Advanced Optical Materials最新文献_第8页

Trap-Engineering the Persistent Luminescence of Ca3Ga4O9:Tb3+ via Al3+ Substitution for Optical Data Storage

IF 8 2区材料科学

Advanced Optical Materials Pub Date : 2024-12-06 DOI: 10.1002/adom.202402353

Thulitha M. Abeywickrama, Angela Guo, Yuanbing Mao

{"title":"Trap-Engineering the Persistent Luminescence of Ca3Ga4O9:Tb3+ via Al3+ Substitution for Optical Data Storage","authors":"Thulitha M. Abeywickrama, Angela Guo, Yuanbing Mao","doi":"10.1002/adom.202402353","DOIUrl":"https://doi.org/10.1002/adom.202402353","url":null,"abstract":"Optically stimulated luminescence (OSL) materials hold great potential for optical data storage (ODS) and anticounterfeiting applications. Nevertheless, the scarcity of suitable luminescent materials with deep-level traps remains a significant obstacle. Herein, a host substation strategy have been employed to tune the persistent luminescence (PersL) and OSL properties of Ca3Ga4O9:Tb3+ by Al3+ substitution through trap engineering and demonstrated their potential. Specifically, the photoluminescence of the Ca2.985(Ga1-y%Aly%)4O9:0.5%Tb3+ of Tb3+ is first investigated due to its different occupancies of Ca2+. The influence of host substitution on the crystal structure, trap depth, trap density, PersL, and OSL properties have further investigated. A series of strong PersL and OSL peaks from the Ca2.985(Ga1-y%Aly%)4O9:0.5%Tb3+ with bluish-green emissions have been observed. The Ca2.985(Ga1-y%Aly%)4O9:0.5%Tb3+ have shown controllable photon release upon thermal and optical stimuli, enhancing their performance for ODS. Thermally stimulated luminescence suggests that vacancy and defect concentrations inside the Ca3-x%(Ga1-y%Aly%)4O9:x%Tb3+ can be manipulated by Tb3+ doping and Al3+ substitution, which ultimately leads to the formation of deep traps and a broad distribution of traps with increased deep trap concentration. The work demonstrates that trap engineering through Al3⁺ substitution is an effective method for tuning PersL and OSL properties of Ca2.985(Ga1-y%Aly%)4O9:0.5%Tb3+ for ODS.","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"13 4","pages":""},"PeriodicalIF":8.0,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143112682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent Advances in Grating Coupled Surface Plasmon Resonance Technology (Advanced Optical Materials 34/2024) 光栅耦合表面等离子体共振技术研究进展（Advanced Optical Materials 34/2024）

IF 8 2区材料科学

Advanced Optical Materials Pub Date : 2024-12-03 DOI: 10.1002/adom.202470110

Divagar Murugan, Marcel Tintelott, Madaboosi S. Narayanan, Xuan-Thang Vu, Tetiana Kurkina, César Rodriguez-Emmenegger, Ulrich Schwaneberg, Jakub Dostalek, Sven Ingebrandt, Vivek Pachauri

{"title":"Recent Advances in Grating Coupled Surface Plasmon Resonance Technology (Advanced Optical Materials 34/2024)","authors":"Divagar Murugan, Marcel Tintelott, Madaboosi S. Narayanan, Xuan-Thang Vu, Tetiana Kurkina, César Rodriguez-Emmenegger, Ulrich Schwaneberg, Jakub Dostalek, Sven Ingebrandt, Vivek Pachauri","doi":"10.1002/adom.202470110","DOIUrl":"https://doi.org/10.1002/adom.202470110","url":null,"abstract":"Grating Coupled Surface Plasmon Resonance TechnologyThe Review by Vivek Pachauri and co-workers (see article number 2401862) delves into the core principles, manufacturing processes, and cutting-edge developments in Grating-coupled Surface Plasmon Resonance (GCSPR). Enhancements in nanofabrication techniques, including roll-to-roll nanoimprint technology, have made scalable and precise on-chip sensor platforms feasible. Innovative experimental setups, incorporation of novel materials, and machine learning-driven data analysis are elevating sensitivity and standardization, critical for clinical adoption, and aligning with the latest IoT healthcare trends. [Image credit: Hocine Bahri and Divagar Murugan, RWTH Aachen.]\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture>\u0000 </div>\u0000 </figure>","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"12 34","pages":""},"PeriodicalIF":8.0,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adom.202470110","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142762249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Aqueous Afterglow Dispersion Enabling On-Site Ratiometric Sensing of Mercury Ions (Advanced Optical Materials 34/2024) 水余辉色散实现汞离子的现场比例传感（Advanced Optical Materials 34/2024）

