Composites Communications最新文献

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Anisotropic nanocomposite double network anti-freezing hydrogels with superior conductivity, high stretchability, and excellent resilience for wearable sensors 各向异性纳米复合双网抗冻水凝胶具有优异的导电性、高拉伸性和优异的可穿戴传感器回弹性
IF 7.7 2区 材料科学
Composites Communications Pub Date : 2025-08-23 DOI: 10.1016/j.coco.2025.102566
Yajie Li, Yushu Liu, Fangzheng Zuo, Zhuoyou Gao, Jiali Zhang, Xin Wen, Hongzan Song
{"title":"Anisotropic nanocomposite double network anti-freezing hydrogels with superior conductivity, high stretchability, and excellent resilience for wearable sensors","authors":"Yajie Li,&nbsp;Yushu Liu,&nbsp;Fangzheng Zuo,&nbsp;Zhuoyou Gao,&nbsp;Jiali Zhang,&nbsp;Xin Wen,&nbsp;Hongzan Song","doi":"10.1016/j.coco.2025.102566","DOIUrl":"10.1016/j.coco.2025.102566","url":null,"abstract":"<div><div>Hydrogel-based artificial ionic skin (I-skin) has gained significant attention in the fields of flexible sensor and intelligent sensing due to their skin-like physicochemical properties and sensory capabilities. Nevertheless, the simultaneous design of conductive hydrogels that exhibit high mechanical strength, exceptional ionic conductivity, and anisotropic structures remains a considerable challenge. Herein, attapulgite (ATP) nanorods-containing nanocomposite double-network anisotropic hydrogels are fabricated by using a two-step technique of primary photopolymerization followed by secondary freezing-thawing method. The synergistic effect of the first polyelectrolyte chemical network of highly charged poly(AMPS-Na) and the second physical network of polyvinyl alcohol (PVA) and ATP embedding endow the hydrogel with high tensile/compressive strength (0.73/2.85 MPa), excellent stretchability (1200 %), good toughness (2.6 MJ/m<sup>3</sup>), remarkable resilience, and unique optical anisotropy. Additionally, ZnCl<sub>2</sub> as an effective anti-freezing and conducting agent enhances the freezing tolerance to −102 °C and significantly improves the conductivity to 43 mS/cm. The as-prepared hydrogel-based flexible sensors show fast responsibility, widely sensing range, good durability, and excellent tensile strain/compressive deformation/temperature sensitivity. Furthermore, these flexible sensors are capable of detecting various body movements and working effectively at extremely low temperatures. Consequently, this research provides novel insights into the design of anisotropic hydrogel materials for high-performance wearable flexible devices.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"59 ","pages":"Article 102566"},"PeriodicalIF":7.7,"publicationDate":"2025-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144903102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An acoustic emission-based characterisation of intrinsically healing fibre-reinforced polymer composites 基于声发射的内在愈合纤维增强聚合物复合材料的表征
IF 7.7 2区 材料科学
Composites Communications Pub Date : 2025-08-21 DOI: 10.1016/j.coco.2025.102563
Claudia Barile, Giovanni Pappalettera, Vimalathithan Paramsamy Kannan
{"title":"An acoustic emission-based characterisation of intrinsically healing fibre-reinforced polymer composites","authors":"Claudia Barile,&nbsp;Giovanni Pappalettera,&nbsp;Vimalathithan Paramsamy Kannan","doi":"10.1016/j.coco.2025.102563","DOIUrl":"10.1016/j.coco.2025.102563","url":null,"abstract":"<div><div>In this research work, two configurations of intrinsically healing carbon fibre-reinforced polymer matrix composites (CFRP) are analysed. Non-localised damage states are created in these composites and the recovery of their flexural properties is analysed. The results show that the tangent and chord moduli are recovered in the composites with unidirectional fibre configuration, whereas they are not recovered in the composites with