Batteries & Supercaps最新文献_第7页

Sputtered Zero-Excess Electrodes with Metallic Seed Layers for Solid-State Sodium Batteries 固体钠电池用金属种子层溅射零过量电极

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-10-25 DOI: 10.1002/batt.202400364

Ansgar Lowack, Paula Grun, Rafael Anton, Henry Auer, Kristian Nikolowski, Mareike Partsch, Mihails Kusnezoff, Alexander Michaelis

{"title":"Sputtered Zero-Excess Electrodes with Metallic Seed Layers for Solid-State Sodium Batteries","authors":"Ansgar Lowack, Paula Grun, Rafael Anton, Henry Auer, Kristian Nikolowski, Mareike Partsch, Mihails Kusnezoff, Alexander Michaelis","doi":"10.1002/batt.202400364","DOIUrl":"https://doi.org/10.1002/batt.202400364","url":null,"abstract":"Zero-excess sodium metal solid-state batteries offer improved safety, lower cost, higher energy density, and reduced resource dependency compared to today's lithium-ion technology. This study demonstrates the fabrication of zero-excess electrodes with unprecedented stability during plating/stripping cycles. The fabrication process involves the sputter deposition of 20 nm metallic seed layers – zinc, silver, indium, or tin – onto NASICON (Na3.4Zr2Si2.4P0.6O12) ceramic separators, followed by the sputter deposition of a 30 μm copper current collector. The favorable influence of these seed layers on the in-situ formation of the sodium|NASICON interface is examined through nucleation and cycling experiments, with a sodium metal reservoir serving as the non-limiting counter electrode. Due to alloy formation the seed layers – particularly tin – stabilize sodium nucleation and cycling substantially and reduce dendrite formation compared to reference cells with bare copper current collectors. Sodium loss during cycling is primarily attributed to local cracking of the current collector and its partial delamination from the NASICON. Compared to polished NASICON, a roughened surface reduces the resistance e. g. of the counter electrode 200-fold to approx. 1 Ωcm2 at 3 MPa and suppresses delamination further.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 5","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400364","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Solid-State Electrolytes for Lithium-Air Batteries 锂-空气电池用固态电解质

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-10-24 DOI: 10.1002/batt.202400625

Xianhai Qi, Dapeng Liu, Haohan Yu, Zerui Fu, Yu Zhang

引用次数: 0

Operando Investigation of Al Plating Regimes on HOPG in [EMImCl]:AlCl3 by Electrochemical Reflection Anisotropy Spectroscopy 电化学反射各向异性光谱法研究[EMImCl]:AlCl3中HOPG镀铝工艺

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-10-22 DOI: 10.1002/batt.202400610

Mario Löw, Matthias M. May

{"title":"Operando Investigation of Al Plating Regimes on HOPG in [EMImCl]:AlCl3 by Electrochemical Reflection Anisotropy Spectroscopy","authors":"Mario Löw, Matthias M. May","doi":"10.1002/batt.202400610","DOIUrl":"https://doi.org/10.1002/batt.202400610","url":null,"abstract":"Rechargeable aluminium batteries show promise as next-generation systems with a more abundant material base than lithium technology. However, the stable native oxide on top of aluminium metal electrodes leads to poor cell performance. Graphite, on the other hand, is a so far rarely investigated alternative that can be used as both the anode and cathode. Here, metallic aluminium is deposited at the anode, while AlCl4− is intercalated at the cathode. For both cases, understanding the electrode–electrolyte interface is crucial for improving the performance of the battery. In this work, we use reflection anisotropy spectroscopy to study the evolution of the interface under applied potentials. We find that the cathode exhibits an irreversible swelling of the topmost graphite layer due to AlCl4− intercalation as well as the formation of an SEI during the first voltammetry cycle. On the anode, the electrodeposition of aluminium is initially well-ordered. However, the evolution of the surface morphology depends on the applied potential, with island-like growth at less cathodic potentials, and layer-by-layer growth at more anodic potentials. With the optical operando spectroscopy, we can follow these qualitatively different plating and stripping regimes in a time-resolved manner.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 5","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400610","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144100746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nickel Hexacyanoferrate as Cathode for Sodium-Ion Batteries: Effects of the Synthesis Conditions on the Material Properties 钠离子电池正极用六氰高铁酸镍：合成条件对材料性能的影响

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-10-22 DOI: 10.1002/batt.202400300

Victoria Carnero-Roldán, Ángela Fernández-Merino, Adrián Licari, Giorgia Zampardi, Fabio la Mantia, Rafael Trócoli

