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The oxidation of arc magmas: A critical review 弧岩浆的氧化:一个重要的回顾
IF 1 1区 地球科学
Earth-Science Reviews Pub Date : 2025-09-28 DOI: 10.1016/j.earscirev.2025.105287
Le Wang , Ben-Xun Su , Massimo Chiaradia , Ya-Jing Mao , Ke-Zhang Qin , Ming-Jian Cao
{"title":"The oxidation of arc magmas: A critical review","authors":"Le Wang ,&nbsp;Ben-Xun Su ,&nbsp;Massimo Chiaradia ,&nbsp;Ya-Jing Mao ,&nbsp;Ke-Zhang Qin ,&nbsp;Ming-Jian Cao","doi":"10.1016/j.earscirev.2025.105287","DOIUrl":"10.1016/j.earscirev.2025.105287","url":null,"abstract":"<div><div>Arc magmas are notably more oxidized than those from mid-ocean ridges, back arcs, and mantle plumes, yet the primary controls on this oxidation— source characteristics or magmatic fractionation processes—remain debated. This review synthesizes geochemical data from 56,450 volcanic rocks across 29 Cenozoic arcs and 1242 zircon analyses from 6 Mesozoic-Cenozoic arcs worldwide to clarify the roles of source and fractionation processes in shaping arc magma oxidation states, with a focus on distinctions between continental and oceanic arc settings. We assess oxygen fugacity using Fe<sup>3+</sup>/ΣFe ratios of volcanic rocks at varying MgO contents to evaluate the fractionation effects, while Ti, Ce, and initial U contents in zircons provide insights into oxygen fugacity trends in evolved magmas. High-MgO volcanic rocks (MgO &gt; 8 wt%) reflect the redox state of arc magma sources, whereas low-MgO rocks (MgO &lt; 8 wt%) and zircons reveal fractionation influences. Thermodynamic modeling with MELTS and Monte Carlo mass balance simulations of cumulates and residual melts further constrain the impact of crustal thickness, partial melting, and mineral fractionation on magma oxidation. Our findings indicate that primitive magmas (MgO &gt; 8 wt%) in continental arcs exhibit slightly more oxidized (average Fe<sup>3+</sup>/ΣFe = 0.33 ± 0.01, 1σ) than those in oceanic arcs (averaging 0.30 ± 0.01). Oxidation increases with differentiation, reaching Fe<sup>3+</sup>/ΣFe values of 0.55 ± 0.01 in continental arcs and 0.49 ± 0.01 in oceanic arcs at low MgO contents (&lt; 1 wt%). Zircon data confirm rising oxygen fugacity with decreasing temperature, with a steeper trend in continental arcs. Higher slab-derived fluxes, lower degrees of partial melting, and fractionation of minerals such as garnet and amphibole, driven by greater crustal thickness, enhance oxidation in continental arcs. This review emphasizes the critical role of magma differentiation on oxidation of arc magmas and provides a comprehensive framework for understanding arc magma oxidation, highlighting distinct processes in continental and oceanic arcs and identifying key avenues for future research.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"271 ","pages":"Article 105287"},"PeriodicalIF":10.0,"publicationDate":"2025-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145217920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Controls on the differential enrichment of metal assemblages in post-collisional porphyry mineralization systems, Jinshajiang-Ailaoshan metallogenic belt, SW China 金沙江—哀牢山成矿带碰撞后斑岩成矿体系中金属组合差异富集的控制因素
IF 1 1区 地球科学
Earth-Science Reviews Pub Date : 2025-09-23 DOI: 10.1016/j.earscirev.2025.105285
Haihui Quan, Peng Chai, Zengqian Hou, Lingling Yuan, Chongbin Su
{"title":"Controls on the differential enrichment of metal assemblages in post-collisional porphyry mineralization systems, Jinshajiang-Ailaoshan metallogenic belt, SW China","authors":"Haihui Quan,&nbsp;Peng Chai,&nbsp;Zengqian Hou,&nbsp;Lingling Yuan,&nbsp;Chongbin Su","doi":"10.1016/j.earscirev.2025.105285","DOIUrl":"10.1016/j.earscirev.2025.105285","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Post-collisional porphyry deposits are among the main global sources of copper (Cu), gold (Au), and molybdenum (Mo). However, the controls on metallogenic assemblages in post-collisional porphyry deposits remain poorly constrained. The Jinshajiang-Ailaoshan metallogenic belt hosts a suite of Eocene-Oligocene post-collisional porphyry Cu, Au-Cu, and Au deposits, offering an ideal natural laboratory to elucidate the factors controlling the differential enrichment of metal assemblages in