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Recent progress on advanced high energy electrode materials for sodium ion batteries 钠离子电池高能电极材料研究进展
Green Energy and Resources Pub Date : 2023-09-01 DOI: 10.1016/j.gerr.2023.100033
Muhammad Mamoor , Yi Li , Lu Wang , Zhongxin Jing , Bin Wang , Guangmeng Qu , Lingtong Kong , Yiyao Li , Zaiping Guo , Liqiang Xu
{"title":"Recent progress on advanced high energy electrode materials for sodium ion batteries","authors":"Muhammad Mamoor ,&nbsp;Yi Li ,&nbsp;Lu Wang ,&nbsp;Zhongxin Jing ,&nbsp;Bin Wang ,&nbsp;Guangmeng Qu ,&nbsp;Lingtong Kong ,&nbsp;Yiyao Li ,&nbsp;Zaiping Guo ,&nbsp;Liqiang Xu","doi":"10.1016/j.gerr.2023.100033","DOIUrl":"https://doi.org/10.1016/j.gerr.2023.100033","url":null,"abstract":"<div><p>The growing demand for sodium-ion batteries (SIBs) in commercial applications has made it imperative to meet the commercial requirements. However, SIBs face significant challenges because of their poor cyclability and low reversible capacity compared with their rival lithium-ion batteries (LIBs). To address these challenges, various techniques, design strategies, surface engineering, and structural modifications have been developed to enhance the electrochemical performance of SIBs. This review focuses on recent developments in improving the electrochemical performance and cyclability of novel promising electrode materials for SIBs. We discuss several unique state-of-the-art research studies of the past five years that demonstrated excellent electrochemical performance through effective methodologies, surface modulations, and substitution of novel elements into the structure, and boosted the efficiency of the materials. Furthermore, we propose that it is important to adopt a nuanced approach when designing SIBs. Rather than copying the designs and methods used for LIBs, ideas should be absorbed from them and approaches should be tailored to meet the specific requirements of SIBs. This will enable the development of SIBs that are optimized for their intended applications and will avoid the challenges that have hindered the commercial success of earlier attempts at constructing SIBs. Thus, the key to creating high-performance SIBs is to draw inspiration from the best practices used in LIBs, while simultaneously innovating and developing new approaches tailored to the unique characteristics of SIBs.</p></div>","PeriodicalId":100597,"journal":{"name":"Green Energy and Resources","volume":"1 3","pages":"Article 100033"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49701185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Reactivation and utilization study of melting furnace slag generated from co-processing MSW incineration fly ash 城市生活垃圾焚烧飞灰共处理产生的熔炉渣再活化及利用研究
Green Energy and Resources Pub Date : 2023-09-01 DOI: 10.1016/j.gerr.2023.100035
Yunyun Li , Tao Li , Yue Li , Siqi Zhang , Xinying chen , Hongjue Yan , Xiaoming Liu , Wen Ni
{"title":"Reactivation and utilization study of melting furnace slag generated from co-processing MSW incineration fly ash","authors":"Yunyun Li ,&nbsp;Tao Li ,&nbsp;Yue Li ,&nbsp;Siqi Zhang ,&nbsp;Xinying chen ,&nbsp;Hongjue Yan ,&nbsp;Xiaoming Liu ,&nbsp;Wen Ni","doi":"10.1016/j.gerr.2023.100035","DOIUrl":"https://doi.org/10.1016/j.gerr.2023.100035","url":null,"abstract":"<div><p>Melting furnace slag (MFS) is a potentially active by-product of the synergistic treatment of iron and steel dust sludge and Municipal Solid Waste (MSW) incineration fly ash in the flue gas magnetization fusion separator furnace of the “fire method + wet method”. This paper focuses on the MFS reactivated by mechanical grinding, and the reactivity of MFS is synergistically enhanced by alkaline, sulfate-based solid wastes. The particle size distribution, specific surface area, morphology, and physical phase composition of MFS with different grinding times resulted in the best performance of MFS when mechanically ground for 80 min and the specific surface area reached 450 m<sup>2</sup>/kg, and the reactivity indexes reached 100.94% and 103.7% for 7 and 28 d, respectively. The synergistic activation of steel slag and flue-gas desulfurization gypsum can play an effective role in stimulating the MFS, and the optimal proportion is m (MFS): m (SS): m (FGDG) = 42%: 42%: 16%. The reactivity enhancement mechanism of the ternary slag-based system on MFS: SS provides high alkalinity hydration reaction conditions for MFS and FGDG provides SO<sub>4</sub><sup>2−</sup>, which continuously promotes the hydrolysis of MFS under the synergistic reactivity stimulation to generate AFt and C–S–H gels.</p></div>","PeriodicalId":100597,"journal":{"name":"Green Energy and Resources","volume":"1 3","pages":"Article 100035"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949720523000322/pdfft?md5=85711bba66bdd34b71e881c82d321a81&pid=1-s2.0-S2949720523000322-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92045589","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrothermal carbonization coupled with pyrolysis: An innovative approach to digestate management 热液碳化与热解相结合:一种创新的消化管理方法
