Inorganic Chemistry Communications最新文献

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Schiff Base Compounds as Versatile Building Blocks for Drug Delivery Systems 希夫碱化合物作为药物传递系统的通用构件
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2026-04-01 Epub Date: 2026-01-13 DOI: 10.1016/j.inoche.2026.116193
Somaye Shahraki , Esmaeil Vaziri , Jing Ding , Kelong Fan
{"title":"Schiff Base Compounds as Versatile Building Blocks for Drug Delivery Systems","authors":"Somaye Shahraki ,&nbsp;Esmaeil Vaziri ,&nbsp;Jing Ding ,&nbsp;Kelong Fan","doi":"10.1016/j.inoche.2026.116193","DOIUrl":"10.1016/j.inoche.2026.116193","url":null,"abstract":"<div><div>Despite the notable success of traditional therapeutic approaches such as chemotherapy, significant limitations remain, including high dosage requirements, drug resistance, nonselectivity, adverse side effects, and poor bioavailability. To address these challenges, drug delivery systems (DDSs) have been developed to more effectively transport therapeutic agents to target sites while minimizing systemic toxicity. Among the strategies for designing smart DDSs, reversible covalent interactions, particularly Schiff base linkages, have emerged as crucial components due to their dynamic and stimuli-responsive properties. In this review, we emphasize the role of Schiff base chemistry in DDSs, highlighting its structural advantages, responsiveness to physiological triggers (e.g., pH), and its contribution to enhanced therapeutic efficacy. We also examine the integration of Schiff base compounds into various polymeric DDS architectures and discuss recent advancements in their applications for selective and controlled drug release. Finally, we consider the current challenges and future directions for achieving precise, targeted drug delivery through Schiff base-based systems.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"186 ","pages":"Article 116193"},"PeriodicalIF":5.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146074455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biomass-derived carbon dots as broad-spectrum adsorbents for industrial wastewater remediation 生物质衍生碳点作为工业废水修复的广谱吸附剂
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2026-04-01 Epub Date: 2026-01-31 DOI: 10.1016/j.inoche.2026.116280
Varun Aggarwal , Rajeev Kumar Aggarwal , Pratima Vaidya , Kumar Venkatesan , Manickam Selvaraj , Ankit Kachore , Ekta Bala , Hemant Singh , Saima , Praveen Kumar Verma
{"title":"Biomass-derived carbon dots as broad-spectrum adsorbents for industrial wastewater remediation","authors":"Varun Aggarwal ,&nbsp;Rajeev Kumar Aggarwal ,&nbsp;Pratima Vaidya ,&nbsp;Kumar Venkatesan ,&nbsp;Manickam Selvaraj ,&nbsp;Ankit Kachore ,&nbsp;Ekta Bala ,&nbsp;Hemant Singh ,&nbsp;Saima ,&nbsp;Praveen Kumar Verma","doi":"10.1016/j.inoche.2026.116280","DOIUrl":"10.1016/j.inoche.2026.116280","url":null,"abstract":"<div><div>Toxic heavy metal ions (HMIs) released through industrial discharges continue to threaten environmental safety and human health, necessitating the development of cost-effective, sustainable, and efficient adsorbents. Within this framework, biomass-derived carbon dots (CDs) offer a promising green solution due to their facile synthesis, abundant surface functionalities, and excellent biocompatibility. However, most reported carbon dot-based adsorbents with either organic or inorganic supports, have been applied using synthetic wastewater. The studies on plant-derived CDs, their green synthesis approaches for removal of multiple HMIs from real industrial effluents is less explored. Thus, there is a dire need for low-cost, sustainable biomass derived CDs for real wastewater treatment applications. This study reports a green, sustainable, novel, and cost-effective approach for synthesizing <em>Tinospora cordifolia</em>-derived carbon dots (CDs@TC) via a simple combustion-microwave-assisted method and demonstrates their application in heavy metal removal from real industrial wastewater. These CDs were characterized by UV–vis, fluorescence, FT-IR, EDS, zeta potential, HR-TEM, XRD, and XPS analyses. These analyses confirmed the size of CDs@TC to be 4.09 nm and rich in oxygen- and nitrogen-containing functional groups. Adsorption experiments using ICP-OES technique revealed efficient removal of multiple heavy metal ions (HMIs), including lead (Pb) (84.06%), iron (Fe) (47.99%), copper (Cu) (74.86%), arsenic (As) (97.39%), zinc (Zn) (61.77%), and chromium (Cr) (90.50%), under optimized conditions. The adsorption mechanism involved ion exchange, surface complexation, electrostatic attraction, and physical adsorption. However, recovery remains a limitation due to the absence of magnetic or polymeric supports. This work highlights the potential of plant-derived CDs as scalable, and eco-friendly adsorbent.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"186 ","pages":"Article 116280"},"PeriodicalIF":5.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146170134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A minireview on recent process in the CO2 reduction reaction of Cu-based nanoarray structure catalysts 铜基纳米阵列结构催化剂CO2还原反应研究进展综述