IF 8 2区材料科学

Advanced Optical Materials Pub Date : 2024-12-03 DOI: 10.1002/adom.202470111

Minjuan Cai, Wuzhen Luo, Feiming Li, Shunyou Cai, Guangqiang Yin, Tao Chen, Zhixiong Cai

引用次数: 0

A Diamond Heater-Thermometer Microsensor for Measuring Localized Thermal Conductivity: A Case Study in Gelatin Hydrogel (Advanced Optical Materials 34/2024) 用于测量局部热导率的金刚石加热器-温度计微传感器：明胶水凝胶的案例研究（Advanced Optical Materials 34/2024）

IF 8 2区材料科学

Advanced Optical Materials Pub Date : 2024-12-03 DOI: 10.1002/adom.202470109

Linjie Ma, Jiahua Zhang, Zheng Hao, Jixiang Jing, Tongtong Zhang, Yuan Lin, Zhiqin Chu

引用次数: 0

Masthead: (Advanced Optical Materials 34/2024) 报头：（Advanced Optical Materials 34/2024）

IF 8 2区材料科学

Advanced Optical Materials Pub Date : 2024-12-03 DOI: 10.1002/adom.202470112

引用次数: 0

Regulating the Aggregation and Dispersion of Carbon Dots to Achieve Stimulus-Responsive Multimodal Luminescence for Dynamic Anti-Counterfeiting

IF 8 2区材料科学

Advanced Optical Materials Pub Date : 2024-11-29 DOI: 10.1002/adom.202402456

Li Yang, Xiaoyun Liang, Zhiyu Wang, Qi Zhang, Shuangshuang Wang, Xingtang Liang, Yongqian Xu, Yanjun Zhang, Yanzhen Yin

{"title":"Regulating the Aggregation and Dispersion of Carbon Dots to Achieve Stimulus-Responsive Multimodal Luminescence for Dynamic Anti-Counterfeiting","authors":"Li Yang, Xiaoyun Liang, Zhiyu Wang, Qi Zhang, Shuangshuang Wang, Xingtang Liang, Yongqian Xu, Yanjun Zhang, Yanzhen Yin","doi":"10.1002/adom.202402456","DOIUrl":"https://doi.org/10.1002/adom.202402456","url":null,"abstract":"Stimulus-responsive multimodal luminescence (MML) within a single material system is highly desirable for anti-counterfeiting and information encryption applications. However, achieving adjustable MML within a unified material framework is challenging due to the distinct responses of different luminescence modes to a common external stimulus. In the work, a novel approach is devised for regulating the aggregation or dispersion state of carbon dots (CDs) to exhibit responsive MML, including fluorescence (FL), room temperature phosphorescence (RTP), and chemiluminescence (CL). Specifically, aggregation-caused luminescence quenching CDs (ACQCDs) are synthesized via a one-step hydrothermal method using levofloxacin. These ACQCDs exhibit ACQ and significant aggregation-induced color change effects. When ACQCDs interact with paper-based materials, they form hydrogen bonds, establishing a high-density hydrogen bond network that induces ACQCDs aggregation. Upon external stimulation, the hydrogen bond network undergoes dynamic changes, triggering ACQCDs dispersion. This process effectively deactivates nonradiative defect centers, stabilizes triplet excitons, and promotes simultaneous MML of tunable FL, RTP, and CL. The integration of multimodal luminescence with external stimulus input enables the creation of a programmable multi-input logic gate, offering significant potential for encoded information anti-counterfeiting applications. Overall, this research provides valuable insights into the conduction of MML CDs, thereby advancing the utilization of nanomaterials in intelligent encryption and anti-counterfeiting technologies. The findings pave the way for the development of more sophisticated and secure anti-counterfeiting measures based on the unique luminescent properties of CDs.","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"13 5","pages":""},"PeriodicalIF":8.0,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143397192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Pressure-Induced Excitation-Dependent Emission Color Tuning and Enhancement in 1D Zigzag Edge-Sharing Perovskites (C6H10N2)PbX4 (X = Br, Cl)

