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A quantitative study of virtual energy storage for rural heat pump heating system based on vehicle-to-home technology 基于车到家技术的农村热泵供暖系统虚拟储能定量研究
Next Energy Pub Date : 2025-01-24 DOI: 10.1016/j.nxener.2025.100246
Xinjia Gao , Ran Li , Siqi Chen , Yalun Li
{"title":"A quantitative study of virtual energy storage for rural heat pump heating system based on vehicle-to-home technology","authors":"Xinjia Gao ,&nbsp;Ran Li ,&nbsp;Siqi Chen ,&nbsp;Yalun Li","doi":"10.1016/j.nxener.2025.100246","DOIUrl":"10.1016/j.nxener.2025.100246","url":null,"abstract":"<div><div>The advent of novel power systems, predominantly reliant on renewable energy sources such as wind and photovoltaics, has precipitated a surge in demand for energy storage solutions. Buildings are undergoing a metamorphosis, emerging as pivotal actors in the realm of electricity generation and consumption, with vast untapped potential for energy storage. However, current research is marred by a dearth of quantitative methodologies for assessing the existing virtual energy storage (VES) resources within building contexts. As a result, it is challenging to provide an accurate evaluation of their potential value and components. In this study, an equivalent battery model is employed, comprising parameters such as equivalent charging and discharging power and energy storage capacity. Integration of VES into traditional energy storage(TES) frameworks. The potential and composition of VES resources within the building area is analyzed. Then, the VES potential of vehicle-to-home system and heat pumps and building thermal capacity are analyzed for winter electric heating in Beijing. The results show that VES system is capable of delivering a maximum equivalent charging power of 432.816 kW, a maximum equivalent discharging power of 385.376 kW, and an equivalent energy storage capacity of 2165.64 kWh. VES can effectively participate in energy management in rural electric heating through rational design and scheduling. No configuration of TES is required. The objective of this work energy planning in the building sector is to provide practical quantitative tools and strategies. It provides guidance on the design and optimization of future distributed energy systems.</div></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":"7 ","pages":"Article 100246"},"PeriodicalIF":0.0,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143092774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance enhancement of full inorganic Sb2S3 solar cells with MnS hole transport layers 具有MnS空穴传输层的全无机Sb2S3太阳能电池的性能增强
Next Energy Pub Date : 2025-01-23 DOI: 10.1016/j.nxener.2025.100240
Minghong Rui, Hangyu Li, Yuan Li, Wenqi Li, Sumei Wang
{"title":"Performance enhancement of full inorganic Sb2S3 solar cells with MnS hole transport layers","authors":"Minghong Rui,&nbsp;Hangyu Li,&nbsp;Yuan Li,&nbsp;Wenqi Li,&nbsp;Sumei Wang","doi":"10.1016/j.nxener.2025.100240","DOIUrl":"10.1016/j.nxener.2025.100240","url":null,"abstract":"<div><div>The hole transport layer (HTL) is a crucial component in planar antimony sulfide (Sb<sub>2</sub>S<sub>3</sub>) solar cell. However, the issue of high cost, poor environmental stability and toxic benzene-based solvents for preparation represent significant challenges for the efficient organic HTLs. In contrast, low-cost and environmentally friendly inorganic hole transport materials have garnered considerable attention due to their excellent carrier mobility and environmental stability. Herein, thermal evaporated inorganic manganese sulfide (MnS) thin films were prepared as HTL for full inorganic Sb<sub>2</sub>S<sub>3</sub> solar cell. The effects of post-annealing treatment on the structure, photoelectric properties of MnS films and device performance were investigated. The post-annealing treatment enables MnS HTL to exhibit high carrier mobility and suitable energy band matching characteristics, thereby suppressing the internal charge recombination and reducing the voltage loss in the device. This ultimately results in a high photovoltaic conversion efficiency (PCE) of 5.66%, which is more than a twofold increase in efficiency compared to that of device with unannealed MnS HTL. Furthermore, the optimal MnS HTL-based Sb<sub>2</sub>S<sub>3</sub> solar cell demonstrated superior environmental stability (around 5.59% degradation in 30 days), compared to that of device with organic Spiro-OMeTAD HTL (around 20% degradation in 30 days). The study offers a material choice and post-processing solution for the development of high-efficiency all-inorganic Sb<sub>2</sub>S<sub>3</sub> solar cells.</div></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":"7 ","pages":"Article 100240"},"PeriodicalIF":0.0,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143128195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simultaneous production during biogas upgrading: Foundational insights from numerical simulation of dual-reflux pressure swing adsorption 沼气升级过程中的同步生产:双回流变压吸附数值模拟的基本见解
