Supramolecular Materials最新文献

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Multifunctional zwitterionic hydrogels: A review of cross-disciplinary applications 多功能两性离子水凝胶:跨学科应用综述
Supramolecular Materials Pub Date : 2026-12-01 Epub Date: 2025-11-22 DOI: 10.1016/j.supmat.2025.100133
Yuechan Xie , Yixuan Wang , Longze Jiao , Zhihao Chen , Lunan Zhao , Jiahao Wang , Wenlong Xu
{"title":"Multifunctional zwitterionic hydrogels: A review of cross-disciplinary applications","authors":"Yuechan Xie ,&nbsp;Yixuan Wang ,&nbsp;Longze Jiao ,&nbsp;Zhihao Chen ,&nbsp;Lunan Zhao ,&nbsp;Jiahao Wang ,&nbsp;Wenlong Xu","doi":"10.1016/j.supmat.2025.100133","DOIUrl":"10.1016/j.supmat.2025.100133","url":null,"abstract":"<div><div>Owing to their unique molecular structure, zwitterionic hydrogels have emerged as a research hotspot in numerous fields in recent years. Cations and anions are uniformly distributed along the polymer chain. Consequently, zwitterionic hydrogels exhibit a large dipole moment and a high density of charged groups while effectively maintaining the overall electrical neutrality of the material. This charge balance not only endows the hydrogels with outstanding properties but also provides a valuable exploration space for breakthroughs in innovative application fields. This paper introduces the molecular structure and cross-linking mechanism of zwitterionic hydrogels, and analyzes the underlying reasons for their excellent hydration, favorable electrical conductivity, mechanical properties, environmental responsiveness and antifreeze performance. Additionally, it summarizes the significant applications of zwitterionic hydrogels in diverse fields such as sustainable water treatment, electrochemical devices, and biomedicine. Meanwhile, the current challenges faced by these materials, including large-scale production costs and high-salt swelling issues, are pointed out, so as to provide directions for future research.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"5 ","pages":"Article 100133"},"PeriodicalIF":0.0,"publicationDate":"2026-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145658618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in organic room temperature phosphorescent gels 有机室温磷光凝胶的研究进展
Supramolecular Materials Pub Date : 2026-12-01 Epub Date: 2025-11-19 DOI: 10.1016/j.supmat.2025.100124
Hua Zhang, Hong Kui Zhang, Yu Feng
{"title":"Recent advances in organic room temperature phosphorescent gels","authors":"Hua Zhang,&nbsp;Hong Kui Zhang,&nbsp;Yu Feng","doi":"10.1016/j.supmat.2025.100124","DOIUrl":"10.1016/j.supmat.2025.100124","url":null,"abstract":"<div><div>Organic room-temperature phosphorescent (RTP) gels have garnered considerable interest as a versatile class of soft materials, integrating the stimuli-responsive and dynamic nature of gels with long-lived phosphorescent emission. Their unique hierarchical and three-dimensional architectures provide tunable mechanical properties, reversible phase transitions, and excellent processability, rendering them highly suitable for both fundamental studies and practical implementations. Despite substantial progress in this field, a comprehensive review consolidating recent breakthroughs remains scarce. This review provides a comprehensive overview of the latest advances in metal-free RTP gel materials. We elaborate on their sophisticated design strategies, luminescence properties and underlying mechanisms, as well as their potential applications in anti-counterfeiting and information encryption, 3D printing, process monitoring, bioimaging and ion detection. Furthermore, we offer perspectives highlighting current challenges and future opportunities for metal-free RTP gels across various disciplines. It is anticipated that this review will provide insightful guidelines and inspire further innovative research on organic RTP gel systems, thereby advancing the development of intelligent luminescent materials and their multifunctional applications.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"5 ","pages":"Article 100124"},"PeriodicalIF":0.0,"publicationDate":"2026-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145799932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyrotaxanes in motion: recent advances in slide-ring supramolecular polymers 运动中的聚轮烷:滑环超分子聚合物的最新进展
Supramolecular Materials Pub Date : 2026-12-01 Epub Date: 2025-06-13 DOI: 10.1016/j.supmat.2025.100114
Zhi-Min Lv , Yue-Yang Liu , Shang-Bo Yu , Jia Tian , Yun-Xiang Xu , Zhan-Ting Li