twill-weave fibre configuration. The results show that the fibre architecture plays a key role in the healability of the CFRP composites. Acoustic emission (AE) testing is used to analyse the damage progression in these composites and its subsequent effect on the healability. In this context, parameter-based data classification using k-means++ and signal-based analysis using continuous wavelet transform (CWT) are used. The results show that the multimode failure and excessive resin bleed in the twill-weave composites are responsible for their poor recovery of flexural moduli. Nevertheless, the results also show the potential of the unidirectional composites in the self-healing applications.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"59 ","pages":"Article 102563"},"PeriodicalIF":7.7,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144894820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrical monitoring of structural health of laminated composite panels under compressive loading using carbon nanotube yarns 压缩载荷作用下复合材料层合板结构健康的碳纳米管纱线电气监测
IF 7.7 2区 材料科学
Composites Communications Pub Date : 2025-08-21 DOI: 10.1016/j.coco.2025.102565
C. Pérez-Aranda , M. Rivero-Ayala , C. Falla , F. Gamboa , F. Avilés
{"title":"Electrical monitoring of structural health of laminated composite panels under compressive loading using carbon nanotube yarns","authors":"C. Pérez-Aranda ,&nbsp;M. Rivero-Ayala ,&nbsp;C. Falla ,&nbsp;F. Gamboa ,&nbsp;F. Avilés","doi":"10.1016/j.coco.2025.102565","DOIUrl":"10.1016/j.coco.2025.102565","url":null,"abstract":"<div><div>A 2 × 2 array of carbon nanotube yarns (CNTYs) was integrated into 10 cm × 10 cm laminated composite panels made of E-glass fiber weaves and a vinyl ester resin to electrically monitor structural health under monotonic and cyclic compression loading. An artificial debond was introduced at the center of selected panels to deliberately trigger localized damage, to better evaluate the damage location capability of the electrical technique using the CNTY array. In panels without debond, damage was localized near the load introduction (upper) edge. In panels with a circular debond, major fiber breakage and delamination occurred near the lateral vicinity of the debond. Real-time concurrent tracking of the CNTY array's electrical resistance combined with an algorithm for data reduction proved to be an effective diagnosis tool for detecting and localizing damage onset and progression, with only four CNTYs. This method accurately identified critical damage zones, which were confirmed by digital image correlation. These findings demonstrate the potential of CNTYs for non-invasive, real-time structural health monitoring without compromising mechanical performance, suggesting promising applications in aerospace, automotive, biomedical, and civil engineering industries.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"59 ","pages":"Article 102565"},"PeriodicalIF":7.7,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144917601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrotunable interfacial friction of polyacrylamide composite hydrogels 聚丙烯酰胺复合水凝胶的电可调界面摩擦
IF 7.7 2区 材料科学
Composites Communications Pub Date : 2025-08-16 DOI: 10.1016/j.coco.2025.102562
Zhongnan Wang , Meiqi Zhang , Xu Zhang , Yao Hu , Beiji Gao , Wanxing Xu , Hongjiang He , Xiaolei Li , Zhaoyu Wang , Peisan (Sharel) E , Bo Gao , Bin Wang , Qiuying Chang , Haihui Lan , Tianyi Han , Chenhui Zhang
