Environmental Technology & Innovation最新文献

{"title":"Bioremediation of soils with emerging organic contaminants using immobilized microorganisms","authors":"Abdelrahman Ibrahim ,&nbsp;Bonface Oginga ,&nbsp;Youai Zhang ,&nbsp;Wanting Ling ,&nbsp;Lei Tang ,&nbsp;Essam Elatafi ,&nbsp;Mohamed Abady ,&nbsp;Yanzheng Gao","doi":"10.1016/j.eti.2025.104345","DOIUrl":"10.1016/j.eti.2025.104345","url":null,"abstract":"<div><div>The escalating global challenge of soil contamination by emerging organic contaminants (EOCs) demands advanced bioremediation solutions. This review explores cutting-edge advancements in enzyme immobilization and microbial engineering for enhanced EOC degradation, focusing on innovative carrier systems like nanobiochar and their role in biocatalyst stabilization. Key molecular interactions between EOCs and biological systems are analyzed, including their potential for DNA damage and ecosystem disruption, alongside challenges posed by environmental persistence. A critical comparison of contemporary immobilization techniques evaluates their efficacy based on associated genes in bacterial and enzymatic systems, with emphasis on structural and functional immobilization characteristics. Furthermore, it highlights the integration of molecular dynamics simulations (MDS) to predict EOC degradation efficiency and enzyme-substrate interactions. Revolutionary CRISPR-based genetic engineering approaches for tailoring microbial degraders are demonstrated, showcasing their precision in optimizing biodegradation pathways. The synergistic potential of combining immobilization techniques with engineered microorganisms, supported by computational modeling and EOC-degradation predictive models, offers an eco-friendly solution that eliminates pathogenic compounds more efficiently than conventional methods. This integrated approach is not only cost-effective, but also achieves faster contaminant degradation, demonstrating superior performance compared to traditional remediation strategies. These techniques serve as both a critical threshold of current technologies and a roadmap for future innovations in environmental biotechnology.</div></div>","PeriodicalId":11725,"journal":{"name":"Environmental Technology & Innovation","volume":"40 ","pages":"Article 104345"},"PeriodicalIF":6.7,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144571445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Integrative genomic and transcriptomic analyses reveal marine Actinomycetota adaptations for hydrocarbon degradation","authors":"Bashar Haruna Gulumbe ,&nbsp;Cristiana Cravo-Laureau ,&nbsp;Robert Duran","doi":"10.1016/j.eti.2025.104361","DOIUrl":"10.1016/j.eti.2025.104361","url":null,"abstract":"<div><div>Marine oil pollution poses critical ecological challenges, necessitating innovative and sustainable bioremediation strategies. This study provides a comprehensive multi-omics investigation into a synthetic coastal marine consortium comprising four strains belonging to Actinomycetota, including <em>Rhodococcus</em> sp. strain 1Y, <em>Gordonia</em> sp. strain BP1o, and two <em>Janibacter indicus</em> strains isolated from hydrocarbon-contaminated sediments. Genomic analysis identified multiple orthologous gene clusters associated with hydrocarbon degradation, encompassing pathways such as <em>alkB</em>, <em>cyp</em> and <em>nah</em>. <em>Rhodococcus</em> sp. strain 1Y exhibited the highest number of these hydrocarbon-degradation gene clusters, highlighting its robust genetic potential and versatility in metabolizing diverse hydrocarbons. Secondary metabolite analysis identified stress-related biosynthetic pathways, including ectoine and siderophore production, supporting hydrocarbon solubilization and enzymatic activity. In a medium containing a mixture of phenanthrene and hexadecane (50 mg/L each) as the sole source of carbon, the consortium demonstrated rapid hydrocarbon degradation, with nearly complete degradation of hexadecane (reduced to 2.76 %) and partial degradation of phenanthrene (reduced to 36.56 %) by Day 12. Transcriptomic profiling across time points revealed dynamic shifts in gene expression, with 502 differentially expressed genes between Day 3 and Day 12, of which 487 were downregulated, enriched in pathways associated with xenobiotics biodegradation, lipid metabolism, and membrane transport. Functional annotations highlighted the transcriptional activation of metabolic pathways enabling hydrocarbon uptake, breakdown, and stress adaptation. This integrated approach connects genomic potential with functional performance, emphasizing the metabolic versatility and ecological resilience of Actinomycetota for oil-spill bioremediation. These findings advance our understanding of microbial hydrocarbon degradation and offer actionable insights for developing eco-friendly remediation strategies.