Shaifali Mishra , Rajesh K. Yadav , Rehana Shahin , Kanchan Sharma , Jin OoK Baeg
{"title":"Rational design and mechanistic insights of a G@DAA photocatalyst for CO₂-driven carboxylation: Sustainable biomass valorization and NADH regeneration in green chemistry","authors":"Shaifali Mishra , Rajesh K. Yadav , Rehana Shahin , Kanchan Sharma , Jin OoK Baeg","doi":"10.1016/j.diamond.2025.112604","DOIUrl":"10.1016/j.diamond.2025.112604","url":null,"abstract":"<div><div>The present study reports the development of an innovative aloe-derived graphene (G) and 2,6-diamino-anthraquinone (DAA)-based artificial photosynthetic system for the efficient conversion and regeneration of biomass-derived furfural (>98.5 %) and the 1,4-NADH co-factor (63.02 % yield and an excellent quantum yield of ~9.34 %). The photocatalyst, designated as G@DAA, was synthesized using diazonium chemistry, integrating G and DAA as key structural components. This newly engineered G@DAA material was further explored for the CO₂-driven carboxylation of arenes and styrenes under metal-free conditions, achieving highly selective carboxylated products with remarkable efficiency (>98 %). These products hold significant potential for application in pharmaceuticals, cosmetics, agriculture, and the food industry. The novelty of the G@DAA catalyst lies in its outstanding properties, including high reusability, sustainability, selectivity, cost-effectiveness, and ease of synthesis. It demonstrates long-lived charge carrier separation, excellent structural stability, and remarkable flexibility. This study underscores the versatility and efficiency of the G@DAA photocatalytic system, presenting it as a promising candidate for solar-driven chemical transformations and contributing to the broader goals of green chemistry, renewable energy utilization, and sustainable biochemical processes.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"158 ","pages":"Article 112604"},"PeriodicalIF":4.3,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144587820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tong Hu , Dongfang Chen , Cheng Chi , Song Hu , Fei Ma , Yuehua Li , Pucheng Pei , Xiaoming Xu
{"title":"High-performance Ag-doped multilayer amorphous carbon coatings on metallic bipolar plates for proton exchange membrane fuel cells","authors":"Tong Hu , Dongfang Chen , Cheng Chi , Song Hu , Fei Ma , Yuehua Li , Pucheng Pei , Xiaoming Xu","doi":"10.1016/j.diamond.2025.112613","DOIUrl":"10.1016/j.diamond.2025.112613","url":null,"abstract":"<div><div>Bipolar plates made from metal substrates exhibit superior malleability and elevated specific power density in comparison to graphite bipolar plate. However, metal substrates are tended to be corroded and oxidized within challenging operational conditions encountered in PEMFCs. In this paper, a new multilayer coating structure that demonstrates a diminished interface contact resistance at 6.15 mΩ·cm<sup>2</sup> and a low corrosion current density at 0.33 μA·cm<sup>−2</sup> is developed. Pure amorphous carbon coating deposited in alternating bias voltage is set as inner layer for its compact structure and Ag-doped amorphous carbon coating is set as outer layer for its high interfacial conductivity. The developed multilayer coating successfully combines the properties of strong anti-corrosion ability and excellent interfacial conductivity. This study presents a new methodology to the design and formulation of coatings intended for metal bipolar plates used in fuel cells, thereby fostering the expeditious advancement of metal bipolar plate technology.