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2026-04-01 Epub Date: 2026-02-05 DOI: 10.1016/j.inoche.2026.116290
Jieshi Luo , Dongliang Li , Renjiao Luo , Yujie Chen , Yajun Wang , Yanan Zou , Xiaomin Kang
{"title":"A minireview on recent process in the CO2 reduction reaction of Cu-based nanoarray structure catalysts","authors":"Jieshi Luo ,&nbsp;Dongliang Li ,&nbsp;Renjiao Luo ,&nbsp;Yujie Chen ,&nbsp;Yajun Wang ,&nbsp;Yanan Zou ,&nbsp;Xiaomin Kang","doi":"10.1016/j.inoche.2026.116290","DOIUrl":"10.1016/j.inoche.2026.116290","url":null,"abstract":"<div><div>Cu-based array structure catalysts represent a novel category of catalysts that have a broad spectrum of applications. Among them, the application in carbon dioxide reduction reaction (CO<sub>2</sub>RR) exhibits great potential due to outstanding catalytic efficiency. This work summarizes the recent researches regarding the utilization of Cu-based array structure catalysts in CO<sub>2</sub>RR. Firstly, the current status of the utilization of Cu-based array catalysts in the field of electrocatalysis., photocatalysis, and photoelectrocatalysis is discussed. Furthermore, Cu-based array structure catalysts with different binary structures are classified to explore their catalytic mechanism, electron transfer process, surface structure, and synergistic effect upon catalytic efficiency for CO<sub>2</sub>RR. The advantages of Cu-based array structure catalysts in CO<sub>2</sub>RR, including efficient CO<sub>2</sub> conversion, superior selectivity, and good stability, are analyzed in depth. Above all, the related methods to enhance the catalytic efficiency of Cu-based array structure catalysts are proposed.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"186 ","pages":"Article 116290"},"PeriodicalIF":5.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146170440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable electrospun PAN@SiO₂*Ag nanofiber composites for efficient removal of toxic Cr(VI) from contaminated water 可持续静电纺PAN@SiO₂*Ag纳米纤维复合材料,用于有效去除污染水中的有毒Cr(VI)
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2026-04-01 Epub Date: 2026-02-02 DOI: 10.1016/j.inoche.2026.116266
Mohamed R. El-Aassar
{"title":"Sustainable electrospun PAN@SiO₂*Ag nanofiber composites for efficient removal of toxic Cr(VI) from contaminated water","authors":"Mohamed R. El-Aassar","doi":"10.1016/j.inoche.2026.116266","DOIUrl":"10.1016/j.inoche.2026.116266","url":null,"abstract":"<div><div>Hexavalent chromium (Cr(VI)), a highly toxic and persistent water pollutant, poses serious environmental and public health risks. Therefore, the development of effective, reusable, and nanostructured adsorbents is essential for improving wastewater treatment technologies. In this study, electrospun polyacrylonitrile@silica*silver (PAN@SiO₂*Ag) composite nanofibers were developed and characterized to synergistically enhance surface functionality, adsorption efficiency, and reusability for Cr(VI) removal. PAN@SiO₂*Ag composite nanofibers were fabricated via a sol–gel synthesis of SiO₂Ag followed by electrospinning and characterized using FE-SEM, TEM, FTIR, XRD, TGA, and BET analyses. The nanofibers exhibited enhanced mesoporosity and thermal stability, achieving a maximum Cr(VI) adsorption capacity of 221.73 mg/g at pH 2.0, with adsorption kinetics following a pseudo-second-order model and equilibrium behavior best described by the Freundlich isotherm. Adsorption kinetics were well described by a pseudo-second-order model, while equilibrium data followed the Freundlich isotherm, indicating heterogeneous, multilayer adsorption. Thermodynamic analysis indicated that the adsorption process was both spontaneous and endothermic, reflecting favorable interfacial interactions between Cr(VI) ions and the composite surface. Moreover, the nanofibers exhibited excellent regeneration and reuse performance over multiple adsorption–desorption cycles, highlighting their structural stability and practical applicability. These results demonstrate the practical potential of PAN@SiO₂*Ag nanofibers as a potential and reusable way to remove heavy metals from wastewater treatment systems.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"186 ","pages":"Article 116266"},"PeriodicalIF":5.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146170504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient and easily recoverable MIL-101 (Fe)/CoFe2O4 catalyst for boosting persulfate-activated antibiotic degradation 高效易回收的MIL-101 (Fe)/CoFe2O4催化剂促进过硫酸盐活化的抗生素降解
