Solar CellsPub Date : 1991-05-01Epub Date: 2003-03-05DOI: 10.1016/0379-6787(91)90050-Y
M. Isomura, X. Xu, S. Wagner
{"title":"What can we learn from the saturation of light-induced defects in amorphous hydrogenated silicon?","authors":"M. Isomura, X. Xu, S. Wagner","doi":"10.1016/0379-6787(91)90050-Y","DOIUrl":"10.1016/0379-6787(91)90050-Y","url":null,"abstract":"<div><p>At a sufficiently high photon flux the density of light-induced defects in amorphous hydrogenated silicon (a-Si:H) can be made to saturate within a few hours. The saturated defect density <span><math><mtext>N</mtext><msub><mi></mi><mn><mtext>sat</mtext></mn></msub></math></span> is independent of light intensity, of temperature and of further illumination over a wide range of conditions. Therefore, <span><math><mtext>N</mtext><msub><mi></mi><mn><mtext>sat</mtext></mn></msub></math></span> can serve as a robust criterion for the rapid evaluation of the stability of a-Si:H. In this paper we show that <span><math><mtext>N</mtext><msub><mi></mi><mn><mtext>sat</mtext></mn></msub></math></span> is correlated with the rate of defect buildup during light-soaking, so that the entire defect history and the useful life of a particular sample may be inferred from <span><math><mtext>N</mtext><msub><mi></mi><mn><mtext>sat</mtext></mn></msub></math></span>. So far, we have measured values of <span><math><mtext>N</mtext><msub><mi></mi><mn><mtext>sat</mtext></mn></msub></math></span> between 4 × 10<sup>16</sup> and 2 × 10<sup>17</sup> cm<sup>−3</sup> in electronic-grade a-Si:H. <span><math><mtext>N</mtext><msub><mi></mi><mn><mtext>sat</mtext></mn></msub></math></span>, and thus the rate of defect buildup, rises with the value of the band gap and with the hydrogen content; it drops with increasing deposition temperature. <span><math><mtext>N</mtext><msub><mi></mi><mn><mtext>sat</mtext></mn></msub></math></span> is not correlated with either the initial defect density or the Urbach energy. We demonstrate an application of the correlation between the saturated defect density and the optical gap to predict the long-term performance of solar cells.</p></div>","PeriodicalId":101172,"journal":{"name":"Solar Cells","volume":"30 1","pages":"Pages 177-191"},"PeriodicalIF":0.0,"publicationDate":"1991-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0379-6787(91)90050-Y","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72774499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar CellsPub Date : 1991-05-01Epub Date: 2003-03-05DOI: 10.1016/0379-6787(91)90068-Z
L.M. Fraas, J.E. Avery, P.E. Gruenbaum, R.J. Ballantyne, E. Malocsay
{"title":"Tandem gallium solar cell voltage-matched circuit performance projections","authors":"L.M. Fraas, J.E. Avery, P.E. Gruenbaum, R.J. Ballantyne, E. Malocsay","doi":"10.1016/0379-6787(91)90068-Z","DOIUrl":"10.1016/0379-6787(91)90068-Z","url":null,"abstract":"<div><p>Using tandem cell test units with GaAs and GaSb concentrator cells, we have achieved a NASA verified conversion efficiency of 30.8% for space applications. Here, we describe tandem gallium cell assemblies and flex circuit tape interconnect concepts for use in practical power generating concentrator panels. The forward and reverse characteristics of tandem cell voltage-matched circuits are described. It is noted that the GaSb IR cell doubles as a bypass diode, providing shading protection for the GaAs cell.</p></div>","PeriodicalId":101172,"journal":{"name":"Solar Cells","volume":"30 1","pages":"Pages 355-361"},"PeriodicalIF":0.0,"publicationDate":"1991-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0379-6787(91)90068-Z","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89910879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar CellsPub Date : 1991-05-01Epub Date: 2003-03-05DOI: 10.1016/0379-6787(91)90063-U
S.A. Hussien, P. Colter, A. Dip, J.R. Gong, M.U. Erdogan, S.M. Bedair
{"title":"Materials aspects of multijunction solar cells","authors":"S.A. Hussien, P. Colter, A. Dip, J.R. Gong, M.U. Erdogan, S.M. Bedair","doi":"10.1016/0379-6787(91)90063-U","DOIUrl":"10.1016/0379-6787(91)90063-U","url":null,"abstract":"<div><p>Atomic layer epitaxy (ALE) was used to grow several components of the cascade solar cell structure in the AlGaAs/GaAs system. An ALE reactor was constructed for multiwafer growth with a growth rate of 0.6 μm h<sup>−1</sup>. Device quality GaAs and <span><math><mtext>As</mtext><msub><mi></mi><mn>x</mn></msub><mtext>Ga</mtext><msub><mi></mi><mn>1−x</mn></msub><mtext>As</mtext></math></span> films were grown with p-type background carbon doping in the ranges 10<sup>15</sup>–10<sup>19</sup> cm<sup>−3</sup> and 10<sup>16</sup>–10<sup>20</sup> cm<sup>−3</sup> respectively. N-type films were achieved by SiH<sub>4</sub> doping, producing carrier concentrations in the range 10<sup>16</sup>–10<sup>18</sup> cm<sup>−3</sup>. In addition, the potential applications of the ALE technique in the photovoltaic field are discussed.</p></div>","PeriodicalId":101172,"journal":{"name":"Solar Cells","volume":"30 1","pages":"Pages 305-311"},"PeriodicalIF":0.0,"publicationDate":"1991-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0379-6787(91)90063-U","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72900496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar CellsPub Date : 1991-05-01Epub Date: 2003-03-05DOI: 10.1016/0379-6787(91)90078-4
