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Carbon Aerogel/Myristic Acid Palmitic Acid Phase Change Composites With High Solar/Electro-Thermal Conversion for Thermal Energy Storage 碳气凝胶/肉豆蔻酸棕榈酸相变复合材料的高太阳能/电热转换用于热能储存
Energy Storage Pub Date : 2025-12-18 DOI: 10.1002/est2.70326
Yunlin Wu, Zekun Wang, Xianjie Liu, Xin Min, Yangai Liu, Ruiyu Mi, Xiaowen Wu, Zhaohui Huang, Minghao Fang
{"title":"Carbon Aerogel/Myristic Acid Palmitic Acid Phase Change Composites With High Solar/Electro-Thermal Conversion for Thermal Energy Storage","authors":"Yunlin Wu,&nbsp;Zekun Wang,&nbsp;Xianjie Liu,&nbsp;Xin Min,&nbsp;Yangai Liu,&nbsp;Ruiyu Mi,&nbsp;Xiaowen Wu,&nbsp;Zhaohui Huang,&nbsp;Minghao Fang","doi":"10.1002/est2.70326","DOIUrl":"https://doi.org/10.1002/est2.70326","url":null,"abstract":"<div>\u0000 \u0000 <p>Phase change materials (PCMs) have garnered significant attention in thermal storage owing to their high latent heat, near-constant phase transition temperature, and negligible volumetric change during phase transition. However, their inherent disadvantages, such as leakage during melting, low thermal conductivity, poor photothermal response, and electrical insulation, have considerably limited their practical application in solar energy utilization and electrothermal conversion systems. In this study, we propose for the first time the design and fabrication of a lightweight biomass-derived carbon aerogel (CKA) with a highly porous structure and superior light absorption, prepared via controlled carbonization process using natural kapok fibers (KF) with sodium silicate as the structural binder. The resultant CKA was employed as the encapsulation of myristic acid-palmitic acid (MA-PA) binary PCM by a vacuum impregnation method. The obtained CKA/MA-PA composite PCMs (CMPPs) exhibit excellent form stability, enhanced thermal properties, and high energy storage density. These results show that the unique three-dimensional network structure of CKA enables a high PCM loading ratio (&gt; 80%) and outstanding thermal cycling reliability. The carbonized structure forms continuous heat conduction pathways, yielding a thermal conductivity of 1.676 W m<sup>−1</sup> K<sup>−1</sup>, which is 3.37 times higher than that of the noncarbonized samples (KMPP). Moreover, CMPPs demonstrate a high enthalpy of phase change (165.7–166.2 J/g) and significantly improved photo/electro-to-thermal conversion performance. The design offers a novel biomass-carbonization-based strategy for developing high-performance composite PCMs, which show great potential for applications in solar energy storage and building energy efficiency.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145846067","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Genetic Algorithm-Based PID Tuning and Time-of-Use Tariff-Based Control for Bidirectional Operation and Cost Optimization of EV Bidirectional Charging 基于遗传算法PID整定和分时电价控制的电动汽车双向充电运行与成本优化
Energy Storage Pub Date : 2025-12-18 DOI: 10.1002/est2.70317
Sarasij Adhikary, Pabitra Kumar Biswas, Furkan Ahmad, Ameni Boumaiza
{"title":"Genetic Algorithm-Based PID Tuning and Time-of-Use Tariff-Based Control for Bidirectional Operation and Cost Optimization of EV Bidirectional Charging","authors":"Sarasij Adhikary,&nbsp;Pabitra Kumar Biswas,&nbsp;Furkan Ahmad,&nbsp;Ameni Boumaiza","doi":"10.1002/est2.70317","DOIUrl":"https://doi.org/10.1002/est2.70317","url":null,"abstract":"<div>\u0000 \u0000 <p>Incorporating energy aggregators is essential for reducing the strain placed on the system by coordinating Electric Vehicle (EV) charging activities. As EV adoption accelerates, their charging demand, particularly under Grid-to-Vehicle (G2V) operations, significantly alters the system's load profile. A Time-of-Use (TOU) tariff plan is used to alleviate the problems caused by peak demand and decrease the peak-to-valley load differential, promoting