Environmental TechnologyPub Date : 2025-05-01Epub Date: 2024-11-14DOI: 10.1080/09593330.2024.2428441
Saiyun He, Pan Yu, Yi Shao, Xintong Gao, Takashi Sakamaki, Xianning Li
{"title":"Enhanced activity of mixed-culture electroactive biofilms and sulfamethoxazole removal efficiency by adding N-acyl-homoserine lactones in bio-electrochemical system.","authors":"Saiyun He, Pan Yu, Yi Shao, Xintong Gao, Takashi Sakamaki, Xianning Li","doi":"10.1080/09593330.2024.2428441","DOIUrl":"10.1080/09593330.2024.2428441","url":null,"abstract":"<p><p>The addition of exogenous quorum sensing signaling molecules significantly enhanced the degradation efficiency of antibiotics, such as chloramphenicol in bio-electrochemical systems (BESs). However, the effects and mechanisms by which AHLs addition in BES facilitated the removal of sulfamethoxazole (SMX) remained inadequately explored. This study systematically compared the electrochemical performance and SMX removal efficiency in BES under two conditions: with and without the addition of N-acyl-homoserine lactones (AHLs) signaling molecules. In comparison to the control group, the AHL-treated group exhibited an increase in maximum output voltage from 340 to 489.67 mV, alongside a notable enhancement in SMX removal efficiency over 120 h ranging from 14.65% to 15.76%. Analyses of the live and dead cells and extracellular polymeric substances (EPS) composition revealed that following AHLs addition, both the ratio of live to dead cells and protein content within EPS increased by 12.66% and 74.37%, respectively. Furthermore, microbial community structure analysis indicated that after AHLs supplementation, there was a marked increase in the abundance of electroactive microorganisms as well as antibiotic-degrading and nitrogen-removing bacteria. Notably, <i>Klebsiella</i> - characterised by its electroactivity along with antibiotic degradation and nitrogen removal capabilities - exhibited a relative abundance reaching 56.84% in AHL, reflecting an increase of 28.31% compared to Blank; additionally, electroactive bacteria <i>Dysgonomonas</i> showed a relative abundance rise of 2.49%. Collectively, these findings suggested that enhancements in SMX removal efficiency upon AHLs addition were primarily driven by improvements in electrochemical performance coupled with alterations in microbial community structure.<b>Highlights</b> The electrochemical performance in AHL was improved compared with Blank.The protein content in extracellular polymeric substances increased by 74.37% in AHL.The removal efficiency of sulfamethoxazole in 120 h increased by up to 15.76% in AHL.The abundance of functional bacteria such as Klebsiella increased in AHL.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"2254-2267"},"PeriodicalIF":2.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142617017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Environmental TechnologyPub Date : 2025-05-01Epub Date: 2024-10-16DOI: 10.1080/09593330.2024.2416094
Juan Wang, Xindong Wang, Chunlin Bian, Jianguo Liu, Benyi Xiao
{"title":"Effect of aeration pretreatment on anaerobic digestion of swine manure.","authors":"Juan Wang, Xindong Wang, Chunlin Bian, Jianguo Liu, Benyi Xiao","doi":"10.1080/09593330.2024.2416094","DOIUrl":"10.1080/09593330.2024.2416094","url":null,"abstract":"<p><p>To investigate the effects of aeration pretreatment on the anaerobic digestion (AD) of swine manure, five pretreatment groups were established with dissolved oxygen (DO) in each group set to 0.0, 0.4, 0.8, 1.4, and 2.0 mg/L, respectively. The results demonstrated that compared to the non-aeration group, methane production increased to varying degrees with different aeration pretreatments (AP), with a maximum increase of 27.98% (DO = 2.0 mg/L). AP reduced the hydrogen sulfide (H<sub>2</sub>S) content of biogas. The H<sub>2</sub>S concentration in the DO = 2.0 mg/L was only 0.209%, and this represented an increased H<sub>2</sub>S removal rate of 49.27% compared to that of the DO = 0.0 mg/L (0.412%). Simultaneously, AP increases the hydrolysis rate. When the DO concentration reached 2.0 mg/L, the hydrolysis rate reached its maximum. An increase in the hydrolysis rate further enhanced the removal rate of organic matter. The organic matter removal rate was highest (36.96%) at DO = 2.0 mg/L. AP effectively prolonged the methane generation time and shortened the lag time of methane generation. AP creates a brief micro aerobic environment, accelerates substrate hydrolysis, and promotes the production and consumption of total volatile fatty acids, particularly acetic acid. Additionally, AP promoted the symbiotic relationship between <i>Caldicoprobacter</i> (20.93%-34.96%) and <i>Metanosaeta</i> (14.73%-18.45%).</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"2035-2051"},"PeriodicalIF":2.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142461190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Environmental TechnologyPub Date : 2025-05-01Epub Date: 2024-11-18DOI: 10.1080/09593330.2024.2428440