T.A. Gessert, X. Li, T.J. Coutts
{"title":"Practical guidelines for grid metallization in photovoltaic solar cell research","authors":"T.A. Gessert, X. Li, T.J. Coutts","doi":"10.1016/0379-6787(91)90078-4","DOIUrl":"10.1016/0379-6787(91)90078-4","url":null,"abstract":"<div><p>During the research stage, many photovoltaic solar cells suffer substantial power loss due to the use of non-optimum top contact grids. The very nature of solar cell research implies that many cell parameters will be in a continual state of change and thus the grid will seldom be truly optimized. However, several things can be done to ensure that a solar cell grid will perform well even if the parameters vary. In this paper, critical parameters for solar cell grid modeling and design are identified and discussed. Particular attention is paid to the manner in which process aspects affect these parameters and the subsequent power loss of the grid. Finally, practical guidelines are presented, the use of which can minimize the effect of process variation.</p></div>","PeriodicalId":101172,"journal":{"name":"Solar Cells","volume":"30 1","pages":"Pages 459-472"},"PeriodicalIF":0.0,"publicationDate":"1991-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0379-6787(91)90078-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84993725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar CellsPub Date : 1991-05-01Epub Date: 2003-03-05DOI: 10.1016/0379-6787(91)90067-Y
R. Venkatasubramanian, M.L. Timmons, T.S. Colpitts, J.S. Hills
{"title":"Advances in the development of an AlGaAs/GaAs cascade solar cell using a patterned germanium tunnel interconnect","authors":"R. Venkatasubramanian, M.L. Timmons, T.S. Colpitts, J.S. Hills","doi":"10.1016/0379-6787(91)90067-Y","DOIUrl":"10.1016/0379-6787(91)90067-Y","url":null,"abstract":"<div><p>In this paper, we discuss various aspects of the development of an inverted-grown AlGaAs/GaAs cascade solar cell incorporating a patterned germanium tunnel junction. Topics include the development of the Al<sub>0.37</sub>Ga<sub>0.63</sub>As top cell, the growth of the GaAs bottom cell over the patterned germanium tunnel junction, and a technique for selective removal of thin AlGaAs/GaAs heterostructures after lattice-matched growth of germanium substrates. The problems to be overcome for the achievement of around 30% efficiencies in the AlGaAs/GaAs cascade cell under concentrator applications are also discussed.</p></div>","PeriodicalId":101172,"journal":{"name":"Solar Cells","volume":"30 1","pages":"Pages 345-354"},"PeriodicalIF":0.0,"publicationDate":"1991-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0379-6787(91)90067-Y","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80318465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar CellsPub Date : 1991-05-01Epub Date: 2003-03-05DOI: 10.1016/0379-6787(91)90044-P
T.L. Chu, S.S. Chu, C. Ferekides, J. Britt, C.Q. Wu, G. Chen, N. Schultz
{"title":"Thin films of II–VI compounds and alloys","authors":"T.L. Chu, S.S. Chu, C. Ferekides, J. Britt, C.Q. Wu, G. Chen, N. Schultz","doi":"10.1016/0379-6787(91)90044-P","DOIUrl":"10.1016/0379-6787(91)90044-P","url":null,"abstract":"<div><p>II–VI semiconductors and their alloys are promising thin film photovoltaic materials. Polycrystalline films of cadmium telluride (CdTe), zinc telluride (ZnTe), cadmium zinc telluride (<span><math><mtext>Cd</mtext><msub><mi></mi><mn>x</mn></msub><mtext>Zn</mtext><msub><mi></mi><mn>1−x</mn></msub><mtext>Te</mtext></math></span>), and mercury zinc telluride (<span><math><mtext>Hg</mtext><msub><mi></mi><mn>x</mn></msub><mtext>Zn</mtext><msub><mi></mi><mn>1−x</mn></msub><mtext>Te</mtext></math></span>) were deposited onto glass and transparent-conducting-semiconductor (TCS) coated glass substrates by metal-organic chemical vapor deposition. Emphasis was directed to the doping of CdTe films, ohmic contacts to p-CdTe, and thin film CdTe homojunctions. CdTe films may be doped intrinsically or extrinsically; gallium and arsenic were used as the extrinsic n and p dopant respectively. p<sup>+</sup>-ZnTe films deposited <em>in situ</em> were used as an ohmic contact to p-CdTe films. Thin film CdTe homojunctions were prepared by the successive <em>in situ</em> deposition of n-CdTe, p-CdTe, and p<sup>+</sup>-ZnTe films on SnO<sub>2</sub>-coated glass substrates, and their properties were investigated. The properties of <span><math><mtext>Cd</mtext><msub><mi></mi><mn>x</mn></msub><mtext>Zn</mtext><msub><mi></mi><mn>1−x</mn></msub><mtext>Te</mtext></math></span> and <span><math><mtext>Hg</mtext><msub><mi></mi><mn>x</mn></msub><mtext>Zn</mtext><msub><mi></mi><mn>1−x</mn></msub><mtext>Te</mtext></math></span> films with band gap energy in the range 1.65–1.75 eV deposited onto glass and TCS-coated glass substrates were studied.</p></div>","PeriodicalId":101172,"journal":{"name":"Solar Cells","volume":"30 1","pages":"Pages 123-130"},"PeriodicalIF":0.0,"publicationDate":"1991-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0379-6787(91)90044-P","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73976133","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar CellsPub Date : 1991-05-01Epub Date: 2003-03-05DOI: 10.1016/0379-6787(91)90090-C