Next Energy Pub Date : 2025-01-22 DOI: 10.1016/j.nxener.2025.100242
Mohd Hardyianto Vai Bahrun , Awang Bono , Norasikin Othman , Muhammad Abbas Ahmad Zaini
{"title":"Simultaneous production during biogas upgrading: Foundational insights from numerical simulation of dual-reflux pressure swing adsorption","authors":"Mohd Hardyianto Vai Bahrun ,&nbsp;Awang Bono ,&nbsp;Norasikin Othman ,&nbsp;Muhammad Abbas Ahmad Zaini","doi":"10.1016/j.nxener.2025.100242","DOIUrl":"10.1016/j.nxener.2025.100242","url":null,"abstract":"<div><div>Biogas upgrading is a key step in improving the properties of biogas, particularly its methane concentration and, consequently, its energy content, by separating carbon dioxide. This process holds significant environmental and economic relevance, especially when high-purity methane and carbon dioxide can be simultaneously produced. In this regard, dual-reflux pressure swing adsorption (DR-PSA) emerges as a promising technology that achieves the separation objective. In this study, a numerical simulation model of a non-isothermal DR-PSA was established using the Aspen Adsorption simulation tool to evaluate the dynamics of the system for binary separation of biogas feed mixture containing 45 mol% CO<sub>2</sub> + 55 mol% CH<sub>4</sub>, using a CO<sub>2</sub>-selective silica gel as the solid adsorbent. The goal was to provide preliminary insights into the capability of the DR-PSA process (with silica gel) to produce two useful products, CH<sub>4</sub> and CO<sub>2</sub>, under typical biogas feed conditions. The behavior of the DR-PSA is described through pressure and temperature profiles within the bed column at cyclic steady-state conditions. The results indicate that, under preliminary unoptimized conditions, 86.0% of CH<sub>4</sub> could be recovered with a purity of 85.8% as a light product, whereas CO<sub>2</sub> enriched to 82.9% was achievable as a heavy product, with a recovery of 82.9%, using a pressure ratio, <em>P</em><sub><em>H</em></sub><em>/P</em><sub><em>L</em></sub> of 5. Further work is recommended to investigate several operating parameters to achieve optimal binary separation with the highest possible recoveries.</div></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":"7 ","pages":"Article 100242"},"PeriodicalIF":0.0,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143092747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reducing the temperature of monofacial double-glass photovoltaic module by enhancing in-plane thermal conductivity 通过提高面内导热系数来降低单面双玻璃光伏组件的温度
Next Energy Pub Date : 2025-01-22 DOI: 10.1016/j.nxener.2024.100236
Xilian Sun , Yangping Tan , Xintao Cui , Lang Zhou , Xiuqin Wei , Jikui Zhang , Wei Xia , Yaokai Liu
{"title":"Reducing the temperature of monofacial double-glass photovoltaic module by enhancing in-plane thermal conductivity","authors":"Xilian Sun ,&nbsp;Yangping Tan ,&nbsp;Xintao Cui ,&nbsp;Lang Zhou ,&nbsp;Xiuqin Wei ,&nbsp;Jikui Zhang ,&nbsp;Wei Xia ,&nbsp;Yaokai Liu","doi":"10.1016/j.nxener.2024.100236","DOIUrl":"10.1016/j.nxener.2024.100236","url":null,"abstract":"<div><div>Photovoltaic cooling is critical to ensure stable and safe operation of PV power stations. Conventional cooling methods focus on heat dissipation from the surface of PV modules. Few studies have shown the in-plane thermal conductivity influence on the temperature of PV modules. In this paper, Al foil with high thermal conductivity was introduced in the PV module, and the in-plane temperature distribution of the monofacial double-glass PV module was investigated. The results show that the temperature decreases gradually from the center to the edge of the PV module, and the maximum temperature and the in-plane temperature difference of Al-incorporated PV modules are lower than that of the standard PV module. Al foil improves the heat dissipation along the in-plane direction and achieves a temperature difference reduction of 6.170 ℃ on the whole PV module. This demonstrates that the improvement of in-plane heat dissipation is of great significance in decreasing the temperature of PV modules. Additionally, the temperature and in-plane temperature difference between PV modules with/without Al foil incorporation increase with the increase of ambient temperature and solar irradiation.