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"158 ","pages":"Article 112613"},"PeriodicalIF":4.3,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144634388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Plasma sprayed Cr3C2-NiCr coating with in-situ exfoliated graphene for enhanced corrosion resistance","authors":"Shubhendra Shivam Maurya, Abhishek Kumar Grain, Anup Kumar Keshri","doi":"10.1016/j.diamond.2025.112606","DOIUrl":"10.1016/j.diamond.2025.112606","url":null,"abstract":"<div><div>This study investigates the enhancement of corrosion resistance in Cr<sub>3</sub>C<sub>2</sub>-NiCr coatings through the incorporation of in-situ exfoliated graphene via plasma spraying. Three coating compositions were examined: pure Cr<sub>3</sub>C<sub>2</sub>-NiCr, and those reinforced with 1 wt% and 2 wt% graphene. Electrochemical tests in 3.5 wt% NaCl solution revealed significant improvements in corrosion resistance with graphene addition. The 2 wt% reinforced graphene Cr<sub>3</sub>C<sub>2</sub>-NiCr coating exhibited the highest corrosion potential (−849 mV) and lowest corrosion current density (6.2 μA/cm<sup>2</sup>), resulting in an 93.45 % reduction in corrosion rate compared to the Cr<sub>3</sub>C<sub>2</sub>-NiCr coating. Microstructural and phase analysis revealed a reduction in the average crystallite size from 22.4 nm in Cr<sub>3</sub>C<sub>2</sub>-NiCr to 20.8 nm in 2 wt% graphene reinforced Cr<sub>3</sub>C<sub>2</sub>-NiCr coating, contributing to faster formation of a more uniform and dense protective oxide layer, effectively inhibiting chloride ion penetration. XPS analysis confirmed the formation of a Cr<sub>2</sub>O<sub>3</sub>-rich passivation layer in the 2 wt% graphene reinforced Cr<sub>3</sub>C<sub>2</sub>-NiCr coating. High-magnification FE-SEM images revealed exfoliated graphene filling pores and sandwiching between splats, restricting crack formation. Additionally, the 2 wt% reinforced graphene Cr<sub>3</sub>C<sub>2</sub>-NiCr coating maintained superior adhesion strength (28.87 MPa) and hardness (1285.56 HV) after corrosion exposure. The enhanced performance is attributed to exfoliated graphene's barrier effect, promotion of a protective oxide layer, and preservation of coating integrity. This study demonstrates that in-situ exfoliation of graphene during plasma spraying offers a cost-effective route to producing high-performance corrosion-resistant coatings for harsh environmental applications.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"158 ","pages":"Article 112606"},"PeriodicalIF":4.3,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144557168","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Su-Fang Wang , Zi-Xuan Xin , Li-Yong Chen , You Xie , Yu-Ling Song
{"title":"First-principles study on the regulation of methane adsorption on vacancy defect graphene by uniaxial strain","authors":"Su-Fang Wang , Zi-Xuan Xin , Li-Yong Chen , You Xie , Yu-Ling Song","doi":"10.1016/j.diamond.2025.112605","DOIUrl":"10.1016/j.diamond.2025.112605","url":null,"abstract":"<div><div>Methane (CH<sub>4</sub>) poses challenges for safe and efficient storage and transport as a low-carbon transitional fuel. This study aims to enhance the performance of graphene-based gas sensors via strain. Using the first-principles approach, the effects of uniaxial strain on the adsorption of CH<sub>4</sub> on vacancy graphene (VG/CH<sub>4</sub>) were systematically explored. The results show that the compressive strain induces an interesting enhancement in the adsorption of CH<sub>4</sub> molecular, and improves the sensitivity of VG substrate to CH<sub>4</sub>. Besides, the magnetic moment of the adsorption system can be significantly tuned by applying strain in the substrate. Light absorption of VG with adsorbed methane also shows strain-induced anisotropy, offering crucial insights for optoelectronic device design. These findings improve our understanding of graphene-based gas sensors and suggest new material optimization strategies.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"158 ","pages":"Article 112605"},"PeriodicalIF":4.3,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144571003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhenqing Li, Zhongqi Wei, Xiulin Shang, Di Tang, Zhijun Zhang