Li Zhang, Kaishu Liu, Diannan Huang, Yunan Gao, Jiaxin Li
{"title":"Analysis of the regulation mechanism for salt-tolerant anammox process: process performance and metabolic insights.","authors":"Li Zhang, Kaishu Liu, Diannan Huang, Yunan Gao, Jiaxin Li","doi":"10.1080/09593330.2024.2428440","DOIUrl":"10.1080/09593330.2024.2428440","url":null,"abstract":"<p><p>In this study, the start-up and microbial domestication of a salt-tolerant functional anammox system was investigated by gradually increasing the salinity level in a stabilized anammox system in the laboratory. After 44 days of stable operation, the salt-tolerant system was successfully activated, at which time the salinity of the influent water was 3 g/L, and the maximum removal efficiency of ammonia nitrogen and nitrite nitrogen in the system reached 94.18% and 96.66%, respectively, and then the ammonia nitrogen and nitrite nitrogen removal efficiency were stabilized at 88.17% and 96.48% after the enrichment domestication for 89 days. The system was operated in the salinity of 10 g/L, with the concentration of each nitrogen compound measured at the same time. The ammonia nitrogen removal efficiency decreased to 59.93% at a salinity of 10 g/L, which had a significant impact on the system. High-throughput sequencing revealed that the system was enriched with a large number of <i>Chloroflexi</i>, the relative abundance of which increased from 19.46% to 52.33%, and the genus of AnAOB was transformed from <i>Candidatus Brocadia</i> to <i>Candidatus Kuenenia, Candidatus Kuenenia</i>, with a percentage of 4.78%. The system successfully achieved the simultaneous removal of ammonia nitrogen and nitrite nitrogen under salinity stress, which to a certain extent indicated that AnAOB could achieve the initiation and enrichment domestication under salinity conditions, and could provide a basis for the efficient and low-consumption treatment of high salinity nitrogen-containing wastewater.<b>Highlights</b>Anammox reaction can be successfully initiated under low salinity conditionsSalinity of 10 g/L has a severe shock effect on the anammox systemAfter salinity enrichment and domestication, the abundance of norank_f__norank__o___SBR1031 and Candidatus Kuenenia in the anammox reaction reached 26.7% and 4.78%, respectively.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"2240-2253"},"PeriodicalIF":2.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142666351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Environmental TechnologyPub Date : 2025-05-01Epub Date: 2024-11-04DOI: 10.1080/09593330.2024.2421463
Chuancheng Zhang, Jiesheng Liu, Xiang He
{"title":"The strength and hydraulic conductivity characteristics of sewage sludge ash and natural soil mixtures - a sustainable alternate landfill liner material.","authors":"Chuancheng Zhang, Jiesheng Liu, Xiang He","doi":"10.1080/09593330.2024.2421463","DOIUrl":"10.1080/09593330.2024.2421463","url":null,"abstract":"<p><p>This paper examines the feasibility of the natural soil and sewage sludge ash (SSA) mixtures, which satisfy the criteria to be used as landfill liners. The effect of SSA content on hydraulic conductivity and strength characteristics of natural soil and SSA mixtures has been investigated through a series of laboratory tests. The results demonstrate that mixtures exhibit an increase in both hydrodynamic diffusion coefficient and strength with the increasing SSA content. With the content of SSA from 0% to 5%, the values of the hydrodynamic diffusion coefficient (<math><mi>D</mi></math>) ranged from 3.5 × 10<sup>-10</sup> to 15 × 10<sup>-10</sup> cm<sup>2</sup>/s. The increase in the hydrodynamic diffusion coefficient is minor for low SSA content and significant for SSA content exceeding 5%. The inclusion of 5% SSA content results in a hydrodynamic diffusion coefficient that is approximately three times higher than that observed in natural soil. The results were obtained from soil triaxial tests, revealing that the mixtures containing SSA exhibited a significant increase in both the initial tangent modulus and the ultimate principal stress difference compared to those of natural soil. The SSA content with the highest value exhibits maximum initial tangent modulus and ultimate principal stress. The comprehensive analysis of the strength and hydraulic diffusion conductivity of the mixtures demonstrates that the incorporation of 3% SSA results in a significant enhancement in strength, while marginally increasing hydrodynamic diffusion coefficients. Therefore, it can be inferred that the utilization of mixtures containing 3% SSA content as a liner material is suitable.