post-collisional porphyry mineralization systems. To identify the primary factors controlling the differential enrichment of metallogenic assemblages, over 2500 published whole-rock and mineral geochemical data from mineralization-related porphyries in post-collisional porphyry deposits of the Jinshajiang-Ailaoshan metallogenic belt were compiled and combined with geophysical and thermodynamic modeling results. The results indicate that the parental magmas of mineralization-related porphyries in the Jinshajiang-Ailaoshan metallogenic belt were generated by variable mixing proportions of juvenile lower-crust melts and underlying metasomatized subcontinental lithospheric mantle (SCLM) melts. Our results demonstrate that the degree of magma differentiation, oxygen fugacity, water contents, and crustal thickness progressively decrease as the metallogenic assemblage transitions from Cu to Au-Cu and finally to Au. Magma undergoes prolonged evolution in lower crustal reservoirs (2.19 kbar) beneath thick crust (60–63 km), exhibiting higher degrees of magma differentiation, oxygen fugacity (∆FMQ = 1.79–2.76), and water contents (3.89 wt% H&lt;sub&gt;2&lt;/sub&gt;O), thereby promoting the formation of post-collisional porphyry Cu deposits. However, higher pressure and water contents promote early sulfide saturation, which in turn causes Au depletion through the precipitation of sulfides. Additionally, high oxygen fugacity (∆FMQ &gt; ∼1.00) suppresses Au dissolution in the magma. In contrast, shallow magma reservoirs (&lt; 1.00 kbar) in thinner crust (33–36 km) undergo brief evolution and are characterized by lower degrees of magma differentiation, oxygen fugacity (∆FMQ = 0.78), and water contents (2.91 wt% H&lt;sub&gt;2&lt;/sub&gt;O). Meanwhile, lower pressures and water contents delayed sulfide saturation, favoring Au enrichment and creating conditions conducive to forming post-collisional porphyry Au deposits. Moreover, moderate degrees of magma differentiation, pressure (1.01–1.64 kbar), water contents (3.29–3.60 wt% H&lt;sub&gt;2&lt;/sub&gt;O), and oxygen fugacity (∆FMQ = 1.22–1.98) in medium-thick crust (42–51 km) collectively promote the simultaneous enrichment of Au and Cu in the magma, providing sufficient metal for the formation of post-collisional porphyry Au-Cu deposits. During fluid exsolution, the salinity of the exsolved fluid decreases with decreasing magma emplacement depth, thereby reducing Cu extraction but enhancing Au extraction from the melt, as Au is primarily transported as bisu","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"271 ","pages":"Article 105285"},"PeriodicalIF":10.0,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145217919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Continental growth in eastern Central Asian Orogenic Belt: Evidence from Middle Permian–Middle Jurassic magmatism 中亚造山带东部大陆生长:来自中二叠统-中侏罗统岩浆活动的证据
IF 1 1区 地球科学
Earth-Science Reviews Pub Date : 2025-09-21 DOI: 10.1016/j.earscirev.2025.105283
Hong-Yan Wang , Jian-Bo Zhou , Peter A. Cawood , Bin Huang , Zi-Yi Zhu , Cheng-Qiang Li , Gong-Yu Li
{"title":"Continental growth in eastern Central Asian Orogenic Belt: Evidence from Middle Permian–Middle Jurassic magmatism","authors":"Hong-Yan Wang ,&nbsp;Jian-Bo Zhou ,&nbsp;Peter A. Cawood ,&nbsp;Bin Huang ,&nbsp;Zi-Yi Zhu ,&nbsp;Cheng-Qiang Li ,&nbsp;Gong-Yu Li","doi":"10.1016/j.earscirev.2025.105283","DOIUrl":"10.1016/j.earscirev.2025.105283","url":null,"abstract":"<div><div>The Zhangguangcai Terrane, Northeast China, provides an ideal site to investigate Phanerozoic continental crustal growth through the Permian to Jurassic tectono-magmatic evolution of Northeast China. A systematic review of the 266–163 Ma magmatic rocks in the Zhangguangcai Terrane, integrating geochronology, geochemical, and whole-rock Sr-Nd and zircon Hf isotopic data, reveals a four-stage magmatic history. Adakitic and I-type rocks characterize the 266–240 Ma magmatic pulse, whereas 229–210 Ma, 209–185 Ma, and 184–163 Ma magmatic rocks exhibit three distinct suites of adakitic, I-type and A-type rocks. Geochemical features are indicative of a lower crustal source, with some mantle-derived materials. The petrogenetic history of these rocks, integrated with temporal changes in crustal