Advanced Materials Interfaces最新文献_第2页

Hierarchical Cauliflower-Like Structural Surfaces for Efficient Anti-Condensation Under Extreme Supercooling Condition 在极端过冷条件下高效防冷凝的分层花椰菜状结构表面

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-09-12 DOI: 10.1002/admi.202500363

Enming Cui, Zehong Zhao, Ningning Sun, Yiwei Zhang, Mengfan Zhang, Lei Zhao, Yahua Liu, Shile Feng

{"title":"Hierarchical Cauliflower-Like Structural Surfaces for Efficient Anti-Condensation Under Extreme Supercooling Condition","authors":"Enming Cui, Zehong Zhao, Ningning Sun, Yiwei Zhang, Mengfan Zhang, Lei Zhao, Yahua Liu, Shile Feng","doi":"10.1002/admi.202500363","DOIUrl":"https://doi.org/10.1002/admi.202500363","url":null,"abstract":"Efficient removal of condensation droplets from cooled superhydrophobic surfaces is pivotal for practical applications such as anti-icing, water collection, and condensation heat transfer. However, these surfaces often lose their superhydrophobicity as microdroplets become trapped within their structures during condensation, particularly under high supercooling conditions. Here, a fluorine-free superhydrophobic surface, fabricated via a facile one-step vapor deposition method, is introduced, featuring a hierarchical cauliflower-like structure. This design restricts condensation droplet size to a maximum diameter of ≈50 µm and a coverage rate of ≈16%, markedly enhancing droplet shedding efficiency, due to a hierarchical cauliflower-like structure enhances the larger Laplace force and smaller adhesion. Notably, the surface maintains stable superhydrophobicity even after 720 min of exposure to 100 °C vapor (supercooling of ≈99 °C), surpassing the durability of traditional superhydrophobic surfaces by two orders of magnitude, highlighting its efficacy in anti-condensation under extreme supercooling conditions. Beyond anti-condensation, this design demonstrates enhanced self-cleaning even via condensation droplets or for high-adhesive nanoparticles, eco-friendliness, and demonstrates robust durability, including thermal stability above 500 °C and anti-ultraviolet radiation, thereby broadening its potential for industrial applications in various harsh environments.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 19","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500363","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation and Characterization of GdVO4:Tb,Eu Nanoparticles/ Carbon Dots Composites via Hydrothermal Deposition and Physical Mixing for Luminescent Nanothermometry 热液沉积和物理混合制备GdVO4:Tb，Eu纳米颗粒/碳点复合材料及其发光纳米热测量性能

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-09-12 DOI: 10.1002/admi.202500410

Rut Sisó-Moliné, Concepción Cascales, Maria Méndez, Laura Fuentes-Rodriguez, Araceli de Aquino, Maria Cinta Pujol, Carlos Zaldo, Joan J. Carvajal

{"title":"Preparation and Characterization of GdVO4:Tb,Eu Nanoparticles/ Carbon Dots Composites via Hydrothermal Deposition and Physical Mixing for Luminescent Nanothermometry","authors":"Rut Sisó-Moliné, Concepción Cascales, Maria Méndez, Laura Fuentes-Rodriguez, Araceli de Aquino, Maria Cinta Pujol, Carlos Zaldo, Joan J. Carvajal","doi":"10.1002/admi.202500410","DOIUrl":"https://doi.org/10.1002/admi.202500410","url":null,"abstract":"Carbon dots (CDs) stand out for their facile synthesis, strong photoluminescence, and easy surface modification, making them excellent candidates for integration with other nanostructures to enhance physical and chemical properties.In this work, CDs derived from eco-friendly precursors (xylose and biomass-derived hemicellulose) are combined with GdVO4:Tb,Eu nanoparticles (NPs) via two distinct approaches: (i) hydrothermal deposition onto the lanthanide-doped particles and (ii) physical mixing of prefabricated components. Notably, the spectroscopic properties of the resulting composites depend on the fabrication route. While method (i) enables competitive energy transfers from the vanadate charge transfer band (CTB) to Eu3⁺ and CDs, method (ii), which involves lower concentrations of the emissive components, promotes a cooperative mechanism wherein CDs sensitize the CTB, enhancing the Eu3⁺ red emission. In both scenarios, Tb3+ is believed to serve as an intermediary, aiding the repopulation of the Eu3+ 5Dj energy levels. The dual-emissive nature of the composites results in violet-magenta chromaticity, reflecting intermediate behavior between the blue CDs and red-emitting Ln-NPs, and supporting their use in tunable optical applications. The described mechanisms also influence the composites' performance as ratiometric nanothermometers. Upon evaluating their thermal response from 298 K to 358 K, distinct behaviors emerge, with relative thermal sensitivities ranging from 0.84% K−1 (298 K) to 5.6% K−1 (358 K)—the latter being among the highest reported for similar materials.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 19","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500410","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Phase Transformations in Evaporated Ph-BTBT-10 Thin Films and Impact on the Device Performance 蒸发Ph-BTBT-10薄膜相变及其对器件性能的影响