{"title":"Subject index of volume 30","authors":"","doi":"10.1016/0379-6787(91)90090-C","DOIUrl":"https://doi.org/10.1016/0379-6787(91)90090-C","url":null,"abstract":"","PeriodicalId":101172,"journal":{"name":"Solar Cells","volume":"30 1","pages":"Pages 575-580"},"PeriodicalIF":0.0,"publicationDate":"1991-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0379-6787(91)90090-C","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"137344394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar CellsPub Date : 1991-05-01Epub Date: 2003-03-05DOI: 10.1016/0379-6787(91)90079-5
F.A. Abou-Elfotouh, G.S. Horner, T.J. Coutts, M.W. Wanlass
{"title":"Broad band spectroscopic ellipsometry for the characterization of photovoltaic materials","authors":"F.A. Abou-Elfotouh, G.S. Horner, T.J. Coutts, M.W. Wanlass","doi":"10.1016/0379-6787(91)90079-5","DOIUrl":"10.1016/0379-6787(91)90079-5","url":null,"abstract":"<div><p>The availability of commercial spectroscopic ellipsometers (SE) has been restricted to the UV-visible range from 250–900 nm. Although this is useful for many applications, it must be extended to the near IR region (up to 1700 nm) for the study of the optical behavior of most photovoltaic materials. This paper discusses the development of a broad band (300–1700 nm) SE which has been used to measure the optical characteristics of various materials. Among these are the polycrystalline thin film materials, CuInSe<sub>2</sub> and CdTe (for which single crystal samples have also been investigated), and materials for high efficiency cascade solar cells including InP, InGaAs and InGaAsP. Most of these data are not presently available over such a wide spectral range.</p><p>Experimentally, a rotating polarizer-fixed analyzer ellipsometer with an a.c. detection system has been developed for accurate measurement of ψ and Δ, the relevant ellipsometric parameters, in the near IR. This approach has certain advantages over the rotating analyzer-fixed polarizer systems including reduced sensitivity to room light. The analytical methods include the use of a specially developed computer modeling program which gives ψ and Δ for a given set of values related to the film thickness (which may be finite or zero) and to the optical properties of the substrate.</p></div>","PeriodicalId":101172,"journal":{"name":"Solar Cells","volume":"30 1","pages":"Pages 473-485"},"PeriodicalIF":0.0,"publicationDate":"1991-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0379-6787(91)90079-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75399041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Solar CellsPub Date : 1991-05-01Epub Date: 2003-03-05DOI: 10.1016/0379-6787(91)90051-P
W. Luft, B. Stafford, B. von Roedern
{"title":"Needs of the amorphous silicon program with respect to stabilized module performance","authors":"W. Luft, B. Stafford, B. von Roedern","doi":"10.1016/0379-6787(91)90051-P","DOIUrl":"10.1016/0379-6787(91)90051-P","url":null,"abstract":"<div><p>Amorphous silicon technology offers an avenue for low-cost thin film photovoltaic applications. The performance of amorphous silicon-based solar cells is limited by light-induced degradation. Inadequate description of the electronic phenomena in these materials and devices hampers resolution of this problem. We are posing questions which should stimulate researchers to develop better descriptions for device performance and better microscopic models for defect sites. The issue of Staebler-Wronski degradation should not be addressed separately from initial performance, but research should focus on material and device properties in the stabilized state. The main focus of a-Si:H research sponsored by the U.S. Department of Energy will be improvement of stabilized performance, which we anticipate to accomplish through focused development of optimized multijunction device structures, combined with an improved understanding of materials.</p></div>","PeriodicalId":101172,"journal":{"name":"Solar Cells","volume":"30 1","pages":"Pages 195-205"},"PeriodicalIF":0.0,"publicationDate":"1991-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0379-6787(91)90051-P","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88006297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}