Supramolecular Materials最新文献_第2页

Fundamental and Application of Co-assembly of Peptides and Proteins: Experiment and Computation 多肽与蛋白质共组装的基础与应用：实验与计算

Supramolecular Materials Pub Date : 2025-04-05 DOI: 10.1016/j.supmat.2025.100103

Newton A. Ihoeghian, Qing Shao

{"title":"Fundamental and Application of Co-assembly of Peptides and Proteins: Experiment and Computation","authors":"Newton A. Ihoeghian, Qing Shao","doi":"10.1016/j.supmat.2025.100103","DOIUrl":"10.1016/j.supmat.2025.100103","url":null,"abstract":"<div><div>Peptides and proteins can co-assemble into various nanostructures based on complementary non-covalent interactions such as electrostatic forces, hydrogen bonding, and hydrophobic associations. These co-assemblies create a design space of functional materials for a wide spectrum of energy, environmental, and biomedical applications. This review focuses on the fundamentals and applications of three co-assembling systems: ultra-short peptides, peptides, and proteins. We will present and discuss experimental studies demonstrating applications in drug delivery, tissue engineering, and biomaterials development. We will also discuss the contribution of computational research, including molecular dynamics simulations and machine learning, to enhance our understanding of assembly mechanisms. Integrating experimental and computational methods would provide crucial insights for understanding and designing robust functional co-assemblies with precisely controlled compositions and properties. These advances would support the development of sophisticated biomaterials for applications ranging from targeted therapeutics to regenerative medicine.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"4 ","pages":"Article 100103"},"PeriodicalIF":0.0,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Erratum to “Supramolecular microgels/microgel scaffolds for tissue repair and regeneration” [Supramolecular Materials 1 (2022) 100006]

Supramolecular Materials Pub Date : 2025-03-21 DOI: 10.1016/j.supmat.2025.100102

Kai Wang, Zhaoyi Wang, Haijun Hu, Changyou Gao

引用次数: 0

Controllable ultrahigh-affinity molecular recognition 可控超高亲和分子识别

Supramolecular Materials Pub Date : 2025-03-20 DOI: 10.1016/j.supmat.2025.100101

Fang-Yuan Chen , Han-Fang Zhang , Kang Cai , Dong-Sheng Guo

引用次数: 0

3D-Printed metal organic frameworks-based supramolecular hydrogel as biological materials 基于3d打印金属有机框架的超分子水凝胶作为生物材料

Supramolecular Materials Pub Date : 2025-02-11 DOI: 10.1016/j.supmat.2025.100100

Moses Kumi , Bridget Kpomah , Onome Ejeromedoghene , Aboagye Gifty Takyiwaa , Onomen Agnes Ehizojie

{"title":"3D-Printed metal organic frameworks-based supramolecular hydrogel as biological materials","authors":"Moses Kumi , Bridget Kpomah , Onome Ejeromedoghene , Aboagye Gifty Takyiwaa , Onomen Agnes Ehizojie","doi":"10.1016/j.supmat.2025.100100","DOIUrl":"10.1016/j.supmat.2025.100100","url":null,"abstract":"<div><div>In the dynamic landscape of biomaterials, the fusion of 3D-printed Metal-Organic Frameworks (MOFs) with supramolecular hydrogel technologies marks a pivotal shift toward generating next-generation biological materials. This comprehensive review sheds light on the fabrication of MOF-based supramolecular hydrogels using state-of-the-art 3D-printing methodologies. Herein, the distinct structural and functional attributes of these hybrid materials, setting the stage for their groundbreaking applications as biomaterials for wound care, bone regeneration, wearable electronics, and biosensing devices were addressed. These applications demonstrate the ability of 3D-printed MOF-based supramolecular hydrogels to redefine the norms in biomedical engineering and wearable technology landscapes. A deep dive into the functional properties of 3D-printed MOF-based biomaterials reveals their remarkable biofunctional attributes and the harmonious interplay between 3D-printed MOF structures and hydrogel networks. The review navigates through the existing challenges and unfolds the prospects within this fast-evolving domain, offering valuable insights into emergent growth trajectories and the scalability prospects of these hybrid materials. In conclusion, we spotlight the bright prospects of 3D-printed MOF-based supramolecular hydrogels, advocating their pivotal role in spearheading the development of biofunctional materials. Serving as an essential guide, this review targets researchers and industry experts, steering the course for future explorations and utilizations in this flourishing area of research.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"4 ","pages":"Article 100100"},"PeriodicalIF":0.0,"publicationDate":"2025-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143419556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Lego-like Visible Assembly of Responsive Components via Flexible Supramolecular Connectivity to Realize High-capacity Information Encoding 利用柔性超分子连接实现响应组件的乐高式可见组装，实现大容量信息编码