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2026-04-01 Epub Date: 2026-02-09 DOI: 10.1016/j.inoche.2026.116278
Dinh Trinh Tran , Anh-Tuan Phan , Tran-Bao Pham , Phuc-Quan Do , Huu-Tap Van
{"title":"Efficient and easily recoverable MIL-101 (Fe)/CoFe2O4 catalyst for boosting persulfate-activated antibiotic degradation","authors":"Dinh Trinh Tran ,&nbsp;Anh-Tuan Phan ,&nbsp;Tran-Bao Pham ,&nbsp;Phuc-Quan Do ,&nbsp;Huu-Tap Van","doi":"10.1016/j.inoche.2026.116278","DOIUrl":"10.1016/j.inoche.2026.116278","url":null,"abstract":"<div><div>MIL-101(Fe)/CoFe<sub>2</sub>O<sub>4</sub> catalyst was successfully synthesized using hydrothermal treatment processes. Characteristic analyses reveal that CoFe<sub>2</sub>O<sub>4</sub> spherical particles uniformly distribute on MIL-101(Fe)’ surfaces. MIL-101(Fe)/CoFe<sub>2</sub>O<sub>4</sub> catalyst is a porous material, with a specific surface area of 39.96 m<sup>2</sup>/g, an average pore diameter of 17.52 nm. The degradation of tetracycline shows that synergic effects between CoFe<sub>2</sub>O<sub>4</sub> and MIL-101(Fe) lead to an improvement of 1.16–1.42 times in catalytic activity compared to all individuals. The catalytic activity of MIL-101(Fe)/CoFe<sub>2</sub>O<sub>4</sub> is influenced by pH, catalyst dosage, persulfate concentration, initial concentration of the pollutant, co-existing ions. Under optimal conditions, 91.25 ± 2.25% of tetracycline were removed within 60 min, while 72% are mineralized into CO<sub>2</sub> and H<sub>2</sub>O. The pseudo-second-order kinetics model best fits tetracycline degradation, with a R<sup>2</sup> value within 0.937–0.987. SO₄<sup>•-</sup>, HO<sup>•</sup> are mainly responsible for tetracycline degradation. The catalyst exhibits excellent reusability, retaining 82.38% of its initial capacity after five treatment cycles without any significant modifications of its nature. Dissolved heavy metal (Co, Fe) concentration from the leaching process is lower than the limit values for surface water. MIL-101(Fe)/CoFe<sub>2</sub>O<sub>4</sub> shows highly applicable in livestock wastewater treatment. This work presents a simple method for constructing effective and easily recoverable catalysts, contributing to sustainable pollution remediation.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"186 ","pages":"Article 116278"},"PeriodicalIF":5.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146170047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advanced composite textile materials based on cotton and PET with incorporated metal-organic framework UiO-66 以棉和PET为基础,加入金属有机框架UiO-66的高级复合纺织材料
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2026-04-01 Epub Date: 2026-02-12 DOI: 10.1016/j.inoche.2026.116330
Valeriia V. Lobanova, Grigory V. Mamontov
{"title":"Advanced composite textile materials based on cotton and PET with incorporated metal-organic framework UiO-66","authors":"Valeriia V. Lobanova,&nbsp;Grigory V. Mamontov","doi":"10.1016/j.inoche.2026.116330","DOIUrl":"10.1016/j.inoche.2026.116330","url":null,"abstract":"<div><div>UiO-66@PET and UiO-66@cotton composites, containing nanosized metal-organic framework, are synthesized via solvothermal method. Two strategies for UiO-66 immobilization into the textile structure are used: in situ growth of MOF in the presence of textile using relatively low volume of solvent as well as the pre-impregnation of textiles with Zr precursor following with the MOF assembly in a DMF solution of terephthalic acid. The synthesized UiO-66@PET and UiO-66@cotton are characterized by X-ray diffraction analysis, low-temperature adsorption-desorption of N<sub>2</sub> and scanning electron microscopy (SEM). It is shown that the first approach allows forming less than 1%wt. UiO-66 on the PET surface, while the second approach provides the immobilization of 7.1%wt. and 25.5%wt. into PET and cotton, respectively. High mechanical stability toward ultrasound treatment is shown for UiO-66@PET composite that is caused by high chemical affinity of UiO-66 to the PET surface and MOF distribution on the textiles surface in the dispersed state. The UiO-66 immobilization into textile material leads to rise in the sorption properties. It is shown that the sorption capacity of UiO-66@PET and UiO-66@cotton composites to toluene vapor is of 56 and 183 mg/g, respectively.