</div></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":"7 ","pages":"Article 100236"},"PeriodicalIF":0.0,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143105255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Double three-dimensional structures enabled spherical lithium deposition for advanced lithium metal anode 双三维结构实现了先进金属锂阳极的球形锂沉积
Next Energy Pub Date : 2025-01-15 DOI: 10.1016/j.nxener.2024.100237
Tao Wei , Xingtong Guo , Yanyan Zhou , Mengting Wang , Pengyu Hao , Xiaonuo Jiang , Jiahao Lu , Ruiqi Li , Xiu Ye , Ruizhi Yang
{"title":"Double three-dimensional structures enabled spherical lithium deposition for advanced lithium metal anode","authors":"Tao Wei ,&nbsp;Xingtong Guo ,&nbsp;Yanyan Zhou ,&nbsp;Mengting Wang ,&nbsp;Pengyu Hao ,&nbsp;Xiaonuo Jiang ,&nbsp;Jiahao Lu ,&nbsp;Ruiqi Li ,&nbsp;Xiu Ye ,&nbsp;Ruizhi Yang","doi":"10.1016/j.nxener.2024.100237","DOIUrl":"10.1016/j.nxener.2024.100237","url":null,"abstract":"<div><div>Spherical lithium has gradually attracted much attention due to its smooth surface and small specific surface area, which can effectively avoid serious safety hazards and guarantee higher Coulombic efficiency and longer cycle life. However, how to obtain spherical lithium in lithium metal anodes is still challenging for researchers. In this paper, spherical lithium deposition was realized in a facile-designed double three-dimensional (3D) structure, which was constructed by petaloid metal–organic framework derivatives and 3D nickel foam. Specifically, the prepared composite lithium metal anode was shown to cycle stably for 1600 h at an extremely high areal capacity (6 mAh cm<sup>−2</sup>) and current density (6 mA cm<sup>−2</sup>). We believe that this double 3D design provides a new strategy for achieving spherical lithium deposition and fabricating dendrite-free lithium anodes in the future.</div></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":"7 ","pages":"Article 100237"},"PeriodicalIF":0.0,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143105253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lithium-ion battery recycling evolution: Could entire cell regeneration be the next step? 锂离子电池的回收演变:整个电池的再生会是下一步吗?
Next Energy Pub Date : 2025-01-08 DOI: 10.1016/j.nxener.2024.100234
Ayesha Tariq , Qing Ai , Yifan Zhu , Katlyn Schmeltzer , Tianyou Xie , Jun Lou
{"title":"Lithium-ion battery recycling evolution: Could entire cell regeneration be the next step?","authors":"Ayesha Tariq ,&nbsp;Qing Ai ,&nbsp;Yifan Zhu ,&nbsp;Katlyn Schmeltzer ,&nbsp;Tianyou Xie ,&nbsp;Jun Lou","doi":"10.1016/j.nxener.2024.100234","DOIUrl":"10.1016/j.nxener.2024.100234","url":null,"abstract":"<div><div>Lithium-ion batteries (LIBs) have experienced significant growth across various industries over the past decades. However, the disposal of the spent LIBs, which contributes to a substantial amount of solid waste, has become a rapidly escalating global issue. While numerous recycling techniques focus on recovering individual components of the battery, these oftentimes energy-intensive methods, despite yielding notable results, pose a significant environmental threat due to the generation of toxic by-products. In this review, we investigate the currently practiced industry-scale battery-recycling techniques along with a few lab-scale techniques that hold the potential to be scalable whilst ensuring environmental preservation. After a careful analysis, we steer the readers in the direction of exploring a new green method that targets the convenient and complete regeneration of the LIB.</div></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":"7 ","pages":"Article 100234"},"PeriodicalIF":0.0,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143101058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advanced thermal management with heat pipes in lithium-ion battery systems: Innovations and AI-driven optimization 锂离子电池系统热管的先进热管理:创新和人工智能驱动的优化