more balanced energy consumption patterns. To enable bidirectional power flow in Vehicle-to-Grid (V2G) applications, to enable energy exchange between EVs and the grid, certain chargers are needed, thereby providing economic incentives to users. In this work, a comprehensive bidirectional EV charging model is developed using the MATLAB/Simulink platform. The model comprises a DC-DC bidirectional converter, an AC-DC front-end, and an LCL filter, all configured for a Level 2 charger that supports a 32A bidirectional current. The Proportional-Integral (PI) controller, on which the control strategy is based, has its settings improved by a Genetic Algorithm (GA) to improve system performance. An evaluation of previous research informs the TOU tariff structure used for cost analysis. Simulation results demonstrate the efficacy of the proposed GA-based optimization framework in minimizing operational costs during both V2G and G2V modes, while considering the charger's power rating and dynamic pricing signals.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145824675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intercalation-Enabled Charge Storage in Tertiary Nanocomposites of Polypyrrole, Sulphonated Carbon Quantum Dots, and Y2O3 for Advanced Asymmetric Supercapacitors 先进非对称超级电容器中聚吡咯、磺化碳量子点和Y2O3三级纳米复合材料的插层电荷存储
Energy Storage Pub Date : 2025-12-18 DOI: 10.1002/est2.70319
Monika Dhanda
{"title":"Intercalation-Enabled Charge Storage in Tertiary Nanocomposites of Polypyrrole, Sulphonated Carbon Quantum Dots, and Y2O3 for Advanced Asymmetric Supercapacitors","authors":"Monika Dhanda","doi":"10.1002/est2.70319","DOIUrl":"https://doi.org/10.1002/est2.70319","url":null,"abstract":"<div>\u0000 \u0000 <p>This research involved the synthesis and systematic evaluation of a series of ternary nanocomposites made from polypyrrole (PPY), sulphonated carbon quantum dots (CQDs), and yttrium oxide (Y<sub>2</sub>O<sub>3</sub>) as advanced electrode materials for high-performance supercapacitors. The combination of CQDs and Y<sub>2</sub>O<sub>3</sub> within the conductive PPY matrix resulted in a synergistic enhancement of electrochemical properties, featuring excellent electrical conductivity, numerous redox-active sites, and superior structural stability. Among all formulations, the 0.4 PCY(PPY, sulphonated CQDs, and Y<sub>2</sub>O<sub>3</sub>) composite demonstrated the highest specific capacitance of 894.3 F/g at a rate of 2 mV/s, surpassing pure PPY (493.3 F/g), CQDs (128.2 F/g), and Y<sub>2</sub>O<sub>3</sub> (398.2 F/g). This significant enhancement is attributed to the optimized charge transfer pathways facilitated by CQDs and the strong pseudocapacitive effect of Y<sub>2</sub>O<sub>3</sub>, which promote efficient ion diffusion and electron transport. Galvanostatic charge–discharge tests further validated the exceptional performance of 0.4 PCY, which achieved a specific capacitance of 860.16 F/g at 1 A/g, maintaining 42% (361.79 F/g) even at 5 A/g. The electrode reached an impressive energy density of 119.4 Wh/kg and a corresponding power density of 2022.5 W/kg, exhibiting remarkable cycling stability with 98.1% capacitance retention after 10 000 cycles. These findings illustrate the high reversibility and durability of the composite. An asymmetric supercapacitor (ASC) device constructed with 0.4 PCY as the positive electrode successfully powered a 1 V Light-emitting diode (LED) for 4.43 min following a 10-min charge at 3 V, demonstrating its practical applicability. In summary, the study emphasizes the 0.4 PCY nanocomposite as a promising and efficient electrode material for future flexible and high-energy-density supercapacitor systems.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145824674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetic Field Induced Improved Performance of Asymmetric Supercapacitor Device Based on RGO and CoFe2O4/RGO Nanocomposite 磁场诱导下RGO和CoFe2O4/RGO纳米复合材料非对称超级电容器器件性能的改善