{"title":"Electrotunable interfacial friction of polyacrylamide composite hydrogels","authors":"Zhongnan Wang ,&nbsp;Meiqi Zhang ,&nbsp;Xu Zhang ,&nbsp;Yao Hu ,&nbsp;Beiji Gao ,&nbsp;Wanxing Xu ,&nbsp;Hongjiang He ,&nbsp;Xiaolei Li ,&nbsp;Zhaoyu Wang ,&nbsp;Peisan (Sharel) E ,&nbsp;Bo Gao ,&nbsp;Bin Wang ,&nbsp;Qiuying Chang ,&nbsp;Haihui Lan ,&nbsp;Tianyi Han ,&nbsp;Chenhui Zhang","doi":"10.1016/j.coco.2025.102562","DOIUrl":"10.1016/j.coco.2025.102562","url":null,"abstract":"<div><div>Hydrogels exhibit the significant application potential in flexible electronics, biomedical engineering, lubrication technology, robotics, and related fields. The electrotunable interfacial friction of hydrogels provides a conceptual framework for developing intelligent materials. Here, the polyacrylamide (PAAm) composite hydrogels were synthesized via photopolymerization using acrylamide as the monomers. The tribological tests under applied electric potential were conducted using PAAm composite hydrogel discs and silicon nitride balls as the friction pairs, showing the effects of sliding velocity and lubricants on the electrotunable interfacial friction behaviors of the PAAm composite hydrogels. The applied electric potential serves as a critical determinant governing the friction coefficient which is primarily attributed to (1) the differential diffusion kinetics of weakly bound water and non-bound water within the cross-linked polymer networks, and (2) the formation of hydrated cationic layers via strong electro-adsorption of hydrated cations at the interfaces. The findings provide the profound insights into the electrically modulated lubrication mechanisms of the soft contact interfaces from a combined perspective of intrinsic polymer network properties and lubricating molecule-surface interactions.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"59 ","pages":"Article 102562"},"PeriodicalIF":7.7,"publicationDate":"2025-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144889474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-parameter prediction and yarn interlacing behavior simulation in the step-by-step three-dimensional rotatry braiding process 分步三维旋转编织过程中的多参数预测及纱线交织行为模拟
IF 7.7 2区 材料科学
Composites Communications Pub Date : 2025-08-13 DOI: 10.1016/j.coco.2025.102560
Jiale Liu, Yicen Gao, Zhongde Shan, Zheng Sun, Zitong Guo, Xiangyu Zhu
{"title":"Multi-parameter prediction and yarn interlacing behavior simulation in the step-by-step three-dimensional rotatry braiding process","authors":"Jiale Liu,&nbsp;Yicen Gao,&nbsp;Zhongde Shan,&nbsp;Zheng Sun,&nbsp;Zitong Guo,&nbsp;Xiangyu Zhu","doi":"10.1016/j.coco.2025.102560","DOIUrl":"10.1016/j.coco.2025.102560","url":null,"abstract":"<div><div>To address the issues of parameter design iteration and high experimental costs in the manufacturing process of three-dimensional rotary braiding, this study proposes a mechanically enhanced kinematic model capable of efficiently simulating yarn interlacing behavior and predicting braiding parameters. The model integrates process parameters such as yarn tension, initial convergence zone length, and braiding pitch. Based on the dynamic analysis of yarn slippage and interaction forces, it achieves precise predictions of pattern formation, braiding angle, and convergence zone length. The model exhibits high computational efficiency, completing the process simulation of the braiding procedure within a few minutes, thereby verifying its applicability in complex three-dimensional braiding processes. This study provides a theoretical foundation and practical guidance for optimizing composite materials' three-dimensional stepwise braiding process.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"59 ","pages":"Article 102560"},"PeriodicalIF":7.7,"publicationDate":"2025-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144858131","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance piezoresistive sensor based on indium tin oxide nanoparticles/cellulose nanofiber composite for human activity monitoring 基于氧化铟锡纳米颗粒/纤维素纳米纤维复合材料的高性能压阻式人体活动监测传感器
IF 7.7 2区 材料科学
Composites Communications Pub Date : 2025-08-12 DOI: 10.1016/j.coco.2025.102544