thickness and evidence from previous studies, suggests that the tectono-magmatic history of the Zhangguangcai Terrane was dominated by the westward subduction and ultimate closure of the Heilongjiang Ocean. Convergent plate interaction occurred from 266 to 210 Ma, leading to prolonged crustal growth and reworking. A magmatic lull at ca. 240–230 Ma is ascribed to low-angle (or flat-slab) subduction of the Heilongjiang oceanic plate. Closure (209–180 Ma) of the Heilongjiang Ocean and obduction of ocean fragments (180–163 Ma) culminated in the final amalgamation of the Jiamusi-Khanka Block with the Central Asian Orogenic Belt, and the tectonic exhumation and emplacement of blueschist in the Heilongjiang Accretionary Complex. Our analysis of the Zhangguangcai Terrane indicates that it represents a combination of Paleozoic to early Mesozoic accretionary complex and continental arc intruded by multi-stage granites, which contrasts with previous models that argued that it constitutes a Neoproterozoic basement block.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"271 ","pages":"Article 105283"},"PeriodicalIF":10.0,"publicationDate":"2025-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145155506","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-proxy palaeoecological studies from peatlands: a comprehensive review of recent advances and future developments 泥炭地的多代古生态学研究:近期进展和未来发展的综合综述
IF 1 1区 地球科学
Earth-Science Reviews Pub Date : 2025-09-19 DOI: 10.1016/j.earscirev.2025.105278
Mariusz Lamentowicz , Luke Andrews , Sambor Czerwiński , Katarzyna Marcisz
{"title":"Multi-proxy palaeoecological studies from peatlands: a comprehensive review of recent advances and future developments","authors":"Mariusz Lamentowicz ,&nbsp;Luke Andrews ,&nbsp;Sambor Czerwiński ,&nbsp;Katarzyna Marcisz","doi":"10.1016/j.earscirev.2025.105278","DOIUrl":"10.1016/j.earscirev.2025.105278","url":null,"abstract":"<div><div>Multi-proxy approaches in palaeoecological studies have gained prominence due to their ability to provide comprehensive insights into palaeoenvironmental changes. This method enhances the complexity and richness of environmental reconstructions by integrating various proxies, such as testate amoebae, pollen, plant macrofossils, charcoal, and stable isotopes. While synthesising these records can be challenging, due both to their complexity and varying journal guidelines for publication, it remains essential for a more precise understanding of past ecosystems. Multi-proxy studies are invaluable for cross-referencing local to extra-local data with proxies from nearby areas, thus validating palaeoclimatic records and minimising speculative conclusions. The approach reveals significant human impacts on ecosystems, particularly peatlands, serving as natural archives for historical environmental and anthropogenic activities. Integrating diverse methodologies from ecology, palaeoecology, archaeology, and history with high-resolution palaeoecological data offers profound insights into settlement patterns, economic development, and historical demography. Despite the challenges of handling extensive datasets, advanced statistical methods enable meaningful interpretations while maintaining the integrity of the data. Historical records enrich the understanding of human and climatic impacts upon a range of peatland ecosystems. By reconstructing long-term changes in food webs through peat records, researchers can gain a deeper understanding of past ecosystem structures and functions, thereby paving the way for future ecological advances. Though underutilised in archaeological and historical contexts, this interdisciplinary approach has significant potential across various academic fields, emphasising the importance of integrating comprehensive datasets to approach complex ecological questions and inform ecological restoration. This review presents the potential of high-resolution, multi-proxy studies of peatlands, shows examples of such studies and summarises best practices and key considerations for conducting such research.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"271 ","pages":"Article 105278"},"PeriodicalIF":10.0,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145155505","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fracture systems and fluid inclusions in Upper Devonian organic-rich shales in the Western Canada Sedimentary Basin and Rocky Mountains Foreland Belt, West-Central Alberta, Canada 加拿大西部沉积盆地和落基山脉前陆带上泥盆统富有机质页岩裂缝体系及流体包裹体
