Colloid and Interface Science Communications最新文献

筛选
英文 中文
From dairy waste to value-added bio-based surfactants 从乳制品废料到高附加值的生物基表面活性剂
IF 4.7 3区 材料科学
Colloid and Interface Science Communications Pub Date : 2024-09-21 DOI: 10.1016/j.colcom.2024.100807
Giorgia Ballabio , Sara Sangiorgio , Eleonora Pargoletti , Rita Gelli , Massimo Bonini , Marco Rabuffetti , Giuseppe Cappelletti , Giovanna Speranza
{"title":"From dairy waste to value-added bio-based surfactants","authors":"Giorgia Ballabio ,&nbsp;Sara Sangiorgio ,&nbsp;Eleonora Pargoletti ,&nbsp;Rita Gelli ,&nbsp;Massimo Bonini ,&nbsp;Marco Rabuffetti ,&nbsp;Giuseppe Cappelletti ,&nbsp;Giovanna Speranza","doi":"10.1016/j.colcom.2024.100807","DOIUrl":"10.1016/j.colcom.2024.100807","url":null,"abstract":"<div><div>Cheese whey permeate, the main waste stream of dairy industry, was used as a starting material for the production of bio-based surfactants (SFAEs). Specifically, the first step in the sustainable chemoenzymatic synthesis of <em>n</em>-butyl 6-<em>O</em>-palmitoyl-<span>D</span>-glycosides (Fischer glycosylation followed by enzymatic esterification) was optimized by a chemometric study. The surfactancy of the prepared isomeric mixtures was deeply investigated in terms of static and dynamic interfacial tension and emulsifying capability over time.</div></div>","PeriodicalId":10483,"journal":{"name":"Colloid and Interface Science Communications","volume":"63 ","pages":"Article 100807"},"PeriodicalIF":4.7,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2215038224000426/pdfft?md5=eec654311e93bf0c2e385beccb257318&pid=1-s2.0-S2215038224000426-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142312182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Colloidal photonic crystals with tunable reflection wavelengths or intensities derived from their reconfigurable structures 具有可调反射波长或强度的可重构结构胶体光子晶体
IF 4.7 3区 材料科学
Colloid and Interface Science Communications Pub Date : 2024-09-01 DOI: 10.1016/j.colcom.2024.100806
Hikaru Namigata , Kanako Watanabe , Tom A.J. Welling , Keishi Suga , Daisuke Nagao
{"title":"Colloidal photonic crystals with tunable reflection wavelengths or intensities derived from their reconfigurable structures","authors":"Hikaru Namigata ,&nbsp;Kanako Watanabe ,&nbsp;Tom A.J. Welling ,&nbsp;Keishi Suga ,&nbsp;Daisuke Nagao","doi":"10.1016/j.colcom.2024.100806","DOIUrl":"10.1016/j.colcom.2024.100806","url":null,"abstract":"<div><p>Colloidal photonic crystals (CPCs), which are the ordered assemblies of colloidal particles, can reflect specific wavelengths of light. In particular, CPCs with controllable optical properties are promising materials for advanced photonic applications. Principally, the optical properties of CPCs, i.e., reflection wavelengths and reflection intensities, are controllable. These two characteristics are closely related to the assembled structures of CPCs, especially interplanar spacing and regularity of the assembled structures. The reflection wavelength is proportional to the interplanar spacing of the structure; thus, uniform expanding/contracting of particle-to-particle distance causes red/blue shift of reflection peaks. On the other hand, the regularity affects the reflection intensity; reversible order–disorder transitions enable tuning of the reflection peak intensities. To control the structures of CPCs, various stimuli-responsive polymers and electromagnetic interactions of colloids have been employed. This review explains the above methods and clarifies the future perspectives.</p></div>","PeriodicalId":10483,"journal":{"name":"Colloid and Interface Science Communications","volume":"62 ","pages":"Article 100806"},"PeriodicalIF":4.7,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2215038224000414/pdfft?md5=1a401ae7e9b68616a27dcb098314523e&pid=1-s2.0-S2215038224000414-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142148643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gold nanoparticles antibacterial activity: Does the surface matter? 金纳米粒子的抗菌活性:表面重要吗?