Green Energy and Resources Pub Date : 2023-09-01 DOI: 10.1016/j.gerr.2023.100034
Ziyi Shi , Sirui Liu , Shule Wang , Lukasz Niedzwiecki , Marcin Baranowski , Michał Czerep , Chuchu Tang , Sibudjing Kawi , Chi-Hwa Wang , Jianchun Jiang , Mikael S. Hedenqvist , Halina Pawlak-Kruczek , Wangzhong Mu , Yuming Wen , Pär Göran Jönsson , Weihong Yang
{"title":"Hydrothermal carbonization coupled with pyrolysis: An innovative approach to digestate management","authors":"Ziyi Shi ,&nbsp;Sirui Liu ,&nbsp;Shule Wang ,&nbsp;Lukasz Niedzwiecki ,&nbsp;Marcin Baranowski ,&nbsp;Michał Czerep ,&nbsp;Chuchu Tang ,&nbsp;Sibudjing Kawi ,&nbsp;Chi-Hwa Wang ,&nbsp;Jianchun Jiang ,&nbsp;Mikael S. Hedenqvist ,&nbsp;Halina Pawlak-Kruczek ,&nbsp;Wangzhong Mu ,&nbsp;Yuming Wen ,&nbsp;Pär Göran Jönsson ,&nbsp;Weihong Yang","doi":"10.1016/j.gerr.2023.100034","DOIUrl":"https://doi.org/10.1016/j.gerr.2023.100034","url":null,"abstract":"<div><p>Anaerobic digestion presents a viable approach for managing biodegradable waste. However, the process generates a significant amount of digestate, which, if not appropriately managed, can contribute to eutrophication and salinization. This research explores the integration of hydrothermal carbonization (HTC) and pyrolysis as a potential solution for digestate management, emphasizing volume reduction and energy recovery. The study specifically focuses on the production of biochar from agricultural waste digestate (AWD) in an energy-efficient manner. Utilizing HTC as a pretreatment was found to enhance the heating value of both the AWD and the subsequent pyrolytic char, and it also improved the carbonization degree of the resulting char. Energy balance analysis revealed that the pyrolysis of AWD shifted from an endothermic to an exothermic reaction upon HTC pretreatment. This transition decreased the reaction's energy absorption from 41.1 to 1557.6 MJ to an energy release of 685.1 to 960.6 MJ per ton of digestate, thereby optimizing energy consumption in digestate management. Additionally, it was noted that using acetone as a solvent in gas chromatography for biooil samples with high ammonia content led to the formation of diacetonamine, an outcome that is deemed undesirable.</p></div>","PeriodicalId":100597,"journal":{"name":"Green Energy and Resources","volume":"1 3","pages":"Article 100034"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2949720523000310/pdfft?md5=eebaba029eb841553fbfbcea5e80801c&pid=1-s2.0-S2949720523000310-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92045631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in single-atom catalysts for electrocatalytic synthesis of hydrogen peroxide 电催化合成过氧化氢的单原子催化剂研究进展
Green Energy and Resources Pub Date : 2023-09-01 DOI: 10.1016/j.gerr.2023.100031
Helai Huang , Mingze Sun , Mei Li , Lei Tang , Shengbo Zhang
{"title":"Recent advances in single-atom catalysts for electrocatalytic synthesis of hydrogen peroxide","authors":"Helai Huang ,&nbsp;Mingze Sun ,&nbsp;Mei Li ,&nbsp;Lei Tang ,&nbsp;Shengbo Zhang","doi":"10.1016/j.gerr.2023.100031","DOIUrl":"https://doi.org/10.1016/j.gerr.2023.100031","url":null,"abstract":"<div><p>The electro-synthesis of hydrogen peroxide has attracted extensive research interest and is expected to replace conventional chemical processes as a mild and safe approach. Single-atom catalysts (SACs) have been applied in a wide variety of thermo- and electro-chemical reactions due to their high atom utilization and highly tunable electronic structure. Herein, an in-depth discussion on recent advances of SACs in the field of hydrogen peroxide electro-synthesis is summarized, specifically on the surface structure and electronic effects that enable high activity and selectivity of SACs. Different synthesis and modification strategies of SACs are discussed in detail, emphasizing the remarkable versatility of SACs utilization in this field. Finally, the opportunities and challenges of SACs for electrocatalytic synthesis of hydrogen peroxide are summarized in terms of rational design, controlled synthesis, and the stability of operation at high current densities of SACs to meet practical requirements.