{"title":"Molecular dynamics simulation of coal-to-diamond based on reactive force field","authors":"Zhenqing Li, Zhongqi Wei, Xiulin Shang, Di Tang, Zhijun Zhang","doi":"10.1016/j.diamond.2025.112603","DOIUrl":"10.1016/j.diamond.2025.112603","url":null,"abstract":"<div><div>Coal-to-diamond is a new technology for clean utilization of coal, and the development of this technology is of great significance for enhancing the utilization value of coal resources. Using reactive force field molecular dynamics (ReaxFF MD), a detailed study on bituminous coal to diamond have been performed. With the increase of temperature, the pressure of diamond nucleation (<em>P</em><sub>n</sub>) in coal decreases, and compared to graphite, the <em>P</em><sub>n</sub> is higher. The diamond nucleus of coal is hexagonal diamond (HD) category, whereas that of graphite is cubic diamond (CD) category. The conversion ratio of coal to diamond (<em>C</em><sub>d</sub>) is directly proportional to temperature. Following the formation of diamond nucleus in coal, an increase in pressure will prompt coal to enter a transitionary period within the diamond growth stage. During this period, the <em>C</em><sub>d</sub> increased slowly with the increase of pressure. Following transitionary period, the <em>C</em><sub>d</sub> increased significantly with the increase of pressure. At 4000 K and 75.50 GPa, the <em>C</em><sub>d</sub> is 31.75 %, of which CD category accounts for 22.86 %. According to <em>C</em><sub>cd</sub> and <em>C</em><sub>hd</sub>, the conversion process of bituminous coal to diamond at 4000 K can be divided into single-type conversion stage, competition conversion stage, and tendency to the cubic diamond stage.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"158 ","pages":"Article 112603"},"PeriodicalIF":4.3,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144581200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wenxuan Zhao , Feng Xu , Ao Yu , Shengji Zhou , Shuo Sun , Yuan Liu , Dunwen Zuo
{"title":"Morphological evolution mechanism of maskless diamond nanocones via Ar ion etching","authors":"Wenxuan Zhao , Feng Xu , Ao Yu , Shengji Zhou , Shuo Sun , Yuan Liu , Dunwen Zuo","doi":"10.1016/j.diamond.2025.112610","DOIUrl":"10.1016/j.diamond.2025.112610","url":null,"abstract":"<div><div>The exceptional functional properties of diamonds are shaped not only by their intrinsic physical and chemical attributes but also by their surface morphology. In this study, diamond nanocones were fabricated on silicon wafers. The effects of ion quantity and etching time on the morphology of nanocones were investigated. Monte Carlo simulations were employed to model the trajectories of Ar<sup>+</sup> during the etching process, and an ion sputtering model was established to analyze the sputtering phenomena at varying incident angles and quantities. The etching of diamond nanocones is a dynamic process driven by Ar<sup>+</sup> bombardment, where variations in incident angle and ion quantity drive the transition from a dome-like structure to a stable nanocone as the sputtering yield peaks at 76°.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"158 ","pages":"Article 112610"},"PeriodicalIF":4.3,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144571004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yi Zhao , Yu Han , Hongyan Zhang , Bohan Hu , Shukun Qu , Chenxue Miao , Liwei Qin , Guang Song
{"title":"The investigation of the photocatalytic degradation and bio-antimicrobial properties based on the biomass carbon dots and the composite nanofiber membranes of biomass carbon dots and PLA","authors":"Yi Zhao , Yu Han , Hongyan Zhang , Bohan Hu , Shukun Qu , Chenxue Miao , Liwei Qin , Guang Song","doi":"10.1016/j.diamond.2025.112612","DOIUrl":"10.1016/j.diamond.2025.112612","url":null,"abstract":"<div><div>In this study, carbon dots (CDs) were synthesized from <em>zanthoxylum bungeanum</em> (ZB) via a hydrothermal method. The morphology and structure of ZB-based CDs (ZCDs) and nitrogen-doped