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Selective metasomatism of ultramafic cumulates within Archean supracrustal sequences 奥陶纪超基性岩序列中超基性岩积块的选择性变质作用
IF 8.9 1区 地球科学
Geoscience frontiers Pub Date : 2024-05-08 DOI: 10.1016/j.gsf.2024.101851
Lingyu Zhang , Sampriti Basak , David Zakharov , Kristoffer Szilas
{"title":"Selective metasomatism of ultramafic cumulates within Archean supracrustal sequences","authors":"Lingyu Zhang ,&nbsp;Sampriti Basak ,&nbsp;David Zakharov ,&nbsp;Kristoffer Szilas","doi":"10.1016/j.gsf.2024.101851","DOIUrl":"https://doi.org/10.1016/j.gsf.2024.101851","url":null,"abstract":"<div><p>The Neoarchean Storø Supracrustal Belt in SW Greenland comprises a sequence of mature quartzite, metapelite, amphibolite, and ultramafic rocks that underwent amphibolite facies metamorphism during the amalgamation of the Mesoarchean Akia Terrane and the Eoarchean Færingehavn Terrane. In this belt, tourmaline is found in a transition zone between ultramafic and metapelitic rocks, but also occurs as orbicules within the ultramafic rocks. These tourmaline orbicules hosted by ultramafic rocks are reported for the first time in the North Atlantic craton, thus indicating a unique formation mechanism. We conducted a comprehensive examination of the petrology, whole-rock and mineral chemistry, and oxygen isotope compositions from borehole samples in the Storø Supracrustal Belt, to elucidate the metasomatic events associated with the formation of the orbicular tourmalines. The Storø ultramafic rocks have high MgO, Cr, and Ni contents, with low abundances of REE and HFSE, and preserve a typical cumulate texture. These features are similar to those of ultramafic cumulates found in other Archean supracrustal belts, suggesting a cumulate origin for the Storø ultramafic rocks. Furthermore, the morphology and composition of the tourmaline orbicules within these cumulates indicate that they originated from melts with high boron and high water concentrations that infiltrated the ultramafic rocks. The main factor influencing the morphology of the tourmaline orbicules is the silicification of the ultramafic rocks, driven by their lower chemical potential of SiO<sub>2</sub> compared to the surrounding rocks. This silicification process, in combination with compositional variations of cumulates during fractional crystallization, has contributed to the geochemical diversity observed in Archean ultramafic rocks. Thus, it is crucial to understand the effects of such selective metasomatism on Archean ultramafic rocks, as this will facilitate the extraction of original information preserved in the early rock record.</p></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"15 5","pages":"Article 101851"},"PeriodicalIF":8.9,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674987124000756/pdfft?md5=708f427e3aed73c7e6515b115e315ba1&pid=1-s2.0-S1674987124000756-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140947160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Jacques Touret (1936–2024) 雅克-图雷(1936-2024)
IF 8.5 1区 地球科学
Geoscience frontiers Pub Date : 2024-05-06 DOI: 10.1016/j.gsf.2024.101845
Maria Luce Frezzotti, Daniel Harlov, Jan Marten Huizenga, Alfons van den Kerkhof
{"title":"Jacques Touret (1936–2024)","authors":"Maria Luce Frezzotti,&nbsp;Daniel Harlov,&nbsp;Jan Marten Huizenga,&nbsp;Alfons van den Kerkhof","doi":"10.1016/j.gsf.2024.101845","DOIUrl":"10.1016/j.gsf.2024.101845","url":null,"abstract":"","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"15 4","pages":"Article 101845"},"PeriodicalIF":8.5,"publicationDate":"2024-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674987124000690/pdfft?md5=de86e7b1855276bdf04b6f9db3dc625e&pid=1-s2.0-S1674987124000690-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141047305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Late Neoproterozoic to early Cambrian high-grade metamorphism from Mikir Hills (Assam-Meghalaya gneissic Complex, northeast India): Implications for eastern Gondwana assembly 印度东北部 Mikir 山(阿萨姆-梅加拉亚片麻岩复合体)新元古代晚期至寒武纪早期的高品位变质作用:冈瓦纳东部组装的影响
IF 8.9 1区 地球科学