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"2110-2122"},"PeriodicalIF":2.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142575411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Environmental TechnologyPub Date : 2025-05-01Epub Date: 2024-10-23DOI: 10.1080/09593330.2024.2417316
Jingjing Li, Zhaosheng Yu, Jinxi Dong, Zi You, Wen Teng, Xiaoqian Ma
{"title":"Experimental study on enrichment of heavy metals by modified mullite during co-combustion of lignite with eucalyptus wood.","authors":"Jingjing Li, Zhaosheng Yu, Jinxi Dong, Zi You, Wen Teng, Xiaoqian Ma","doi":"10.1080/09593330.2024.2417316","DOIUrl":"10.1080/09593330.2024.2417316","url":null,"abstract":"<p><p>Modifying the content of oxygen vacancies (OVs) has emerged as a crucial approach to tailoring silicate's adsorption properties, microstructure, conductivity, and catalytic performance. Some studies have reported the formation of OVs during ammonia treatment. However, there are limited studies on the production of OV-enriched mullite by treating it with N-containing compounds at low temperatures. In this work, formamide, urea, and ammonium acetate were used as ammonia-assisted reduction modifiers to induce oxygen vacancies in mullite at 30 ℃, 60 ℃, and 90 °C. The aim was to enhance the enrichment effect of heavy metals (Cr, Cu, Mn, Ni, Pb, Zn) during the co-combustion of coal and biomass. The modified mullite was analyzed by using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) surface area analysis, scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). The results indicated that the particle size of mullite decreased, and the concentration of internal Al<sup>3+</sup> ions and oxygen vacancies was enhanced. Coal-biomass-mullite combustion experiments were conducted in a tubular furnace at 900 °C, revealing a significant enhancement in the enrichment of heavy metals during the combustion process, particularly when the modification temperature was 60 °C using ammonium acetate as the modifier. This work holds significant importance for developing novel heavy metal adsorbents and the reduction of pollutant emissions from coal-biomass co-combustion in industrial applications.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"2052-2063"},"PeriodicalIF":2.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142497503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Benzo(a)pyrene degradation by the interaction of <i>Aspergillus brasilensis</i> and <i>Sphigobacterium spiritovorum</i> in wastewater: optimisation and kinetic response.","authors":"Nurhidayah Hamzah, Norasyikin Ismail, Norhafezah Kasmuri","doi":"10.1080/09593330.2024.2428442","DOIUrl":"10.1080/09593330.2024.2428442","url":null,"abstract":"<p><p>Benzo(a)pyrene (BaP) is a well-known environmental contaminant that poses significant risks due to its carcinogenic nature and it is crucial to remove it from the environment, especially in wastewater. Thus, this study aims to enhance the degradation of BaP in wastewater through the optimised interaction of the fungus <i>Aspergillus brasiliensis</i> and the bacterium <i>Sphingomonas spiritovorum</i>. The ideal initial pH and temperature ranges for optimising BaP breakdown were determined using response surface methodology (RSM). For that, the range of initial pH chosen was pH 4-9 and the temperature was between 25℃ - 40℃. The first-order kinetic was used to determine the kinetic response for monoculture and co-culture. The co-culture of <i>A. brasiliensis</i> and <i>S. spiritovorum</i> successfully produced a BaP removal rate of over 50%, which was much higher than the removal rates observed in monoculture treatments under optimisation conditions. The kinetic response was obtained with 0.067 d<sup>-</sup><sup>1</sup> (<i>A. brasiliensis</i>), 0.127 d<sup>-</sup><sup>1</sup> (<i>S.spriritovorum</i>) and 0.144 d<sup>-</sup><sup>1</sup> (co-culture) for the degradation rate constant, K. The degradation half-life time, t<sub>1/2</sub> shows the decrement for the co-culture (4.83 days) compared to monoculture. The increased degradation has been attributed to the synergistic biochemical pathways, in which fungal ligninolytic enzymes initiate the breakdown of BaP, followed by bacterial degradation of the resulting compounds. The study's results, which have been validated by Analysis of Variance (ANOVA), offer insightful information for the enhancement of bioremediation strategies. This information is practicable for researchers, practitioners, and policymakers in the context of addressing carcinogenic pollutants in wastewater.