IF 4.7 3区 材料科学
Colloid and Interface Science Communications Pub Date : 2024-09-01 DOI: 10.1016/j.colcom.2024.100804
Marwan Saed, Raphael D. Ayivi, Jianjun Wei, Sherine O. Obare
{"title":"Gold nanoparticles antibacterial activity: Does the surface matter?","authors":"Marwan Saed,&nbsp;Raphael D. Ayivi,&nbsp;Jianjun Wei,&nbsp;Sherine O. Obare","doi":"10.1016/j.colcom.2024.100804","DOIUrl":"10.1016/j.colcom.2024.100804","url":null,"abstract":"<div><p>The misuse and overuse of antibiotics have ushered in the rapid rise of antimicrobial resistance (AMR). Gold nanoparticles (AuNPs) are considered a potential solution for AMR due to their dual role as antibacterial agents and antibiotic-delivery vehicles. AuNPs with varied surface area, charge, and morphology have been utilized alone and with antibiotics tailored on their surface to overcome resistant bacteria. However, transitioning AuNPs from lab to bedside faces challenges due to the inconsistent antibacterial outcomes and the need for a consensus on the optimal AuNP features that harness their potential as antibacterial agents. This review navigates through the interplay of AuNPs' surface and their antibacterial behavior, considering their surface charge, surface potential, surface coating, surface area, morphology, and antibiotic functionalization. Our review serves as a guide for AuNPs surface features that elicit the most favorable antibacterial outcomes, which will aid in formulating a novel antibacterial agent capable of counteracting AMR.</p></div>","PeriodicalId":10483,"journal":{"name":"Colloid and Interface Science Communications","volume":"62 ","pages":"Article 100804"},"PeriodicalIF":4.7,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2215038224000396/pdfft?md5=d9e712ecde12e50bba21f06c886a9b7a&pid=1-s2.0-S2215038224000396-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142148688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unraveling the stress-induced toxicity of black phosphorus nanosheets and the underlying mechanism 揭示黑磷纳米片的应力诱导毒性及其内在机理
IF 4.7 3区 材料科学
Colloid and Interface Science Communications Pub Date : 2024-09-01 DOI: 10.1016/j.colcom.2024.100802
Zhenlin Fan , Shunjie Wu , Ziheng An , Yiyang Wang , Bohan Xu , Xiaotong Wang , Yihua Xu , He Li , Guangxin Duan , Shitong Zhang , Xin Tian
{"title":"Unraveling the stress-induced toxicity of black phosphorus nanosheets and the underlying mechanism","authors":"Zhenlin Fan ,&nbsp;Shunjie Wu ,&nbsp;Ziheng An ,&nbsp;Yiyang Wang ,&nbsp;Bohan Xu ,&nbsp;Xiaotong Wang ,&nbsp;Yihua Xu ,&nbsp;He Li ,&nbsp;Guangxin Duan ,&nbsp;Shitong Zhang ,&nbsp;Xin Tian","doi":"10.1016/j.colcom.2024.100802","DOIUrl":"10.1016/j.colcom.2024.100802","url":null,"abstract":"<div><p>The unique physicochemical properties of black phosphorus (BP) nanomaterials make them extremely versatile, and growing concern has emerged regarding their biocompatibility. Here, we investigate the toxic profile of BP nanosheets under oxidative stress conditions in living cells and a simple animal model, <em>Caenorhabditis elegans</em>. Under normal conditions, BP nanosheets exhibit no adverse effects on cells and worms. However, the ability of cells and worms to resist oxidative stress is significantly impaired by BP nanosheets. Mechanism studies show that hydroxyl radical overproduction is induced by the reaction between BP nanosheets and H<sub>2</sub>O<sub>2</sub>, which may disrupt mitochondrial integrity and promote the leakage of cytochrome <em>c</em> from mitochondria into cytoplasm. Meanwhile, BP nanosheets are degraded under oxidative stress conditions, providing opportunities for BP nanosheets to interact with cytochrome <em>c</em>, thereby disrupting the cellular antioxidant defense system and ultimately producing toxicity. Our research uncovers the potential mechanism of BP nanosheets with oxidative stress-induced toxicity.</p></div>","PeriodicalId":10483,"journal":{"name":"Colloid and Interface Science Communications","volume":"62 ","pages":"Article 100802"},"PeriodicalIF":4.7,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2215038224000372/pdfft?md5=82f969790541e80b697370db402b6b9e&pid=1-s2.0-S2215038224000372-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142148691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Influence of the chemically reduced graphene oxide interface on the antioxidant multienzyme properties of Prussian blue nanoparticles” [Colloid and Interface Science Communications 52 (2023) 100689] 化学还原氧化石墨烯界面对普鲁士蓝纳米颗粒抗氧化多酶特性的影响》[《胶体与界面科学通讯》52 (2023) 100689]更正