{"title":"Polyrotaxanes in motion: recent advances in slide-ring supramolecular polymers","authors":"Zhi-Min Lv ,&nbsp;Yue-Yang Liu ,&nbsp;Shang-Bo Yu ,&nbsp;Jia Tian ,&nbsp;Yun-Xiang Xu ,&nbsp;Zhan-Ting Li","doi":"10.1016/j.supmat.2025.100114","DOIUrl":"10.1016/j.supmat.2025.100114","url":null,"abstract":"<div><div>Polyrotaxanes (PRs) are mechanically interlocked supramolecular systems with the ring components threading linear axle component. When two rings are connected with a covalent linker and incorporating PRs into main-chain or side-chain polymers, the sliding of the rings over the threaded covalent networks produces pulley effect, by which the polymer chains can pass through the rings to equalize the tensions cooperatively and avoid localization of the stress. Since the pioneering work on the α−CD/polyethylene glycol-composed system by Okumura and Ito in 2001, such slide-ring supramolecular polymers (SRSPs) have been developed as a new kind of mechanically interlocked materials that display specific conformational freedom, high movability, as well as exceptional mechanic performances, which include enhanced toughness, stretchability, recoverability and self-healing ability. In addition to α−CD, β−CD, crown ethers, pillar[5]arene, and discrete macrocycles have been used as the ring components. A diversity of sliding and interpenetrating patterns has also been developed. With the establishment of the preparation methods and structure-property relationship evaluations, SRSPs have been vigorously explored as promising materials for a variety of functions and applications, including anti-scratch, anti-fracture, anti-puncture and anti-impact, as well as enhanced hydrogels, rubbers and elastomers. In this review, we summarize recent progresses, mainly those obtained in the past five years, in the preparations, structures, functions and applications of this family of supramolecular polymers. In the final section, we give our perspectives of future research and challenges.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"5 ","pages":"Article 100114"},"PeriodicalIF":0.0,"publicationDate":"2026-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145748196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Light-triggered one-pot synthesis of covalent-supramolecular double network elastomer 光触发一锅法合成共价超分子双网状弹性体
Supramolecular Materials Pub Date : 2026-12-01 Epub Date: 2025-10-22 DOI: 10.1016/j.supmat.2025.100121
Muhammad Arslan, Yi Ding, Wenbin Wang, Jingxi Deng, Yuanhao Wang, Chuan Yue, Jianzhen Wu, Shaolei Qu, Yuhang Liu, Ruixue Bai, Xuzhou Yan, Zhaoming Zhang
{"title":"Light-triggered one-pot synthesis of covalent-supramolecular double network elastomer","authors":"Muhammad Arslan,&nbsp;Yi Ding,&nbsp;Wenbin Wang,&nbsp;Jingxi Deng,&nbsp;Yuanhao Wang,&nbsp;Chuan Yue,&nbsp;Jianzhen Wu,&nbsp;Shaolei Qu,&nbsp;Yuhang Liu,&nbsp;Ruixue Bai,&nbsp;Xuzhou Yan,&nbsp;Zhaoming Zhang","doi":"10.1016/j.supmat.2025.100121","DOIUrl":"10.1016/j.supmat.2025.100121","url":null,"abstract":"<div><div>The double-network (DN) structure is an important strategy for toughening elastomers. Developing efficient preparation methods for DN elastomers remains a key challenge in this field. Herein, we developed a one-pot, single-step strategy to fabricate covalent-supramolecular double-network elastomers by utilizing light to simultaneously form both covalent (CN) and supramolecular networks (SN). In specific, the CN was formed via thiol-ene click chemistry using styrene-butadiene rubber as the backbone, while the SN was constructed through photo-induced crosslinking of poly(ethylene glycol) based polymers mediated by quadruple hydrogen bonding. Mechanical tests revealed that the DN elastomer exhibited significantly enhanced properties compared with the control (pure CN). Specifically, the DN exhibited superior fracture stress (0.74 <em>vs.</em> 0.45 MPa), fracture strain (268 <em>vs.</em> 99 %), and toughness (1.47 <em>vs.</em> 0.29 MJ/m<sup>3</sup>). Cyclic tensile testing and stress-relaxation experiments demonstrated that the superior performance of the DN elastomer was attributed to the excellent energy dissipation capacity of its SN. Furthermore, supramolecular monomers can be introduced into pre-formed CN through swelling, establishing a novel methodology for toughening commercial CN elastomers via the double-network strategy.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"5 ","pages":"Article 100121"},"PeriodicalIF":0.0,"publicationDate":"2026-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145799956","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Coordination chemistry enabled in vivo radioprotective material for alleviating acute radiation syndrome 配位化学使体内放射性防护材料能够减轻急性辐射综合征
