magnetization; however, its inherent shortcomings, including low dielectric loss, high density, and magnetic agglomeration, limit its application as an ideal absorbent. This study investigated a microstructure regulation strategy to mitigate the inherent disadvantages of pristine CoFe2O4 synthesized via a sol–gel auto-combustion method. A series of CoFe2O4 foams (S0.5, S1.0, and S1.5, corresponding to foams with citric acid (CA)-to-Fe(NO3)3·9H2O molar ratios of 0.5, 1.0, and 1.5, respectively) with two-dimensional (2D) curved surfaces were obtained through the adjustment of CA-to-Fe3+ ratio, and the electromagnetic parameters were adjusted through morphology regulation. Owing to the appropriate impedance matching and conductance loss provided by moderate complex permittivity, the effective absorption bandwidth (EAB) of S0.5 was as high as 7.3 GHz, exceeding those of most CoFe2O4-based absorbents. Moreover, the EAB of S1.5 reached 5.0 GHz (8.9–13.9 GHz), covering most of the X band, owing to the intense polarization provided by lattice defects and the heterogeneous interface. The three-dimensional (3D) foam structure circumvented the high density and magnetic agglomeration issues of CoFe2O4 nanoparticles, and the good conductivity of 2D curved surfaces could effectively elevate the complex permittivity to ameliorate the dielectric loss of pure CoFe2O4. This study provides a novel idea for the theoretical design and practical production of lightweight and broadband pure ferrites.</div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 7","pages":"1388 - 1397"},"PeriodicalIF":2.232,"publicationDate":"2023-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4550158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 8

Influence of substituting B2O3 with Li2O on the viscosity, structure and crystalline phase of low-reactivity mold flux 用Li2O取代B2O3对低反应性结晶剂粘度、结构和晶相的影响

IF 2.232 2区材料科学

International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-05-13 DOI: 10.1007/s12613-023-2621-x

Rongzhen Mo, Xubin Zhang, Ying Ren, Junjie Hu, Lifeng Zhang

{"title":"Influence of substituting B2O3 with Li2O on the viscosity, structure and crystalline phase of low-reactivity mold flux","authors":"Rongzhen Mo, Xubin Zhang, Ying Ren, Junjie Hu, Lifeng Zhang","doi":"10.1007/s12613-023-2621-x","DOIUrl":"10.1007/s12613-023-2621-x","url":null,"abstract":"<div>The low-reactivity mold flux with low SiO2 content is considered suitable for the continuous casting of high-aluminum steel since it can significantly reduce the reaction between Al in steel and SiO2 in mold flux. However, the traditional low-reactivity mold flux still presents some problems such as high viscosity and strong crystallization tendency. In this study, the co-addition of Li2O and B2O3 in CaO–Al2O3–10wt%SiO2 based low-reactivity mold flux was proposed to improve properties of mold flux for high-aluminum steel, and the effect of Li2O replacing B2O3 on properties of mold flux was investigated. The viscosity of the mold flux with 2wt% Li2O and 6wt% B2O3 reached a minimum value of 0.07 Pa·s. The break temperature and melting point showed a similar trend with the viscosity. Besides, the melt structure and precipitation of the crystalline phase were studied using Raman and X-ray diffraction spectra to better understand the evolution of viscosity. It demonstrated that with increasing Li2O content in the mold flux from 0 to 6wt%, the degree of polymerization of aluminate and the aluminosilicate network structure increased because of increasing Li+ released by Li2O, indicating the added Li2O was preferentially associated with Al3+ as a charge compensator. The precipitation of LiAlO2 crystalline phase gradually increased with the replacement of B2O3 by Li2O. Therefore, Li2O content should be controlled below 2wt% to avoid LiAlO2 precipitation, which was harmful to the continuous casting of high-aluminum steels.</div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 7","pages":"1320 - 1328"},"PeriodicalIF":2.232,"publicationDate":"2023-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4550165","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Effect of solvents on the morphology and structure of barium titanate synthesized by a one-step hydrothermal method 溶剂对一步水热法合成钛酸钡的形貌和结构的影响

IF 2.232 2区材料科学

International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-05-13 DOI: 10.1007/s12613-023-2614-9

Xiaoxiao Pang, Tingting Wang, Bin Liu, Xiayue Fan, Xiaorui Liu, Jing Shen, Cheng Zhong, Wenbin Hu