Geoscience frontiers Pub Date : 2024-05-06 DOI: 10.1016/j.gsf.2024.101850
Rahul Nag , H. Hrushikesh , Nathan Cogné , N. Prabhakar
{"title":"Late Neoproterozoic to early Cambrian high-grade metamorphism from Mikir Hills (Assam-Meghalaya gneissic Complex, northeast India): Implications for eastern Gondwana assembly","authors":"Rahul Nag ,&nbsp;H. Hrushikesh ,&nbsp;Nathan Cogné ,&nbsp;N. Prabhakar","doi":"10.1016/j.gsf.2024.101850","DOIUrl":"10.1016/j.gsf.2024.101850","url":null,"abstract":"&lt;div&gt;&lt;p&gt;Mikir Hills region, which represents the eastern segment of the Assam-Meghalaya Gneissic Complex (AMGC) in northeast India, constitutes part of the Eastern Gondwana. The Mikir Hills preserves multiple metamorphic and magmatic events ranging from Early Mesoproterozoic to Early Cambrian. Out of these events, documenting the late Neoproterozoic to early Cambrian tectonothermal events is helpful in correlating the continental blocks of Eastern Gondwana. We present an integrated study involving field relations, petrology, &lt;em&gt;P–T&lt;/em&gt; history and zircon-monazite geochronology of hitherto poorly studied pelitic and quartzo-feldspathic gneisses from the Mikir Hills region. These gneisses have experienced at least three deformation events (D&lt;sub&gt;1&lt;/sub&gt;, D&lt;sub&gt;2&lt;/sub&gt; and D&lt;sub&gt;3&lt;/sub&gt;) with dominant foliation indicated by ENE–WSW striking and shallow-moderately dipping (&lt;40°) S&lt;sub&gt;2&lt;/sub&gt; gneissic foliation. The peak metamorphism in pelitic and quartzo-feldspathic gneisses is characterized by garnet(core)–K-feldspar–sillimanite–plagioclase–biotite–rutile–quartz–ilmenite–melt and garnet–plagioclase–K-feldspar–biotite–quartz–ilmenite–melt assemblages, respectively. The application of thermobarometric methods constrains the peak &lt;em&gt;P–T&lt;/em&gt; conditions of 7.5–8.4 kbar at 674–778 °C and 6.7–7.4 kbar at 601–618 °C for pelitic and quartzo-feldspathic gneisses, respectively. These results are consistent with the values estimated using phase equilibria modelling and melt reintegration approach. The results of pseudosection modelling suggests a clockwise&lt;!--&gt; &lt;em&gt;P–T&lt;/em&gt; &lt;!--&gt;path for pelitic gneisses involving migmatisation during peak metamorphism followed by near isothermal decompression from 8.0 to 8.6 kbar at 768–780 °C to 4.0–5.0 kbar at 720–765 °C. In contrast, quartzo-feldspathic gneisses preserved slightly lower peak &lt;em&gt;P–T&lt;/em&gt; conditions at 3.8–4.6 kbar and 590–650 °C. The U–Pb zircon dating of migmatised pelitic and quartzo-feldspathic gneisses yielded concordant ages of&lt;!--&gt; &lt;!--&gt;1647 ± 11 Ma and 1590 ± 7 Ma, respectively. These dates represent the inherited igneous protolith components, possibly equivalent to the Mesoproterozoic granulite facies metamorphism in the western AMGC. The rarely preserved cores of monazite in pelitic gneisses yielded an older population of&lt;!--&gt; &lt;!--&gt;1058 ± 35 Ma, most likely representing a weak tectonic imprint associated with the amalgamation of India with Western Australia and East Antarctica in the Rodinia assembly. However, the majority of monazite grains in pelitic and quartzo-feldspathic gneisses show high Th/U ratios with ages between 496 ± 7 Ma and 467 ± 16 Ma, indicating the timing of migmatisation that is contemporary with voluminous ∼ 500 Ma granite magmatism in and around the Mikir Hills. The similarities in&lt;!--&gt; &lt;em&gt;P–T–t&lt;/em&gt; &lt;!--&gt;histories&lt;!--&gt; &lt;!--&gt;estimated in this study (eastern AMGC) and those obtained from the Sonapahar-Umpretha region (central AMGC) confirm that these domains experience","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"15 5","pages":"Article 101850"},"PeriodicalIF":8.9,"publicationDate":"2024-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674987124000744/pdfft?md5=8ba8166c0cc87ac8005f3136423509ad&pid=1-s2.0-S1674987124000744-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141049620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of source facies and maturity on individual carbon isotopic compositions of oil 源面和成熟度对石油单个碳同位素组成的影响