Pengju Huang , Yiming Cai , Qianzhao Jia , Yang Yang , Tao Yue , Songyi Zhong
{"title":"High-performance piezoresistive sensor based on indium tin oxide nanoparticles/cellulose nanofiber composite for human activity monitoring","authors":"Pengju Huang ,&nbsp;Yiming Cai ,&nbsp;Qianzhao Jia ,&nbsp;Yang Yang ,&nbsp;Tao Yue ,&nbsp;Songyi Zhong","doi":"10.1016/j.coco.2025.102544","DOIUrl":"10.1016/j.coco.2025.102544","url":null,"abstract":"<div><div>The rapid growth of wearable technologies demands the development of flexible, high-performance, and environmentally sustainable pressure sensors. However, the fabrication of environmentally friendly and excellent performance pressure sensors using simple and cost-effective methods remains a great challenge. Herein, we develop a novel piezoresistive sensor based on indium tin oxide nanoparticles (ITO NPs)/cellulose nanofibers (CNF) composite, where the sustainability advantage originates from the biodegradable CNF substrate. The sensor is fabricated by sandwiching conductive ITO NPs/CNF composite film between a polyimide encapsulation layer and a paper-based interdigitated electrode. It demonstrates a wide sensing range (0–125 kPa), high sensitivity (1715.35 kPa<sup>−1</sup>), rapid response time (37.82 ms), and exceptional cyclic stability (over 5000 cycles). Moreover, the sensor demonstrates the capability to detect both large and subtle human movements, as well as spatial pressure distribution, showing great potential for applications in wearable electronics.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"59 ","pages":"Article 102544"},"PeriodicalIF":7.7,"publicationDate":"2025-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144866937","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanism of nanoscale TiB whisker improving the high-temperature strength and plasticity of TA15 matrix composite 纳米TiB晶须提高TA15基复合材料高温强度和塑性的机理
IF 7.7 2区 材料科学
Composites Communications Pub Date : 2025-08-12 DOI: 10.1016/j.coco.2025.102559
Siyu Tian , Yu Zhang , Ziyuan Jia , Qiyuan Yu , Huan Zhang , Lujun Huang , Shuai Wang , Lin Geng
{"title":"Mechanism of nanoscale TiB whisker improving the high-temperature strength and plasticity of TA15 matrix composite","authors":"Siyu Tian ,&nbsp;Yu Zhang ,&nbsp;Ziyuan Jia ,&nbsp;Qiyuan Yu ,&nbsp;Huan Zhang ,&nbsp;Lujun Huang ,&nbsp;Shuai Wang ,&nbsp;Lin Geng","doi":"10.1016/j.coco.2025.102559","DOIUrl":"10.1016/j.coco.2025.102559","url":null,"abstract":"<div><div>This study employs low-energy ball milling with hot press sintering technique to fabricate network-structure TA15 matrix composites with TiB<sub>2</sub> of different sizes (5 μm, 0.5 μm, and 100 nm). For 5 μm or 0.5 μm TiB<sub>2</sub>, in-situ synthesized TiB whisker (TiBw) exhibit rod-like morphology with aspect ratio of 7.8 or 7.5, forming quasi-continuous networks at primary β phase boundaries to induce heterogeneous nucleation of primary α (α<sub>p</sub>). Their room-temperature yield strength and elongation are 890 MPa and 7.7 %, 896 MPa and 8.2 %, respectively. Meanwhile, their high-temperature strength at 600 °C is 518 MPa and 543 MPa. However, when the size of TiB<sub>2</sub> is reduced to 100 nm, TiBw exhibited a much smaller diameter accompanied by a remarkably high average aspect ratio of 16.2, leading to the formation of a needle-like morphology. The morphological transformation of TiBw is governed by its nucleation sites and the concentration gradient of B atomic diffusion. This needle TiBw/TA15 composite exhibits a very good room-temperature yield strength of 1135 MPa and high-temperature properties of 589 MPa in strength and 16.4 % in fracture strain at 600 °C. The enhanced high-temperature elongation stems from TA15 matrix softening, which reduces crack propagation resistance and promotes crack deflection into the matrix.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"59 ","pages":"Article 102559"},"PeriodicalIF":7.7,"publicationDate":"2025-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144886257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Porous single-layer thermoplastic polyurethane triboelectric nanogenerator prepared by supercritical carbon dioxide foaming for efficient energy harvesting and sensing 采用超临界二氧化碳发泡制备多孔单层热塑性聚氨酯摩擦电纳米发电机,用于高效能量收集和传感