IF 4.7 3区 材料科学
Colloid and Interface Science Communications Pub Date : 2024-09-01 DOI: 10.1016/j.colcom.2024.100805
Yunong Zhang , Liubov Pershina , David Kudriashov , Andreas Offenhäusser , Yulia Mourzina
{"title":"Corrigendum to “Influence of the chemically reduced graphene oxide interface on the antioxidant multienzyme properties of Prussian blue nanoparticles” [Colloid and Interface Science Communications 52 (2023) 100689]","authors":"Yunong Zhang ,&nbsp;Liubov Pershina ,&nbsp;David Kudriashov ,&nbsp;Andreas Offenhäusser ,&nbsp;Yulia Mourzina","doi":"10.1016/j.colcom.2024.100805","DOIUrl":"10.1016/j.colcom.2024.100805","url":null,"abstract":"","PeriodicalId":10483,"journal":{"name":"Colloid and Interface Science Communications","volume":"62 ","pages":"Article 100805"},"PeriodicalIF":4.7,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2215038224000402/pdfft?md5=f4933453da549678c39e0c798640ac23&pid=1-s2.0-S2215038224000402-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142244168","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced anticancer activity of N,N-bis(5-ethyl-2-hydroxybenzyl)methylamine (EMD) hydrophobic drug encapsulated in β-cyclodextrin nanosponges 增强包裹在β-环糊精纳米海绵中的 N,N-双(5-乙基-2-羟基苄基)甲胺(EMD)疏水性药物的抗癌活性
IF 4.7 3区 材料科学
Colloid and Interface Science Communications Pub Date : 2024-09-01 DOI: 10.1016/j.colcom.2024.100803
Sunisa Thongsom , Paolo Di Gianvincenzo , Suchittra Konkankun , Agustín Blachman , Silvestre Bongiovanni Abel , Natcha Madared , Chanchai Boonla , Pithi Chanvorachote , Sergio E. Moya
{"title":"Enhanced anticancer activity of N,N-bis(5-ethyl-2-hydroxybenzyl)methylamine (EMD) hydrophobic drug encapsulated in β-cyclodextrin nanosponges","authors":"Sunisa Thongsom ,&nbsp;Paolo Di Gianvincenzo ,&nbsp;Suchittra Konkankun ,&nbsp;Agustín Blachman ,&nbsp;Silvestre Bongiovanni Abel ,&nbsp;Natcha Madared ,&nbsp;Chanchai Boonla ,&nbsp;Pithi Chanvorachote ,&nbsp;Sergio E. Moya","doi":"10.1016/j.colcom.2024.100803","DOIUrl":"10.1016/j.colcom.2024.100803","url":null,"abstract":"<div><p><em>N, N-</em>bis (5-ethyl-2-hydroxybenzyl) methylamine (EMD) is a synthetic benzoxazine dimer compound. EMD targets and degrades the pro-oncogenic transcription factor c-Myc, initiating apoptosis in cancer cells. However, its use is restricted because of poor aqueous solubility and in physiological media. Cyclodextrin nanosponges (CN), a type of supramolecular macrocyclic polymer nanoparticles with hydrophobic cavities but soluble in water, are utilized here to load EMD in order to enhance its solubility. CNs with three different molar ratios of β-cyclodextrin (βCD)-to-citric acid crosslinker are synthesized: CN1 (βCD/citric acid 1:3), CN2 (βCD/citric acid 1:5), and CN3 (βCD/citric acid 1:8), and then loaded with EMD. EMD-CN2 exhibits a significantly higher solubilization efficiency (579.1 μg/mL) compared to the free EMD (59.09 μg/mL). The increased aqueous solubility of CN encapsulated EMD enhanced its anti-cancer efficacy. In vitro cytotoxicity, colony formation inhibition, and c-Myc suppression of EMD in cancer cells (A549 and HCT116) <em>are</em> improved over free EMD administration.</p></div>","PeriodicalId":10483,"journal":{"name":"Colloid and Interface Science Communications","volume":"62 ","pages":"Article 100803"},"PeriodicalIF":4.7,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2215038224000384/pdfft?md5=e86ae260a8588682692db3551f969899&pid=1-s2.0-S2215038224000384-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142148692","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of micro-porous polymeric coating with dynamic drug-eluting property on plastic biliary stent for antiproliferative treatment 在塑料胆道支架上制作具有动态药物洗脱特性的微孔聚合物涂层,用于抗增生治疗
