RSC Applied Interfaces最新文献_第10页

Degradation of a lithium cobalt oxide cathode under high voltage operation at an interface with an oxide solid electrolyte† 锂钴氧化物正极在与氧化物固体电解质的界面上高压运行时的降解†。

RSC Applied Interfaces Pub Date : 2024-04-03 DOI: 10.1039/D3LF00251A

Kotaro Ito, Kazuhisa Tamura, Keisuke Shimizu, Norifumi L. Yamada, Kenta Watanabe, Kota Suzuki, Ryoji Kanno and Masaaki Hirayama

{"title":"Degradation of a lithium cobalt oxide cathode under high voltage operation at an interface with an oxide solid electrolyte†","authors":"Kotaro Ito, Kazuhisa Tamura, Keisuke Shimizu, Norifumi L. Yamada, Kenta Watanabe, Kota Suzuki, Ryoji Kanno and Masaaki Hirayama","doi":"10.1039/D3LF00251A","DOIUrl":"https://doi.org/10.1039/D3LF00251A","url":null,"abstract":"Lithium (de)intercalation of layered rocksalt-type cathodes in high-voltage regions is of great importance for achieving a high energy density in lithium batteries. The reversible capacity of LiCoO2 at high voltages is not well known because of oxidative side reactions with the electrolyte species. In this study, a model thin-film battery was fabricated using an epitaxially grown LiCoO2 cathode and an amorphous Li3PO4 solid electrolyte to suppress oxidative degradation. The film battery operated stably at high voltages, ranging up to 4.6 V, without severe side reactions of LiCoO2 and Li3PO4, resulting in a reversible capacity greater than 200 mA h g−1. However, the charge–discharge capacities of the battery decreased with cycling at 4.7 V. In situ synchrotron X-ray diffraction studies revealed an irreversible structural change in LiCoO2 at 3.0 V after charging at 4.7 V. Structural degradation occurred both in the bulk and surface regions of the LiCoO2 film, indicating intrinsic irreversibility of the crystal structure changes of highly delithiated LiCoO2, although the LiCoO2/electrolyte interface remained stable.","PeriodicalId":101138,"journal":{"name":"RSC Applied Interfaces","volume":" 4","pages":" 790-799"},"PeriodicalIF":0.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/lf/d3lf00251a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141561079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microfluidic-organic thin film transistor coupled platform for simple solution exposure† 用于简单溶液暴露的微流体-有机薄膜晶体管耦合平台†。

RSC Applied Interfaces Pub Date : 2024-03-28 DOI: 10.1039/D3LF00269A

Nicholas T. Boileau, Benjamin King, Sparsh Kapar, Ali Najafi Sohi, Joseph G. Manion, Michel Godin and Benoît H. Lessard

引用次数: 0

Electrochromic active matrix with plasmonic metasurfaces† 具有等离子体元表面的电致变色有源矩阵†

RSC Applied Interfaces Pub Date : 2024-03-28 DOI: 10.1039/D3LF00266G

Oliver Olsson, Marika Gugole, Jolie C. Blake, Maxim Chukharkin and Andreas Dahlin

{"title":"Electrochromic active matrix with plasmonic metasurfaces†","authors":"Oliver Olsson, Marika Gugole, Jolie C. Blake, Maxim Chukharkin and Andreas Dahlin","doi":"10.1039/D3LF00266G","DOIUrl":"https://doi.org/10.1039/D3LF00266G","url":null,"abstract":"Reflective pixels made by plasmonic metasurfaces and tuned by electrochromics exhibit significant potential to be used as flexible, polychromatic, electronic paper. This is attributed to their high reflectivity, low power consumption, and ultrathin dimensions. However, to date, only single pixels of electrochromics combined with plasmonics have been demonstrated. To make a graphical display, pixels in a matrix are required. A matrix configuration that has been successful for emissive displays such as liquid crystal displays (LCD) and organic light emitting-diodes (OLED) is the active matrix. Active matrix configurations consist of thin-film transistors (TFT) in an array where the transistors block unwanted signals. In this study, we demonstrate the suitability of a commercial, flexible TFT array as a substrate for depositing plasmonic metasurfaces in a red, green, and blue subpixel configuration. The conjugated polymer PProDOT-Me2 can be directly polymerized onto selected pixels from a monomer solution and individual pixels can be controlled. We demonstrate the ability of the TFT array to function both in an electrochemical 3-electrode setup and as a 2-electrode flexible device.","PeriodicalId":101138,"journal":{"name":"RSC Applied Interfaces","volume":" 4","pages":" 719-727"},"PeriodicalIF":0.0,"publicationDate":"2024-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/lf/d3lf00266g?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141561071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

