Batteries & Supercaps最新文献_第7页

Acoustic Particle Patterning Aided by Phase-inversion for Efficient Structuring of Low-Tortuosity Battery Electrodes 低弯曲度电池电极有效结构的相位反转辅助声粒子图

IF 4.7 4区材料科学

Batteries & Supercaps Pub Date : 2025-02-05 DOI: 10.1002/batt.202400745

Yifan Zhang, M Shahriar, Shan Hu

引用次数: 0

Electrolyte Strategies at Extreme Temperatures for Aqueous Zinc Batteries 水溶液锌电池极端温度下的电解质策略

IF 4.7 4区材料科学

Batteries & Supercaps Pub Date : 2025-02-01 DOI: 10.1002/batt.202400811

Xingtai Liu, Jia Yao, Chao Xia, Xiaofang Wang, Lin Lv, Jun Zhang, Houzhao Wan, Hao Wang

{"title":"Electrolyte Strategies at Extreme Temperatures for Aqueous Zinc Batteries","authors":"Xingtai Liu, Jia Yao, Chao Xia, Xiaofang Wang, Lin Lv, Jun Zhang, Houzhao Wan, Hao Wang","doi":"10.1002/batt.202400811","DOIUrl":"10.1002/batt.202400811","url":null,"abstract":"The state of aqueous zinc batteries at extreme temperature environment is an important parameter for their widespread application. However, low ionic conductivity and sluggish ionic diffusion at low temperature, and aggravated untoward reactions in the interface of electrode-electrolyte at high temperature, seriously limit the practical application of zinc-ion batteries. Currently, numerous zinc-ion batteries capable of operating within a broad temperature range have been proposed. Herein, the reason of the performance decline at extreme temperature is discussed from the perspective of thermodynamics and dynamics. Then, from the additives/co-solvents, high concentration salts, hydrogels and other aspects, the main strategies of electrolyte are introduced in detail. Finally, the possible directions to further improve the high and low temperature performance of zinc-ion batteries are proposed. It is hoped that this review will be helpful to the design and manufacture of wide temperature zinc-ion battery electrolyte and provide reference for the application of rechargeable zinc-ion battery in extreme environment.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 8","pages":""},"PeriodicalIF":4.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144810936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The Value Chain of Sustainable Dual Carbon Sodium Ion Capacitors 可持续发展双碳钠离子电容器的价值链

IF 4.7 4区材料科学

Batteries & Supercaps Pub Date : 2025-01-30 DOI: 10.1002/batt.202400807

Roman Mysyk, Daniel Carriazo, Damien Saurel, Maria Arnaiz, Olivier Crosnier, Thierry Brousse, Kangkang Ge, Pierre-Louis Taberna, Patrice Simon, Sander Ratso, Einar Karu, Alberto Varzi, Juan Pablo Badillo, Andrea Hainthaler, Akshaya Sidharthan, Andrea Balducci, Obinna Egwu Eleri, Amaia Saenz de Buruaga, Javier Olarte, Juan Dayron Lopez Cardona, Fatemeh Bahmei, Sebastian P. Bautista, Marcel Weil, Jon Ajuria

{"title":"The Value Chain of Sustainable Dual Carbon Sodium Ion Capacitors","authors":"Roman Mysyk, Daniel Carriazo, Damien Saurel, Maria Arnaiz, Olivier Crosnier, Thierry Brousse, Kangkang Ge, Pierre-Louis Taberna, Patrice Simon, Sander Ratso, Einar Karu, Alberto Varzi, Juan Pablo Badillo, Andrea Hainthaler, Akshaya Sidharthan, Andrea Balducci, Obinna Egwu Eleri, Amaia Saenz de Buruaga, Javier Olarte, Juan Dayron Lopez Cardona, Fatemeh Bahmei, Sebastian P. Bautista, Marcel Weil, Jon Ajuria","doi":"10.1002/batt.202400807","DOIUrl":"10.1002/batt.202400807","url":null,"abstract":"Now that fast action is needed to mitigate the effects of climate change, developing new technologies to reduce the worldwide carbon footprint is critical. Sodium ion capacitors can be a key enabler for widespread transport electrification or massive adoption of renewable technologies. However, a years-long journey needs to be made from the first proof-of-concept report to a degree of maturity for technology transfer to the market. To shorten this path, this work gathers all the stakeholders involved in the technical development of the sodium ion capacitor technology, covering the whole value chain from academics (TRL 1–3) and research centers (TRL3–5) to companies and end-users (TRL 6–9). A 360-degree perspective is given on how to focus the research and technology development of sodium ion capacitors, or related electrochemical energy storage technologies, from understanding underlying operation mechanisms to setting up end-user specifications and industrial requirements for materials and processes. This is done not only in terms of performance metrics, but mainly considering relevant practical parameters, i. e., processability, scalability, and cost, leading up to the final sustainability evaluation of the whole of the technology by Life Cycle Assessment (LCA) and Life Cycle Cost (LCC) analysis, which is of utmost importance for society and policymakers.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 8","pages":""},"PeriodicalIF":4.7,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400807","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144809266","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Saccharinate-Based Ionic Liquids and Lithium Battery Electrolytes 基于糖精的离子液体和锂电池电解质