{"title":"Nickel Hexacyanoferrate as Cathode for Sodium-Ion Batteries: Effects of the Synthesis Conditions on the Material Properties","authors":"Victoria Carnero-Roldán, Ángela Fernández-Merino, Adrián Licari, Giorgia Zampardi, Fabio la Mantia, Rafael Trócoli","doi":"10.1002/batt.202400300","DOIUrl":"https://doi.org/10.1002/batt.202400300","url":null,"abstract":"The increment in the energy demand and the limited availability of materials for manufacturing large-scale energy storage batteries based on Li-ion chemistry has increased the study of alternative technologies, including Na-ion batteries. The quest for superior electrochemical performances has led to the development new cathodes, such as Prussian blue and its analogs. Among the different members of this family of materials, KNi[Fe(CN)6] has attracted great attraction because of its low synthesis cost and excellent stability. Multiple synthesis approaches based on coprecipitation methods have been explored to optimize its capacity to intercalate sodium; however, the effects of the synthesis conditions on the structural and electrochemical properties of KNi[Fe(CN)6] remain vague. Therefore, in this work, we propose a detailed analysis of how the main synthesis parameters define the structural and electrochemical properties of KNi[Fe(CN)6].","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 1","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400300","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143118231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Alleviating Voltage Hysteresis by Interconnecting Truncated Octahedral LiNi0.5Mn1.5O4 Cathode Particles Using Exfoliated Graphene 利用剥离石墨烯互联截顶八面体 LiNi0.5Mn1.5O4 阴极颗粒以缓解电压滞后问题

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-10-20 DOI: 10.1002/batt.202400515

Putri Nadia Suryadi, Dr. Jotti Karunawan, Dr. Oktaviardi Bityasmawan Abdillah, Dr. Octia Floweri, Dr. Sigit Puji Santosa, Dr. Arie Wibowo, Prof. Ferry Iskandar

{"title":"Alleviating Voltage Hysteresis by Interconnecting Truncated Octahedral LiNi0.5Mn1.5O4 Cathode Particles Using Exfoliated Graphene","authors":"Putri Nadia Suryadi, Dr. Jotti Karunawan, Dr. Oktaviardi Bityasmawan Abdillah, Dr. Octia Floweri, Dr. Sigit Puji Santosa, Dr. Arie Wibowo, Prof. Ferry Iskandar","doi":"10.1002/batt.202400515","DOIUrl":"https://doi.org/10.1002/batt.202400515","url":null,"abstract":"High-voltage spinel LiNi0.5Mn1.5O4 (LNMO) has been highlighted as one of the most promising cathode materials for next-generation Li-ion batteries. However, its performance is known to have shortcomings, i. e., voltage hysteresis induced by the increasing impedance of LNMO during electrochemical cycling at high voltage operation. This paper demonstrates an innovative design of LNMO cathode materials to alleviate voltage hysteresis by combining unique characteristics of truncated octahedral LNMO with 2D exfoliated graphene (EG). The exposed (100) plane of truncated LNMO particles is known to have superior Li+ ion conduction. Meanwhile, the (111) plane is known to have excellent resistance to metal dissolution. Moreover, it was revealed that the presence of the EG framework as an interconnection aide could significantly improve the charge transfer process, helping to alleviate the voltage polarization. The sample with optimum LNMO-EG composition shows a stable electrochemical performance with a capacity retention of 86.56 % after 300 cycles of charge-discharge measurement at 1 C while exhibiting almost 3 times lower voltage hysteresis (0.233 mV/cycle) compared to the pristine LNMO (0.678 mV/cycle). This result demonstrates that combining the uniqueness of truncated LNMO and 2D EG can be a promising strategy to improve the electrochemical performance of LNMO cathode materials for next-generation batteries.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 4","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143826712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

3D Ternary Hybrid of VSe2/e-MXene/CNT with a Promising Energy Storage Performance for High Performance Asymmetric Supercapacitor VSe2/e-MXene/CNT 的三维三元混合体在高性能不对称超级电容器中具有可喜的储能性能

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-10-16 DOI: 10.1002/batt.202400466

Pavithra Siddu, Sree Raj K A, Sithara Radhakrishnan, Sang Mun Jeong, Chandra Sekhar Rout

