Uzma Majeed , Hala M. Abo-Dief , Mongi Amami , Abhinav Kumar , Ankit Dilipkumar Oza
{"title":"水热法制备新型Dy2MoO6/rGO纳米材料作为增强OER应用的潜在电催化剂","authors":"Uzma Majeed , Hala M. Abo-Dief , Mongi Amami , Abhinav Kumar , Ankit Dilipkumar Oza","doi":"10.1016/j.inoche.2025.115536","DOIUrl":null,"url":null,"abstract":"<div><div>Water electrocatalysis is excessively being investigated for energy production to address the energy issues resulting by excessive use of fossil fuels. Water electrolysis results production of oxygen and hydrogen by oxygen evolution reaction (OER) and hydrogen evolution reaction but it needs a good catalyst. The efforts are being made to develop electrocatalysts for OER which is limiting reaction of water oxidation owing to its sluggish reaction kinetics. In our study, a novel electrocatalyst Dy<sub>2</sub>MoO<sub>6</sub>/rGO composite was synthesized via simple hydrothermal method for OER efficiency. Different physical tests like SEM (scanning electron microscope), XRD (X ray diffraction), FTIR (Fourier transform infrared spectroscopy) and Raman confirmed the successful fabrication of materials. The Dy<sub>2</sub>MoO<sub>6</sub>/rGO showed versatile with reduced graphene oxide (rGO) sheets resulting in increased active sites and surface availability of nanocatalyst. The Dy<sub>2</sub>MoO<sub>6</sub>/rGO composite showed improved OER activity than pristine materials having overpotential (ղ) and Tafel related 233 mV, 35 mV/dec while Dy<sub>2</sub>MoO<sub>6</sub> has (287 mV, 50 mV/dec) and rGO has (321 mV, 70 mV/dec). The fabricated Dy<sub>2</sub>MoO<sub>6</sub>/rGO catalyst holds the stability over 30 h with minute decrease in current density. The exceptional physical and electrochemical features of Dy<sub>2</sub>MoO<sub>6</sub>/rGO make it a promising electrocatalyst for electrical and other related applications in future.</div></div>","PeriodicalId":13609,"journal":{"name":"Inorganic Chemistry Communications","volume":"182 ","pages":"Article 115536"},"PeriodicalIF":5.4000,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hydrothermal production of novel Dy2MoO6/rGO nanomaterial as potential electrocatalyst for enhanced OER application\",\"authors\":\"Uzma Majeed , Hala M. Abo-Dief , Mongi Amami , Abhinav Kumar , Ankit Dilipkumar Oza\",\"doi\":\"10.1016/j.inoche.2025.115536\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Water electrocatalysis is excessively being investigated for energy production to address the energy issues resulting by excessive use of fossil fuels. Water electrolysis results production of oxygen and hydrogen by oxygen evolution reaction (OER) and hydrogen evolution reaction but it needs a good catalyst. The efforts are being made to develop electrocatalysts for OER which is limiting reaction of water oxidation owing to its sluggish reaction kinetics. In our study, a novel electrocatalyst Dy<sub>2</sub>MoO<sub>6</sub>/rGO composite was synthesized via simple hydrothermal method for OER efficiency. Different physical tests like SEM (scanning electron microscope), XRD (X ray diffraction), FTIR (Fourier transform infrared spectroscopy) and Raman confirmed the successful fabrication of materials. The Dy<sub>2</sub>MoO<sub>6</sub>/rGO showed versatile with reduced graphene oxide (rGO) sheets resulting in increased active sites and surface availability of nanocatalyst. The Dy<sub>2</sub>MoO<sub>6</sub>/rGO composite showed improved OER activity than pristine materials having overpotential (ղ) and Tafel related 233 mV, 35 mV/dec while Dy<sub>2</sub>MoO<sub>6</sub> has (287 mV, 50 mV/dec) and rGO has (321 mV, 70 mV/dec). The fabricated Dy<sub>2</sub>MoO<sub>6</sub>/rGO catalyst holds the stability over 30 h with minute decrease in current density. The exceptional physical and electrochemical features of Dy<sub>2</sub>MoO<sub>6</sub>/rGO make it a promising electrocatalyst for electrical and other related applications in future.</div></div>\",\"PeriodicalId\":13609,\"journal\":{\"name\":\"Inorganic Chemistry Communications\",\"volume\":\"182 \",\"pages\":\"Article 115536\"},\"PeriodicalIF\":5.4000,\"publicationDate\":\"2025-09-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387700325016533\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387700325016533","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Hydrothermal production of novel Dy2MoO6/rGO nanomaterial as potential electrocatalyst for enhanced OER application
Water electrocatalysis is excessively being investigated for energy production to address the energy issues resulting by excessive use of fossil fuels. Water electrolysis results production of oxygen and hydrogen by oxygen evolution reaction (OER) and hydrogen evolution reaction but it needs a good catalyst. The efforts are being made to develop electrocatalysts for OER which is limiting reaction of water oxidation owing to its sluggish reaction kinetics. In our study, a novel electrocatalyst Dy2MoO6/rGO composite was synthesized via simple hydrothermal method for OER efficiency. Different physical tests like SEM (scanning electron microscope), XRD (X ray diffraction), FTIR (Fourier transform infrared spectroscopy) and Raman confirmed the successful fabrication of materials. The Dy2MoO6/rGO showed versatile with reduced graphene oxide (rGO) sheets resulting in increased active sites and surface availability of nanocatalyst. The Dy2MoO6/rGO composite showed improved OER activity than pristine materials having overpotential (ղ) and Tafel related 233 mV, 35 mV/dec while Dy2MoO6 has (287 mV, 50 mV/dec) and rGO has (321 mV, 70 mV/dec). The fabricated Dy2MoO6/rGO catalyst holds the stability over 30 h with minute decrease in current density. The exceptional physical and electrochemical features of Dy2MoO6/rGO make it a promising electrocatalyst for electrical and other related applications in future.
期刊介绍:
Launched in January 1998, Inorganic Chemistry Communications is an international journal dedicated to the rapid publication of short communications in the major areas of inorganic, organometallic and supramolecular chemistry. Topics include synthetic and reaction chemistry, kinetics and mechanisms of reactions, bioinorganic chemistry, photochemistry and the use of metal and organometallic compounds in stoichiometric and catalytic synthesis or organic compounds.