</div></div>","PeriodicalId":11725,"journal":{"name":"Environmental Technology & Innovation","volume":"40 ","pages":"Article 104361"},"PeriodicalIF":6.7,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144557524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring the potential of sewage sludge for gasification and resource recovery: A review","authors":"Greta Brandstätter ,&nbsp;Katharina Fürsatz ,&nbsp;Arabel Long ,&nbsp;Thomas Karl Hannl ,&nbsp;Teresa Schubert","doi":"10.1016/j.eti.2025.104346","DOIUrl":"10.1016/j.eti.2025.104346","url":null,"abstract":"<div><div>The production of sewage sludge, a by-product of wastewater treatment plants, is steadily increasing. With its hazardous properties but valuable resources and materials, sewage sludge requires innovative management strategies to tackle environmental challenges and create opportunities for energy recovery and circular resource utilization. The most common applications currently include incineration, agricultural use and composting. The trend towards thermal treatment is steadily increasing, especially in Europe. State-of-the-art is to incinerate sewage sludge, which offers the benefits of volume reduction and the destruction of toxins, pathogens as well as the potential for recovery of the critical resource phosphorus from the generated ash. The latter is becoming increasingly important, particularly due to emerging regulations within the EU. Gasification as a thermal treatment method is also gaining traction as a suitable approach. The thermochemical process offers the same benefits as incineration but additionally produces gas (synthesis gas), a versatile fuel for energy generation and a precursor for the chemical industry. Sewage sludge gasification has yet to be adopted on a large scale due to gaps in research, technological development and systemic requirements as well as financial constraints. This review provides a comprehensive overview of legislation related to sewage sludge management and feedstock characteristics, including ash chemistry. Furthermore, it explores the fundamentals of gasification, focusing on optimizing parameters for sewage sludge by summarizing findings from studies on the effects of feedstock parameters, process designs and operating conditions on efficiency and output. It concludes with an outlook on large-scale implementation to maximize waste valorization through gasification.</div></div>","PeriodicalId":11725,"journal":{"name":"Environmental Technology & Innovation","volume":"40 ","pages":"Article 104346"},"PeriodicalIF":6.7,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144633744","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Two types of agroforestry wastes as bedding materials: Microenvironmental dynamics, microbial community structure, and impacts on growth performance of heifers","authors":"Bin Wu,&nbsp;Chongchong Zhao,&nbsp;Qiusheng Lv,&nbsp;Weiguang Hao,&nbsp;Guowen Li,&nbsp;Shengjuan Wei","doi":"10.1016/j.eti.2025.104364","DOIUrl":"10.1016/j.eti.2025.104364","url":null,"abstract":"<div><div>The economic and ecological benefits of recycled manure solids (RMS) make them a popular choice for bovine bedding. The stable operation of the fermentation-based RMS beds hinges on understanding their internal dynamics. This study utilized sawdust (SD) and fermented cow manure (FCM) as bedding materials to investigate the microenvironmental changes during in situ fermentation and their impacts on heifers. Results demonstrated FCM exhibited lower fermentation temperature, higher nitrate-nitrogen, smaller pH variation rate, and reduced ammonia concentrations, but higher electrical conductivity (EC) and methane emissions compared to SD. Bedding type significantly influenced the composition of both bacterial and fungal communities, whereas bedding duration affected only bacterial community structure. Key physicochemical factors shaping microbial communities included EC, C/N ratio, total nitrogen, water content, temperature, pH, organic matter and nitrate-nitrogen; ammonium nitrogen exclusively impacted fungal communities. Predictive functional analysis of bacteria revealed higher relative abundances of metabolic pathways related to nucleotide metabolism, carbohydrate metabolism and genetic information processing in FCM bedding. Notably, bedding type had no significant effects on heifers’ growth performance and serum parameters. This research provides a theoretical foundation for the resource utilization of cattle manure and scientific management of bedding materials in livestock systems.