IF 8 2区材料科学

Advanced Optical Materials Pub Date : 2024-11-29 DOI: 10.1002/adom.202402136

Xueqian Wu, Yiyang Sun, Lingrui Wang, Yijia Huang, Jiaxiang Wang, Yifang Yuan, Urooj Shahzadi, Ruijing Fu, Kai Wang, Haizhong Guo

{"title":"Pressure-Induced Excitation-Dependent Emission Color Tuning and Enhancement in 1D Zigzag Edge-Sharing Perovskites (C6H10N2)PbX4 (X = Br, Cl)","authors":"Xueqian Wu, Yiyang Sun, Lingrui Wang, Yijia Huang, Jiaxiang Wang, Yifang Yuan, Urooj Shahzadi, Ruijing Fu, Kai Wang, Haizhong Guo","doi":"10.1002/adom.202402136","DOIUrl":"https://doi.org/10.1002/adom.202402136","url":null,"abstract":"1D zigzag edge-sharing perovskites have generated intense research interest due to their unique structures and optoelectronic properties. Recent efforts have focused on refining these structures to enhance their efficiency across various applications. Herein, high-pressure is utilized to modulate the properties of two Pb-based perovskites, (AMP)PbCl4 and (AMP)PbBr4 (where AMP2+ = C6H10N22+), characterized by 1D zigzag edge-sharing [PbX4]2−∞ chains linked by AMP through hydrogen bonding. An inverse excitation-dependent emission phenomenon and emission enhancement are observed in these two perovskites, attributed to the contraction of inhomogeneously coordinated [PbX6]4− octahedra. Pressure-induced lattice contraction promotes the overlap of Pb and X orbitals, resulting in a decrease in the bandgap. Concurrently, pressure-induced phase transitions, due to the distortion of [PbX6]4− octahedra, lead to discontinuous decreases in the bandgap. These high-pressure optical and structural explorations facilitate the systematic design of halide perovskites with desired characteristics.","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"13 3","pages":""},"PeriodicalIF":8.0,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143120605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Flexible Liquid Crystal Cascade Dielectric Metasurface for Dynamically Controlling Terahertz Beam Deflection

IF 8 2区材料科学

Advanced Optical Materials Pub Date : 2024-11-29 DOI: 10.1002/adom.202402113

Yunyun Ji, Xinhao Jiang, Fei Fan, Huijun Zhao, Xipu Dong, Jierong Cheng, Shengjiang Chang

{"title":"Flexible Liquid Crystal Cascade Dielectric Metasurface for Dynamically Controlling Terahertz Beam Deflection","authors":"Yunyun Ji, Xinhao Jiang, Fei Fan, Huijun Zhao, Xipu Dong, Jierong Cheng, Shengjiang Chang","doi":"10.1002/adom.202402113","DOIUrl":"https://doi.org/10.1002/adom.202402113","url":null,"abstract":"Terahertz (THz) beam deflection devices with tunable capabilities are highly desired in future wireless communication and radar systems. In this work, a cascaded metadevice is constructed by integrating liquid crystal (LC) into a dielectric metasurface, and then the phase of each meta-atom is designed to achieve different polarization conversions and spatial phase gradient distributions. Therefore, by changing the polarization of the incident wave or the LC optical axis orientation, an active THz beam deflection device that can actively and independently control the spin state and deflection angle of the output wave can be obtained. Specifically, the output right circularly polarized (RCP) wave is deflected to the +1st diffraction order, and the output left circularly polarized (LCP) wave is deflected to the +2nd diffraction order. The experimental results indicate that the cascaded metadevice exhibits a large angular spatial dispersion in the frequency angle scanning range of +25°–+17.5° (+1st order) and +52.5°–+35° (+2nd order) corresponding to the broadband range of 0.6–0.83 THz. The spin isolation of all diffraction order channels can reach over 10 dB and the maximum diffraction efficiency of 56% can be obtained. In addition, the universality of the proposed LC-cascaded metasurface design concept has also been verified, providing a feasible path for complex, multifunctional, and active THz wavefront manipulation, thereby exploring more possible application scenarios.","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"13 2","pages":""},"PeriodicalIF":8.0,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143120898","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dynamic Disassembling Strategy of Luminescent Nanoclusters Assemblies for Integrating Multiple-Node Information Encryption with Transient Imaging Feature