IF 1 1区 地球科学
Earth-Science Reviews Pub Date : 2025-09-19 DOI: 10.1016/j.earscirev.2025.105282
Elena Konstantinovskaya , Qing He , Don Hall , Wipawon Phiukhao , Matthew Steele-MacInnis , Nicholas B. Harris , Guido Garcia Rodriguez
{"title":"Fracture systems and fluid inclusions in Upper Devonian organic-rich shales in the Western Canada Sedimentary Basin and Rocky Mountains Foreland Belt, West-Central Alberta, Canada","authors":"Elena Konstantinovskaya ,&nbsp;Qing He ,&nbsp;Don Hall ,&nbsp;Wipawon Phiukhao ,&nbsp;Matthew Steele-MacInnis ,&nbsp;Nicholas B. Harris ,&nbsp;Guido Garcia Rodriguez","doi":"10.1016/j.earscirev.2025.105282","DOIUrl":"10.1016/j.earscirev.2025.105282","url":null,"abstract":"<div><div>Unraveling phases of fracture formation and hydrocarbon generation enhances our understanding of the maturation and burial history of organic-rich shales. The Upper Devonian organic-rich shales of the Western Canada Sedimentary Basin (Duvernay Formation) and the Rocky Mountains Foreland belt (Perdrix Formation) experienced distinct structural and burial histories reflected in the orientation and mineralization of developed veins, and the temperature and composition of trapped fluid inclusions. Duvernay shales typically contain vertical and sub-vertical calcite veins with light oil inclusions. The compositions and homogenization temperatures of these inclusions indicate that the trapped fluids are more liquid-rich than the produced fluids and were likely trapped under variable overpressures during fracturing. These inclusions may have formed prior to peak burial (e.g., ∼140 °C), while further burial (maximum &lt;160 °C, at a depth of 4.5 km) resulted in generation of the current reservoir fluid (mostly gas with minor condensate). In contrast, Perdrix shales commonly contain horizontal and sub-horizontal quartz-calcite veins with gas and two-phase aqueous inclusions, where the gas phase is predominantly methane with minor ethane, propane, and benzene indicated by Raman and mass spectrometry. The compositions and temperatures of fluid inclusions in the Perdrix outcrop samples of the Foreland Belt are consistent with highly mature, free-phase thermogenic gas trapped at highly variable temperatures ranging from 180 °C to ≥300 °C (mostly 220–270 °C) and at burial depths of up to 9 km. The results obtained help us analyze the tectonic evolution, stresses, and pressures experienced by the Upper Devonian shales within the mountain ranges and the basin.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"271 ","pages":"Article 105282"},"PeriodicalIF":10.0,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145118933","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review of Ostracoda stable isotopes in palaeoclimate reconstruction on the Tibetan Plateau
IF 1 1区 地球科学
Earth-Science Reviews Pub Date : 2025-09-18 DOI: 10.1016/j.earscirev.2025.105279
Dada Yan , Bernd Wünnemann , Nils Andersen
{"title":"A review of Ostracoda stable isotopes in palaeoclimate reconstruction on the Tibetan Plateau","authors":"Dada Yan ,&nbsp;Bernd Wünnemann ,&nbsp;Nils Andersen","doi":"10.1016/j.earscirev.2025.105279","DOIUrl":"10.1016/j.earscirev.2025.105279","url":null,"abstract":"<div><div>Ostracods in Tibetan Plateau (TP) waters have well-constrained ecological preferences, pronounced with favourable moult season and last-instar shell calcification in summer, their shell (biogenic carbonates) stable isotopes, therefore, have a great potential use as a palaeoclimate indicator, notably on seasonal basis. However, our understanding of the isotopic fractionations in a long record remains elusive, particularly as biocarbonates frequently precipitate out of thermodynamics-based isotopic equilibrium with ambient waters. The knowledge gap arises from the different roles of metabolic and kinetic effects in disequilibrium fractionations, in addition to the impacts of various surface processes in the lake catchment on the input and output of isotopic flux of a lake basin. In this review, we