Supramolecular Materials Pub Date : 2026-12-01 Epub Date: 2026-01-18 DOI: 10.1016/j.supmat.2026.100134
Ruotong Deng , Hanjie Zhu , Xinyue Zhang , Ziwei Zhang , Rui Duan , Wei Chen , Yining Ou , Fengrui Liu , Wei Cao
{"title":"Coordination chemistry enabled in vivo radioprotective material for alleviating acute radiation syndrome","authors":"Ruotong Deng ,&nbsp;Hanjie Zhu ,&nbsp;Xinyue Zhang ,&nbsp;Ziwei Zhang ,&nbsp;Rui Duan ,&nbsp;Wei Chen ,&nbsp;Yining Ou ,&nbsp;Fengrui Liu ,&nbsp;Wei Cao","doi":"10.1016/j.supmat.2026.100134","DOIUrl":"10.1016/j.supmat.2026.100134","url":null,"abstract":"<div><div>The most life-threatening injury induced by radiation is acute radiation syndrome (ARS), which is featured by damage to the hematopoietic system and vital organs. However, most efforts focus on scavenging radiation-induced reactive oxygen species (ROS). Designing more direct strategies like in vivo radiation shielding remains in its infancy. Here we propose a supramolecularly orchestrated high-atomic number (<em>Z</em>) strategy, designing a bismuth-coordinated melanin-based radioprotectant for achieving physical shielding in vivo. The supramolecular coordination of bismuth endows the biomaterial with superior photon-shielding capacity, while maintaining melanin’s inherent ROS-scavenging function. In animal experiments, this strategy effectively alleviated ARS, maintained normal hematopoietic function and protected the gastrointestinal tract, resulting in improved long-term survival from 20 % to 60 %. This radioprotectant also exhibited excellent biocompatibility and metabolism. High-<em>Z</em> nanomaterials for in vivo applications utilize supramolecular coordination to combine metals with natural macromolecules, offering an effective strategy for developing radioprotectants. Moreover, Bi-coordinated poly <em>L</em>-3,4-dihydroxyphenylalanine melanin outperforms its polydopamine analogue, revealing that side-chain subtleties dictate radioprotective potency.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"5 ","pages":"Article 100134"},"PeriodicalIF":0.0,"publicationDate":"2026-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146187387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Supramolecular wearable patch for continuous non-invasive blood glucose monitoring 用于连续无创血糖监测的超分子可穿戴贴片
Supramolecular Materials Pub Date : 2026-12-01 Epub Date: 2026-01-19 DOI: 10.1016/j.supmat.2026.100135
Zhaoxiang Li , Minghao Zhao , Yueyue Chen
{"title":"Supramolecular wearable patch for continuous non-invasive blood glucose monitoring","authors":"Zhaoxiang Li ,&nbsp;Minghao Zhao ,&nbsp;Yueyue Chen","doi":"10.1016/j.supmat.2026.100135","DOIUrl":"10.1016/j.supmat.2026.100135","url":null,"abstract":"<div><div>Diabetes is a chronic disease that requires continuous glucose monitoring for effective management, but current monitoring methods exist invasive and non-continuous problems. In this study, we firstly developed a non-invasive skin patch for glucose continuous monitoring using MXene-based (Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>) conductive supramolecular hydrogels. The hydrogel, composed of MXene, polyacrylamide (PAM), polyvinyl alcohol (PVA), and glucose oxidase (GOx), exhibited highly conductive, soft, and good enzyme activity, with gold nanoparticles (AuNPs) and Prussian blue particles deposited on the electrode, which served as a supramolecular electrochemical sensing platform (GM3PAS). Combined with reverse iontophoresis (RI), GM3PAS worn by New Zealand rabbit models and human volunteers extracted glucose from interstitial fluid on the surface of skin for non-invasive monitoring, whose results consistent with fingertip glucose meters. The biosensor demonstrated excellent conductivity, stability, and a wide detection range from 0 to 5.3 mM glucose with a limit of detection of 9 μmol. It proved that GM3PAS patch can use on human skin for three weeks, whose monitoring cycle longer than commercial products. This study provides a new continuous non-invasive blood glucose monitoring wearable device for diabetes, which will be expected to be applied to clinical transformation in the future.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"5 ","pages":"Article 100135"},"PeriodicalIF":0.0,"publicationDate":"2026-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Underwater adhesive photonic-ionogels with unchangeable structural color for motion sensing 运动传感用结构颜色不变的水下粘接光子离子凝胶