</div></div>","PeriodicalId":11725,"journal":{"name":"Environmental Technology & Innovation","volume":"40 ","pages":"Article 104364"},"PeriodicalIF":6.7,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144571405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Development of a novel (Eu (III) post-functionalized zirconium-based metal-organic framework) dual-emission ratiometric fluorescent probe for rapid and highly selective detection of Pb2+ and Cu2+","authors":"Yu He ,&nbsp;Suqing Liu ,&nbsp;Yan Zhou ,&nbsp;Junping Wang","doi":"10.1016/j.eti.2025.104359","DOIUrl":"10.1016/j.eti.2025.104359","url":null,"abstract":"<div><div>At present, with the development of society, different enterprises inevitably produce industrial wastewater and waste residue containing lead and copper. Therefore, there is an urgent need for a rapid and simple method to detect lead and copper in pollutants. In this paper, a metal-organic framework (MOF) doped with Eu(Ⅲ) (Eu³⁺/UiO-66-NH₂) was successfully prepared by one-pot hydrothermal technique. The probe is capable of detecting Pb²⁺ and Cu²⁺ with high sensitivity. Pb²⁺ and Cu²⁺ have detection ranges of 5–340 μM and 0.01–200 μM, respectively. The detection limit for Pb²⁺ was as low as 1.01 μM, and the detection limit for Cu²⁺ was 6.46 μM. This approach has a good detection performance when compared to the method described in the literature. It shows that the prepared sensor has great potential in the detection of actual lead and copper, and provides a practical and effective method for rapid and accurate detection of heavy metal ions.</div></div>","PeriodicalId":11725,"journal":{"name":"Environmental Technology & Innovation","volume":"40 ","pages":"Article 104359"},"PeriodicalIF":6.7,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144571444","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surface-modified porous polycarbonate membrane with tannic acid anchored by functionalized TiO2@GA for efficient oily water separation","authors":"Amirjamshid Rahimnejad,&nbsp;Farzin Zokaee Ashtiani,&nbsp;Elshan Bonyadi","doi":"10.1016/j.eti.2025.104351","DOIUrl":"10.1016/j.eti.2025.104351","url":null,"abstract":"<div><div>Oily wastewater poses substantial environmental challenges. To address the accumulation of organics and contaminants on the membrane surface and the reduced lifespan of membranes, in this study, a novel surface modification strategy was developed involving the deposition of tannic acid (TA) as an intermediate layer on polycarbonate (PC) membranes, followed by the incorporation of gallic acid (GA)-functionalized TiO₂ nanoparticles (NPs). This hybrid coating enhanced the surface hydrophilicity and antifouling properties by preventing NPs agglomeration and ensuring uniform distribution. Characterization confirmed improved surface properties, including higher wettability, with a lower water contact angle of 16.5°and an underwater oil contact angle (158.9°). The optimized membrane demonstrated exceptional performance, achieving an oil/water separation flux of 310.11 L/m².h, 99.72 % oil rejection, and an excellent fouling recovery ratio (FRR) of 93.77 % at a near-zero operating pressure. These findings suggest that an eco-friendly, low-cost, high-performance modified membrane is desirable for oil-water separation in industrial applications with limited facilities.</div></div>","PeriodicalId":11725,"journal":{"name":"Environmental Technology & Innovation","volume":"40 ","pages":"Article 104351"},"PeriodicalIF":6.7,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144631287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Quasi-homogeneous adsorption behavior of a magnetic iron-based hydrated material for Congo red","authors":"Shuo Ai,&nbsp;Kaili Gao,&nbsp;Linghui Liu,&nbsp;Wanguo Yu","doi":"10.1016/j.eti.2025.104362","DOIUrl":"10.1016/j.eti.2025.104362","url":null,"abstract":"<div><div>Congo red (CR) and its degradation products are hazardous to water environment. A hydrated floccule material was prepared with iron salts and ammonia, and CR could be efficiently removed via adsorption. The experimental