IF 7.7 2区 材料科学
Composites Communications Pub Date : 2025-08-12 DOI: 10.1016/j.coco.2025.102561
Wenyu Ma , Tianyu Jiao , Xiaohu Bing , Xueyun Li , Peng Gao , Long Wang
{"title":"Porous single-layer thermoplastic polyurethane triboelectric nanogenerator prepared by supercritical carbon dioxide foaming for efficient energy harvesting and sensing","authors":"Wenyu Ma ,&nbsp;Tianyu Jiao ,&nbsp;Xiaohu Bing ,&nbsp;Xueyun Li ,&nbsp;Peng Gao ,&nbsp;Long Wang","doi":"10.1016/j.coco.2025.102561","DOIUrl":"10.1016/j.coco.2025.102561","url":null,"abstract":"<div><div>The challenges in the complex structure and preparation method for triboelectric nanogenerators (TENGs) currently hinder their widespread application. In this study, the thermoplastic polyurethane (TPU) foam-based single-layer TENGs were developed. The excellent dispersion of carbon nanostructure (CNS) in TPU improves the cell structures, dielectric constant and conductivity of TPU foams. The cell size reaches 4.15 μm and the dielectric constant of TPU foam increases from 12 to 4678. The improved dielectric properties and conductivity of TPU foams enhance the output performance of single-layer TENGs. The maximum output voltage of the TPU foam-based single-layer TENGs is 15 V. The short-circuit current of the TENGs reaches 90 nA. This work presents a TPU foam-based TENGs characterized by a simple structure and straightforward preparation process.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"59 ","pages":"Article 102561"},"PeriodicalIF":7.7,"publicationDate":"2025-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144842495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Coaxially electrospun PCDA-ZnO nanofibrous membranes with UV protection for high-temperature reversible thermochromism and colorimetric response to lactic acid 同轴静电纺PCDA-ZnO纳米纤维膜的高温可逆热致变色及对乳酸的比色响应
IF 7.7 2区 材料科学
Composites Communications Pub Date : 2025-08-11 DOI: 10.1016/j.coco.2025.102557
Xidi Liu , Pan Wang , Yang Xiang , Zixin Zhao , Haoqian Guo , Boli Yang , Kui Li , Ying Li , Zhongxiang Bai , Xulin Yang , Kun Jia
{"title":"Coaxially electrospun PCDA-ZnO nanofibrous membranes with UV protection for high-temperature reversible thermochromism and colorimetric response to lactic acid","authors":"Xidi Liu ,&nbsp;Pan Wang ,&nbsp;Yang Xiang ,&nbsp;Zixin Zhao ,&nbsp;Haoqian Guo ,&nbsp;Boli Yang ,&nbsp;Kui Li ,&nbsp;Ying Li ,&nbsp;Zhongxiang Bai ,&nbsp;Xulin Yang ,&nbsp;Kun Jia","doi":"10.1016/j.coco.2025.102557","DOIUrl":"10.1016/j.coco.2025.102557","url":null,"abstract":"<div><div>Various colorimetric sensing materials have been developed based on polydiacetylene (PDA), however, their sensing performance is limited by conventional low-temperature responsiveness and irreversibility. This study integrates a conventional PDA monomer, 10, 12-pentacosadiynoic acid (PCDA), with ZnO to fabricate core-shell structural PCDA-ZnO nanofibrous membranes by coaxial electrospinning technology. Here, PCDA-ZnO membranes demonstrated a thermochromic range of 100–210 °C, with reversibility observed below 170 °C. Additionally, the PCDA in the core is protected from short-term ultraviolet (UV) exposure by the inclusion of UV absorbers, ZnO, in the shell layer, thus preventing discoloration during storage. The coordination bond between polymerized PCDA (poly(PCDA)) and ZnO endows