Energy Storage Pub Date : 2025-12-11 DOI: 10.1002/est2.70322
Pooja Devi, Manish Srivastava, Debabrata Mishra
{"title":"Magnetic Field Induced Improved Performance of Asymmetric Supercapacitor Device Based on RGO and CoFe2O4/RGO Nanocomposite","authors":"Pooja Devi,&nbsp;Manish Srivastava,&nbsp;Debabrata Mishra","doi":"10.1002/est2.70322","DOIUrl":"https://doi.org/10.1002/est2.70322","url":null,"abstract":"<div>\u0000 \u0000 <p>Supercapacitors have gained substantial attention as devices for storing energy. This is because of their exceptional power density, rapid charging-discharging process, and longer lifetime. In this study, a hydrothermal synthesis procedure was followed to prepare two distinct nanostructures: cobalt ferrite (CoFe<sub>2</sub>O<sub>4</sub>) nanoparticles and cobalt ferrite-reduced graphene oxide (CoFe<sub>2</sub>O<sub>4</sub>/RGO) nanocomposite. Our results indicate that CoFe<sub>2</sub>O<sub>4</sub> NPs has a specific capacity of 44.12 mA h g<sup>−1</sup> at 0.5 A g<sup>−1</sup>, whereas CoFe<sub>2</sub>O<sub>4</sub>/RGO nanocomposite has a specific capacity of 198.62 mA h g<sup>−1</sup>at the same current density. Subsequently, we utilized the positive electrodes as CoFe<sub>2</sub>O<sub>4</sub>/RGO nanocomposite and RGO as the negative electrode to fabricate asymmetric supercapacitor devices. For the CoFe<sub>2</sub>O<sub>4</sub>/RGO//RGO asymmetric supercapacitor device, we measure a specific capacity of 60.15 mA h g<sup>−1</sup> (@1 Ag<sup>−1</sup>). The energy density and power density of the device are found to be 13.36 W h kg<sup>−1</sup> and 802 W kg<sup>−1</sup>, respectively, at the same current density. Notably, when subjecting the CoFe<sub>2</sub>O<sub>4</sub>/RGO//RGO asymmetric supercapacitor devices to a 0.5 T external magnetic field, a significant enhancement in specific capacity was recorded, with an increase of ∼36% (81.96 mA h g<sup>−1</sup>) at 1 A g<sup>−1</sup> of current density.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145719546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Valorizing Refinery Byproducts: Thermal Enhancement of Paraffin Wax With Algerian Slack Wax for Energy Storage 炼油副产品的增值:用阿尔及利亚松蜡对石蜡进行热强化储能
Energy Storage Pub Date : 2025-12-07 DOI: 10.1002/est2.70308
Djahida Mahmoudi, Abdel Illah Nabil Korti, Houcine Guellil, Houssem Hachemi, Noureddine Embarek
{"title":"Valorizing Refinery Byproducts: Thermal Enhancement of Paraffin Wax With Algerian Slack Wax for Energy Storage","authors":"Djahida Mahmoudi,&nbsp;Abdel Illah Nabil Korti,&nbsp;Houcine Guellil,&nbsp;Houssem Hachemi,&nbsp;Noureddine Embarek","doi":"10.1002/est2.70308","DOIUrl":"https://doi.org/10.1002/est2.70308","url":null,"abstract":"<div>\u0000 \u0000 <p>The global transition to sustainable energy systems demands high-performance thermal energy storage, with paraffin wax standing as a prominent phase change material (PCM) due to its high latent heat, chemical stability, and cost-effectiveness. However, its low thermal conductivity (about 0.2 W/m·K) and phase segregation significantly limit its practical application. While nanofillers and carbon additives can enhance conductivity, they often reduce latent heat, increase costs, and complicate processing. This study introduces a novel, sustainable solution by valorizing Algerian slack wax, a local petroleum refinery byproduct, as a multifunctional enhancer for paraffin. Composites with 6, 10, 15, and 20 mass% slack wax were formulated and characterized using the T-history method. The results demonstrate a breakthrough in simultaneous property enhancement, overcoming typical trade-offs. The 20% composite achieved a 35.65% increase in latent heat (from 106.93 to 145.06 kJ/kg), a 30.48% rise in specific heat (from 3.51 to 4.58 kJ/kg·K), and a 33% improvement in thermal conductivity (from 0.18 to 0.24 