CdS-carbon black hybrid nanocomposite buffer layer for antimony sulfide solar cells† 用于硫化锑太阳能电池的 CdS-碳黑杂化纳米复合缓冲层†。

RSC Applied Interfaces Pub Date : 2024-03-26 DOI: 10.1039/D3LF00235G

Ronal Edgardo Castellanos-Pineda, Agustin Baron-Jaimes, Mario Alejandro Millán-Franco, Marina Elizabeth Rincón and Oscar Andrés Jaramillo-Quintero

{"title":"CdS-carbon black hybrid nanocomposite buffer layer for antimony sulfide solar cells†","authors":"Ronal Edgardo Castellanos-Pineda, Agustin Baron-Jaimes, Mario Alejandro Millán-Franco, Marina Elizabeth Rincón and Oscar Andrés Jaramillo-Quintero","doi":"10.1039/D3LF00235G","DOIUrl":"https://doi.org/10.1039/D3LF00235G","url":null,"abstract":"Hydrothermal synthesis of antimony sulfide (Sb2S3) has emerged as a suitable method to fabricate Sb2S3 solar cells. Conventionally, a CdS film is essential to obtain homogeneous and high-quality Sb2S3 films, which in turn improves the photovoltaic performance of Sb2S3 devices. However, the CdS film also requires a post-treatment process to achieve the desired electronic conductivity. Herein, we report a hybrid nanocomposite buffer layer consisting of CdS and carbon black nanoparticles synthesized on a TiO2 film by a one-pot chemical bath deposition route. This method enables high electrical conductivity of the buffer layer with low roughness and n-type nature. Thus, devices based on the nanocomposite buffer layer improve the junction quality at the buffer layer/Sb2S3 interface, reducing the trap state recombination. As a result, the power conversion efficiency of the Sb2S3 solar cell increases from 4.95 to 6.03%. Such improvement demonstrates that using the nanocomposite buffer layer is a facile and efficient approach to reduce the need for a post-treatment process of CdS.","PeriodicalId":101138,"journal":{"name":"RSC Applied Interfaces","volume":" 4","pages":" 741-747"},"PeriodicalIF":0.0,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/lf/d3lf00235g?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141561074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Surface modification of bioactive glasses for successful incorporation with poly(lactic-co-glycolic acid) (PLGA)† 对生物活性玻璃进行表面改性，使其与聚乳酸-共聚乙醇酸 (PLGA)† 成功结合

RSC Applied Interfaces Pub Date : 2024-03-26 DOI: 10.1039/D3LF00273J

Nishant Jain, Johannes Schmidt, Oliver Görke, David Karl, Aleksander Gurlo and Franziska Schmidt