IF 4.7 3区 材料科学
Colloid and Interface Science Communications Pub Date : 2024-08-27 DOI: 10.1016/j.colcom.2024.100801
Baozhang Shi , Hao Wei , Hongyue Miu , Liangliang Li , Jianing Zhu , Yubing Huo , Liping Xu , Wei Sun
{"title":"Fabrication of micro-porous polymeric coating with dynamic drug-eluting property on plastic biliary stent for antiproliferative treatment","authors":"Baozhang Shi ,&nbsp;Hao Wei ,&nbsp;Hongyue Miu ,&nbsp;Liangliang Li ,&nbsp;Jianing Zhu ,&nbsp;Yubing Huo ,&nbsp;Liping Xu ,&nbsp;Wei Sun","doi":"10.1016/j.colcom.2024.100801","DOIUrl":"10.1016/j.colcom.2024.100801","url":null,"abstract":"<div><p>The current study aims to construct additional drug-eluting carrier for commercially available biliary stent, providing a practical strategy for the cost-efficient treatment of benign biliary stricture. Specifically, the commercially available biliary stent was endowed with porous polylactic acid coating <em>via in-situ</em> pore-formation induced by solvent treatment. The drug-eluting stent with fibroblast inhibition effect was successfully established by efficiently loading the antiproliferative drug of triamcinolone acetonide into the porous coating. The drug release behavior could be dynamically controlled by adjusting the pore morphology of the porous coating. The <em>in-vitro</em> coating degradation and the fibroblast inhibition effect of the drug-eluting stents were further evaluated to prove the effectiveness of the fabricated porous coating as an antiproliferative drug carrier.</p></div>","PeriodicalId":10483,"journal":{"name":"Colloid and Interface Science Communications","volume":"62 ","pages":"Article 100801"},"PeriodicalIF":4.7,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2215038224000360/pdfft?md5=86a5a25e7dac12c0d628a8181babf102&pid=1-s2.0-S2215038224000360-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142078055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Molecular dynamics characterization of the interfacial structure and forces of the methane-ethane sII gas hydrate interface 甲烷-乙烷 sII 气体水合物界面结构和作用力的分子动力学表征
IF 4.7 3区 材料科学
Colloid and Interface Science Communications Pub Date : 2024-08-24 DOI: 10.1016/j.colcom.2024.100800
Samuel Mathews, André Guerra, Phillip Servio, Alejandro Rey
{"title":"Molecular dynamics characterization of the interfacial structure and forces of the methane-ethane sII gas hydrate interface","authors":"Samuel Mathews,&nbsp;André Guerra,&nbsp;Phillip Servio,&nbsp;Alejandro Rey","doi":"10.1016/j.colcom.2024.100800","DOIUrl":"10.1016/j.colcom.2024.100800","url":null,"abstract":"<div><p>The nucleation of gas hydrates is of great interest in flow assurance, global energy demand, and carbon capture and storage. A complex molecular understanding is critical to control hydrate nucleation and growth in potential applications. Molecular dynamics is employed combined with the mechanical definition of surface tension to assess the surface stresses controlling interfacial behavior. We characterize the interfacial tension for sII methane/ethane hydrate and gas mixtures for different temperatures and pressures. We find that the surface tension trends positively with temperature in a balance of water-solid and water-gas interactions. The molecular dipole shows the complexities of water molecule behavior in small, compressed pre-melting layer that emerges as a quasi-liquid. These behaviors contribute to the developing knowledge base surrounding practical applications of this interface.</p></div>","PeriodicalId":10483,"journal":{"name":"Colloid and Interface Science Communications","volume":"62 ","pages":"Article 100800"},"PeriodicalIF":4.7,"publicationDate":"2024-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2215038224000359/pdfft?md5=dbdd03c47502284992443a43601c0102&pid=1-s2.0-S2215038224000359-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142058313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Molecular dynamic simulation (MD) for COF-based membrane in water treatment 基于 COF 的膜在水处理中的分子动力学模拟 (MD)
IF 4.7 3区 材料科学
Colloid and Interface Science Communications Pub Date : 2024-08-12 DOI: 10.1016/j.colcom.2024.100798