W/m·K in the solid state). Furthermore, the material's thermal responsiveness was enhanced, with a 25% reduction in solidification time (from 165 to 120 s) and a 20% faster melting rate (from 125 to 100 s). These improvements are attributed to molecular interactions that disrupt paraffin's crystalline order, facilitating more efficient phonon transport and energy distribution. By transforming an industrial waste into a high-performance PCM, this work provides a cost-effective, scalable, and circular pathway for advanced thermal storage, directly benefiting solar energy integration, building efficiency, and industrial waste heat recovery.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145750722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-Temperature Supercapacitors Enabled by Fluorine-Free Ionic Liquid and Synergistic Alkali-Doped Graphene Oxides 无氟离子液体和协同碱掺杂石墨烯氧化物的高温超级电容器
Energy Storage Pub Date : 2025-12-07 DOI: 10.1002/est2.70311
Gaurav Tatrari, Tanmoy Rath, Klaudia Maślana, Rajesh Bhatt, Xuecheng Chen, Ewa Mijowska, Rong An, Solomon Tesfalidet, Faiz Ullah Shah
{"title":"High-Temperature Supercapacitors Enabled by Fluorine-Free Ionic Liquid and Synergistic Alkali-Doped Graphene Oxides","authors":"Gaurav Tatrari,&nbsp;Tanmoy Rath,&nbsp;Klaudia Maślana,&nbsp;Rajesh Bhatt,&nbsp;Xuecheng Chen,&nbsp;Ewa Mijowska,&nbsp;Rong An,&nbsp;Solomon Tesfalidet,&nbsp;Faiz Ullah Shah","doi":"10.1002/est2.70311","DOIUrl":"https://doi.org/10.1002/est2.70311","url":null,"abstract":"<p>This study explores the synthesis and electrochemical performance of graphene oxide co-doped with sodium and potassium (Na–K–GO) as electrode materials for supercapacitors (SCs) designed to operate at 60°C over an extended voltage window. The Na–K–GO is employed as the electrode material, while a fluorine-free ionic liquid (IL), [P<sub>4444</sub>][MEEA]—comprising a tetrabutylphosphonium cation and a 2-2-(2-methoxyethoxy)ethoxy anion—served as the electrolyte, enabling stable operation over a wide voltage window at elevated temperatures. Using this combination, three coin-cell SCs are fabricated: two symmetric devices (SC-1 and SC-2) and one asymmetric device (SC-3). All the three exhibited remarkable charge storage abilities, a retaining performance over 10 000 charge–discharge cycles at 60°C. Among the three devices, SC-3 exhibited the best overall electrochemical performance, delivering a high specific capacitance of 47.01 F g<sup>−1</sup> and an energy density of 27.77 Wh kg<sup>−1</sup> at 0.5 A g<sup>−1</sup>. Even at a higher current density of 1 A g<sup>−1</sup>, SC-3 maintained a maximum power density of 1000 W kg<sup>−1</sup> while sustaining an energy density of 14.21 Wh kg<sup>−1</sup>, reflecting its strong rate capability. Moreover, the long-term cycling tests at 2 A g<sup>−1</sup> demonstrated an outstanding durability of SC-3, which retained 99% coulombic efficiency after 10 000 cycles, significantly outperforming the SC-2 (90%) and SC-1 (79%).</p>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/est2.70311","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145750587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Role of Heteroatom-Doped Donors and Internal Acceptors in Enhancing Photovoltaic Properties of 2,2′:5′,2″-Terthiophene π-Bridged Photosensitizers 杂原子掺杂给体和内受体在提高2,2 ':5 ',2″-特噻吩π桥接光敏剂光电性能中的作用
Energy Storage Pub Date : 2025-12-04 DOI: 10.1002/est2.70313
Pooja Kundu, Vipin Kumar, Someshwar Pola, Prabhakar Chetti