{"title":"Surface modification of bioactive glasses for successful incorporation with poly(lactic-co-glycolic acid) (PLGA)†","authors":"Nishant Jain, Johannes Schmidt, Oliver Görke, David Karl, Aleksander Gurlo and Franziska Schmidt","doi":"10.1039/D3LF00273J","DOIUrl":"https://doi.org/10.1039/D3LF00273J","url":null,"abstract":"Bioactive glass (BG)–polymer composites are promising materials for bone grafting in bone tissue regeneration. BG provides rigidity and can initiate bone growth, whereas the polymer matrix provides flexibility and biocompatibility. However, due to the complex composition of BG, incorporation into the polymer matrix is difficult and often leads to unwanted porosity and low interface strength between both components. In this study, we investigate the surface treatment of commercially available micronized melt-derived BG with varying compositions (45S5 and 1393) to improve its incorporation into a poly(lactic-co-glycolic acid) (PLGA) matrix by improving surface roughness, surface charge and active sites on the BG. The surfaces of BG are modified by treatment in simulated body fluid (SBF) for 3 days prior to composite production. This leads to the formation of carbonated hydroxyapatite on the surface of both BG types, as demonstrated by XRD, FTIR, XPS and EDX. This also leads to a change in surface texture and an increase in specific surface area from initially 3 to 116 m2 g−1 and from 2 to 65 m2 g−1 for 45S5 and 1393, respectively. Subsequently, composite PLGA–BG microspheres are fabricated using a probe-ultrasonication assisted solid-in-oil-in-water emulsion method. Additionally, the surface interaction of bioactive glasses with PLGA is discussed in detail.","PeriodicalId":101138,"journal":{"name":"RSC Applied Interfaces","volume":" 4","pages":" 748-758"},"PeriodicalIF":0.0,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/lf/d3lf00273j?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141561075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Oxygen grain-boundary diffusion in (La,Sr)FeO3−δ perovskite-oxides probed by molecular-dynamics simulations† 分子动力学模拟探测(La,Sr)FeO3-δ包晶氧化物中的氧晶界扩散†

RSC Applied Interfaces Pub Date : 2024-03-25 DOI: 10.1039/D3LF00263B

Alexander Bonkowski, John A. Kilner and Roger A. De Souza

{"title":"Oxygen grain-boundary diffusion in (La,Sr)FeO3−δ perovskite-oxides probed by molecular-dynamics simulations†","authors":"Alexander Bonkowski, John A. Kilner and Roger A. De Souza","doi":"10.1039/D3LF00263B","DOIUrl":"https://doi.org/10.1039/D3LF00263B","url":null,"abstract":"Faster grain-boundary diffusion of oxygen has been observed experimentally in polycrystalline samples of Fe-based perovskite oxides at low temperatures, but this behaviour is at present not well understood. In our study, the influence of grain boundaries on oxygen diffusion is studied by means of classical atomistic simulation techniques. Oxygen tracer diffusion coefficients are determined for monocrystalline and polycrystalline simulation cells of orthorhombic La0.9Sr0.1FeO3−δ and cubic La0.6Sr0.4FeO3−δ by molecular-dynamics simulations at temperatures in the range 1000 ≤ T/K ≤ 2000. In particular, the effects of different oxygen nonstoichiometries δ and of equilibrium (as opposed to random) defect distributions were examined. Our results indicate, that the disrupted structures of the grain boundaries hinder oxygen diffusion; that Sr accumulation within grain-boundary regions does not produce faster diffusion; but that faster grain-boundary diffusion is observed when δ is decreased substantially with a consequent decrease in the rate of lattice diffusion.","PeriodicalId":101138,"journal":{"name":"RSC Applied Interfaces","volume":" 4","pages":" 699-710"},"PeriodicalIF":0.0,"publicationDate":"2024-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/lf/d3lf00263b?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141561069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhancement of replacement lithography by combination of photocleavable groups with ultrashort thiolates†‡ 通过将光可裂解基团与超短硫代硫酸盐相结合来增强置换光刻技术†‡