Samaneh Bandehali , Sajad Moradi , Maryam Khalili , Meysam Bandehali , Arash Alimadadi
{"title":"Molecular dynamic simulation (MD) for COF-based membrane in water treatment","authors":"Samaneh Bandehali ,&nbsp;Sajad Moradi ,&nbsp;Maryam Khalili ,&nbsp;Meysam Bandehali ,&nbsp;Arash Alimadadi","doi":"10.1016/j.colcom.2024.100798","DOIUrl":"10.1016/j.colcom.2024.100798","url":null,"abstract":"<div><p>COF-based membranes represent a new class of porous materials utilized in water treatment. A comprehensive exploration of these membranes, encompassing their properties and transport mechanisms, is crucial for elucidating the underlying principles and unresolved issues in membrane processes. Molecular dynamics (MD) simulations offer a molecular-level exploration of membrane properties, both static and dynamic. This paper investigates the role of MD simulations in enhancing our understanding of COF-based membranes for water treatment processes.</p><p>This study discusses the structure and properties of COF materials, synthesis strategies, and their applications in water treatment. Furthermore, it explores the fundamental principles of MD simulation and various simulation methods pertinent to water treatment using COF-based membranes. By reviewing existing literature on MD simulations of COF-based membranes, this paper proposes future research directions in this promising field of membrane technology.</p></div>","PeriodicalId":10483,"journal":{"name":"Colloid and Interface Science Communications","volume":"62 ","pages":"Article 100798"},"PeriodicalIF":4.7,"publicationDate":"2024-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2215038224000335/pdfft?md5=bef2b7d011d2534fff4b789614fc10bc&pid=1-s2.0-S2215038224000335-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141979183","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
It is not a rule that the first aggregation state of an ionic surfactant consists of spherical micelles. The case of tetradecyltrimethylammonium salicylate 离子型表面活性剂的第一种聚集状态由球形胶束组成,这并不是一种规则。以十四烷基三甲基水杨酸铵为例
IF 4.7 3区 材料科学
Colloid and Interface Science Communications Pub Date : 2024-08-11 DOI: 10.1016/j.colcom.2024.100799
Álvaro Javier Patiño-Agudelo, Suelen Gauna Trindade, Larissa de Almeida Ueti, Edvaldo Sabadini
{"title":"It is not a rule that the first aggregation state of an ionic surfactant consists of spherical micelles. The case of tetradecyltrimethylammonium salicylate","authors":"Álvaro Javier Patiño-Agudelo,&nbsp;Suelen Gauna Trindade,&nbsp;Larissa de Almeida Ueti,&nbsp;Edvaldo Sabadini","doi":"10.1016/j.colcom.2024.100799","DOIUrl":"10.1016/j.colcom.2024.100799","url":null,"abstract":"<div><p>Ionic surfactants can assemble into wormlike micelles (WLM) at high concentrations, forming supramolecular structures that exhibit similarities to polymeric solutions. Although the rheology of these supramolecular aggregates is well understood, experimental thermodynamic studies at low concentrations are still in their early stages. In this study, we employed tetradecyltrimethylammonium salicylate (TTASal) to investigate the driving forces behind WLM formation for the first time, using isothermal titration calorimetry, electrical conductivity measurements, and cryogenic transmission electron microscopy. Our findings indicate that TTASal initially aggregates into WLM rather than spherical micelles, demonstrating that WLM formation is influenced by surfactant ion-counterion interactions rather than concentration alone. Notably, the enthalpy change associated with the aggregation process emerges as a key determinant in dictating the aggregation of free monomers into spherical or WLM.</p></div>","PeriodicalId":10483,"journal":{"name":"Colloid and Interface Science Communications","volume":"62 ","pages":"Article 100799"},"PeriodicalIF":4.7,"publicationDate":"2024-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2215038224000347/pdfft?md5=993774af40b93b8006b96d4b66d0f6d2&pid=1-s2.0-S2215038224000347-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141932295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信