Homogeneous distributed natural pyrite-derived composite induced by modified graphite as high-performance lithium-ion batteries anode

IF 5.6 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Juan Yu, Yinbo Wei, Bicheng Meng, Jiaxin Peng, Kai Yang, Tianxing Chen, Naixing Yang, Xiuyun Chuan
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引用次数: 0

Abstract

Natural minerals-based energy materials have attracted enormous attention because of the advantages of good materials consistency, high production, environmental friendliness, and low cost. The uniform distribution of grains can effectively inhibit the aggregation of active materials, improving lithium storage performance. In this work, natural graphite is modified by polyvinylpyrrolidone to obtain modified graphite with reduced size and better dispersion. Natural pyrite composite polyvinylpyrrolidone-modified graphite (pyrite/PG) material with uniform particle distribution is obtained by the ball milling process. The subsequent calcination process converts pyrite/PG into Fe1−xS compounded with polyvinylpyrrolidone-modified graphite (Fe1−xS/PG). The homogeneous grain distributions of active material can facilitate the faster transfer of electrons and promote the efficient utilization of active materials. The as-prepared Fe1−xS/PG electrode exhibits a remarkably reversible specific capacity of 613.0 mAh·g−1 at 0.2 A·g−1 after 80 cycles and an excellent rate capability of 523.0 mAh·g−1 at 5 A·g−1. Even at a higher current density of 10 A·g−1, it can deliver a specific capacity of 348.0 mAh·g−1. Moreover, the dominant pseudocapacitance in redox reactions accounts for the impressive rate and cycling stability. This work provides a low-cost and facile method to fabricate natural mineral-based anode materials and apprise readers about the impact of uniform particle distribution on lithium storage performance.

改性石墨诱导均匀分布的天然黄铁矿衍生复合材料作为高性能锂离子电池负极
天然矿物基能源材料因其材料一致性好、产量高、环境友好、成本低等优点而受到广泛关注。晶粒的均匀分布可以有效抑制活性物质的聚集,提高锂的储存性能。本文采用聚乙烯吡咯烷酮对天然石墨进行改性,得到粒径减小、分散性好的改性石墨。采用球磨法制备了颗粒分布均匀的天然黄铁矿复合聚乙烯吡咯烷酮改性石墨(黄铁矿/PG)材料。随后的煅烧过程将黄铁矿/PG转化为Fe1−xS与聚乙烯吡咯烷酮改性石墨(Fe1−xS/PG)复合。活性物质的均匀晶粒分布有利于电子的快速转移,促进活性物质的高效利用。制备的Fe1−xS/PG电极在0.2 a·g−1下循环80次后具有613.0 mAh·g−1的可逆比容量,在5 a·g−1下具有523.0 mAh·g−1的优良倍率容量。即使在10 a·g−1的高电流密度下,它也可以提供348.0 mAh·g−1的比容量。此外,在氧化还原反应中占主导地位的赝电容解释了令人印象深刻的速率和循环稳定性。这项工作提供了一种低成本和简便的方法来制造天然矿物基阳极材料,并向读者介绍均匀颗粒分布对锂存储性能的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
9.30
自引率
16.70%
发文量
205
审稿时长
2 months
期刊介绍: International Journal of Minerals, Metallurgy and Materials (Formerly known as Journal of University of Science and Technology Beijing, Mineral, Metallurgy, Material) provides an international medium for the publication of theoretical and experimental studies related to the fields of Minerals, Metallurgy and Materials. Papers dealing with minerals processing, mining, mine safety, environmental pollution and protection of mines, process metallurgy, metallurgical physical chemistry, structure and physical properties of materials, corrosion and resistance of materials, are viewed as suitable for publication.
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