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"2268-2280"},"PeriodicalIF":2.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142709509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Preparation of adsorbent from coal gasification slag for the treatment of waste water from lanchar and its adsorption mechanism.","authors":"Huan-Xi Wang, Jia-Rui Zhao, Yu-Tong He, Yun-Hua Xu","doi":"10.1080/09593330.2024.2420285","DOIUrl":"10.1080/09593330.2024.2420285","url":null,"abstract":"<p><p>Solid waste coal gasification slag has certain hardness, porosity, pore structure and specific surface area, etc. which can be utilized in environmental protection materials and other areas of high value. Yulin City, high-quality coal resources derived from the excellent quality of charcoal products, but its processing will produce a large number of high chemical oxygen demand (COD), high volatile phenol, high ammonia nitrogen 'three high' wastewater, the ecological environment is very harmful. The results of the modification of the refined coal gasification fine residue showed that the removal rates of the three were enhanced to 91%, 89% and 83%, respectively, after adsorption at a pH of 9.5, an injection ratio of 1:5 and 25 ℃ for 25 min. The reason is that the modification treatment significantly increased the specific surface area of the adsorbent from 103 m<sup>2</sup>/g to 606 m<sup>2</sup>/g, which effectively increased the adsorption active sites for the pollutant molecules. The adsorption process of COD from modified refining coal gasification slag for the treatment of charcoal wastewater was thermodynamically investigated. The thermodynamic study shows that the adsorption process of modified refining coal gasification slag on pollutants in the charcoal wastewater is an exothermic and spontaneous process.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"2092-2109"},"PeriodicalIF":2.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142521452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Assessment of dew harvesting as a sustainable water source and air quality indicator: a case study of Dhanbad, Jharkhand, India.","authors":"Shweta Singh, Suresh Pandian Elumalai, Sasmita Chand, Prangya Ranjan Rout","doi":"10.1080/09593330.2024.2422552","DOIUrl":"10.1080/09593330.2024.2422552","url":null,"abstract":"<p><p>Dew formation takes place when atmospheric water vapor condenses on the surface which cools down due to radiation deficit. As it is a local phenomenon, its study gives information about the pollutants present in the atmosphere. Also, since dew formation is a natural phenomenon, and involves passive cooling, this can be a potential method for atmospheric water harvesting. The main intention of this present research work was the collection of dew samples and their analysis for yield and chemical composition. Dew samples were collected on a self-fabricated dew collection set up during the winter season. In total 30 dew samples were collected and analyzed for ionic constituents. The results were then compared to those of rain samples. The pH of dew was found to be in the range of 7-8.7, showing the neutral to alkaline nature of dew. Ionic compositions were higher in dew than in rain. While sulfate largely contributed to the ion composition of dew, nitrate was the least contributing ion. The average concentration for sulfate and nitrate in dew were found to be 0.55 and 0.03 meq/L, respectively. The average yield of dew was found to be 0.13L/m<sup>2</sup>. This yield value from the simplest of collection set-up ensures that dew can be considered as the potential water source with advanced condensing material and passive/active cooling in arid and semi-arid regions.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"2123-2131"},"PeriodicalIF":2.