Next Energy Pub Date : 2024-12-30 DOI: 10.1016/j.nxener.2024.100223
Mehwish Khan Mahek , Mohamad Ramadan , Mohammed Ghazal , Fahid Riaz , Daniel S. Choi , Mohammad Alkhedher
{"title":"Advanced thermal management with heat pipes in lithium-ion battery systems: Innovations and AI-driven optimization","authors":"Mehwish Khan Mahek ,&nbsp;Mohamad Ramadan ,&nbsp;Mohammed Ghazal ,&nbsp;Fahid Riaz ,&nbsp;Daniel S. Choi ,&nbsp;Mohammad Alkhedher","doi":"10.1016/j.nxener.2024.100223","DOIUrl":"10.1016/j.nxener.2024.100223","url":null,"abstract":"<div><div>Heat pipes (HP) have been extensively used for thermal management in many sectors as a flexible potential heat transfer mechanism, including laptop computer CPUs, projectors, solar collectors, and battery thermal management systems (BTMSs). This study reviews and compiles the latest advancements in using HPs for efficient thermal management of high-performance lithium-ion battery systems. This review examines the most recent BTMS that are based on HPs, with a particular emphasis on the role of artificial intelligence (AI) in optimizing thermal performance. It also addresses significant distinctions from prior research, including AI-driven predictive models and hybrid cooling techniques. A classification is created using various wick topologies, working fluids within a lithium-ion BTMS's temperature range, and their appropriate envelope materials. The instances of each one's application in the BTMS or potential uses in the future have been presented. HPs are divided into several categories depending on their form (tubular, flat, loop, etc.) and each variety is given thorough explanations, illustrations, and data on how it performed in various trials. Furthermore, extensive literature research reveals AI's role in fine-tuning operational parameters, crafting algorithms to predict core temperatures in HP systems, and employing advanced optimization and deep learning techniques for efficient and safe management of HP-cooled reactors under stringent power limitations. Moreover, hybrid cooling strategies, including air-cooled, liquid-cooled, phase change material (PCM) cooled, and thermoelectrically cooled HPs, are also highlighted. Future research work recommendations have been provided for several studies on HPs to cool lithium-ion batteries.</div></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":"7 ","pages":"Article 100223"},"PeriodicalIF":0.0,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143101059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Catalytic ammonia cracking: Future of material chemistry research for sustainable hydrogen energy economy 催化氨裂解:可持续氢能源经济材料化学研究的未来
Next Energy Pub Date : 2024-12-30 DOI: 10.1016/j.nxener.2024.100227
Rituraj Dubey , Rajasekhar Bhimireddi , Youngil Lee , Laxman Singh
{"title":"Catalytic ammonia cracking: Future of material chemistry research for sustainable hydrogen energy economy","authors":"Rituraj Dubey ,&nbsp;Rajasekhar Bhimireddi ,&nbsp;Youngil Lee ,&nbsp;Laxman Singh","doi":"10.1016/j.nxener.2024.100227","DOIUrl":"10.1016/j.nxener.2024.100227","url":null,"abstract":"<div><div>To date, no one can imagine our sustainable growth without developing efficient energy storage, utilization of renewable energies sources, transportation, energy saving. In order to look into the alternatives of traditional fossil fuels to renewable energy sources, in recent times, significant development carried out towards sustainable hydrogen production. Moreover, its physio-chemical characteristics create its transport and storage one of the major obstacles for its commercial-scale applications. To resolve this issue, ammonia, a gas of having large hydrogen quantity and energy density, has proved itself as a promising zero-carbon energy transporter for mass energy storage. Catalytic ammonia cracking has been used for hydrogen regeneration due to non-production of NOx. Herein, we have discussed about its various protocols to conceptuealize <em>“hydrogen-energy economy”</em> which is an integrated development of hydrogen production protocols, storage methods, and followed by utilization as energy through fuel cells.</div></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":"7 ","pages":"Article 100227"},"PeriodicalIF":0.0,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143092748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The potentials of vehicle-grid integration on peak shaving of a community considering random behavior of aggregated vehicles 考虑车辆随机行为的车网融合在社区调峰中的潜力