provide a comprehensive overview on multiple factors for value variation of biological carbonate isotopes in terms of ostracods from different lakes over the Tibetan Plateau, to reduce the knowledge gap for future study. We address (1) the ecological preferences of ostracod species used for stable isotope analysis on the TP and the analytical reproducibility error of an individual measurement on several genus/species; (2) multiple factors for different shell isotope values of modern ostracods including metabolic and kinetic effects in disequilibrium fractionations as well as the impacts of in-lake and catchment processes on isotopic signal change in ambient waters; (3) the differences and related indications of stable isotope values of nature and culture modern and fossil ostracods from the same species (<em>Eucypris mareotica</em>); (4) the spatial stable isotope distribution patterns of the reported ostracod populations and their controlling factors in one lake and/or between several lakes through time and (5) different temporal distribution patterns of stable isotopes and their relevant triggers in four selected TP lakes with comparable or incomparable hydrological conditions during a long period of the last 15,000 to 32,000 years. The successful use of difference transformation of stable isotope data from Nam Co Lake for further reconstruction of palaeotemperature anomaly in terms of various seasonal anomalies show a great potential of this tool in palaeoclimate reconstruction at interannual scale in the future.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"271 ","pages":"Article 105279"},"PeriodicalIF":10.0,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145155503","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reappraisal of Eocene climate patterns in East Asia: A synthetic review 东亚始新世气候模式的再评价:一个综合综述
IF 1 1区 地球科学
Earth-Science Reviews Pub Date : 2025-09-17 DOI: 10.1016/j.earscirev.2025.105281
Yulong Xie , Fuli Wu , Yunfa Miao , Liye Yang , Xiaomin Fang
{"title":"Reappraisal of Eocene climate patterns in East Asia: A synthetic review","authors":"Yulong Xie ,&nbsp;Fuli Wu ,&nbsp;Yunfa Miao ,&nbsp;Liye Yang ,&nbsp;Xiaomin Fang","doi":"10.1016/j.earscirev.2025.105281","DOIUrl":"10.1016/j.earscirev.2025.105281","url":null,"abstract":"<div><div>Proxy-based reconstructions and modeling studies have long yielded conflicting patterns for the Eocene East Asian climate, hindering a coherent understanding of its dynamics. The recent discovery of Eocene monsoon-arid climate signatures has reignited debates regarding the spatiotemporal origins and drivers of this system. To resolve these discrepancies, we undertake a synthesis of multi-proxy paleoclimate records from 71 key Eocene sites across China to systematically reevaluate the spatiotemporal evolution of climate patterns in southern, central, and northern China. Our analysis delineates three distinct climatic phases: (1) During the early Eocene, a zonal broad arid-semiarid belt extended across central-southern China (20–40°N), flanked by two humid zones in Hainan Island-southern Tibet (&lt;20°N) and northern China (&gt;40°N), respectively; (2) Subsequently, by the middle Eocene, a humid monsoonal climate advanced northward in southern China (&lt;25°N), while central China remained persistently arid and northern China maintained its humid conditions; (3) During the late Eocene, the humid monsoonal climate in southern China expanded further northward (26–28°N), the eastern part of central China experienced intermittent humid intervals, the western part of central China (northwest China) underwent pronounced aridification, and northern China witnessed a southward expansion of its humid zone into the Bohai Bay Basin. A pivotal climatic reorganization occurred at 41 Ma, characterized by the synchronous intensification of the Asian monsoon in southern China and aridification of the Asian interior, marking the inception of the Asian monsoon-arid system. This study reconciles long-standing inconsistencies by demonstrating that middle–late Eocene humidification in southern China was primarily driven by the intensification of the East Asian (EAM) and South Asian (SAM) monsoons, rather than primarily by latitudinal migrations of the