IF 8.9 1区 地球科学
Geoscience frontiers Pub Date : 2024-04-18 DOI: 10.1016/j.gsf.2024.101846
Jingkun Zhang , Jian Cao , Baoli Xiang
{"title":"Effects of source facies and maturity on individual carbon isotopic compositions of oil","authors":"Jingkun Zhang ,&nbsp;Jian Cao ,&nbsp;Baoli Xiang","doi":"10.1016/j.gsf.2024.101846","DOIUrl":"https://doi.org/10.1016/j.gsf.2024.101846","url":null,"abstract":"<div><p>Carbon isotopes have been used extensively in tracing the sources of oil. However, primary source facies and secondary alteration controls on oil isotopic compositions have not been well resolved, resulting in application uncertainties. A case study was undertaken for an alkaline lacustrine oil system in a lower Permian formation in the Junggar Basin, NW China. Results indicate that increasing maturity causes the carbon isotopic composition to become heavier for only short–middle-chain compounds, whereas source facies-related carbon assimilation controls the compositions of short-, middle-, and long-chain compounds. In particular, light-carbon assimilation during organic-matter degradation makes the isotopic composition lighter, whereas heavy carbon from the water mass makes it heavier. Accordingly, oils in this study area were divided into Type U and Type N oils based on individual compound carbon isotopic compositions, reflecting the difference in source facies in a highly saline and reducing stratified water environment. The results provide a better understanding of the controls on carbon isotopes in oil in sedimentary basins, reducing the uncertainty in oil–source correlation and addressing the origin of oil.</p></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"15 5","pages":"Article 101846"},"PeriodicalIF":8.9,"publicationDate":"2024-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674987124000707/pdfft?md5=8a6cb3047931084f85d83bbcea79700f&pid=1-s2.0-S1674987124000707-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140641449","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Understanding arsenic behavior in alluvial aquifers: Evidence from sediment geochemistry, solute chemistry and environmental isotopes 了解冲积含水层中砷的行为:沉积物地球化学、溶质化学和环境同位素提供的证据
IF 8.9 1区 地球科学
Geoscience frontiers Pub Date : 2024-04-18 DOI: 10.1016/j.gsf.2024.101844
Shailesh Kumar Yadav , AL. Ramanathan , Chidambaram Sabarathinam , Alok Kumar , Manoj Kumar , Anshula Dhiman
{"title":"Understanding arsenic behavior in alluvial aquifers: Evidence from sediment geochemistry, solute chemistry and environmental isotopes","authors":"Shailesh Kumar Yadav ,&nbsp;AL. Ramanathan ,&nbsp;Chidambaram Sabarathinam ,&nbsp;Alok Kumar ,&nbsp;Manoj Kumar ,&nbsp;Anshula Dhiman","doi":"10.1016/j.gsf.2024.101844","DOIUrl":"https://doi.org/10.1016/j.gsf.2024.101844","url":null,"abstract":"<div><p>The hydro-geochemistry and isotopic variations in groundwater, coupled with sediment geochemistry, were investigated in the Middle Gangetic Plain, India, to better understand the aquifer dynamics that influence the arsenic (As) evolution and mobilization. Eighty-four groundwater samples, thirteen River water samples, and two sediment cores (33 mbgl) were studied. The samples were analyzed for major ions and trace metals, including As and stable isotopic variability (<em>δ</em><sup>2</sup>H, <em>δ</em><sup>18</sup>O, and <em>δ</em><sup>13</sup>C). The study area was categorized into older and younger alluvium based on existing geomorphological differences. Younger alluvium exhibits higher As enrichment in sediment and groundwater, ranging of 2.59–31.52 mg/kg and bdl to 0.62 mg/L. Groundwater samples were thermodynamically more stable with As(OH)<sub>3</sub> species ranging from 88.5% to 91.4% and FeOOH from 69% to 81%, respectively. PHREEQC and mineralogical analysis suggested goethite and siderite act as a source and sink for As. However, statistical analysis suggested reductive dissolution as the primary mechanism for As mobilization in the study area. Spatio-temporal analysis revealed elevated concentrations of As