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-09-12 DOI: 10.1002/admi.202500599

Lamiaa Fijahi, Shunya Yan, Ann Maria James, Min Zhang, Alba Cazorla, Adrián Tamayo, Jinghai Li, Carmen Ocal, Esther Barrena, Roland Resel, Marta Mas-Torrent

{"title":"Phase Transformations in Evaporated Ph-BTBT-10 Thin Films and Impact on the Device Performance","authors":"Lamiaa Fijahi, Shunya Yan, Ann Maria James, Min Zhang, Alba Cazorla, Adrián Tamayo, Jinghai Li, Carmen Ocal, Esther Barrena, Roland Resel, Marta Mas-Torrent","doi":"10.1002/admi.202500599","DOIUrl":"https://doi.org/10.1002/admi.202500599","url":null,"abstract":"This paper reports on the phase transformation occurring in evaporated thin films of the organic semiconductor 2-decyl-7-phenyl[1]benzothieno[3,2-b][1]benzothiophene (Ph-BTBT-10), along with its impact on the performance of organic thin-film field-effect transistors (OFETs). Temperature-dependent X-ray reflectivity (XRR) studies reveal that the films crystallize in a single-layer structure, which converts to a bilayer phase in the temperature range of 110°C –140°C; at further elevated temperatures, a liquid-crystal phase is formed. The conversion of the as-evaporated films to the bilayer structure is investigated by atomic force microscopy (AFM) and Kelvin probe force microscopy (KPFM) at specific annealing temperatures. The combination of XRR, AFM, and KPFM points out that only at the higher annealing temperature the phase transformation is completed. In a subsequent stage, the films are investigated as active layers in OFETs. An enhanced performance is observed in the annealed films with a higher mobility and reduced level of charge traps. The best electrical characteristics are realized when the bilayer transformation is fully accomplished.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 19","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500599","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Highly Efficient Removal of Perfluorooctanoic Acid from Water Using Zirconium Terephthalate (UiO-66) Gel (Adv. Mater. Interfaces 17/2025) 使用对苯二甲酸锆（UiO-66）凝胶（Adv. Mater）高效去除水中全氟辛酸。接口17/2025)

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-09-08 DOI: 10.1002/admi.70135

Giuseppe Di Palma, Pritam Banerjee, Kasper Enemark-Rasmussen, Sara Talebi Deylamani, Joerg R. Jinschek

引用次数: 0

Electrochemical Response of α/β-peptides: Influence of the Peptide Length, Stereochemistry and Self-Assembly on the Performance of Peptide-Based Electrochemical Sensors α/β-肽的电化学响应：肽长度、立体化学和自组装对肽基电化学传感器性能的影响

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-09-08 DOI: 10.1002/admi.202500254

Merve Gul, Dulce A. Quintana-Romero, Adrián Fontana-Escartín, Maria Luisa Gelmi, Maria M. Pérez-Madrigal, Enrica Chiesa, Raffaella Bucci, Carlos Alemán

{"title":"Electrochemical Response of α/β-peptides: Influence of the Peptide Length, Stereochemistry and Self-Assembly on the Performance of Peptide-Based Electrochemical Sensors","authors":"Merve Gul, Dulce A. Quintana-Romero, Adrián Fontana-Escartín, Maria Luisa Gelmi, Maria M. Pérez-Madrigal, Enrica Chiesa, Raffaella Bucci, Carlos Alemán","doi":"10.1002/admi.202500254","DOIUrl":"https://doi.org/10.1002/admi.202500254","url":null,"abstract":"The electrochemical response of α/β-peptides with (L-Ala-β-Fpg)n sequence, where β-Fpg refers to syn 3-amino-2-(2-fluorophenyl)-3-phenylpropanoic acid, has been investigated examining the effects of the peptide length (n = 1–3), the stereochemistry of the β2,3-diaryl-amino acid and their self-assembly. α/β-Peptides have been deposited by drop-casting on a conducting polymer (CP) film, which is previously electropolymerized on a stainless steel conducting substrate. The current-potential response of the CP coated by the different studied peptides suggests that, for α/β-peptides, the role played by the electron transport through intermolecular stacking of aromatic side groups prevails over peptide length and stereochemistry. In order to prove such a hypothesis, the experimental conditions used to achieve an ordered self-assembly are optimized for one of the α/β-peptides. The achieved self-assembled structures, which consist of well-defined long microfibers, considerably improve the electrochemical response of the CP. Finally, the prepared α/β-peptide-based electrodes are used to electrochemically detect the oxidation of nicotinamide adenine dinucleotide (NADH). The analytical parameters are better for electrodes with well-defined peptide microfibers than for uncoated CP, corroborating the importance of π-π stacking interactions in the response of α/β-peptides.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 19","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500254","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

