Advanced Materials Interfaces最新文献_第2页

UCST-Responsive PMEGA: From Solution Behavior to Functional Hydrogel Surfaces ucst响应PMEGA：从溶液行为到功能水凝胶表面

IF 4.5 3区材料科学

Advanced Materials Interfaces Pub Date : 2026-10-08 Epub Date: 2026-08-27 DOI: 10.1002/admi.70658

Thi Phuong Thu Nguyen, Léa Milenkovic, Bruno Bresson, Nadège Pantoustier, Yvette Tran

{"title":"UCST-Responsive PMEGA: From Solution Behavior to Functional Hydrogel Surfaces","authors":"Thi Phuong Thu Nguyen, Léa Milenkovic, Bruno Bresson, Nadège Pantoustier, Yvette Tran","doi":"10.1002/admi.70658","DOIUrl":"https://doi.org/10.1002/admi.70658","url":null,"abstract":"Thermoresponsive polymer coatings have attracted considerable attention for applications in materials science, biotechnology, and surface engineering. Materials exhibiting upper critical solution temperature (UCST) behavior remain comparatively underexplored in comparison to lower critical solution temperature (LCST), particularly in the form of structured thin films. The present work illustrates the use of poly(2-(methacryloyloxy)ethylureido glycinamide) (PMEGA) as a versatile UCST-responsive platform for the fabrication of surface-attached hydrogel coatings with controlled architecture and functionality. This polymer, with straightforward monomer synthesis, exhibits a well-defined UCST transition in aqueous solution. Based on thiol–ene click chemistry, the herein presented strategy displays the tunable engineering of homogeneous and microstructured hydrogel films by the cross-linking and grafting (CLAG) approach. This method enables the fabrication of hydrogel coatings with precisely controlled thicknesses, as well as the generation of well-defined micropatterns via UV-induced photolithography like for photoresist. Importantly, the thermoresponsive swelling behavior of the surface-grafted hydrogels can be adjusted by adjusting UV irradiation parameters, providing direct control over the UCST response in confined geometries. Overall, the combination of straightforward polymer synthesis, scalable thin-film processing, and tunable thermo-responsive properties opens new opportunities for the development of advanced functional coatings and microstructured surfaces.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"13 19","pages":""},"PeriodicalIF":4.5,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.70658","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149125925","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Efficient Sunlight Degradation of Wide-Spectrum Antibiotics Through Enhanced Charge Separation in SnTCPP NPs-Nb2C Schottky Heterojunction: Ultrafast Carrier Dynamic Study SnTCPP NPs-Nb2C Schottky异质结中增强电荷分离对广谱抗生素的高效日光降解：超快载流子动态研究

IF 4.5 3区材料科学

Advanced Materials Interfaces Pub Date : 2026-10-08 Epub Date: 2026-09-01 DOI: 10.1002/admi.70588

Juanxuan Guo, Sheng Liao, Ranye Liao, Xinyan Ke, Ming-De Li, Li Dang

{"title":"Efficient Sunlight Degradation of Wide-Spectrum Antibiotics Through Enhanced Charge Separation in SnTCPP NPs-Nb2C Schottky Heterojunction: Ultrafast Carrier Dynamic Study","authors":"Juanxuan Guo, Sheng Liao, Ranye Liao, Xinyan Ke, Ming-De Li, Li Dang","doi":"10.1002/admi.70588","DOIUrl":"https://doi.org/10.1002/admi.70588","url":null,"abstract":"To leverage the synergistic benefits of sunlight-responsive metalloporphyrin complexes and conductive MXene materials, a Schottky heterojunction comprising tin-porphyrin (SnTCPP) nanoparticles (NPs) and Nb2C MXene was rationally constructed. Notably, the SnTCPP NPs-Nb2C Schottky heterojunctions demonstrate exceptional sunlight-driven catalytic activity toward tetracycline antibiotics and ofloxacin degradation, achieving a removal efficiency of up to 99.9% within 60 min of irradiation in both model wastewater and natural water. The unique energy structure of SnTCPP NPs-Nb2C facilitates rapid charge transfer while inhibiting the recombination of photogenerated carriers, thereby enhancing the generation of reactive oxygen species, such as holes and superoxide anion radicals, which are the key factors driving tetracycline antibiotics and ofloxacin degradation. Ultrafast spectroscopic results unveil efficient Schottky junction-mediated ultrafast charge transfer and separation at the SnTCPP NPs-Nb2C interface. The integrated DFT and liquid chromatography-mass spectrometry demonstrated the sequential cleavage of tetracycline's functional groups, including the dimethylamino group, phenolic moiety, and tetracyclic ring structure, ultimately leading to the mineralization of tetracycline into harmless small molecules. Notably, the high degradation efficiency can be maintained over multiple consecutive recycling cycles without significant loss of catalytic activity. These studies pave the way for the rational design of next-generation sunlight-driven heterojunction catalysts for environmental pollutant remediation.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"13 19","pages":""},"PeriodicalIF":4.5,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.70588","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149125766","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Probing the Architecture of Organic Heterojunctions Based on Zn(Salen)-Type/Lu(Bis-phthalocyanine) Complexes and Their Potential Application as Gas Sensors 基于Zn（Salen）型/Lu（双酞菁）配合物的有机异质结结构及其在气体传感器中的潜在应用