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142575391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of carbon materials with different nano-iron oxide loadings on aerobic granular sludge systems.","authors":"Kai-Peng Deng, Jun-Guo He, Wei-Xun Jiang, Xin-Ping Liu, Zhi-Han Gong, Yu Zhang, Ya-Qing Xu","doi":"10.1080/09593330.2025.2482078","DOIUrl":"https://doi.org/10.1080/09593330.2025.2482078","url":null,"abstract":"<p><p>This study investigated iron oxide-loaded powdered activated carbon (FONP-PAC) with varying Fe/C ratios (FC1 in S1, FC2 in S2) in aerobic granular sludge (AGS) systems. S2 achieved the fastest sludge growth, reaching 1106 μm by day 80 (87.14% larger than control S0). During stable operation, S2 exhibited superior pollutant removal: 95.96% COD, 100% NH4+-N, and 79.53% TN removal, alongside the highest aerobic denitrification rate (9.93 mg·gVSS⁻¹·h⁻¹, 71.68% above S0). Comparatively, S1 showed slightly lower efficiencies (94.20% COD, 100% NH4+-N, 71.50% TN) and denitrification activity (8.35 mg·gVSS⁻¹·h⁻¹). Microbial analysis revealed enriched Bacteroidota phyla and sustained Zoogloea genus abundance in FONP-PAC reactors. Higher iron oxide loading enhanced interspecies electron transfer, accelerating granule growth and nitrogen removal. Larger granules in S2 promoted stratified microbial niches, improving oxygen gradient-dependent processes like simultaneous nitrification-denitrification. These findings demonstrate that optimized FONP-PAC dosing strengthens sludge structure and metabolic synergy, achieving dual benefits of rapid granulation and high-efficiency nutrient removal through physicochemical-microbial interactions. The study provides insights into nano-material mediated AGS enhancement for wastewater treatment optimization.HighlightsThe threshold effect of nano-iron oxide loading on the granulation rate of AGS (Anaerobic Granular Sludge) was revealed.The mechanism by which FONP-PAC (Functionalized Oxide Nanoparticles-Polymeric Aluminum Chloride) promotes interspecies electron transfer through a conductive network was elucidatedA strategy for the targeted enrichment of Thauera and Zoogloea by the material was proposed.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"1-12"},"PeriodicalIF":2.2,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143984589","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Erhui Ren, Jiatong Yan, Shan Jiang, Biyu Peng, Ronghui Guo, Fan Yang, Hongyan Xiao, Mi Zhou
{"title":"Facile synthesis of Collagen/V<sub>2</sub>CT<sub>x</sub> composite aerogel by directional freeze-drying with excellent mechanical strength and oil absorption.","authors":"Erhui Ren, Jiatong Yan, Shan Jiang, Biyu Peng, Ronghui Guo, Fan Yang, Hongyan Xiao, Mi Zhou","doi":"10.1080/09593330.2025.2485356","DOIUrl":"https://doi.org/10.1080/09593330.2025.2485356","url":null,"abstract":"<p><p>Efficient removal of oils has attracted wide attention and researchers have tried to develop effective oil absorbents with increasingly serious oily pollution. Collagen (COL)/V<sub>2</sub>C Aluminium Carbide (V<sub>2</sub>CT<sub>x</sub>) composite aerogels were synthesized using a simple method of blending and directional freezing-drying with original materials of COL and V<sub>2</sub>CT<sub>x</sub>, in which V<sub>2</sub>CT<sub>x</sub> MXene was prepared by etching V<sub>2</sub>AlC with hydrofluoric acid under stirring at room temperature. Modern testing and analysis techniques were used to characterize the structural properties and surface morphology of the hybrid aerogel. The COL/V<sub>2</sub>CT<sub>x</sub> composite aerogel shows excellent mechanical properties with 83 kPa compressive stress at 70% strain, low density (about 25 mg/cm<sup>3</sup>), outstanding thermal stability with 58.67% weight loss from 240℃ to 600℃ and thermal insulation with heat conductivity coefficient 0.05304 W/mK. Importantly, COL/V<sub>2</sub>CT<sub>x</sub> aerogel exhibits higher oil absorption capacity and stability than that of COL aerogel for various oils. The absorbency of COL/V<sub>2</sub>CT<sub>x</sub> aerogel for methylene chloride is up to 54 times its weight under Vander Waals forces, intermolecular interaction, and capillary interaction between the aerogel and oily liquids. Therefore, COL/V<sub>2</sub>CT<sub>x</sub> aerogel possesses a promising application in the field of oil absorption and wastewater treatment.HIGHLIGHTSA novel COL/V<sub>2</sub>CT<sub>x</sub> aerogel was prepared by a simple method of blending and directional freezing-drying.The absorption capacity of COL/V<sub>2</sub>CT<sub>x</sub> aerogel for methylene chloride achieves up to 54 times its weight.The COL/V<sub>2</sub>CT<sub>x</sub> composite aerogel exhibits excellent mechanical properties with 83 kPa compressive stress at 70% strain, low density (about 25 mg/cm<sup>3</sup>), and good thermal stability with 58.67% weight loss from 240℃ to 600℃.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"1-15"},"PeriodicalIF":2.2,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143993418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}