{"title":"Effect of solvents on the morphology and structure of barium titanate synthesized by a one-step hydrothermal method","authors":"Xiaoxiao Pang, Tingting Wang, Bin Liu, Xiayue Fan, Xiaorui Liu, Jing Shen, Cheng Zhong, Wenbin Hu","doi":"10.1007/s12613-023-2614-9","DOIUrl":"10.1007/s12613-023-2614-9","url":null,"abstract":"<div>Tetragonal barium titanate was synthesized from barium hydroxide octahydrate and titanium tetrachloride through a simple one-step hydrothermal method. The effect of different solvents on the crystal structure and morphology of barium titanate nanoparticles during the hydrothermal process was investigated. Except for ethylene glycol/water solvent, impurity-free barium titanate was synthesized in pure water, methanol/water, ethanol/water, and isopropyl alcohol/water mixed solvents. Compared with other alcohols, ethanol promotes the formation of a tetragonal structure. In addition, characterization studies confirm that particles synthesized in methanol/water, ethanol/water, and isopropyl alcohol/water mixed solvents are smaller in size than those synthesized in pure water. In the case of alcohol-containing solvents, the particle size decreases in the order of isopropanol, ethanol, and methanol. Among all the media used in this study, ethanol/water is considered the optimum reaction media for barium titanate with high tetragonality (defined as the ratio of two lattice parameters c and a, c/a = 1.0088) and small average particle size (82 nm), which indicates its great application potential in multilayer ceramic capacitors.</div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 7","pages":"1407 - 1416"},"PeriodicalIF":2.232,"publicationDate":"2023-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4552916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Fabrication of g-C3N4 nanosheet/Bi5O7Br/NH2-MIL-88B (Fe) nanocomposites: Double S-scheme photocatalysts with impressive performance for the removal of antibiotics under visible light g-C3N4纳米片/Bi5O7Br/NH2-MIL-88B (Fe)纳米复合材料的制备:具有可见光下去除抗生素性能的双s方案光催化剂

IF 2.232 2区材料科学

International Journal of Minerals, Metallurgy, and Materials Pub Date : 2023-05-13 DOI: 10.1007/s12613-023-2618-5

Nasrin Sedaghati, Aziz Habibi-Yangjeh, Alireza Khataee

{"title":"Fabrication of g-C3N4 nanosheet/Bi5O7Br/NH2-MIL-88B (Fe) nanocomposites: Double S-scheme photocatalysts with impressive performance for the removal of antibiotics under visible light","authors":"Nasrin Sedaghati, Aziz Habibi-Yangjeh, Alireza Khataee","doi":"10.1007/s12613-023-2618-5","DOIUrl":"10.1007/s12613-023-2618-5","url":null,"abstract":"<div>Novel graphitic carbon nitride (g-C3N4) nanosheet/Bi5O7Br/NH2-MIL-88B (Fe) photocatalysts (denoted as GCN-NSh/Bi5O7Br/Fe-MOF, in which MOF is metal-organic framework) with double S-scheme heterojunctions were synthesized by a facile solvothermal route. The resultant materials were examined by X-ray photoelectron spectrometer (XPS), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), photoluminescence spectroscopy (PL), Fourier transform infrared spectroscopy (FT-IR), UV-Vis diffuse reflection spectroscopy (UV-vis DRS), photocurrent density, electrochemical impedance spectroscopy (EIS), and Brunauer–Emmett–Teller (BET) analyses. After the integration of Fe-MOF with GCN-NSh/Bi5O7Br, the removal constant of tetracycline over the optimal GCN-NSh/Bi5O7Br/Fe-MOF (15wt%) nanocomposite was promoted 33 times compared with that of the pristine GCN. The GCN-NSh/Bi5O7Br/Fe-MOF (15wt%) nanocomposite showed superior photoactivity to azithromycin, metronidazole, and cephalexin removal that was 36.4, 20.2, and 14.6 times higher than that of pure GCN, respectively. Radical quenching tests showed that ·O\u0000 −2\u0000 \u0000 and h+ mainly contributed to the elimination reaction. In addition, the nanocomposite maintained excellent activity after 4 successive cycles. Based on the developed n–n heterojunctions among n-GCN-NSh, n-Bi5O7Br, and n-Fe-MOF semiconductors, the double S-scheme charge transfer mechanism was proposed for the destruction of the selected antibiotics.</div>","PeriodicalId":14030,"journal":{"name":"International Journal of Minerals, Metallurgy, and Materials","volume":"30 7","pages":"1363 - 1374"},"PeriodicalIF":2.232,"publicationDate":"2023-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4842511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3