{"title":"3D Ternary Hybrid of VSe2/e-MXene/CNT with a Promising Energy Storage Performance for High Performance Asymmetric Supercapacitor","authors":"Pavithra Siddu, Sree Raj K A, Sithara Radhakrishnan, Sang Mun Jeong, Chandra Sekhar Rout","doi":"10.1002/batt.202400466","DOIUrl":"https://doi.org/10.1002/batt.202400466","url":null,"abstract":"MXene and TMDs are two of the emerging electrode materials for supercapacitors owing to their unique physicochemical properties such as high conductivity, large surface area, and rich redox active sites. However, sheet restacking, volume expansion and oxidation hinder these materials from being used in practical applications. In this work, a 3D ternary hybrid structure of metallic VSe2, Ti3C2Tx MXene and carbon nanotube was designed to address some of the challenges in 2D materials-based electrodes for supercapacitor application. The exfoliated MXene and CNT decorated VSe2 3D structure showed excellent synergy between each component to deliver promising energy storage and cycling performance. The ternary hybrid structure also can suppress the surface oxidation of MXene sheets during the hydrothermal reaction. Furthermore, an asymmetric supercapacitor fabricated with VSe2/e-MXene/CNT and MoS2/MXene delivered the highest energy density of 35.91 Wh/kg at a power density of 1280 W/kg and a remarkable cycle life.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 1","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400466","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143115875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Covalent Organic Frameworks (COFs): A New Class of Materials for Multivalent Metal-Ion Energy Storage Systems 共价有机骨架（COFs）：一类用于多价金属离子储能系统的新材料

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-10-16 DOI: 10.1002/batt.202400537

Vedang A. Sonar, Abhishek A. Kulkarni, Prashant Sonar, Deepak P. Dubal

{"title":"Covalent Organic Frameworks (COFs): A New Class of Materials for Multivalent Metal-Ion Energy Storage Systems","authors":"Vedang A. Sonar, Abhishek A. Kulkarni, Prashant Sonar, Deepak P. Dubal","doi":"10.1002/batt.202400537","DOIUrl":"https://doi.org/10.1002/batt.202400537","url":null,"abstract":"The rise of electronic societies is driving a surge in the demand for energy storage solutions, particularly in the realm of renewable energy technologies like batteries, which rely heavily on efficient electrode materials and separators. As an answer to this necessity, Covalent Organic Frameworks (COFs) are emerging and a highly intriguing class of materials, garnering increased attention in recent years for their extensive properties and possible applications. This review addresses the remarkable versatility and boundless potential of COFs in scientific fields, mainly focusing on multivalent metal ion batteries (MMIBs), which include AIB (Aluminium-ion batteries), MIB (Magnesium-ion battery), CIB (Calcium-ion battery), and ZIB (Zinc-ion battery), as both electrode materials and separators across a spectrum of battery technology. Inclusive of their approaches, merits, and reaction mechanisms, this review offers an extensive summary of COFs concerning multivalent ion batteries. By providing a rigorous analysis of COF attributes, electrochemical behaviour, and methodologies, our explanation contributes to a deeper understanding of their potential in advancing battery technology.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 4","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143826704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrolyte-free cathode design for solid-state batteries demonstrated with bifunctional Li2VCl4 用双功能 Li2VCl4 演示固态电池的无电解质阴极设计

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-10-16 DOI: 10.1002/batt.202400520

Takuma Kasahara, Peng Song, Itaru Honma, Saneyuki Ohno

{"title":"Electrolyte-free cathode design for solid-state batteries demonstrated with bifunctional Li2VCl4","authors":"Takuma Kasahara, Peng Song, Itaru Honma, Saneyuki Ohno","doi":"10.1002/batt.202400520","DOIUrl":"https://doi.org/10.1002/batt.202400520","url":null,"abstract":"All-solid-state batteries have attracted much attention because of the expected high energy density and inherent safety stemming from their nonflammable property. While improving the energy density of the cathode poses a significant challenge, here we introduce a novel battery design strategy to enhance energy density by employing bifunctional cathode material, allowing the weight ratio of the active material to be increased without using an electrolyte for the cathode. By employing lithium-containing vanadium halide Li2VCl4, serving as both active material and electrolyte, the all-solid-state battery cell with no electrolyte for the cathode with a capacity approaching the theoretical limit is demonstrated. In addition, we present a guideline for improving capacity retention from the perspective of interfacial stability. Notably, thermodynamic analysis revealed interfacial instability between Li2VCl4 and sulfide material. A double-layer separator, incorporating halide materials for the cathode side, was implemented to enhance the interfacial stability and mitigate the capacity degradation. Furthermore, it was found that the rate capability depends on the lithium content in synthesized Li2-xVCl4 and does not change with the state of charge significantly. This study will contribute to designing the bifunctional cathode material for an all-solid-state battery and describe its unique properties.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 3","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/batt.202400520","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632892","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synergistic Dual Electrolyte System of LATP and In- Situ Solod-State PDOL System and its Improvement on the Performance of NCM811 Batteries LATP和原位PDOL双电解质协同体系及其对NCM811电池性能的改善