Supramolecular Materials Pub Date : 2025-02-10 DOI: 10.1016/j.supmat.2025.100099

Guiqiang Zhu , Qian Zhang , Benwei Peng , Siyuan Liu , Cuiling Lin , Alexander J.C. Kuehne , Mengjiao Cheng , Feng Shi

{"title":"Lego-like Visible Assembly of Responsive Components via Flexible Supramolecular Connectivity to Realize High-capacity Information Encoding","authors":"Guiqiang Zhu , Qian Zhang , Benwei Peng , Siyuan Liu , Cuiling Lin , Alexander J.C. Kuehne , Mengjiao Cheng , Feng Shi","doi":"10.1016/j.supmat.2025.100099","DOIUrl":"10.1016/j.supmat.2025.100099","url":null,"abstract":"<div><div>Self-assembly in life that creates complex creatures with colorful biological activities, relies heavily on all-scale diverse components and high-capacity assembly information, which directs assembly patterns by specifying the connectivity of components. Despite of nanoscale colloids or connectivity via DNA hybridization providing rich possibility to store information, the execution of encoding at the level of macroscopic bulk materials remains improving, especially on the connectivity diversity. Here, we demonstrate visible self-assembly of millimeter-scaled hydrogels with flexible Lego-like connectivity for high-capacity encoding by storing the assembly information of both orthogonally stimulus-responsive components and interfacial supramolecular binding. Three categories of hydrogels with response to temperature, redox conditions, and UV light, are used as the intelligent building components. Meanwhile, reversible electrostatic interactions are applied as the interfacial supramolecular connectivity, which undergoes on-demand assembly/disassembly to create diverse structures similar to Lego playing. Mechanistic study is obtained by quantify the connectivity via in-situ measurements of interfacial binding forces between components. The flexible supramolecular connectivity of responsive components has provided abundant assembly possibility with good control, leading to a high encoding capacity of over 800 billion codes for a simple 5 × 5 assembly. This strategy induces myriad self-assembly pathways to broaden the design of information storage, and improves the execution of encoding at a bulk material level.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"4 ","pages":"Article 100099"},"PeriodicalIF":0.0,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143419555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ratiometric luminescent temperature sensor based on amorphous complex of europium (III) and quantum dots 基于非晶铕（III）与量子点配合物的比例发光温度传感器

Supramolecular Materials Pub Date : 2025-02-01 DOI: 10.1016/j.supmat.2025.100098

Ruzanna M. Ziyatdinova, Andrey A. Knyazev, Dmitriy O. Sagdeev, Yuriy G. Galyametdinov

引用次数: 0

Advancements in active filler-contained polymer solid-state electrolytes for lithium-metal batteries: A concise review 锂金属电池用活性填料聚合物固态电解质的研究进展