IF 4.7 4区材料科学

Batteries & Supercaps Pub Date : 2025-01-29 DOI: 10.1002/batt.202400758

Mukhtiar Ahmed, Ashok Kushwaha, Andrei Filippov, Patrik Johansson, Faiz Ullah Shah

{"title":"Saccharinate-Based Ionic Liquids and Lithium Battery Electrolytes","authors":"Mukhtiar Ahmed, Ashok Kushwaha, Andrei Filippov, Patrik Johansson, Faiz Ullah Shah","doi":"10.1002/batt.202400758","DOIUrl":"10.1002/batt.202400758","url":null,"abstract":"Fluorine-free ionic liquids (ILs) and electrolytes based on ether-functionalized pyrrolidinium or imidazolinium cations coupled with a “greener”, non-basic, and hydrolytically stable saccharinate (Sac) anion, are herein presented with their thermal, transport and electrochemical properties. The thermal stability, glass transition temperature, and electrochemical stability of the imidazolinium based ILs surpasses the pyrrolidinium IL, while the latter offer better (ion) transport properties. Ether-functionalization of the IL cation improves the transport properties with negligible effects on the thermal and electrochemical stabilities. The Li+ conducting electrolytes – created by adding 10 mol % of lithium saccharinate (LiSac) to the neat (BMMIm)(Sac) and (C201MMIm)(Sac) ILs show an as low initial overpotential as ±0.05 V and outstanding Li stripping/plating performance over 100 hours at 60 °C for the latter, but a very large polarization interfacial resistance, 4730 Ω cm2, impeding the kinetics of stripping/plating, even at these elevated temperatures for the former. Hence the rather modest modification has an enormous impact in practice.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 8","pages":""},"PeriodicalIF":4.7,"publicationDate":"2025-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400758","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144809286","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tailoring the Composition of Ternary NiCoFe Layered Double Hydroxide with Graphitic Carbon Nitride as a Positive Electrode Material for High-Performance Hybrid Supercapacitors 以氮化石墨碳作为高性能混合超级电容器正极材料的三元NiCoFe层状双氢氧化物

IF 4.7 4区材料科学

Batteries & Supercaps Pub Date : 2025-01-27 DOI: 10.1002/batt.202400754

Elaiyappillai Elanthamilan, Sea-Fue Wang

{"title":"Tailoring the Composition of Ternary NiCoFe Layered Double Hydroxide with Graphitic Carbon Nitride as a Positive Electrode Material for High-Performance Hybrid Supercapacitors","authors":"Elaiyappillai Elanthamilan, Sea-Fue Wang","doi":"10.1002/batt.202400754","DOIUrl":"10.1002/batt.202400754","url":null,"abstract":"This work reports a simple hydrothermal-assisted method to prepare a high-performance nickel cobalt iron layered double hydroxide/graphitic carbon nitride (NiCoFe LDH/g-C3N4) composite for supercapacitor (SC) applications. Various spectral and analytical techniques were used to confirm the formation of NiCoFe LDH/g-C3N4 composite. The NiCoFe LDH/g-C3N4 composite demonstrates battery-like SC behavior in the three-electrode measurements. The NiCoFe LDH/g-C3N4 composite has a maximum specific capacity (366 C g−1 at 1 A g−1) compared to the individual NiCoFe LDH and g-C3N4 electrode materials. Further, the NiCoFe LDH/g-C3N4 composite electrode shows 89 % capacity retention even after 8000 galvanostatic charge-discharge (GCD) cycles at 6 A g−1. In addition, a hybrid supercapacitor (HSC) is fabricated by using NiCoFe LDH/g-C3N4 composite as a positive electrode and activated carbon (AC) as a negative electrode. The as-fabricated NiCoFe LDH/g-C3N4//AC HSC demonstrates an impressive energy density of 76.44 Wh kg−1 and a power density of 1279.9 W kg−1, along with excellent long-term cycle stability of 83 % capacity retention even after 6000 GCD cycles at 6 A g−1. Considering its simplicity of fabrication and exceptional energy storage capabilities, the as-fabricated NiCoFe LDH/g-C3N4//AC hybrid supercapacitor has significant promise for practical use in the near future.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 8","pages":""},"PeriodicalIF":4.7,"publicationDate":"2025-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144809308","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Progress and Challenges of Water-in-Salt Electrolytes: Exploring Physical Chemistry Properties and Solid Electrolyte Interphase Formation Mechanisms 盐包水电解质的进展与挑战：物理化学性质与固体电解质界面形成机制的探索