Intertropical Convergence Zone (ITCZ). Central China was predominantly under the influence of subtropical high pressure throughout the Eocene, with episodic monsoonal incursions limited to the late Eocene. Conversely, the hydroclimate of northeast China was predominantly governed by westerlies transporting moisture from the proto-Paratethys Sea, rather than by the EAM. We propose that the evolution of Eocene climate patterns was driven by the combined effects of Tibetan Plateau uplift, the retreat of the proto-Paratethys Sea (a key driver of the climatic shift at 41 Ma), and global cooling. Our findings establish an integrative framework linking tectonic forcing and global change to East Asia's paleoenvironmental evolution, offering pivotal insights into the origins of the modern Asian climate system.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"271 ","pages":"Article 105281"},"PeriodicalIF":10.0,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145107161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geochemical processes and environmental implications of carbon mineralization in basalts: A comprehensive review 玄武岩碳矿化的地球化学过程及其环境意义综述
IF 1 1区 地球科学
Earth-Science Reviews Pub Date : 2025-09-17 DOI: 10.1016/j.earscirev.2025.105260
Shijia Ma , Changyou Xia , Zhihao Gao , Xiaojie Yu , Muxin Liu , Xi Liang
{"title":"Geochemical processes and environmental implications of carbon mineralization in basalts: A comprehensive review","authors":"Shijia Ma ,&nbsp;Changyou Xia ,&nbsp;Zhihao Gao ,&nbsp;Xiaojie Yu ,&nbsp;Muxin Liu ,&nbsp;Xi Liang","doi":"10.1016/j.earscirev.2025.105260","DOIUrl":"10.1016/j.earscirev.2025.105260","url":null,"abstract":"<div><div>The growing urgency to mitigate global warming has driven the development of Carbon Capture, Utilization, and Storage (CCUS) technologies. Among these, carbon mineralization in basalt formations offers a permanent and secure pathway for CO<sub>2</sub> storage. This review synthesizes recent advances in carbon mineralization in basalt, emphasizing geochemical mechanisms, fluid-rock interactions, and environmental implications. Two distinct pathways are identified: dissolved CO<sub>2</sub> injection, which produces uniform reaction fronts via bulk transport, and supercritical CO<sub>2</sub> injection, where thin-film interfacial reactions dominate. Fluid chemistry evolution is strongly temperature-dependent, with systematic trends in pH, Ca, Mg, and Fe concentrations, controlling carbonate and clay precipitation. Porosity and permeability changes reflect a dynamic balance between dissolution-driven pore enlargement and precipitation-induced clogging, with field trials generally showing minimal alteration while laboratory studies reveal contrasting outcomes. Reactive transport models highlight the importance of mineralogical heterogeneity, feedbacks, and chemo-mechanical coupling in governing long-term reservoir behaviour. By linking molecular-scale interfacial reactions with continuum-scale hydrodynamics and petrophysical evolution, this review develops an integrated framework for understanding CO<sub>2</sub>-basalt systems and highlights the importance of mechanistic pathways, temperature-dependent fluid chemistry, and porosity-permeability feedbacks, providing new insights for optimizing injection strategies and improving predictive modelling toward large-scale, environmentally safe basalt carbon mineralization.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"271 ","pages":"Article 105260"},"PeriodicalIF":10.0,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145155502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tsunami versus storms: Diagnostic sedimentary criteria in coastal lakes, lagoons and sinkhole deposits 海啸与风暴:沿海湖泊、泻湖和天坑沉积物的沉积诊断标准
IF 1 1区 地球科学
Earth-Science Reviews Pub Date : 2025-09-15 DOI: 10.1016/j.earscirev.2025.105277
Patrick D. Sharrocks, Jeffrey Peakall, David M. Hodgson, Natasha L.M. Barlow