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"186 ","pages":"Article 116330"},"PeriodicalIF":5.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146170051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The markedly enhanced elimination of tetracycline over a novel mesoporous AgVO3/BaTiO3 piezo-photocatalyst with S-scheme heterojunction and visible light-induced performance 具有s -图式异质结和可见光诱导性能的新型介孔AgVO3/BaTiO3压电光催化剂显著增强了四环素的消除
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2026-04-01 Epub Date: 2026-01-25 DOI: 10.1016/j.inoche.2026.116231
Hind Alshaikh , Tamer M. Khedr
{"title":"The markedly enhanced elimination of tetracycline over a novel mesoporous AgVO3/BaTiO3 piezo-photocatalyst with S-scheme heterojunction and visible light-induced performance","authors":"Hind Alshaikh ,&nbsp;Tamer M. Khedr","doi":"10.1016/j.inoche.2026.116231","DOIUrl":"10.1016/j.inoche.2026.116231","url":null,"abstract":"<div><div>The main challenge for decomposition and removing water contaminants using semiconductor-based photocatalysis is the efficient separation of charge carriers. In this research contribution, we rationally developed a dual piezoelectric-semiconducting heterostructure photocatalyst, composed of a mesoporous step-scheme (S-scheme) of AgVO<sub>3</sub>/BaTiO<sub>3</sub>, to synergistically promote charge carrier separation and kinetic rates for the highly efficient elimination of tetracycline by synergistic impacts under stirring and visible light exposure. The optical absorption examinations demonstrated that the AgVO<sub>3</sub>/BaTiO<sub>3</sub> composites unveiled outstanding abilities to absorb and utilize light energy in the region of the visible spectrum. Additionally, PL and photocurrent evaluations verified that the AgVO<sub>3</sub>/BaTiO<sub>3</sub> hybrids had the best capacities to spatially separate the charge carriers. The alteration in binding energy values within the AgVO<sub>3</sub>/BaTiO<sub>3</sub> compared to pure samples additionally endorsed the directional flow of electrons from BaTiO<sub>3</sub> to AgVO<sub>3</sub> whenever there was no illumination, which implied that charges move in response to the S-scheme model when subjected to irradiation. Responding to the decomposition evaluations, the piezo-photocatalytic capacity was substantially enhanced by the most appropriate concentration of AgVO<sub>3</sub> (15 wt%). This implies that sewage treatment might benefit from these heterostructures. After only 60 min of encountering visible illumination and stirring, tetracycline was entirely (100%) degraded over the 15 wt% AgVO<sub>3</sub>/BaTiO<sub>3</sub> hybrid. This proceeded at an overall degradation rate of 2.4872 μmol min<sup>−1</sup>, which was 39.2-fold more efficient than the degradation rate achieved by pure BaTiO<sub>3</sub> (0.0635 μmol min<sup>−1</sup>). Meanwhile, the 15 wt% AgVO<sub>3</sub>/BaTiO<sub>3</sub> hybrid showcased superb stability and durability, signifying that this heterostructure material might be utilized over and over and endure for an extended duration. The simultaneous impact of the stir-generated piezoelectric field and the interfacial electric field substantially enhanced the charges' spatial separation and directional flux of the charges, which efficiently degraded and eliminated tetracycline. The research presented here shares crucial understandings and perspectives concerning the feasible design of innovative heterostructures with superior piezo-photocatalytic functionality to sustainably alleviate water contamination issues.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"186 ","pages":"Article 116231"},"PeriodicalIF":5.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146074379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrothermal assisted in-situ growth of faceted titania on Ti3C2 surface: Exploration of photocatalytic mechanism for the removal of HAMLA-550 insecticide 水热辅助二氧化钛在Ti3C2表面原位生长:光催化去除HAMLA-550杀虫剂的机理探讨
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2026-04-01 Epub Date: 2026-01-23 DOI: 10.1016/j.inoche.2026.116204
C.P. Prathibha , Srinivas Mallapur , B.M. Rajesh , Sanjeev P. Maradur , Sakthivel Kandaiah , S. Girish Kumar