adsorption capacity reached 32,622 mg/g floccule, tenfold to hundredfold the state-of-the-art values. Fe^2 + and hydrated structure were vital for its removal ability. FTIR, UV-Vis, Raman, XPS, and Zeta potential results confirmed that the SO₃^– groups in CR were strongly attracted by Fe²⁺ ions in the adsorbent via electrostatic and coordination interactions. The adsorption process followed pseudo-second-order and intraparticle diffusion kinetics in dilute and concentrated CR solutions, respectively. UPS, XPS, EDS, and ICP-OES data proved that the adsorbent surface was covered by a monolayer of CR, which could diffuse into the bulk of adsorbent with resistance. This floccule material exhibited quasi-homogeneous adsorption behavior for CR, consistent with a Langmuir isotherm model. The adsorbent could be reused 15 times with removal rates ≥ 99 % (pristine CR content = 1000 ppm), and CR could be recovered through desorption with alkali solutions. Merely 0.2 % of iron was wasted due to leaching during reuse.</div></div>","PeriodicalId":11725,"journal":{"name":"Environmental Technology & Innovation","volume":"40 ","pages":"Article 104362"},"PeriodicalIF":6.7,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144557522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Plant phenomics-assisted selection of Trichoderma spp. strains effective in the biocontrol of tomato soil-borne fungal diseases","authors":"Cono Vincenzo ,&nbsp;Pasquale Tripodi ,&nbsp;Nadia Lombardi ,&nbsp;Gelsomina Manganiello ,&nbsp;Catello Pane","doi":"10.1016/j.eti.2025.104357","DOIUrl":"10.1016/j.eti.2025.104357","url":null,"abstract":"<div><div>The genus <em>Trichoderma</em> is a valuable source of biological control agents: useful means for sustainable crop disease management. Speeding up screening phase in the set-up of new microbial means is crucial to meet needs for managing pathogens. Functional phenomics expressing through objective spectral data the result of the plant genotype's interactions with the environment, can contribute to the performance-based selection. In this study nineteen <em>Trichoderma</em> spp., including strains belonging to the species <em>T. atroviride</em>, <em>T. harzianum</em>, <em>T. longibrachiatum</em> and <em>T. rifaii</em>, were screened for the biocontrol of <em>Fusarium oxysporum</em> f. sp. <em>lycopersici</em> and <em>Sclerotium rolfsii</em> infections on tomato plants, with the help of phenomics measures on infected plants subjected to symptom-reducing effects of the beneficial microbial treatments, alongside the traditional method. <em>Trichoderma</em> spp. isolates showed an antagonistic behavior in plate assays against the two pathogens, while four and five out of total isolates significantly lowered, respectively, wilt and Southern blight symptoms on plants. Detection of the plant phenotype closer to that of the healthy ideotype, defined through the overall computation of biometric and spectral traits acquired by a multispectral dual scan platform, individuated <em>T. harzianum</em> T2 and PB3 as the best performing strains in controlling both tomato pathogens. Leaf area and Normalized Chlorophyll Pigment Ratio Index Average acted as engine vectors for phenotypic clustering with non-infected plants in both systems. Voxel Volume Total, 3D-Leaf area, Green Leaf Index Average, Hue Average, and Surface Angle Average assumed importance under <em>F. oxysporum</em> assay. Specifically, the phenomics assisted procedure contributed to prompt results in the individuation of the best performing <em>Trichoderma</em> strains against <em>F. oxysporum</em> and <em>S. rolfsii</em>.</div></div>","PeriodicalId":11725,"journal":{"name":"Environmental Technology & Innovation","volume":"40 ","pages":"Article 104357"},"PeriodicalIF":6.7,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144571503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Redox zonation and bioclogging interaction in managed aquifer recharge systems: A laboratory-scale investigation","authors":"Jinhui Liu ,&nbsp;Haichi You ,&nbsp;Weijie Zhang ,&nbsp;Mengjie Qin ,&nbsp;Longyun Liu ,&nbsp;Lu Xia","doi":"10.1016/j.eti.2025.104344","DOIUrl":"10.1016/j.eti.2025.104344","url":null,"abstract":"<div><div>Managed aquifer recharge (MAR) processes induce dynamic changes in groundwater redox conditions, which subsequently affect the formation of bioclogging during subsurface infiltration. To explore this relationship, we conducted controlled laboratory column experiments simulating both