{"title":"Role of Heteroatom-Doped Donors and Internal Acceptors in Enhancing Photovoltaic Properties of 2,2′:5′,2″-Terthiophene π-Bridged Photosensitizers","authors":"Pooja Kundu,&nbsp;Vipin Kumar,&nbsp;Someshwar Pola,&nbsp;Prabhakar Chetti","doi":"10.1002/est2.70313","DOIUrl":"https://doi.org/10.1002/est2.70313","url":null,"abstract":"<div>\u0000 \u0000 <p>This study investigated metal-free organic dyes having D-π-A and D-A′-π-A frameworks for organic solar cells (OSCs). The influence of modifying the donor and internal acceptor in reference molecules (<b>N</b>, <b>O</b>, and <b>S</b>) on the structural, electronic, photovoltaic, and optical characteristics was analyzed by employing density functional theory (DFT). The UV–visible spectrum of the designed dyes was also simulated by employing time-dependent DFT (TD-DFT). The highest occupied molecular orbital (HOMO), lowest unoccupied molecular orbital (LUMO), and their energy gap (E<sub>gap</sub>) are advantageous to understand the electron injection, electron transfer, and regeneration of the dye. The evaluated results suggest that short-circuit current density (J<sub>SC</sub>), energy for dye regeneration (ΔG<sub>reg</sub>), electron injection driving force (ΔG<sub>inj</sub>), light harvesting efficiency (LHE), open circuit voltage (V<sub>OC</sub>), density of state (DOS), and power conversion efficiency (η) are affected by the insertion of donors and internal acceptors. The dye <b>N</b> with Carbazole donor has an efficacy of 4.15% at J<sub>SC</sub> of 15 mA cm<sup>−2</sup>. The outcomes indicate that heteroatom-doped donors and inserting internal acceptors have an impact on absorption energies and improve the photovoltaic characteristics in the D-π-A arrangement, suggesting that these dyes are better sensitizers for the assembly of OSCs.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145686093","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Boron Doped Ti2CrV Alloy as Room Temperature Reversible Solid State Hydrogen Storage Media 硼掺杂Ti2CrV合金作为室温可逆固态储氢介质
Energy Storage Pub Date : 2025-12-03 DOI: 10.1002/est2.70307
Asheesh Kumar, Seemita Banerjee, Priyanka Ruz, V. Sudarsan
{"title":"Boron Doped Ti2CrV Alloy as Room Temperature Reversible Solid State Hydrogen Storage Media","authors":"Asheesh Kumar,&nbsp;Seemita Banerjee,&nbsp;Priyanka Ruz,&nbsp;V. Sudarsan","doi":"10.1002/est2.70307","DOIUrl":"https://doi.org/10.1002/est2.70307","url":null,"abstract":"<div>\u0000 \u0000 <p>Effect of boron doping on the structure and hydrogenation-dehydrogenation characteristics of Ti<sub>2</sub>CrV alloy has been investigated in detail. The alloys were prepared by arc melting method and were characterized using techniques such as XRD, SEM and EDX. With boron incorporation, the plateau pressure of hydrogen absorption increases with a decrease in enthalpy value, confirming destabilization of the hydride. The alloy, Ti<sub>1.9</sub>CrVB<sub>0.1</sub>, shows a maximum total hydrogen absorption capacity of 3.8 wt%, under ambient conditions with enthalpy and entropy of hydrogenation reactions, −48 kJmol<sup>−1</sup> and 112 Jmol<sup>−1</sup> K<sup>−1</sup>, respectively. With further increase in B addition in the alloy, the hydrogen absorption capacity decreases to 3.5 wt% at room temperature. As prepared alloys exist in BCC structure which phase transforms into FCC structure up on hydrogenation. In situ hydrogen desorption temperature is found to decrease with an increase in B concentration. Around 30°C decrease in hydrogen desorption temperature was observed for Ti<sub>1.9</sub>CrVB<sub>0.1</sub> alloy compared to parent Ti<sub>2</sub>CrV alloy, confirming the improved dehydrogenation properties upon B addition. Compared to the parent alloy, Ti<sub>2</sub>CrV, the hydrogen absorption rate of Ti<sub>1.9</sub>CrVB<sub>0.1</sub> alloy improved significantly with an increase in the number of hydrogenation/dehydrogenation cycles due to the pulverization of the alloy. Studies confirmed that a small amount of B addition, (i.e., Ti<sub>1.9</sub>CrVB<sub>0.1</sub> alloy) leads to better de-hydrogenation behavior, higher hydrogen absorption kinetics and improved cyclic stability compared to the parent Ti<sub>2</sub>CrV alloy.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145686350","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hexagonal BeX (X: S, Te) Monolayer as Potential Electrode Material for Alkali Metal-Ion Batteries: A DFT Perspective 六方BeX (X: S, Te)单层作为碱金属离子电池电位电极材料的DFT研究