Next Energy Pub Date : 2024-12-28 DOI: 10.1016/j.nxener.2024.100233
Yalun Li , Kun Wang , Chaojie Xu , Yu Wu , Liguo Li , Yuejiu Zheng , Shichun Yang , Hewu Wang , Minggao Ouyang
{"title":"The potentials of vehicle-grid integration on peak shaving of a community considering random behavior of aggregated vehicles","authors":"Yalun Li ,&nbsp;Kun Wang ,&nbsp;Chaojie Xu ,&nbsp;Yu Wu ,&nbsp;Liguo Li ,&nbsp;Yuejiu Zheng ,&nbsp;Shichun Yang ,&nbsp;Hewu Wang ,&nbsp;Minggao Ouyang","doi":"10.1016/j.nxener.2024.100233","DOIUrl":"10.1016/j.nxener.2024.100233","url":null,"abstract":"<div><div>With large-scale electric vehicles (EVs) promoted and connected to the power grid, the uncontrolled charging of EVs enlarges the peak-valley range of load in the distribution grid. To alleviate the peak-valley range and enhance the stability of the distribution grid, vehicle-grid integration (VGI) is proposed as an economic and potential solution. However, the impact of disorderly charging and the potential of VGI considering random user behavior requires clarification. This paper established a mixed-integer linear programming model with user behavior simulated by the Monte Carlo algorithm. The travel and charging behavior of EVs are provided by Monte Carlo simulation with characteristic parameters from statistical data of urban vehicle travel data. A digital model describing the VGI charging boundary is built to restrict the transition from uncontrolled charging to VGI. Through analysis of the global optimization results, the comparison of disorderly charging with VGI under different scenarios is provided to illustrate the effectiveness of avoiding load uplift and reducing load peak-valley range. In a typical residential community with 100 EVs per 1000 people, disorderly charging increases the peak load by 17.1%, while VGI, with a participation ratio of 30%, reduces the load range by 74.8%. This study clearly demonstrates the effectiveness of VGI and guides the implementation of VGI in the rapid growth of EVs.</div></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":"7 ","pages":"Article 100233"},"PeriodicalIF":0.0,"publicationDate":"2024-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143105254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Constructing hierarchical hollow microspheres with Co9S8-modified CoS nanosheets for high-performance sodium storage 用co9s8修饰CoS纳米片构建层次化中空微球用于高性能钠存储
Next Energy Pub Date : 2024-12-24 DOI: 10.1016/j.nxener.2024.100230
Yamei Wang , Rui Wu , Xiaobin Niu , Hanchao Li , Jun Song Chen , Wei Li
{"title":"Constructing hierarchical hollow microspheres with Co9S8-modified CoS nanosheets for high-performance sodium storage","authors":"Yamei Wang ,&nbsp;Rui Wu ,&nbsp;Xiaobin Niu ,&nbsp;Hanchao Li ,&nbsp;Jun Song Chen ,&nbsp;Wei Li","doi":"10.1016/j.nxener.2024.100230","DOIUrl":"10.1016/j.nxener.2024.100230","url":null,"abstract":"<div><div>Transition metal sulfides have drawn increasing attention as anode materials for sodium-ion batteries (SIBs) due to their high theoretical capacities. However, their practical application is still hindered by the rapid decay of capacity and severe volume variation during cycling. Herein, we constructed a hollow microspheres material composed of Co<sub>9</sub>S<sub>8</sub>-modified CoS nanosheets with the heterostructured interface through a one-step solvothermal method. When applied as the anode for SIBs, CoS/Co<sub>9</sub>S<sub>8</sub> exhibited a superior specific capacity of 600 mAh g<sup>−1</sup> after 100 cycles at 0.5 A g<sup>−1</sup>, and a remarkable cycling performance of 456 mAh g<sup>−1</sup> after 1500 cycles at 5 A g<sup>−1</sup>. The outstanding electrochemical performance can be owed to the unique three-dimensional hollow hierarchical structure, which can effectively alleviate volume expansion during cycling. Moreover, density functional theory calculation further verified the improved electronic conductivity and structural stability because of the CoS/Co<sub>9</sub>S<sub>8</sub> heterostructure.</div></div>","PeriodicalId":100957,"journal":{"name":"Next Energy","volume":"7 ","pages":"Article 100230"},"PeriodicalIF":0.0,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143105256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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