Supramolecular Materials Pub Date : 2025-01-19 DOI: 10.1016/j.supmat.2025.100097

Hang Ding , Mingli Wang , Xinyuan Shan , Guang Yang , Ming Tian

{"title":"Advancements in active filler-contained polymer solid-state electrolytes for lithium-metal batteries: A concise review","authors":"Hang Ding , Mingli Wang , Xinyuan Shan , Guang Yang , Ming Tian","doi":"10.1016/j.supmat.2025.100097","DOIUrl":"10.1016/j.supmat.2025.100097","url":null,"abstract":"<div><div>Lithium-metal batteries (LMBs) usually are regarded as the pinnacle of next-generation energy storage due to the high specific capacity and low redox potential of the Li-metal anode. However, their development is hindered by safety hazards related to flammable electrolytes and uncontrolled side reactions within the battery. Both polymer and solid-state inorganic electrolytes, despite their potential, exhibit shortcomings that limit their practical applications. Active filler-containing polymer electrolytes (AFPEs) offer a promising solution by combining the benefits of both types. Enhanced by supramolecular interactions between the polymer matrix and active fillers, AFPEs demonstrate superior electrochemical performance over traditional polymer electrolytes. This review discusses the progress in active fillers and various polymer matrices, examining the factors that enhance performance, particularly ionic conductivity. It also outlines the future research directions of AFPEs, aiming to broaden the application of solid electrolytes in high-performance LMBs.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"4 ","pages":"Article 100097"},"PeriodicalIF":0.0,"publicationDate":"2025-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143101769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Engineering chiral mesoporous silica nanoparticles: Template design and structural control for advanced applications 工程手性介孔二氧化硅纳米颗粒：先进应用的模板设计和结构控制

Supramolecular Materials Pub Date : 2025-01-18 DOI: 10.1016/j.supmat.2025.100095

Yu Yin , Wu Wei , Kai Zhang

{"title":"Engineering chiral mesoporous silica nanoparticles: Template design and structural control for advanced applications","authors":"Yu Yin , Wu Wei , Kai Zhang","doi":"10.1016/j.supmat.2025.100095","DOIUrl":"10.1016/j.supmat.2025.100095","url":null,"abstract":"<div><div>Chiral mesoporous silica nanoparticles (CMSNs) are a distinct subset of mesoporous silica nanoparticles, combining the favorable physicochemical properties of MSNs with unique chiral architectures at both molecular and macroscopic scales. These helical structures endow CMSNs with specialized functionalities, enabling their applications in chiral catalysis, enantioselective recognition, chiral separation, drug delivery, and optical devices, making them a focal point in materials and biomedical research. Significant progress has been achieved in the synthesis of CMSNs, particularly in understanding the mechanisms of chirality formation and the critical role of surfactant templates in guiding chiral structures. This review summarizes these advancements, emphasizing experimental and theoretical insights. Key applications of CMSNs, especially in drug delivery systems, are explored in detail, highlighting their potential to enhance bioavailability and therapeutic efficacy. Looking ahead, CMSN research presents exciting opportunities, including precise control over chiral structures, the development of novel templating strategies, and the exploration of broader applications. These advancements are expected to drive progress in nanoporous silica technologies and open new frontiers in materials science and nanomedicine.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"4 ","pages":"Article 100095"},"PeriodicalIF":0.0,"publicationDate":"2025-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143101770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Piezoelectric-triboelectric hybrid nanogenerator based on tough, stretchable BaTiO3 doped antibacterial hydrogel for self-powered sensors 基于坚韧、可拉伸的BaTiO3掺杂抗菌水凝胶的压电-摩擦电混合纳米发电机，用于自供电传感器

Supramolecular Materials Pub Date : 2025-01-18 DOI: 10.1016/j.supmat.2025.100096

Runi Hou, Lijian Xu, Maolin Yu, Zengmin Tang, Bin Zhou, Qiao Zhang, Na Li, Jianxiong Xu