In Situ Monitoring and Electrical Modulation of Cellular Behaviors Directly at the Cell–Electrode Interface (Adv. Mater. Interfaces 17/2025) 直接在细胞-电极界面的细胞行为的原位监测和电调制。接口17/2025)

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-09-08 DOI: 10.1002/admi.70134

Khandoker Asiqur Rahaman, Yeon Jae Chang, Hyeok Kim, Tae Kyoung Lee, Jaeyeon Jun, Min Jung Kim, Jimin Park, Hyung-Seop Han

引用次数: 0

Ultrafast Dynamics of Complete Sb2S3 Solar Cells Unveiled via a Bifacial Architecture 基于双面结构的Sb2S3太阳能电池的超快动力学研究

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-09-08 DOI: 10.1002/admi.202500387

Robert C. Hamburger, Sofia Korenko, Selina Kern, Pascal Büttner, Katharina E. Dehm, Matthew W. Reeves, Ryan W. Crisp, Julien Bachmann, Elizabeth R. Young

{"title":"Ultrafast Dynamics of Complete Sb2S3 Solar Cells Unveiled via a Bifacial Architecture","authors":"Robert C. Hamburger, Sofia Korenko, Selina Kern, Pascal Büttner, Katharina E. Dehm, Matthew W. Reeves, Ryan W. Crisp, Julien Bachmann, Elizabeth R. Young","doi":"10.1002/admi.202500387","DOIUrl":"https://doi.org/10.1002/admi.202500387","url":null,"abstract":"Charge transfer and recombination dynamics are key to understanding and optimizing photovoltaic devices. However, metallic contacts are typically used to fabricate devices, making them incompatible with transmission spectroscopic techniques such as transient absorption spectroscopy (TAS). Omission of the top contact to avoid this issue results in mismatched results and has limited previous work examining the dynamics in thin-film Sb2S3-based devices. In this work, this challenge is overcome by developing a new methodology, adding a protective layer of ZnO over hole transport materials, allowing fabrication of transparent (i.e., bifacial) solar cell devices. Photovoltaic characterization reveals similar J-V curves between reference and bifacial cells. Examination with TAS reveals a modified mechanism that builds off of previously proposed models for similar systems. Optical modeling supports the understanding of several important changes to the mechanism. These results provide a path toward the investigation of photo-driven dynamics under more realistic operating conditions.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 19","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500387","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Balance of Electroplating and Electrophoresis for Construction of Robust Photocatalytic Copper–titanium Dioxide Composite Coating 电镀和电泳平衡制备坚固的光催化铜-二氧化钛复合涂层

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-09-06 DOI: 10.1002/admi.202401022

Xianfeng Luo, Yuefeng Gan, Xiaotao Yang, Yixiao Wang, Hui Yang, Zhenyu Dai, Zhongpeng Zhu, Ye Tian, Lei Jiang