the nanofibrous membranes with the response capability to lactic acid solutions. The sensitivity of PCDA-ZnO membranes to lactic acid solutions fluctuates according to the ZnO concentration. Special high-performance polyarylene ether nitrile (PEN) was employed as the substrate material for PCDA to fabricated shell component, which enhances the stability of nanofibrous membranes under high-temperature, and corrosion, while also regulating the maximum reversible thermochromic temperature of the PCDA-ZnO membrane. The developed core-shell PCDA-ZnO nanofibrous membranes enhance the colorimetric response efficacy of PDA-based colorimetric sensors.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"59 ","pages":"Article 102557"},"PeriodicalIF":7.7,"publicationDate":"2025-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144866936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A smart epoxy coating based on Zn-imidazole metal-organic framework/graphene oxide nanocomposite for corrosion protection 基于锌-咪唑金属-有机骨架/氧化石墨烯纳米复合材料的智能环氧防腐涂层
IF 7.7 2区 材料科学
Composites Communications Pub Date : 2025-08-11 DOI: 10.1016/j.coco.2025.102556
Danial Hayati, Shahram Ghasemi, Moslem Mansour Lakouraj, Farimah Mousavi
{"title":"A smart epoxy coating based on Zn-imidazole metal-organic framework/graphene oxide nanocomposite for corrosion protection","authors":"Danial Hayati,&nbsp;Shahram Ghasemi,&nbsp;Moslem Mansour Lakouraj,&nbsp;Farimah Mousavi","doi":"10.1016/j.coco.2025.102556","DOIUrl":"10.1016/j.coco.2025.102556","url":null,"abstract":"<div><div>Developing smart coatings for metal substrates is increasingly significant for advancing corrosion protection technologies. This study focuses on reinforcing epoxy polymer coating using a nanocomposite consisting of graphene oxide (GO) nanosheets and polyhedron zeolitic imidazolate framework-8 (ZIF-8) impregnated with benzotriazole (BTA) inhibitor. Morphological and structural analyses were conducted using transmission electron microscopy (TEM) and field-emission scanning electron microscopy (FE-SEM) coupled with energy dispersive X-ray spectroscopy (EDS). X-ray diffraction (XRD) patterns have demonstrated the crystalline structure of the samples and the reasonable synthesis route for the GO/ZIF-8/BTA nanocomposite. Fourier-transform infrared (FTIR), Raman, and X-ray photoelectron (XPS) spectroscopies have identified various oxygen- and nitrogen-containing functional groups in the nanocomposite as possible bonding sites to metal surfaces and enhance the corrosion protection of the film. The claim was further confirmed using density functional theory (DFT). The N<sub>2</sub> adsorption/desorption results declared a superior specific surface area of 1761 m<sup>2</sup> g<sup>−1</sup> for the ZIF-8 sample, providing a high amount of accessible micropores to store BTA molecules. Diverse samples of epoxy (EP) films were loaded with under-study materials and coated on steel (ST) blades. They were subjected to a series of experiments, including FE-SEM, EDS, elemental mapping, contact angle measurement, salt spray testing, Tafel polarization, and electrochemical impedance spectroscopy (EIS). The optimized ST/GO/ZIF-8/BTA/EP sample exhibited an open-circuit potential of −280 mV, a corrosion current density of 0.02 μA cm<sup>−2</sup>, and a charge-transfer resistance of 54.50 kΩ cm<sup>2</sup>, indicating 99 % improvement over ST/EP. The study revealed reliable long-term anticorrosion performance of GO/ZIF-8/BTA/EP film to protect metal surfaces.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"59 ","pages":"Article 102556"},"PeriodicalIF":7.7,"publicationDate":"2025-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144886311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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