IF 4.5 3区材料科学

Advanced Materials Interfaces Pub Date : 2026-10-08 Epub Date: 2026-08-31 DOI: 10.1002/admi.70643

Agostino Attinà, Petr Bečvár, Martin Hruska, Rita Meunier-Prest, Eric Lesniewska, Santo Di Bella, Marcel Bouvet

{"title":"Probing the Architecture of Organic Heterojunctions Based on Zn(Salen)-Type/Lu(Bis-phthalocyanine) Complexes and Their Potential Application as Gas Sensors","authors":"Agostino Attinà, Petr Bečvár, Martin Hruska, Rita Meunier-Prest, Eric Lesniewska, Santo Di Bella, Marcel Bouvet","doi":"10.1002/admi.70643","DOIUrl":"https://doi.org/10.1002/admi.70643","url":null,"abstract":"Organic semiconductor devices based on planar (PHJ) and bulk (BHJ) heterojunctions have attracted considerable interest in recent decades. This work reports the preparation and characterization of heterojunctions based on a Zn(salen)-type complex (ZnL) and lutetium bis-phthalocyanine (LuPc2), either as ZnL/LuPc2 bilayers or ZnL:LuPc2 mixed films deposited on indium tin oxide interdigitated electrodes. Morphological, optical, and electrical properties were investigated by AFM, PeakForce TUNA nanoconductivity mapping, Raman and UV–vis spectroscopy, as well as current–voltage and impedance measurements. Bilayer films exhibited a uniform rough surface, whereas mixed films showed pillar-like or alveolar structures. Raman and AFM analyses revealed homogeneous mixed films containing distinct ZnL and LuPc2 domains. PeakForce TUNA demonstrated that the pillar-like features correspond to highly conductive LuPc2 domains dispersed within a less conductive ZnL matrix, evidencing heterogeneous conductive pathways at the nanoscale. Thermal annealing induced significant changes in the optical and electrical properties of both bilayer and mixed films. The potential of these materials as conductometric ammonia sensors was also examined. At 90 ppm NH3, as-prepared mixed films showed a tenfold higher relative response (−40%) than bilayers (−4.1%). Annealing further enhanced sensor performance for both systems.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"13 19","pages":""},"PeriodicalIF":4.5,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.70643","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149125842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ti3C2Tx MXene/Silver Composite Foams For Lightweight, High-Performance Electromagnetic Interference Shielding and Joule Heating (Adv. Mater. Interfaces 19/2026) 用于轻质、高性能电磁干扰屏蔽和焦耳加热的Ti3C2Tx MXene/银复合泡沫材料接口19/2026)

IF 4.5 3区材料科学

Advanced Materials Interfaces Pub Date : 2026-10-08 DOI: 10.1002/admi.70624

Abdullah A. Mahmood, Mingxuan Li, Vahid Rad, Mehdi Zarei, Chen-Yu Yeh, Masoud Soroush, Guangyong Li, Paul W. Leu

引用次数: 0

Adsorbent Materials for Hydrocarbons Removal by Geopolymerization of Halloysite Clay Nanotubes Filled Within Chitosan Matrix 壳聚糖基质内填充高岭土粘土纳米管的地聚合脱烃吸附材料

IF 4.5 3区材料科学

Advanced Materials Interfaces Pub Date : 2026-10-08 Epub Date: 2026-09-10 DOI: 10.1002/admi.70668

Alessandro Lo Bianco, Marta Giuseppina Ebbreo, Giuseppe Cavallaro, Martina Maria Calvino, Yafei Zhao, Simonpietro Agnello, Giuseppe Lazzara