in the central and northeastern regions of the study area. Stable isotope (<em>δ</em><sup>2</sup>H and <em>δ</em><sup>18</sup>O) analysis inferred active recharge conditions primarily driven by precipitation. The depleted <em>d-excess</em> value and enriched <em>δ</em><sup>18</sup>O in the groundwater of younger alluvium indicate the effect of groundwater recharge with significant evaporation enrichment. Groundwater recharge potentially decreased the quantity of arsenic in groundwater, whereas evaporation enrichment increased it. Rainwater infiltration during recharge introduces oxygenated water into the aquifer, leading to changes in the redox conditions and facilitating biogeochemical reactions. The carbon isotope (<em>δ</em><sup>13</sup>C) results suggest that high microbial activity in younger alluvium promotes As leaching from sediment into the groundwater.</p></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"15 5","pages":"Article 101844"},"PeriodicalIF":8.9,"publicationDate":"2024-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674987124000689/pdfft?md5=313da3760666937497f0a1b0e1ce8f83&pid=1-s2.0-S1674987124000689-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140647720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative analysis of CO2 emissions and economic performance in the United States and China: Navigating sustainable development in the climate change era 美国和中国二氧化碳排放与经济表现的比较分析:气候变化时代的可持续发展之路
IF 8.9 1区 地球科学
Geoscience frontiers Pub Date : 2024-04-16 DOI: 10.1016/j.gsf.2024.101843
Khalid Mehmood , Syed Tauseef Hassan , Xuchun Qiu , Shahid Ali
{"title":"Comparative analysis of CO2 emissions and economic performance in the United States and China: Navigating sustainable development in the climate change era","authors":"Khalid Mehmood ,&nbsp;Syed Tauseef Hassan ,&nbsp;Xuchun Qiu ,&nbsp;Shahid Ali","doi":"10.1016/j.gsf.2024.101843","DOIUrl":"10.1016/j.gsf.2024.101843","url":null,"abstract":"<div><p>Economic growth has brought a global climate change into the spotlight, and CO<sub>2</sub> emissions demonstrate significant challenges in reducing environmental shifts worldwide. Globally, the United States and China contribute the largest amount of CO<sub>2</sub> emissions. The purpose of this study is to examine the relationship between different types of CO<sub>2</sub> emissions and economic growth by using a modeling approach. We analyze total CO<sub>2</sub> emissions, coal CO<sub>2</sub> emissions, oil CO<sub>2</sub> emissions, the global share of coal CO<sub>2</sub> emissions, the global share of oil CO<sub>2</sub> emissions, and economic growth. This study provides unique insights into how to simultaneously reduce CO<sub>2</sub> emissions and sustain economic growth. A bootstrap autoregressive distributed lag (BARDL) simulation method is utilized to examine the long- and short-run effects of predictors on CO<sub>2</sub> emissions. Coal CO<sub>2</sub> emissions are found to have a significant positive effect on economic growth in the short run but a negative impact on economic growth over the long run in the United States. The United States needs to implement stronger measures to balance coal CO<sub>2</sub> emissions with economic growth for sustainable development. In contrast, oil CO<sub>2</sub> emissions have positive effect for China in both the long run and short run. Thus, China can continue to reduce CO<sub>2</sub> emissions from oil while maintaining positive economic growth. The China's policies promoting cleaner energy alternatives can be adapted and implemented to maintain a balance between economic growth and carbon reduction. The study has valuable insights for policymakers seeking to balance economic growth with carbon reduction strategies. It emphasizes the need to better understand the complex relationship between CO<sub>2</sub> emissions and economic growth.</p></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"15 5","pages":"Article 101843"},"PeriodicalIF":8.9,"publicationDate":"2024-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674987124000677/pdfft?md5=375d3671e5992d273be70b0376c60d5e&pid=1-s2.0-S1674987124000677-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140762494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The resource-based Kuznets curve hypothesis: An empirical exploration 基于资源的库兹涅茨曲线假说:实证探索