aerobic and anaerobic recharge scenarios. By integrating monitoring of changes in hydraulic conductivity, quantification of bacterial growth, assessment of metabolic activity, and analysis of redox-sensitive indicators, we characterized bioclogging patterns and revealed the associated hydrochemical transformations. The results indicated distinct spatial distributions of bioclogging under varying redox recharge conditions. Aerobic recharge led to more severe bioclogging, with deeper penetration along flow paths compared to anaerobic conditions (<em>p</em> &lt; 0.001 for differences in bacterial biomass). Conversely, the accumulation of extracellular polymeric substances (EPS) exhibited an inverse trend, with concentrations under anaerobic recharge reaching 4.2 times those observed under aerobic conditions. Redox zonation analysis revealed that aerobic infiltration maintained weakly oxidizing conditions (ORP: 5.7 – 109.8 mV), whereas anaerobic recharge resulted in progressive transitions from initial weak oxidation (ORP: 1.3 – 103.9 mV) to reducing conditions (ORP: −29.4 – −10.2 mV). These redox gradients facilitated sequential biogeochemical reactions: the aerobic system displayed bacterial-mediated oxygen respiration followed by nitrate attenuation (denitrification) and sulfate reduction, whereas the anaerobic environment favored concurrent oxygen respiration and nitrate reduction (dissimilatory nitrate reduction to ammonium, DNRA), followed by sulfate depletion. Our findings elucidate the interrelated hydrogeochemical mechanisms that govern redox evolution and bioclogging dynamics during MAR operations. This research provides empirical evidence that can inform the optimization of recharge strategies to mitigate clogging risks while preserving groundwater quality.</div></div>","PeriodicalId":11725,"journal":{"name":"Environmental Technology & Innovation","volume":"40 ","pages":"Article 104344"},"PeriodicalIF":6.7,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144571443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A heterostructure MIL-101(Fe)/graphene oxide peroxymonosulfate catalyst for triclosan degradation: Response surface methodology and evolutionary-based adaptive neuro-fuzzy inference system models","authors":"Afshin Ebrahimi ,&nbsp;Kun-Yi Andrew Lin ,&nbsp;Malihe Moazeni","doi":"10.1016/j.eti.2025.104360","DOIUrl":"10.1016/j.eti.2025.104360","url":null,"abstract":"<div><div>Triclosan (TCS), a widely used antimicrobial agent, poses significant environmental and health risks due to its persistence and bioaccumulation in aquatic systems. This study presents a novel heterogeneous catalyst, MIL-101(Fe)/graphene oxide (M(F)/GO), synthesized via a solvothermal method for activating peroxymonosulfate (PMS) to degrade TCS. The structural and physicochemical properties of M(F)/GO were characterized using field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), and other characterization techniques. Batch experiments demonstrated that the M(F)/GO/PMS system achieved up to 98.31 % TCS removal under optimal conditions; pH 9, 0.17 g/L catalyst dosage, 400 μg/L initial TCS concentration, and 8 µM PMS concentration in only 10 min. To model and optimize the degradation efficiency, two approaches, response surface methodology (RSM) based on central composite design (CCD) and an evolutionary algorithm-based adaptive neuro-fuzzy inference system (EV-ANFIS), were employed and compared. The RSM model showed high accuracy (R² = 0.99), while the ANFIS- Harris hawk optimization (HHO) hybrid demonstrated robust predictive performance among the machine learning models tested (R² = 0.94). Catalyst dosage was identified as the most influential parameter affecting TCS removal. Mechanistic studies revealed that sulfate (SO₄^•−) and hydroxyl (HO^•) radicals dominated the degradation pathway. Moreover, minimal Fe leaching confirmed the catalyst's stability and reusability potential. Compared to existing advanced oxidation processes (AOPs), this system offers advantages including high efficiency, reduced catalyst and oxidant dosage, and broad pH applicability. This work introduces a promising strategy for efficiently removing persistent organic pollutants like TCS from water environments.</div></div>","PeriodicalId":11725,"journal":{"name":"Environmental Technology & Innovation","volume":"40 ","pages":"Article 104360"},"PeriodicalIF":6.7,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144571407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}