{"title":"Adsorbent Materials for Hydrocarbons Removal by Geopolymerization of Halloysite Clay Nanotubes Filled Within Chitosan Matrix","authors":"Alessandro Lo Bianco, Marta Giuseppina Ebbreo, Giuseppe Cavallaro, Martina Maria Calvino, Yafei Zhao, Simonpietro Agnello, Giuseppe Lazzara","doi":"10.1002/admi.70668","DOIUrl":"https://doi.org/10.1002/admi.70668","url":null,"abstract":"We propose a protocol for the fabrication of hybrid materials with high adsorption capacity toward aliphatic and aromatic hydrocarbons by alkaline activation of halloysite clay nanotubes filled within a chitosan matrix. First, chitosan/halloysite nanocomposite films with variable composition have been prepared by aqueous casting method. Interestingly, the films have exhibited compactness and robustness although the large halloysite contents (≥30 wt.%) as demonstrated by the elastic modulus and the tensile strength values, which range between 1635–4475 MPa and 5.46–26.5 MPa, respectively. The mesoscopic properties (thermal stability, wettability, and tensile resistance) of the chitosan/halloysite films have been correlated with their morphologies. Then, the chitosan/halloysite films have been immersed in NaOH solution to achieve the alkaline activation of the clay nanotubes. Their successful conversion to geopolymeric materials has been proved by thermogravimetric analysis and FTIR/Raman spectroscopies. Finally, we have investigated the adsorption capacities of chitosan/halloysite (50:50) composite (before and after geopolymerization) toward dodecane vapors and phenol dispersed in water. The geopolymerization process has enhanced hydrocarbon removal by ca. 220% and ca. 50% for dodecane and phenol, respectively. This work highlights that chitosan/halloysite composite films can be easily converted to porous geopolymers suitable for decontamination purposes in vapor and aqueous phases.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"13 19","pages":""},"PeriodicalIF":4.5,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.70668","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149125751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Framework Flexibility on Water Sorption and Transport in ZIF-90: Insights from Neural-Network Molecular Dynamics ZIF-90中水吸附和运输的框架灵活性：来自神经网络分子动力学的见解

IF 4.5 3区材料科学

Advanced Materials Interfaces Pub Date : 2026-10-08 Epub Date: 2026-09-04 DOI: 10.1002/admi.70567

Nick Mackus, Ionut Tranca, Veerapandian Ponnuchamy, Silvia Gaastra-Nedea

{"title":"Framework Flexibility on Water Sorption and Transport in ZIF-90: Insights from Neural-Network Molecular Dynamics","authors":"Nick Mackus, Ionut Tranca, Veerapandian Ponnuchamy, Silvia Gaastra-Nedea","doi":"10.1002/admi.70567","DOIUrl":"https://doi.org/10.1002/admi.70567","url":null,"abstract":"Metal–organic frameworks (MOFs) are promising materials for thermochemical energy storage, yet the role of the flexibility of the framework in governing water adsorption and transport is not adequately understood at the atomistic level. In this work, we employ quantum assisted neural network-based molecular dynamics simulations (DeepMD) to systematically investigate the water uptake, adsorption enthalpies, diffusion coefficients, and structural correlations of a hydrophilic MOF (ZIF-90) with both rigid and flexible frameworks. The simulated results showed that the flexible ZIF-90 exhibits a nearly constant heat of adsorption between –46 and –64 kJ/mol in a wide water loading range (4, 8, 16, 25 and 40 per unit cell), in good agreement with the experimental findings, whereas the rigid framework shows a sharp variation. Similarly, diffusion analysis consistently reveals higher water mobility in the flexible framework, particularly at low and intermediate loadings. The radial distribution functions for key atom pairs (Zn–Ow, O–Hw, O–Ow) show excellent agreement with previous experimental and computational reports, which further validates our simulations. Overall, these findings provide molecular-level insights into the interplay between framework flexibility, adsorption energetics, and transport properties, offering guidance for the rational design of porous materials for thermal energy storage applications.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"13 19","pages":""},"PeriodicalIF":4.5,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.70567","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149125846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Correction to “Region-Selective Growth of Cu2O Shell on Gold Nanoprisms” 修正“Cu2O壳在金纳米片上的区域选择性生长”

IF 4.5 3区材料科学

Advanced Materials Interfaces Pub Date : 2026-10-08 Epub Date: 2026-08-26 DOI: 10.1002/admi.70654

引用次数: 0

Advanced MXene-Based Multifunctional Nanoarchitecture Materials Engineered for Adsorptive Cleanup of Hazardous Radioactive Pollutants: A Comprehensive Critical Review 先进的基于mxeni的多功能纳米结构材料用于有害放射性污染物的吸附清理：综合评述