IF 8.9 1区 地球科学
Geoscience frontiers Pub Date : 2024-04-16 DOI: 10.1016/j.gsf.2024.101841
Mehmet Akif Destek , Tanaya Saha , Gamze Destek , Avik Sinha
{"title":"The resource-based Kuznets curve hypothesis: An empirical exploration","authors":"Mehmet Akif Destek ,&nbsp;Tanaya Saha ,&nbsp;Gamze Destek ,&nbsp;Avik Sinha","doi":"10.1016/j.gsf.2024.101841","DOIUrl":"https://doi.org/10.1016/j.gsf.2024.101841","url":null,"abstract":"<div><p>Countries face the risk of natural resource curse because of making their economic growth excessively dependent on natural resources. Although excessive resource dependence causes such a risk, it is inevitable that resource-rich countries will need resource rent up to a certain level of economic maturity. On the other hand, transferring the wealth achieved after this maturity level to productive investment areas also reduces the resource dependency levels of countries. In this context, countries that capture the possible inverted U-shaped relationship between economic growth and resource dependence can escape the curse. Based on this, the aim of this research is to determine the validity of the Kuznets type relationship between resource dependence and economic growth for the first time in the literature. Nine nations that rely heavily on natural resources are used as a sample for this. The countries with a share of total resource rent in national revenue greater than 25% are taken into consideration throughout the selection process for these countries. Using novel panel data methodologies, the effects of capital accumulation, public spending, foreign direct investment, and economic growth on the dependence on natural resources is examined from 1993 to 2021. The results reveal that capital accumulation reduces resource dependency while foreign investments and government size increases it. In addition, the Resource-Based Kuznets curve concept is supported by empirical data demonstrating an inverted-U-shaped relationship between economic growth and resource dependence for these nations. The thresholds derived from the parameters show that Saudi Arabia and Kazakhstan are well beyond this cutoff. The Democratic Republic of the Congo and the Republic of the Congo, on the other hand, remain a long way from this threshold. Furthermore, Iraq, Mongolia, Iran, and Azerbaijan have national incomes that are close at the threshold.</p></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"15 5","pages":"Article 101841"},"PeriodicalIF":8.9,"publicationDate":"2024-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674987124000653/pdfft?md5=3f16f9164143867c3eed00c353ca4ac2&pid=1-s2.0-S1674987124000653-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140620939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical weathering processes in the Chinese Loess Plateau 中国黄土高原的化学风化过程
IF 8.9 1区 地球科学
Geoscience frontiers Pub Date : 2024-04-16 DOI: 10.1016/j.gsf.2024.101842
Ningpan Chai , Zhiqi Zhao , Xiaoke Li , Jun Xiao , Zhangdong Jin
{"title":"Chemical weathering processes in the Chinese Loess Plateau","authors":"Ningpan Chai ,&nbsp;Zhiqi Zhao ,&nbsp;Xiaoke Li ,&nbsp;Jun Xiao ,&nbsp;Zhangdong Jin","doi":"10.1016/j.gsf.2024.101842","DOIUrl":"https://doi.org/10.1016/j.gsf.2024.101842","url":null,"abstract":"<div><p>Covered by erodible loess and affected by significant seasonal climate variations, chemical weathering in the Chinese Loess Plateau (abbreviated as CLP) has important effects on the hydrochemistry of the Yellow River and the global carbon cycle. However, chemical weathering processes in the CLP are still unclear. Based on 296 river water samples in the CLP in the different seasons, hydrochemistry, weathering processes, and their controlling factors were revealed. River waters in the CLP exhibited slightly alkalinity (pH = 8.4 ± 0.5) with much high total dissolved