IF 4.7 4区材料科学

Batteries & Supercaps Pub Date : 2025-01-27 DOI: 10.1002/batt.202400722

Xuanze Wang, Rossukon Jommongkol, Jie Deng, Kexin Liu, Jiangfeng Qian, Yachao Zhu, Olivier Fontaine

引用次数: 0

Texturing (002)-Oriented Zinc Atop a Cotton Cloth for High-Performance Zn-Ion Batteries 在高性能锌离子电池的棉布上织构（002）取向锌

IF 4.7 4区材料科学

Batteries & Supercaps Pub Date : 2025-01-26 DOI: 10.1002/batt.202400727

Napat Kiatwisarnkij, Zehao Song, Chanin Tangpongkitjaroen, Suttipong Wannapaiboon, Xinyu Zhang, Panyawat Wangyao, Jiaqian Qin

{"title":"Texturing (002)-Oriented Zinc Atop a Cotton Cloth for High-Performance Zn-Ion Batteries","authors":"Napat Kiatwisarnkij, Zehao Song, Chanin Tangpongkitjaroen, Suttipong Wannapaiboon, Xinyu Zhang, Panyawat Wangyao, Jiaqian Qin","doi":"10.1002/batt.202400727","DOIUrl":"10.1002/batt.202400727","url":null,"abstract":"Zn-ion batteries emerge as a promising alternative to conventional Li-ion batteries due to their superior environmental friendliness and high safety, making them suitable for sustainable energy storage in various applications. However, concerns persist regarding the limitations of Zn-ion batteries, such as uncontrolled dendrite growth and side reactions. In this study, the electroplating method was employed to deposit (002) plane-dominated textures on a modified cotton cloth substrate, which consists of a silver conductive layer atop a cotton supporting layer. The electroplating current density and time are critical for the fabrication of dense and compact (002) Zn textures. The optimized condition for this process involves a current density of 40 mA/cm2 and an electroplating time of 30 minutes. Compared to (101)-dominated Zn anodes, the (002)-dominated electrode demonstrates faster deposition kinetics and lower charge transfer resistance, enabling denser and more uniform Zn deposition. Additionally, the (002)-dominated electrode also exhibits an enhanced ability to inhibit side reactions in the mild aqueous electrolyte, further improving the lifespan of Zn-ion batteries. This work demonstrates the feasibility of using ordinary cotton cloth as a substrate for electroplating (002)-dominated Zn, thereby expanding the potential applications of Zn-ion batteries.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 7","pages":""},"PeriodicalIF":4.7,"publicationDate":"2025-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144635652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Towards Scalable Production of Sodium-Ion Batteries: Solvent-Free Layered-Oxide Cathodes and Aqueous-Processed Hard Carbon Anodes for Cost-Effective Full-Cell Manufacturing 钠离子电池的规模化生产：无溶剂层状氧化物阴极和水处理硬碳阳极，用于成本效益高的全电池制造

IF 4.7 4区材料科学

Batteries & Supercaps Pub Date : 2025-01-25 DOI: 10.1002/batt.202400572

Johannes Kühn, Florian Schmidt, Pascal Seete, Tom Boenke, Florian S. Hoffmann, Arthur Dupuy, Benjamin Schumm, Thomas Abendroth, Holger Althues, Stefan Kaskel

{"title":"Towards Scalable Production of Sodium-Ion Batteries: Solvent-Free Layered-Oxide Cathodes and Aqueous-Processed Hard Carbon Anodes for Cost-Effective Full-Cell Manufacturing","authors":"Johannes Kühn, Florian Schmidt, Pascal Seete, Tom Boenke, Florian S. Hoffmann, Arthur Dupuy, Benjamin Schumm, Thomas Abendroth, Holger Althues, Stefan Kaskel","doi":"10.1002/batt.202400572","DOIUrl":"10.1002/batt.202400572","url":null,"abstract":"Achieving commercial viability for more sustainable sodium-ion batteries (SIB) necessitates reducing the environmental impact of production, particularly originating from electrode drying and the use of toxic solvents like N-methyl-2-pyrrolidone (NMP). This study presents the dry-processing of commercial P2-type Na0.75Ni0.25Fe0.25Mn0.50O2 (NFM) via the DRYtraec® process, aiming to lower the binder content of 1 wt.% polytetrafluoroethylene (PTFE) and eliminating the need for electrode drying and NMP recovery. Assessments of electrode morphology and active material crystallinity were conducted to gauge the effects of mechanical stress during processing. The resulting cathodes, loaded at a commercially relevant 2.3–2.7 mAh cm−2 loading, were successfully paired with aqueous-processed hard carbon (HC) anodes, demonstrating stable performance in full-cells. Comparative analysis with entirely wet-processed electrodes revealed comparable capacity accessibility and comparable long-term stability. This showed the competitiveness of dry-processed cathodes. Finally, the integration of NMP-free, dry-processed cathodes and aqueous-processed anodes was scaled to the commercially relevant prototype pouch-cell. The cell demonstrates stable cycling for 400 cycles with an energy density of 102 Wh kg−1 as well as reduced processing costs and environmental footprint.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 5","pages":""},"PeriodicalIF":4.7,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400572","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