RSC Applied Interfaces Pub Date : 2024-03-22 DOI: 10.1039/D3LF00248A

Christian Fischer, Florian Born and Andreas Terfort

{"title":"Enhancement of replacement lithography by combination of photocleavable groups with ultrashort thiolates†‡","authors":"Christian Fischer, Florian Born and Andreas Terfort","doi":"10.1039/D3LF00248A","DOIUrl":"https://doi.org/10.1039/D3LF00248A","url":null,"abstract":"The radiation-induced replacement lithography of self-assembled monolayers (SAMs) is one of the most flexible patterning techniques in nanotechnology as it not only permits a localized substitution, but also a variation in chemistry when applied in a sequential manner. While it typically proceeds by weakening of the molecule–substrate interactions, we present here an approach in which the molecules within the SAM are cleaved, leaving behind a SAM consisting of ultrashort molecules (thioglycolic acid), which are labile enough to be efficiently replaced with a different kind of molecule. The key of this process was the introduction of a photocleavable ortho-nitrobenzyl (ONB) group carrying hexyl groups, which result in primary SAMs stable enough to withstand the carefully chosen replacement conditions. The primary SAMs were characterized by ellipsometry, infrared reflection spectroscopy (IRRAS) and contact angle goniometry, showing a somewhat surprising conformation of the SAM constituents in which the molecular dipole moment is arranged parallel to the surface. This causes the system carrying only one hexyl group to be more stable than the one with two hexyl groups. Upon irradiation with light of 365 nm, the former molecule becomes easily exchanged by (deuterated) dodecanethiol, as could be quantified by IRRAS, with an exchange yield of >80% at an area dose of 48 J cm−2. As a proof of principle, irradiation was performed with differently patterned masks, demonstrating the viability of the method for lithography.","PeriodicalId":101138,"journal":{"name":"RSC Applied Interfaces","volume":" 4","pages":" 759-770"},"PeriodicalIF":0.0,"publicationDate":"2024-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/lf/d3lf00248a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141561076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Patterned organic layers on gold surfaces prepared by electro-grafting of photolabile-protected aryl diazonium salts† 通过电接枝光可亲和保护芳基重氮盐在金表面制备图案化有机层†。

RSC Applied Interfaces Pub Date : 2024-03-21 DOI: 10.1039/D3LF00208J

Max Taras, Jean-Francois Bergamini, Paula A. Brooksby, Philippe Hapiot, Corinne Lagrost and Yann R. Leroux

引用次数: 0

Prevention of uropathogenic E. coli biofilm formation by hydrophobic nanoparticle coatings on polymeric substrates† 聚合物基底上的疏水纳米粒子涂层可防止尿路致病性大肠杆菌生物膜的形成†。

RSC Applied Interfaces Pub Date : 2024-03-20 DOI: 10.1039/D3LF00241A

Stefanie Dietl, Padryk Merkl and Georgios A. Sotiriou

引用次数: 0

Rare-metal-free high-performance water-activated paper battery: a disposable energy source for wearable sensing devices† 不含稀有金属的高性能水激活纸电池：可穿戴传感设备的一次性能源†。

RSC Applied Interfaces Pub Date : 2024-03-18 DOI: 10.1039/D4LF00039K

Kosuke Ishibashi, Shimpei Ono, Jun Kamei, Koju Ito and Hiroshi Yabu

{"title":"Rare-metal-free high-performance water-activated paper battery: a disposable energy source for wearable sensing devices†","authors":"Kosuke Ishibashi, Shimpei Ono, Jun Kamei, Koju Ito and Hiroshi Yabu","doi":"10.1039/D4LF00039K","DOIUrl":"https://doi.org/10.1039/D4LF00039K","url":null,"abstract":"Lightweight, thin paper-based devices are attracting attention due to their portability, lower metal and plastic use, and smaller environmental impact when discarded. For example, paper-based thin diagnostic devices can be mass-produced and their environmental impact after disposal is low, making them promising rapid diagnostic devices for diseases and infectious diseases, especially in developing countries. This report describes a high-performance paper battery activated by water composed of a Mg–air battery with a neutral electrolyte and a safe, high-performance pigment-based electrocatalyst. The paper battery was fabricated by bonding Mg foil to paper and forming a cathode catalyst and gas diffusion layer (GDL) directly on the opposite surface. The fabricated paper battery achieved an OCV of 1.8 V, a 1.0 V current density of 100 mA cm−2, and a maximum output of 103 mW cm−2. The safety of materials used in the paper battery was also examined. Furthermore, applications of the battery in wearable sensing devices, such as a pulse oximeter (SpO2 sensor) and a GPS logger, were also demonstrated.","PeriodicalId":101138,"journal":{"name":"RSC Applied Interfaces","volume":" 3","pages":" 435-442"},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/lf/d4lf00039k?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140919188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0