solids (TDS) values (691 ± 813 mg/L). The water types of river water in the CLP were primarily SO<sub>4</sub><sup>2−</sup> − Cl<sup>−</sup> − Na<sup>+</sup>, HCO<sub>3</sub><sup>−</sup> − Ca<sup>2+</sup> − Mg<sup>2+</sup>, and SO<sub>4</sub><sup>2−</sup> − Cl<sup>−</sup> − Ca<sup>2+</sup> − Mg<sup>2+</sup>. According to the forward model, evaporite dissolution has the largest contribution (55.1% ± 0.2%) to riverine solutes in the CLP, then followed by carbonate weathering (35.6% ± 0.2%) and silicate weathering (6.5% ± 0.1%). For spatio-temporal variations, the contribution of evaporite dissolution in the CLP decreased from northwest to southeast with higher proportion in the dry season, carbonate weathering increased from northwest to southeast with a higher proportion in the wet season, and silicate weathering showed minor spatio-temporal variations. Ca<sup>2+</sup> and Mg<sup>2+</sup> were affected by carbonate precipitation and/or incongruent calcite dissolution, and about 50% of samples exhibited cation exchange reactions. The physical erosion rate in the CLP, which was 372 ± 293 t·km<sup>−2</sup>·yr<sup>−1</sup>, varied greatly and was greater than those of other worldwide rivers. Chemical weathering rates in the CLP showed an increasing trend southward. During the wet season, high runoff led to the release of evaporite and carbonate from loess, while the interfacial reaction kinetic limited the increase of the silicate weathering rates. The CO<sub>2</sub> consumption budget by carbonate weathering (6.1 × 10<sup>10</sup> mol/yr) and silicate weathering (1.6 × 10<sup>10</sup> mol/yr) in the CLP accounted for 0.29% and 0.08% of the global carbon cycle, respectively. Meanwhile, the weathering proportion by sulfuric acids was relatively high with a CO<sub>2</sub> release flux of 6.5 × 10<sup>9</sup> mol/yr. By compiling the data, we propose that the interfacial reaction kinetic and runoff control CO<sub>2</sub> consumption rate by silicate and carbonate weathering, respectively. These results contribute to the understanding of modern weathering processes of loess in the CLP, thus helping to deduce the environmental and climatic evolution of the basin.</p></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"15 5","pages":"Article 101842"},"PeriodicalIF":8.9,"publicationDate":"2024-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674987124000665/pdfft?md5=e2ed678a0e63c3d70c066dacca97ec71&pid=1-s2.0-S1674987124000665-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140646532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Middle Paleozoic metamorphic and sedimentary events in the central Korean Peninsula and their geological implications 朝鲜半岛中部中古生代变质和沉积事件及其地质影响
IF 8.9 1区 地球科学
Geoscience frontiers Pub Date : 2024-04-13 DOI: 10.1016/j.gsf.2024.101840
Byung Choon Lee , Sung Won Kim , Bo Young Lee , Chang Whan Oh , Deung-Lyong Cho , Weon-Seo Kee
{"title":"Middle Paleozoic metamorphic and sedimentary events in the central Korean Peninsula and their geological implications","authors":"Byung Choon Lee ,&nbsp;Sung Won Kim ,&nbsp;Bo Young Lee ,&nbsp;Chang Whan Oh ,&nbsp;Deung-Lyong Cho ,&nbsp;Weon-Seo Kee","doi":"10.1016/j.gsf.2024.101840","DOIUrl":"https://doi.org/10.1016/j.gsf.2024.101840","url":null,"abstract":"<div><p>The Middle Paleozoic tectonic evolution of the central Korean Peninsula (Gyeonggi Massif, Hongseong-Imjingang, and Okcheon zone of Okcheon Belts) remains controversial. Particularly, the occurrence of high-grade metamorphism and sedimentation need further examination. In this study, we conducted zircon U-Pb-rare earth element analyses from in the ultramafic-mafic complex in the central Korean Peninsula (Cheonan and Gapyeong areas) and the Paleozoic metasedimentary rocks in the Okcheon Zone of the Okcheon Belt to constrain the timing of maximum depositional and metamorphic ages. We also examined the metamorphic P-T-t path from garnet-bearing amphibolite in the central Korean Peninsula by pseudosection modeling and geothermobarometer. The results show that (i) some of the ultramafic-mafic complex and metasedimentary