{"title":"Tsunami versus storms: Diagnostic sedimentary criteria in coastal lakes, lagoons and sinkhole deposits","authors":"Patrick D. Sharrocks,&nbsp;Jeffrey Peakall,&nbsp;David M. Hodgson,&nbsp;Natasha L.M. Barlow","doi":"10.1016/j.earscirev.2025.105277","DOIUrl":"10.1016/j.earscirev.2025.105277","url":null,"abstract":"<div><div>Sedimentary deposits of coastal flooding by tsunamis and storms extend archives of these events across millennia. However, the utility of these records remains clouded by an inability to unequivocally differentiate between a deposit of storm or tsunami origin. This review takes a novel approach by compiling a large integrated dataset of modern and palaeo tsunami and storm deposits in coastal lakes and lagoons to infer the processes that occur during these events. We find that storm and tsunami deposits each comprise three differing groups. Using these groups, we infer the processes involved in tsunamis, including the formation of a sediment gravity flow as the tsunami flows into the lake; the progression of a dense, cohesionless flow head, or the displacement of the shallow lake water by the tsunami wave. In contrast, storm deposits are inferred to be formed by bedload under an overwash regime or in a dilute flow under full inundation of the coastal lake or lagoon. From these processes, we show that the composition of tsunami deposits is dependent on the environmental setting of the lake or lagoon whereas, for storms, the event size is a greater factor. Our findings show that in most cases, storm events are inherently unable to generate the tsunami deposits found in coastal lakes and lagoons. This insight enables the establishment of recognition criteria and a framework that can be applied to candidate deposits to differentiate unequivocally between the two event types. Nonetheless, for some deposits, a differentiation on sedimentology alone is impossible.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"271 ","pages":"Article 105277"},"PeriodicalIF":10.0,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145107162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reaction mechanisms and evolution of pore structure and wettability in the CO2-shale system: A systematic review co2 -页岩体系中孔隙结构和润湿性的反应机制及其演化
IF 1 1区 地球科学
Earth-Science Reviews Pub Date : 2025-09-12 DOI: 10.1016/j.earscirev.2025.105262
Yaxiong Zhang , Qihong Feng , Sen Wang
{"title":"Reaction mechanisms and evolution of pore structure and wettability in the CO2-shale system: A systematic review","authors":"Yaxiong Zhang ,&nbsp;Qihong Feng ,&nbsp;Sen Wang","doi":"10.1016/j.earscirev.2025.105262","DOIUrl":"10.1016/j.earscirev.2025.105262","url":null,"abstract":"<div><div>The geochemical reactions involving CO<sub>2</sub>-water-shale induce significant alterations in reservoir pore permeability characteristics and physical properties through mineral dissolution, clay swelling, and micropore structure evolution, exerting a crucial influence on CO<sub>2</sub>-enhanced shale recovery and its geological storage. This review systematically summarizes the patterns and mechanisms of CO<sub>2</sub>-water-shale geochemical reactions, examines the processes and recent advances in CO<sub>2</sub>-shale geochemical interactions, and clarifies the impact of geochemical reactions on shale properties, including shale mineral dissolution, swelling, erosion, and precipitation triggered by CO<sub>2</sub> injection, and integrates the chemo-mechanical coupling mechanisms as well as multi-scale evolution mechanisms from the perspectives of mineral composition, microstructure, mechanical properties, and wettability. Studies indicate that the spatiotemporal coupling of geochemical reactions (e.g., dissolution and precipitation) and physical processes (e.g., swelling) fundamentally alters shale's pore structure, micro-morphology, and mechanical properties. Meanwhile, this process is jointly regulated by temperature, pressure, and the content and composition of minerals such as clay and carbonate. Furthermore, the review prospects challenges and future development trends concerning CO<sub>2</sub>-shale interactions, providing a detailed theoretical foundation and scientific basis for research on injecting CO<sub>2</sub> into shale reservoirs for enhanced oil recovery.</div></div>","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":"271 ","pages":"Article 105262"},"PeriodicalIF":10.0,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145217918","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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