IF 4.5 3区材料科学

Advanced Materials Interfaces Pub Date : 2026-10-08 Epub Date: 2026-09-02 DOI: 10.1002/admi.70659

Stephen Sunday Emmanuel, Shepherd M. Tichapondwa

{"title":"Advanced MXene-Based Multifunctional Nanoarchitecture Materials Engineered for Adsorptive Cleanup of Hazardous Radioactive Pollutants: A Comprehensive Critical Review","authors":"Stephen Sunday Emmanuel, Shepherd M. Tichapondwa","doi":"10.1002/admi.70659","DOIUrl":"https://doi.org/10.1002/admi.70659","url":null,"abstract":"MXenes, as emerging multifunctional nanomaterials, have attracted the attention of the scientific community in recent years for environmental remediation, including adsorptive cleanup of radio-contaminants due to their important characteristic profile, such as large surface area and structural diversity. Thus, this study aims to review MXenes as functional nanosorbents for the adsorptive elimination of radio-contaminants from simulated radio-wastewater. The goal was to explore research advances, identify trends, provide critical insights, highlight challenges, and underscore interesting future research hotspots. Notably, it was discovered that MXenes have an adsorption capacity of 7.76–1376.75 mg/g, with functionalized MXenes taking the lead, while the number of active sites plays a key role. Furthermore, the key mechanisms governing the adsorption operation were complexation/chelation/coordination, chemisorption, ion exchange, and electrostatic interaction. Overfitting of isotherm and kinetics models was suspected. Findings from cyclic stability studies (reusability up to 2–8 times) and the effect of co-existing pollutants further showed that MXenes have potential for practical uses. Lastly, challenges, research gaps, and potential avenues for further study were discussed. The review work led to an inference that MXene-based adsorption techniques can eco-efficiently remove radio-pollutants from water and nuclear wastewater if given adequate attention.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"13 19","pages":""},"PeriodicalIF":4.5,"publicationDate":"2026-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.70659","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149125836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Correction to “Effect of Mesa Sidewall Angle on 4H-Silicon Carbide Trench Filling Epitaxy Using Trichlorosilane and Hydrogen Chloride” 对“三氯硅烷和氯化氢填充4h -碳化硅沟槽外延的台地侧壁角影响”的修正

IF 4.5 3区材料科学

Advanced Materials Interfaces Pub Date : 2026-10-08 Epub Date: 2026-08-13 DOI: 10.1002/admi.70636

引用次数: 0

Redox-Confined Interfacial Polymerization Enables Mechanically Robust and Self-Adhesive Nanofilms 氧化还原限制界面聚合使机械坚固和自粘纳米膜

IF 4.5 3区材料科学

Advanced Materials Interfaces Pub Date : 2026-09-25 Epub Date: 2026-08-17 DOI: 10.1002/admi.70632

Luana Gazzato, Vivek Manish, Giorgio Speranza, Maria F. Pantano, Marco Frasconi

{"title":"Redox-Confined Interfacial Polymerization Enables Mechanically Robust and Self-Adhesive Nanofilms","authors":"Luana Gazzato, Vivek Manish, Giorgio Speranza, Maria F. Pantano, Marco Frasconi","doi":"10.1002/admi.70632","DOIUrl":"https://doi.org/10.1002/admi.70632","url":null,"abstract":"Robust polymer nanofilms are increasingly important for applications that require mechanically strong yet compliant membranes with nanoscale thickness and intimate interfacial contact. While biological membranes naturally combine flexibility, adaptability, and adhesion, achieving these features in synthetic nanomembranes remains challenging. Here, we report a one-step strategy for the synthesis of centimeter-scale, freestanding nanofilms via redox-confined interfacial polymerization at a liquid-liquid interface. Oxidative coupling of a multifunctional thiol monomer is spatially restricted to the aqueous-organic interface, yielding continuous membranes with precisely tunable thicknesses ranging from tens to hundreds of nanometers. Structural and surface analyses reveal uniform network formation across all film thicknesses, consistent with a diffusion-controlled growth mechanism. The resulting nanofilms exhibit high Young's modulus (425 MPa) and tensile strength (38 MPa), solid-like viscoelastic behavior, and intrinsic adhesion to artificial skin despite the absence of dedicated bioadhesive functionalization. Together, these results establish redox-confined interfacial polymerization as a versatile fabrication route to mechanically robust, freestanding nanomembranes with potential relevance for wearable sensing platforms, therapeutic interfaces, separation membranes, and other applications requiring strong ultrathin films with intrinsic adhesion.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":"13 18","pages":""},"PeriodicalIF":4.5,"publicationDate":"2026-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.70632","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149029079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0