rocks in the central Korean Peninsula formed during the Middle Paleozoic (ca. 450–374 Ma); (ii) garnet-bearing amphibolite underwent successive metamorphism from amphibolite facies condition (7.5–8.0 kbar and 540–630 °C) at pre-peak stage to granulite facies condition (10.9–11.8 kbar and 740–820 °C) at peak stage, and then retrograded into amphibolite facies condition (5.7–7.7 kbar and 530–670 °C) along the clockwise P–T path during ca. 403–362 Ma. This and previous studies suggest that the central Korean Peninsula underwent subduction-related orogenic events during the Middle Paleozoic era, and it is well correlated to those of the orogenic events in the North Qinling belt.</p></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"15 5","pages":"Article 101840"},"PeriodicalIF":8.9,"publicationDate":"2024-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674987124000641/pdfft?md5=cbaac4f701b77a085e0b91fe34106fef&pid=1-s2.0-S1674987124000641-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140618542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interpretability and spatial efficacy of a deep-learning-based on-site early warning framework using explainable artificial intelligence and geographically weighted random forests 使用可解释人工智能和地理加权随机森林的基于深度学习的现场预警框架的可解释性和空间效力
IF 8.9 1区 地球科学
Geoscience frontiers Pub Date : 2024-04-12 DOI: 10.1016/j.gsf.2024.101839
Jawad Fayaz , Carmine Galasso
{"title":"Interpretability and spatial efficacy of a deep-learning-based on-site early warning framework using explainable artificial intelligence and geographically weighted random forests","authors":"Jawad Fayaz ,&nbsp;Carmine Galasso","doi":"10.1016/j.gsf.2024.101839","DOIUrl":"https://doi.org/10.1016/j.gsf.2024.101839","url":null,"abstract":"<div><p>Earthquakes pose significant risks globally, necessitating effective seismic risk mitigation strategies like earthquake early warning (EEW) systems. However, developing and optimizing such systems requires thoroughly understanding their internal procedures and coverage limitations. This study examines a deep-learning-based on-site EEW framework known as ROSERS (Real-time On-Site Estimation of Response Spectra) proposed by the authors, which constructs response spectra from early recorded ground motion waveforms at a target site. This study has three primary goals: (1) evaluating the effectiveness and applicability of ROSERS to subduction seismic sources; (2) providing a detailed interpretation of the trained deep neural network (DNN) and surrogate latent variables (LVs) implemented in ROSERS; and (3) analyzing the spatial efficacy of the framework to assess the coverage area of on-site EEW stations. ROSERS is retrained and tested on a dataset of around 11,000 unprocessed Japanese subduction ground motions. Goodness-of-fit testing shows that the ROSERS framework achieves good performance on this database, especially given the peculiarities of the subduction seismic environment. The trained DNN and LVs are then interpreted using game theory-based Shapley additive explanations to establish cause-effect relationships. Finally, the study explores the coverage area of ROSERS by training a novel spatial regression model that estimates the LVs using geographically weighted random forest and determining the radius of similarity. The results indicate that on-site predictions can be considered reliable within a 2–9 km radius, varying based on the magnitude and distance from the earthquake source. This information can assist end-users in strategically placing sensors, minimizing blind spots, and reducing errors from regional extrapolation.</p></div>","PeriodicalId":12711,"journal":{"name":"Geoscience frontiers","volume":"15 5","pages":"Article 101839"},"PeriodicalIF":8.9,"publicationDate":"2024-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S167498712400063X/pdfft?md5=4807f2e1e42727b8dbe335c37b7c83c0&pid=1-s2.0-S167498712400063X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140632553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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