Supramolecular Materials Pub Date : 2026-12-01 Epub Date: 2025-08-21 DOI: 10.1016/j.supmat.2025.100119
Ying Yu, Quanqian Lyu, Zihan Xu, Jing Wang, Zhen Hu, Lianbin Zhang, Jintao Zhu
{"title":"Underwater adhesive photonic-ionogels with unchangeable structural color for motion sensing","authors":"Ying Yu,&nbsp;Quanqian Lyu,&nbsp;Zihan Xu,&nbsp;Jing Wang,&nbsp;Zhen Hu,&nbsp;Lianbin Zhang,&nbsp;Jintao Zhu","doi":"10.1016/j.supmat.2025.100119","DOIUrl":"10.1016/j.supmat.2025.100119","url":null,"abstract":"<div><div>Ionogels have emerged as promising materials for flexible sensors, combining tunable mechanical properties with high ionic conductivity. While integrating colloidal crystals within ionogels can enable dynamic optical modulation and enhanced functionality, existing systems face critical limitations: moisture-induced degradation in humid environments and structural color instability during deformation, both of which compromise sensing reliability. In this work, we develop an adhesive photonic ionogel (APIG) that maintains stable structural color during deformation and robust underwater adhesion. The APIG is fabricated by copolymerization of a hydrophobic polymerizable ionic liquid, acryloyloxyethyl trimethylammonium bis(trifluoromethanesulfonyl)imide ([AETA][TFSI]) with 2-methoxyethyl acrylate (MEA) and 2,2,2-trifluoroethyl acrylate (TFEA), following infiltration into surface-carboxylated polystyrene (PS-COOH) colloidal crystal templates. The resulting APIG exhibits excellent underwater adhesion, with an adhesion strength of 605.0 kPa on stainless steel, and maintains structural color stability during deformation, achieved through a decoupling strategy that minimizes interactions between the non-polar polymer matrix and functionalized colloidal particles. Furthermore, our APIG demonstrates reliable strain-responsive electrical signals, with consistent resistive output over 300 loading-unloading cycles. This unique combination of optical stability, durable adhesion, and robust electromechanical performance positions APIG as an advanced platform for underwater motion monitoring, spatial positioning, and even optical-electrical communication systems.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"5 ","pages":"Article 100119"},"PeriodicalIF":0.0,"publicationDate":"2026-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145799955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Supramolecular engineering of luminescent materials: From molecular design to optoelectronic applications 发光材料的超分子工程:从分子设计到光电应用
Supramolecular Materials Pub Date : 2026-12-01 Epub Date: 2025-10-25 DOI: 10.1016/j.supmat.2025.100122
Yicheng Yuan , Meifang Yang , Xinyi Lin , Wen-Guang Li , Zhenquan Yang , Genling Liu , Qin Xu , Yu-Xin Chen , Huan Pang , Tian Tian
{"title":"Supramolecular engineering of luminescent materials: From molecular design to optoelectronic applications","authors":"Yicheng Yuan ,&nbsp;Meifang Yang ,&nbsp;Xinyi Lin ,&nbsp;Wen-Guang Li ,&nbsp;Zhenquan Yang ,&nbsp;Genling Liu ,&nbsp;Qin Xu ,&nbsp;Yu-Xin Chen ,&nbsp;Huan Pang ,&nbsp;Tian Tian","doi":"10.1016/j.supmat.2025.100122","DOIUrl":"10.1016/j.supmat.2025.100122","url":null,"abstract":"<div><div>Luminescent materials often face trade-offs between efficiency, stability, and dynamic responsiveness, which limit their performance in advanced optoelectronic devices and bioimaging. Supramolecular chemistry offers a strategic solution by precisely modulating non-covalent interactions, enabling assemblies to suppress vibrational relaxation via conformational locking, enhance intersystem crossing through triplet-level tuning, and optimize energy transfer, thereby improving quantum yields and emission lifetimes. This review highlights synergistic supramolecular mechanisms that bridge molecular design and photophysical regulation across perylene bisimide materials, aggregation-induced emission luminogens, perovskite materials, room-temperature phosphorescence materials, and organic nonlinear optical materials, alongside their applications in luminescent displays, bioimaging, and information encryption. Despite notable advances, biocompatibility and signal stability remain challenging. AI and biohybrid approaches offer pathways toward programmable emission control.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"5 ","pages":"Article 100122"},"PeriodicalIF":0.0,"publicationDate":"2026-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145799931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Supramolecular self-assembly in solid-state lithium batteries: Bulk electrolyte design and interface engineering 固态锂电池中的超分子自组装:大块电解质设计和界面工程