{"title":"Hydrothermal assisted in-situ growth of faceted titania on Ti3C2 surface: Exploration of photocatalytic mechanism for the removal of HAMLA-550 insecticide","authors":"C.P. Prathibha ,&nbsp;Srinivas Mallapur ,&nbsp;B.M. Rajesh ,&nbsp;Sanjeev P. Maradur ,&nbsp;Sakthivel Kandaiah ,&nbsp;S. Girish Kumar","doi":"10.1016/j.inoche.2026.116204","DOIUrl":"10.1016/j.inoche.2026.116204","url":null,"abstract":"<div><div>The synthesis of titania crystals from the conventional titanium precursors (alkoxides, halides) is a challenging task as the rapid hydrolysis leads to aggregates in the solution phase. In this context, Ti<sub>3</sub>C<sub>2</sub> MXene emerged as a versatile precursor owing to their inherent sheet-like structure and easy crystallization of TiO<sub>2</sub> from its surface under the moderate reaction conditions. The titania formation was evidenced for 16 h of hydrothermal reaction time, while the longer reaction time (30 <em>h</em>) showed the presence of TiO<sub>2</sub> with co-exposed (001) and (101) facets under the assistance of NaBF<sub>4</sub>. It was revealed that the Ti<sub>3</sub>C<sub>2</sub>/TiO<sub>2</sub> obtained at low reaction time (16 h) had an extremely negative surface charge density, which favoured the pollutant adsorption and degradation process. The electron paramagnetic spectroscopic studies indicated the presence of oxygen vacancies and Ti<sup>3+</sup> sites, which facilitated the spatial separation of electron-hole pairs. The formation of Schottky contact between the Ti<sub>3</sub>C<sub>2</sub> and TiO<sub>2</sub> was confirmed by computational analysis, which additionally contributed to the overall efficiency. The findings of the present work might open an avenue for the synthesis of co-exposed faceted crystals using MXenes substrate under the wet-chemical approaches.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"186 ","pages":"Article 116204"},"PeriodicalIF":5.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146074381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Precursor structure as ingredient controller in CdS/nitrogen-doped carbon composite syntheses and their effect on the catalytic degradation of RhB 前驱体结构作为CdS/氮掺杂碳复合材料合成中的成分控制及其对RhB催化降解的影响
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2026-04-01 Epub Date: 2026-01-27 DOI: 10.1016/j.inoche.2026.116239
Bo Zhao , Senlin Li , Haitao Liu , Xingyang Zhong , Qiaozhen Sun , Bingguang Zhang
{"title":"Precursor structure as ingredient controller in CdS/nitrogen-doped carbon composite syntheses and their effect on the catalytic degradation of RhB","authors":"Bo Zhao ,&nbsp;Senlin Li ,&nbsp;Haitao Liu ,&nbsp;Xingyang Zhong ,&nbsp;Qiaozhen Sun ,&nbsp;Bingguang Zhang","doi":"10.1016/j.inoche.2026.116239","DOIUrl":"10.1016/j.inoche.2026.116239","url":null,"abstract":"<div><div>The constitutes and performances of sinters are affected by many factors when using coordination polymers as precursors in photocatalytic degradation. However, the structural impact of coordination polymer is not involved. Herein, the cadmium compound, [Cd (sip)(dpa)(H<sub>2</sub>O)]<sub>n</sub> (Cd-SD), is carefully selected as a precursor because it contains the same elements as that of [Cd(Hsip)(HL<sub>1</sub>)(H<sub>2</sub>O)<sub>2</sub>·2(H<sub>2</sub>O)]<sub>n</sub> (Cd-CP), which we previously reported but displays different structure and elemental contents. Through in-situ carbonization, CdS/nitrogen doped carbon (CdS/NC-T) composite instead of CdS-CdO/NC-T was generated, and a lot of CdS nanostrips emerged at 600 °C. PXRD and TEM confirmed the formation of hexagonal wurzite CdS nanoparticles on nitrogen-doped carbonaceous scaffolds. The degradation efficiency of Rhodamine B (RhB) by the CdS/NC-600 composites under visible irradiation reached ca. 90% within 2 h. The trapping experiment manifested that the photogenerated h<sup>+</sup> and ·OH were crucial factors in RhB removal. The results implied that the elemental content of the precursor was a crucial factor to determine the photocatalytic performance of CdS/NC-T.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"186 ","pages":"Article 116239"},"PeriodicalIF":5.4,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146074459","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance supercapacitor electrode based on MoS2/porous carbon composite derived from waste Peanut oil cake 基于废花生油饼制备的二硫化钼/多孔碳复合材料的高性能超级电容器电极
IF 5.4 3区 化学
Inorganic Chemistry Communications Pub Date : 2026-04-01 Epub Date: 2026-01-29 DOI: 10.1016/j.inoche.2026.116243
T. Ratnaji , C. Justin Raj , John D. Rodney , L. John Kennedy , Byung Chul Kim
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