ZCDs (N-ZCDs) were characterized. The average size of ZCDs is 3.4 ± 0.63 nm with a lattice spacing of 0.22 nm, while, the N-ZCDs was 6.9 ± 1.1 nm with the same lattice spacing. The incorporation of nitrogen significantly enhanced the photocatalytic activity and degradation capability of CDs for methylene blue (MB) under visible light irradiation. Specifically, the photodegradation efficiency increased from 59 % for undoped ZCDs to 76 % for N-ZCDs within 120 min. This improvement is attributed to N-ZCDs generating not only •O<sub>2</sub><sup>−</sup> and h<sup>+</sup> but also <sup>1</sup>O<sub>2</sub> during light exposure. Furthermore, the nanofiber membranes are prepared using the composite of N-ZCDs and polylactic acid (PLA) via electrospinning technology. The N-ZCDs<sub>8</sub>/PLA nanofiber membrane, containing 8 % N-ZCDs, shows significant antibacterial activity against <em>E. coli DH5α</em> and <em>C. albicans</em>, highlighting the potential application of these nanofiber membranes in wound dressings technologies.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"158 ","pages":"Article 112612"},"PeriodicalIF":4.3,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144571006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Temoporfin loaded g-C3N4/CuO nanocarrier for treatment of hypoxic tumors by synergistic chemo-photodynamic therapy","authors":"Saumya , Durgadevi Veeraiyan , Preeti Nanda Sahu , Tapas Patra , Preeti Joshi , Mika Sillanpää , Bhavani Prasad Naik Nenavathu , Akhileshwar Namani , Anik Sen","doi":"10.1016/j.diamond.2025.112607","DOIUrl":"10.1016/j.diamond.2025.112607","url":null,"abstract":"<div><div>A multifunctional nanocarrier is prepared by loading photosensitizer drug Temoporfin on g-C<sub>3</sub>N<sub>4</sub>/CuO (GC) nanocomposites. g-C<sub>3</sub>N<sub>4</sub>/CuO formulation functionalized with folic acid exhibited the drug encapsulation efficiency (%) of 87.8±0.52 %. At pH 5.4, 53.79±0.18% and 75.50±1.25% drug was released from the nanocarrier in the absence and presence of NIR light, respectively. Cytotoxic effects of temoporfin, GC NC, and FA-GC/Tem are studied against human breast cancer (MDA-MB-231) and lung cancer (A549) cell line for 48 h, in a dose-dependent manner. At the concentration of 2.50 mg/mL, g-C<sub>3</sub>N<sub>4</sub>/CuO nanocomposite treated MDA-MB-231 showed cell viability of 6.99% and 15.96% with and without NIR irradiation, respectively. Whereas, Tem loaded FA-GC, the cell viability was observed to be 2.48% and 18.09% respectively. The IC<sub>50</sub> values of Tem, GC, and Tem-loaded FA-GC are 0.46, 5.13, and 118.95 μg/mL in the presence of NIR light. Besides, IC<sub>50</sub> without NIR exposure are found to be 4.90, 44.6, and 594.28 μg/mL, respectively. Lung cancer (A549) cell line treated with 2.5 mg/mL concentration of GC and Tem loaded FA-GC showed 3.18 % and 10.40% cell viability. The biocompatibility of the Tem-loaded FA-GC towards the immortalized human keratinocyte (HaCaT) Cell line is also confirmed. In silico experiments are carried out to study the interaction between g-C<sub>3</sub>N<sub>4</sub>/CuO with cancer proliferation proteins like EGFR (Kinase inhibitors), HCA (Human Carbonic Anhydrase), and Akt1 (Protein kinase B). The diphenylisobenzofuran (DPBF) assay and Terephthalic acid assay proved the generation of singlet oxygen and OH* radicals respectively, which play an important role in anticancer activity.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"158 ","pages":"Article 112607"},"PeriodicalIF":4.3,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144634390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wenlong Zhang , Jing Jia , Chencheng Liu , Peng Sun , Yuezhong Wang , Yi Zhu , Tong Zhu , Qingwei Yan , Wei Zhang , Hui Song , Cheng-Te Lin , Kazuhito Nishimura , Huasong Liu , Nan Jiang