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-10-15 DOI: 10.1002/batt.202400463

Jian-Hua Cao, Peng Zhang, Ya-kun Wang, Da-Yong Wu

{"title":"Synergistic Dual Electrolyte System of LATP and In- Situ Solod-State PDOL System and its Improvement on the Performance of NCM811 Batteries","authors":"Jian-Hua Cao, Peng Zhang, Ya-kun Wang, Da-Yong Wu","doi":"10.1002/batt.202400463","DOIUrl":"https://doi.org/10.1002/batt.202400463","url":null,"abstract":"1,3-Dioxolane (DOL) can undergo in-situ polymerization in batteries to form solid-state organic electrolyte PDOL. When applied to NCM811||Li battery system, PDOL electrolyte helps optimize the contact and interface stability between electrolyte and electrodes. This study explores the effects of PDOL with PE separators coated with Li1.3Al0.3Ti1.7(PO4)3(LATP) on the performance of NCM811||Li batteries. 2,2,2-trifluoroethyl phosphite (DETFPi), was mixed with DOL at a 1 : 35 mass ratio. Then, LiBF4 was used to initiate in-situ polymerization and thereby obtained DETFPi-PDOL electrolyte after 24 h at room temperature. The composite electrolyte exhibits enhanced ion conductivity (1.59×10−4 S cm−1), high lithium ion transference number (0.78), wide electrochemical stability window (4.53 V), and high critical current density (2.2 mA cm−2). Li||PDOL@LATP||Li battery shows extremely low overpotential (35 mV) after a constant current stable cycle of 500 h at 1.0 mA cm−2. After 500 cycles at 1 C, the remaining capacity is 153.9 mAh g−1 with a capacity retention of 82.1 % in NCM811||PDOL@LATP||Li batteries. This indicates that the LATP coating on the surface of the PE separator plays an important role in optimizing the performance of DETFPI-PDOL electrolyte batteries. LATP and DETFPI-PDOL are effective in improving the cycling stability, rate performance, and interface state of NCM811 batteries.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"8 3","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Flexible Micro-Supercapacitors with Enhanced Energy Density Utilizing Flash Lamp Annealed Graphene-Carbon Nanotube Composite Electrodes 利用闪光灯退火石墨烯-碳纳米管复合电极提高能量密度的柔性微型超级电容器

IF 5.1 4区材料科学

Batteries & Supercaps Pub Date : 2024-10-14 DOI: 10.1002/batt.202400557

Yusik Myung, TaeYoung Kim

{"title":"Flexible Micro-Supercapacitors with Enhanced Energy Density Utilizing Flash Lamp Annealed Graphene-Carbon Nanotube Composite Electrodes","authors":"Yusik Myung, TaeYoung Kim","doi":"10.1002/batt.202400557","DOIUrl":"https://doi.org/10.1002/batt.202400557","url":null,"abstract":"As demand for micro-power sources grows, micro-supercapacitors (MSCs) have become critical for miniaturized devices, offering robust electrochemical energy storage. However, the challenge remains to develop a simple, scalable fabrication method that achieves both high energy and power densities. In this study, we present a refined approach to fabricating MSCs with 3D interconnected graphene/carbon nanotube (CNT) composite electrodes. Our method combines flash lamp annealing (FLA) and laser ablation, where FLA converts graphene oxide (GO) and CNT composite films into 3D-structured graphene/CNT electrodes, and laser ablation precisely patterns them into interdigitated designs. This dual-process technique produces MSCs with exceptional electrochemical performance, including an impressive areal capacitance of 26.11 mF/cm2 and a volumetric capacitance of 31.88 F/cm3. These devices also achieve energy densities of 3.72 μWh/cm2 and 4.43 mWh/cm3, maintaining 97 % of their initial capacitance under extreme bending, demonstrating outstanding mechanical flexibility and durability. Furthermore, the scalability of this method was validated by configuring MSCs in series and parallel, achieving enhanced voltage and current outputs without additional interconnections. Overall, the integration of FLA and laser ablation holds significant promise for advancing the performance and scalability of micro-sized energy storage devices, addressing the growing need for efficient, flexible, and high-capacity micro-power sources.","PeriodicalId":132,"journal":{"name":"Batteries & Supercaps","volume":"7 12","pages":""},"PeriodicalIF":5.1,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142861161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0