{"title":"Piezoelectric-triboelectric hybrid nanogenerator based on tough, stretchable BaTiO3 doped antibacterial hydrogel for self-powered sensors","authors":"Runi Hou, Lijian Xu, Maolin Yu, Zengmin Tang, Bin Zhou, Qiao Zhang, Na Li, Jianxiong Xu","doi":"10.1016/j.supmat.2025.100096","DOIUrl":"10.1016/j.supmat.2025.100096","url":null,"abstract":"<div><div>The pursuit of nanogenerators with superior electrical output performance is crucial for advancing high-performance self-powered sensors, yet enhancing their performance through effective strategies remains a formidable challenge. Herein, a kind of piezoelectric-triboelectric hybrid nanogenerator (PTENG) utilizing a tough, stretchable BaTiO<sub>3</sub> doped hydrogel was developed. To this end, a functional hydrogel of oxidized sodium alginate (OSA) crosslinked poly(acrylic acid-<em>co</em>-acrylamide) (P(AA-<em>co</em>-AM)) in the presence of BaTiO<sub>3</sub> (BTO) nanoparticles was initially prepared and then immersed in FeCl<sub>3</sub> solution to form OSA/P(AA-<em>co</em>-AM)/Fe<sup>3+</sup>-BTO (O/P/Fe-BTO) hydrogels. Due to the multiple interaction (such as dynamic Schiff base cross-linking bond, metal coordination and hydrogen bonding), along with the synergistic contributions of each component, the as-prepared O/P/Fe-BTO hydrogels displayed outstanding mechanical property (tensile stress of 2.14 MPa, tensile strain of 876 %, toughness of 9.96 MJ/m<sup>3</sup>), good conductivity (0.14 S/m) and excellent antibacterial activity. Subsequently, a kind of PTENG was constructed by employing the O/P/Fe-BTO hydrogels as electrode materials. Leveraging both triboelectric and piezoelectric effects, the PTENG demonstrated excellent electrical output performance (open-circuit voltage of 222 V and short-circuit current of 5.35 μA). As a practical demonstration, the application of PTENG in self-powered strain and tactile sensors was demonstrated, manifesting their promising potential in self-powered sensing system. Overall, this work represents a noteworthy advancement in the domain of self-powered flexible electronics, with the potential for application in a wide range of complex scenarios.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"4 ","pages":"Article 100096"},"PeriodicalIF":0.0,"publicationDate":"2025-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143102218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Supramolecular ethanol-water clusters in alcoholic beverages: Review on 2D correlation fluorescence and NMR spectral characterizations 酒精饮料中的超分子乙醇-水团簇：二维相关荧光和核磁共振光谱表征综述

Supramolecular Materials Pub Date : 2025-01-14 DOI: 10.1016/j.supmat.2025.100094

Hui-Shuang Li , Hao-jie Bai , Yi Li , Yuqing Wu

{"title":"Supramolecular ethanol-water clusters in alcoholic beverages: Review on 2D correlation fluorescence and NMR spectral characterizations","authors":"Hui-Shuang Li , Hao-jie Bai , Yi Li , Yuqing Wu","doi":"10.1016/j.supmat.2025.100094","DOIUrl":"10.1016/j.supmat.2025.100094","url":null,"abstract":"<div><div>While the studies have revealed that the type and content of ingredients are crucial factors in determining the quality and taste of alcoholic beverages, the liquid-liquid condensed phase of the supramolecular network of ethanol-water clusters (E-Wc) have been demonstrated playing important influence either. The supramolecular clusters in alcoholic beverages, especially the intrinsic hydrogen-bondings (HBs) to organoleptic sensing and quality assessment, have gradually been elucidated recently. The veiling concealed on the supramolecular entities as a key proportion of the ethanol-water solution (E-Ws) starts to be disclosed with the discrete achievements in this research area. To build a full understanding of the cluster driving in versatile alcoholic beverages <em>via</em> unique techniques for characterization, this review summarizes the involved supramolecular E-Wc by fluorescence emission and NMR spectra. In particular, the two-dimensional correlation (2D-COS) analysis has been introduced as a powerful tool for characterizing the important structural profiles in clusters. With the help of carving important supramolecular E-Wc, it is hoped that the prospects and challenges in this field will be clearer and that such kinds of condensed liquid phases can possess the potential as supramolecular material additives to modulate the products with various tastes and quality in the alcoholic industry.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"4 ","pages":"Article 100094"},"PeriodicalIF":0.0,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143101768","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0