{"title":"Simulation of the thermo-mechanical coupling results of diamond to rival traditional infrared windows under the effects of gas film cooling","authors":"Wenlong Zhang , Jing Jia , Chencheng Liu , Peng Sun , Yuezhong Wang , Yi Zhu , Tong Zhu , Qingwei Yan , Wei Zhang , Hui Song , Cheng-Te Lin , Kazuhito Nishimura , Huasong Liu , Nan Jiang","doi":"10.1016/j.diamond.2025.112608","DOIUrl":"10.1016/j.diamond.2025.112608","url":null,"abstract":"<div><div>For high-speed aircraft, the lateral slot gas film could be adopted to cool the infrared (IR) window, thereby overcoming the thermal shock damage caused by aerodynamic heating. In this paper, ANSYS software was employed to simulate the thermo-mechanical coupling behavior induced by gas film cooling for three typical IR windows, namely diamond, sapphire, and zinc sulfide (ZnS). The cooling gases employed in the study were nitrogen (N₂), helium (He), and argon (Ar). The simulation results showed that the central temperatures for all windows remained within ∼95–380 °C at the heat flux densities of 0.5–2.0 MW/m<sup>2</sup>. At higher heat flux densities of 2.0–4.0 MW/m<sup>2</sup>, only by using He as the cooling gas could more effectively decrease the temperature of sapphire and ZnS to suitable values of ∼286–317 °C and ∼362–410 °C for normal imaging temperature ranges, respectively. Diamond exhibited negligible stress (<93 MPa) and strain (<0.5 %) across all tested heat flux densities. Under the highest heat flux densities (4.0–6.0 MW/m<sup>2</sup>), the traditional sapphire and ZnS windows could fail due to excessive temperature (>600 °C) and stress (>300 MPa). Notably, diamonds demonstrated superior thermo-mechanical performance across all investigated heat flux density conditions, exhibiting optimal stress distribution and thermal stability. It suggested that gas film cooling was a suitable method to enhance the survivability of IR windows. Perfect cooling effects could be obtained by using coolant gas with a high specific heat capacity and IR material with a high thermal conductivity. The present study could provide critical insights into the material selection and cooling strategy optimization for hypersonic vehicle design.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"158 ","pages":"Article 112608"},"PeriodicalIF":4.3,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144572232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Niranjan Patra , Prathipati Ramesh , Gudiguntla Ravi , Ștefan Țălu
{"title":"Electroless deposition of nanoscale Ni-Co-Fe-P coatings on carbon fibers for multifunctional applications","authors":"Niranjan Patra , Prathipati Ramesh , Gudiguntla Ravi , Ștefan Țălu","doi":"10.1016/j.diamond.2025.112602","DOIUrl":"10.1016/j.diamond.2025.112602","url":null,"abstract":"<div><div>This study investigates the electroless deposition of Ni-Co-Fe-P quaternary alloy coatings on carbon fibers and evaluates their structural, thermal, and magnetic properties. SEM and EDX analyses confirm a uniform, nanoscale coating with a homogeneous distribution of Ni, Co, Fe, and P. XRD analysis reveals an amorphous or nanocrystalline structure, ensuring improved corrosion resistance and mechanical stability. Magnetization studies indicate enhanced ferromagnetic behavior, making the coated fibers suitable for EMI shielding and magnetically responsive applications. TGA and DTA analyses demonstrate a significant increase in oxidation resistance, with phase transformations leading to the formation of Ni₃P and Co₂P intermetallic compounds, contributing to superior thermal stability. These findings highlight the potential of Ni-Co-Fe-P-coated carbon fibers for aerospace, electromagnetic shielding, and high-performance composite applications. Future work will focus on optimizing phase transformations and mechanical durability for broader industrial applications.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"158 ","pages":"Article 112602"},"PeriodicalIF":4.3,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144534803","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}