Energy Storage Pub Date : 2025-12-02 DOI: 10.1002/est2.70304
Hetvi Jadav, Sadhana Matth, Himanshu Pandey
{"title":"Hexagonal BeX (X: S, Te) Monolayer as Potential Electrode Material for Alkali Metal-Ion Batteries: A DFT Perspective","authors":"Hetvi Jadav,&nbsp;Sadhana Matth,&nbsp;Himanshu Pandey","doi":"10.1002/est2.70304","DOIUrl":"https://doi.org/10.1002/est2.70304","url":null,"abstract":"<div>\u0000 \u0000 <p>Metal-ion batteries (MIBs) are essential for transitioning to a cleaner and more sustainable energy future. By employing the density functional formalism, we have investigated the hexagonal (<i>h</i>) monolayer of BeS and BeTe as electrode materials for alkali (Li and Na) MIBs. The structural and thermodynamic stability, adsorption of Li/Na atoms, density of states, diffusion, and migration of atoms, as well as capacity, are investigated. The structures of <i>h</i>-BeS and <i>h</i>-BeTe remain stable upon adsorption of the adatoms, with improved electronic conductivity of these monolayers. The climbing image-nudged elastic band calculations estimate a low diffusion barrier of 0.16 eV (0.01 eV) for Li (Na) in <i>h-</i>BeS and 0.20 eV (0.16 eV) for Li (Na) in <i>h-</i>BeTe. Additionally, a maximum storage capacity of 580 mAh g<sup>−1</sup> for Li-ions and 1305 mAh g<sup>−1</sup> for Na-ions in <i>h-</i>BeS as well as 174 mAh g<sup>−1</sup> for both metal ions in <i>h</i>-BeTe, is estimated.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145686062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An Energy Storage Oscillating Wave Test System for Accurate Partial Discharge Detection in Power Cables 用于电力电缆局部放电精确检测的储能振荡波测试系统
Energy Storage Pub Date : 2025-12-01 DOI: 10.1002/est2.70310
Zhaohui Chen, Tao Zhu, Jingshuai Liu, Xiaochuan Wu, Xuan Du
{"title":"An Energy Storage Oscillating Wave Test System for Accurate Partial Discharge Detection in Power Cables","authors":"Zhaohui Chen,&nbsp;Tao Zhu,&nbsp;Jingshuai Liu,&nbsp;Xiaochuan Wu,&nbsp;Xuan Du","doi":"10.1002/est2.70310","DOIUrl":"https://doi.org/10.1002/est2.70310","url":null,"abstract":"<div>\u0000 \u0000 <p>To address the issues of low noise and lack of portability in on-site partial discharge (PD) detection and testing of cables, the paper will present an AC excitation cable oscillation wave detection system using a capacitor bank power supply of energy. By adding two bidirectional high-speed solid-state switches at the output end of the inverter power supply in the traditional frequency modulation series resonant circuit, this paper uses capacitor banks to generate the required oscillation wave voltage, with the advantage of no switching noise interference. At the same time, to avoid pulse interference caused by the generator and reduce the sensitivity of PD detection, the following measures are taken in this article: using capacitor banks for power supply during the testing phase; the test interval utilizes mains power to charge the capacitor bank. This solves the problem of the system's dependence on the generator. After conducting high-capacity capacitance tests and 10 kV distribution cable application tests, the results showed that under the condition of capacitor bank power supply, the system can achieve equivalent 1 μ. The load of the F cable has increased to a peak of 24 kV, and the noise level of PD detection is below 10 mV. This indicates that the system in this article meets the requirements of offline PD detection tests for 10 kV power cables.</p>\u0000 </div>","PeriodicalId":11765,"journal":{"name":"Energy Storage","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145686279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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