{"title":"Balance of Electroplating and Electrophoresis for Construction of Robust Photocatalytic Copper–titanium Dioxide Composite Coating","authors":"Xianfeng Luo, Yuefeng Gan, Xiaotao Yang, Yixiao Wang, Hui Yang, Zhenyu Dai, Zhongpeng Zhu, Ye Tian, Lei Jiang","doi":"10.1002/admi.202401022","DOIUrl":"https://doi.org/10.1002/admi.202401022","url":null,"abstract":"Cu-TiO2 composite coatings have attracted extensive attention due to their combination of the excellent electrical conductivity and ductility of metals with the unique properties of the reinforcing phases, etc. However, the improvement of wear resistance, interfacial solid content, and photocatalytic activity of composite coatings are remaining challenges. In this work, a Cu-TiO2 composite coating with enhanced wear resistance by electroplating of Cu2+ and electrophoresis of TiO2 nanoparticles is prepared. It is intriguing to find that there is an optimal interfacial solid content of TiO2 for Cu-TiO2 composite coating with low surface roughness at the electroplating voltage of 2.6 V, the pH of 4, the duration of 10 min, and the TiO2 nanoparticle concentration of 1 g L−1. A balance mechanism for electroplating and electrophoresis is proposed indicating the deposition of TiO2 nanoparticles and the reduction of copper ions on the substrate is competitive. Based on the Cu-TiO2 composite coating, the photocatalytic degradation performance of various organic compounds under UV light is studied, indicating increased hardness and significantly enhanced photocatalytic degradation performance. The degradation efficiency and universality of the Cu-TiO2 composite coatings are further explored, revealing that various organic dyes can be effectively degraded to below 5% within 24 h.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 19","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202401022","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Assay System Based on Metabolic Glycoengineering-Enabled Click Chemistry for the Efficient Evaluation of Complement-Regulatory Peptide Coatings on Endothelial Cells 基于代谢糖工程的点击化学检测系统，用于有效评估内皮细胞上的补体调节肽涂层

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-09-05 DOI: 10.1002/admi.202500350

Jannes Felsch, Simona Jacquemai, Shugirshan Suthagar, Haijie Zhao, Alexander John Lander, Said Rabbani, Daniel Ricklin, Ekaterina Umnyakova

{"title":"Assay System Based on Metabolic Glycoengineering-Enabled Click Chemistry for the Efficient Evaluation of Complement-Regulatory Peptide Coatings on Endothelial Cells","authors":"Jannes Felsch, Simona Jacquemai, Shugirshan Suthagar, Haijie Zhao, Alexander John Lander, Said Rabbani, Daniel Ricklin, Ekaterina Umnyakova","doi":"10.1002/admi.202500350","DOIUrl":"https://doi.org/10.1002/admi.202500350","url":null,"abstract":"Protective cell-surface coatings with complement-regulatory activity emerge as promising therapeutic strategies, particularly for preventing thromboinflammatory complications during transplantation. However, their development and in vitro evaluation require specialized assay systems. This study establishes an efficient platform to coat endothelial cells with peptides that recruit the physiological complement regulator factor H (FH) and test their activity. Azide-groups are introduced into cell-surface glycans of human and porcine endothelial cells via metabolic glycoengineering to enable covalent attachment of alkyne-labeled FH-binding peptides via click chemistry. By optimizing the type and concentration of azido-sugars, effective incorporation of accessible click handles can be achieved with minimal impact on cell viability. This approach results in uniform, controllable peptide coatings that efficiently recruit FH from purified sources and human serum to endothelial cell surfaces and enhance their resistance to complement-mediated opsonization. This model not only served as validation for the efficacy of FH-recruiting peptides but also provides a versatile platform to evaluate and optimize various parameters that define coating efficacy and gain insight into mechanisms of complement activation. As such, it may facilitate the screening of modulators and the development of protective coatings for future applications in biomedical or preclinical research.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 19","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500350","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Super-Resolution Microscopy in Tissue Engineering 组织工程中的超分辨率显微镜

IF 4.4 3区材料科学

Advanced Materials Interfaces Pub Date : 2025-09-04 DOI: 10.1002/admi.202500437

Navid Rabiee, Mohammad Akrami-Hasan-Kohal, Sidi A. Bencherif

{"title":"Super-Resolution Microscopy in Tissue Engineering","authors":"Navid Rabiee, Mohammad Akrami-Hasan-Kohal, Sidi A. Bencherif","doi":"10.1002/admi.202500437","DOIUrl":"https://doi.org/10.1002/admi.202500437","url":null,"abstract":"Tissue engineering aims to restore or replace damaged organs using scaffolds, cells, and biomolecules. A key challenge remains: visualizing the intricate cellular and molecular interactions within engineered environments. Traditional imaging methods struggle to capture the nanoscale details essential for understanding stem cell behavior, tissue formation, and cell-scaffold interactions. Super-resolution microscopy (SRM) offers a solution by enabling imaging beyond the diffraction limit, revealing critical nanoscale processes involved in tissue engineering. SRM provides valuable insights into cell adhesion, migration, and differentiation, and facilitates the optimization of scaffold designs by visualizing the organization of cellular components and their relationship to the extracellular matrix. By integrating SRM into preclinical studies, researchers can improve the assessment and development of tissue-engineered constructs, bridging the gap between basic research and clinical applications. Overall, SRM holds substantial promise for accelerating progress in organ regeneration by uncovering previously inaccessible details that drive functional tissue integration.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"12 19","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/admi.202500437","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0