New Non-Invasive Method to Monitor and Reverse Faradaic Imbalance in Redox Flow Batteries 无创监测和逆转氧化还原液流电池法拉第不平衡的新方法

IF 4.7 4区材料科学

Batteries & Supercaps Pub Date : 2025-01-25 DOI: 10.1002/batt.202400737

Miguel Cantera, Koray Cavusoglu, Lara Lubián, Rubén Rubio-Presa, Roberto Sanz, Virginia Ruiz, Jose María Cámara, Edgar Ventosa

{"title":"New Non-Invasive Method to Monitor and Reverse Faradaic Imbalance in Redox Flow Batteries","authors":"Miguel Cantera, Koray Cavusoglu, Lara Lubián, Rubén Rubio-Presa, Roberto Sanz, Virginia Ruiz, Jose María Cámara, Edgar Ventosa","doi":"10.1002/batt.202400737","DOIUrl":"10.1002/batt.202400737","url":null,"abstract":"Aqueous Organic Redox Flow Batteries (AORFBs) have received much attention due to the accessibility of their active materials. However, among the key performance indicators that require improvement for AORFBs to become competitive against mature technologies, lifespan is especially critical for stationary energy storage. Faradaic imbalance driven by the occurrence of irreversible electrochemical processes decreases lifespan, so monitoring and correction of this parameter is required to prolong lifespan. This work presents a novel, simple and non-invasive automatized method to monitor the Faradaic imbalance. This method is based on detecting the variation of the minimum derivative of the cell voltage upon cycling, and it is used as the activation criterion for a rebalancing device. The system is tested using an alkaline flow battery consisting of ferrocyanide and 2,6-dihydroxyanthraquinone (2,6-DHAQ), extending the cycle life of the battery to 400 cycles (235 h) without any capacity decay and without Ar-filled glovebox. This demonstrates the feasibility of the proposed system to monitor the state-of-health (SOH) due to Faradaic imbalance and recover the capacity loss.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 8","pages":""},"PeriodicalIF":4.7,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400737","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144809263","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Elliptical Silicon Nanowire Covered by the SEI in a 2D Chemo-Mechanical Simulation 椭圆硅纳米线覆盖的SEI在二维化学-机械模拟

IF 4.7 4区材料科学

Batteries & Supercaps Pub Date : 2025-01-24 DOI: 10.1002/batt.202400604

Raphael Schoof, Lukas Köbbing, Prof. Dr. Arnulf Latz, Prof. Dr. Birger Horstmann, Prof. Dr. Willy Dörfler

{"title":"Elliptical Silicon Nanowire Covered by the SEI in a 2D Chemo-Mechanical Simulation","authors":"Raphael Schoof, Lukas Köbbing, Prof. Dr. Arnulf Latz, Prof. Dr. Birger Horstmann, Prof. Dr. Willy Dörfler","doi":"10.1002/batt.202400604","DOIUrl":"10.1002/batt.202400604","url":null,"abstract":"Understanding the mechanical interplay between silicon anodes and their surrounding solid-electrolyte interphase (SEI) is essential to improve the next generation of lithium-ion batteries. We model and simulate a 2D elliptical silicon nanowire with SEI via a thermodynamically consistent chemo-mechanical continuum ansatz using a higher order finite element method in combination with a variable-step, variable-order time integration scheme. Considering a soft viscoplastic SEI for three half cycles, we see at the minor half-axis the largest stress magnitude at the silicon nanowire surface, leading to a concentration anomaly. This anomaly is caused by the shape of the nanowire itself and not by the SEI. Also for the tangential stress of the SEI, the largest stress magnitudes are at this point, which can lead to SEI fracture. However, for a stiff SEI, the largest stress magnitude inside the nanowire occurs at the major half-axis, causing a reduced concentration distribution in this area. The largest tangential stress of the SEI is still at the minor half-axis. In total, we demonstrate the importance of considering the mechanics of the anode and SEI in silicon anode simulations and encourage further numerical and model improvements.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 5","pages":""},"PeriodicalIF":4.7,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400604","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0