IF 8 2区材料科学

Advanced Optical Materials Pub Date : 2024-11-29 DOI: 10.1002/adom.202402420

Xiwen Zhang, Yuexiang Lu, Mengtong Qu, Huashuo Dou, Bojun Shi, Yueying Liu

{"title":"Dynamic Disassembling Strategy of Luminescent Nanoclusters Assemblies for Integrating Multiple-Node Information Encryption with Transient Imaging Feature","authors":"Xiwen Zhang, Yuexiang Lu, Mengtong Qu, Huashuo Dou, Bojun Shi, Yueying Liu","doi":"10.1002/adom.202402420","DOIUrl":"https://doi.org/10.1002/adom.202402420","url":null,"abstract":"Avoiding the second leakage and boosting the complexity of confidential information have been two key directions in the development of the field of information security. However, it still remains formidable challenges to combine these two strategies in a single luminescent material. Here, it has integrated multiple-node time-gated information encryption and self-erased decryption data with transient imaging feature for enormously enhancing the information security protection based on the dynamic assembling/disassembling process of luminescence copper nanoclusters (CuNCs). Multiple CuNCs-based assemblies for the information encryption are controlled after introducing metal ions (Zn2+ and Al3+) and ammonia, which gives rise to the tremendously fluorescence improvement of CuNCs through aggregation-induced emission (AIE) effect. These assemblies can be disassembled upon adding a chelator agent (EDTA) in concomitant with fluorescence vanishing behavior. Their decomposition rates heavily depend on the type of metal ions, ammonia concentration, and EDTA concentration. Based on the dynamic disassembling process, time-dependent multi-node information is encrypted. The real information can be read observed only once at the correct “time key” and then automatically self-destructed within dozens of minutes. This study provides new insights into designing advanced information security protection against the risk of the second leakage and deciphering data of confidential information.","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"13 5","pages":""},"PeriodicalIF":8.0,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143397378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Realizing 48.5 dB Gain in the E+S Band Using 12 m Bismuth-Doped Fiber

IF 8 2区材料科学

Advanced Optical Materials Pub Date : 2024-11-29 DOI: 10.1002/adom.202401798

Shaokun Liu, Xiaoke Yin, Le He, Wenzhen Li, Yingbo Chu, Nengli Dai, Jinyan Li

{"title":"Realizing 48.5 dB Gain in the E+S Band Using 12 m Bismuth-Doped Fiber","authors":"Shaokun Liu, Xiaoke Yin, Le He, Wenzhen Li, Yingbo Chu, Nengli Dai, Jinyan Li","doi":"10.1002/adom.202401798","DOIUrl":"https://doi.org/10.1002/adom.202401798","url":null,"abstract":"Bismuth-doped fibers (BDFs) are renowned in wideband amplification due to their numerous gain bands, such as O, E, S, and U. However, the low amplification coefficient and excessive usage length hinder its further application, how to achieve a high amplification coefficient remains an unresolved challenge. In this study, a high-efficiency bismuth-doped germanosilicate fiber (BGDF) for E+S band amplification is developed using modified chemical vapor deposition (MCVD) combined with the solution doping technique. The BGDF achieves a gain of 48.5 dB using a length of only 12 m. The effects of bismuth active centers (BACs) and unsaturable loss (UL) determined by fiber drawing parameters and bismuth concentrations on amplification properties of the BGDFs are discussed. New observations and analysis are conducted on how variations in oxygen vacancies and the bismuth concentration impact BGDFs' luminescence intensity and lifetime. A successful optimization approach is devised to increase BACs levels and decrease UL by modifying drawing parameters and the bismuth concentration to facilitate the formation of low-valence bismuth and oxygen vacancies. The results suggest that BGDFs are significant for the future expansion of the gain band to the E+S band.","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"13 3","pages":""},"PeriodicalIF":8.0,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143120661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0