Supramolecular Materials Pub Date : 2025-12-01 Epub Date: 2025-08-19 DOI: 10.1016/j.supmat.2025.100118
Changjian Li , Shanbin Goh , Yu Ou , Chaoyue Sun , Shuaishuai Yan , Wenhui Hou , Yang Lu , Xiao Ma , Zhi Liu , Yuhao Wu , Yingchun Xia , Weili Zhang , Qingbin Cao , Hao Liu , Xuan Song , Xuwen Peng , Jian Feng , Kezhuo Li , Lai Wei , Jia Zhang , Kai Liu
{"title":"Supramolecular self-assembly in solid-state lithium batteries: Bulk electrolyte design and interface engineering","authors":"Changjian Li ,&nbsp;Shanbin Goh ,&nbsp;Yu Ou ,&nbsp;Chaoyue Sun ,&nbsp;Shuaishuai Yan ,&nbsp;Wenhui Hou ,&nbsp;Yang Lu ,&nbsp;Xiao Ma ,&nbsp;Zhi Liu ,&nbsp;Yuhao Wu ,&nbsp;Yingchun Xia ,&nbsp;Weili Zhang ,&nbsp;Qingbin Cao ,&nbsp;Hao Liu ,&nbsp;Xuan Song ,&nbsp;Xuwen Peng ,&nbsp;Jian Feng ,&nbsp;Kezhuo Li ,&nbsp;Lai Wei ,&nbsp;Jia Zhang ,&nbsp;Kai Liu","doi":"10.1016/j.supmat.2025.100118","DOIUrl":"10.1016/j.supmat.2025.100118","url":null,"abstract":"<div><div>The development of solid-state lithium batteries (SSLBs) is pivotal to addressing the escalating global demand for advanced electrochemical energy storage systems, driven notably by electric vehicles and portable electronics. Recently, supramolecular chemistry has demonstrated significant potential in enhancing the performance and stability of SSLBs through precisely controlled molecular interactions and self-assembly processes. This review systematically analyzes recent advancements in supramolecular self-assembly applied to solid-state-electrolyte materials and solid electrode-solid electrolyte interface engineering within SSLBs. Various supramolecular interactions, such as hydrogen bonding, halogen bonding, charge transfer interactions, host-guest interactions, π–π stacking, and dynamic covalent bonding, are comprehensively examined for their roles in constructing electrolytes characterized by superior ionic conductivity, electrochemical stability, mechanical robustness, and self-healing functionality. In addition, we discuss supramolecular strategies for engineering functional interfaces of effectively mitigating lithium dendrite formation, reducing interfacial impedance, and significantly enhancing cycle stability. And the detailed mechanistic insights into how these supramolecular interactions foster optimized ionic conduction pathways, structural integrity, and dynamic adaptability are elucidated. This review underscores the transformative potential of supramolecular chemistry in realizing practical and highly efficient next-generation SSLBs.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"4 ","pages":"Article 100118"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145157270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ratiometric luminescent temperature sensor based on amorphous complex of europium (III) and quantum dots 基于非晶铕(III)与量子点配合物的比例发光温度传感器
Supramolecular Materials Pub Date : 2025-12-01 Epub Date: 2025-02-01 DOI: 10.1016/j.supmat.2025.100098
Ruzanna M. Ziyatdinova, Andrey A. Knyazev, Dmitriy O. Sagdeev, Yuriy G. Galyametdinov
{"title":"Ratiometric luminescent temperature sensor based on amorphous complex of europium (III) and quantum dots","authors":"Ruzanna M. Ziyatdinova,&nbsp;Andrey A. Knyazev,&nbsp;Dmitriy O. Sagdeev,&nbsp;Yuriy G. Galyametdinov","doi":"10.1016/j.supmat.2025.100098","DOIUrl":"10.1016/j.supmat.2025.100098","url":null,"abstract":"<div><div>This work reports synthesis of core-shell CdSe/CdS/ZnS quantum dots (QD) and the amorphous β-diketonate Eu(CPDK<sub>3–5</sub>)<sub>3</sub>bpy<sub>17–17</sub> complex. Oleic and stearic acids were used to stabilize colloid nanoparticles and disperse them in organic solvents. Hybrid films of polymethyl methacrylate with various mass ratios of doped quantum dots and europium complexes were produced by spin-coating. The application potential of these materials as ratiometric temperature sensors was analyzed. The produced films demonstrated the highest sensitivity of photoluminescence in the temperature range of 298 – 393 K among other known analogues.</div></div>","PeriodicalId":101187,"journal":{"name":"Supramolecular Materials","volume":"4 ","pages":"Article 100098"},"PeriodicalIF":0.0,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143377395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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