</p></div>","PeriodicalId":100597,"journal":{"name":"Green Energy and Resources","volume":"1 3","pages":"Article 100031"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49703040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced functional properties of porous carbon materials as high-performance electrode materials for supercapacitors 多孔碳材料作为超级电容器高性能电极材料的增强功能特性
Green Energy and Resources Pub Date : 2023-09-01 DOI: 10.1016/j.gerr.2023.100030
Kai Yang , Qingwen Fan , Chaoyun Song , Yuchun Zhang , Yongmei Sun , Wen Jiang , Peng Fu
{"title":"Enhanced functional properties of porous carbon materials as high-performance electrode materials for supercapacitors","authors":"Kai Yang ,&nbsp;Qingwen Fan ,&nbsp;Chaoyun Song ,&nbsp;Yuchun Zhang ,&nbsp;Yongmei Sun ,&nbsp;Wen Jiang ,&nbsp;Peng Fu","doi":"10.1016/j.gerr.2023.100030","DOIUrl":"https://doi.org/10.1016/j.gerr.2023.100030","url":null,"abstract":"<div><p>Porous carbons with unique electronic, chemical, and surface properties have become a research hotspot in energy storage applications. But the electrodes of porous carbons in supercapacitors cannot meet the ever-inrceasing demands for high energy density for electronic devices. Heteroatom, metal oxide and conductive polymer can provide pseudo-capacitance for porous carbon materials during charging and discharging to improve energy density. Therefore, it is of great interest to develop modified porous carbon composites as electrode materials for supercapacitors. In this review, after a brief introduction for electrochemcial capacitors, we summarize the advances in the recent years, in the preparation and properties of porous carbons for applications in supercapacitors. The advantages and disadvantages of activated carbon, template carbon, carbon nanotubes (CNTs) and graphene are analyzed. Different ways of modification have their own effects on the development of high-performance supercapacitors. Finally, the challenges in the modified porous carbon composites and its future perspectives are highlighted to provide a key insight to the promising factors for future developments of supercapacitor electrodes.</p></div>","PeriodicalId":100597,"journal":{"name":"Green Energy and Resources","volume":"1 3","pages":"Article 100030"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49703041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Advances in CaO-based catalysts for sustainable biodiesel synthesis 可持续生物柴油合成用cao基催化剂研究进展
Green Energy and Resources Pub Date : 2023-09-01 DOI: 10.1016/j.gerr.2023.100032
Siri Fung Basumatary , Sona Brahma , Mainul Hoque , Basanta Kumar Das , Manickam Selvaraj , Sujata Brahma , Sanjay Basumatary
{"title":"Advances in CaO-based catalysts for sustainable biodiesel synthesis","authors":"Siri Fung Basumatary ,&nbsp;Sona Brahma ,&nbsp;Mainul Hoque ,&nbsp;Basanta Kumar Das ,&nbsp;Manickam Selvaraj ,&nbsp;Sujata Brahma ,&nbsp;Sanjay Basumatary","doi":"10.1016/j.gerr.2023.100032","DOIUrl":"https://doi.org/10.1016/j.gerr.2023.100032","url":null,"abstract":"<div><p>It is no longer unfamiliar to the world that usage of fossil-derived fuel is accompanied by several downsides, including environmental fatality associated with toxic gas emissions from diesel engines and the recurring surging price of diesel fuel. The concern regarding the exploitation of natural resources and subsequent environmental threats has caught the attention of all nations. Therefore, scientists have stepped forward to come up with the most suitable alternative to conventional diesel fuel. They utilized abundance of oil feedstocks and performed transesterification reactions with short-chain alcohols to produce less toxic, eco-friendly diesel fuel termed biodiesel which was considered to be a viable substitute. In order to carry out the transesterification reaction feasibly, certain homogeneous and heterogeneous catalysts were employed. Heterogeneous catalysts got more recognition among researchers; however, many of these catalysts did not attain large-scale production. Among many heterogeneous catalysts, calcium oxide (CaO) appeared to be one of the most suitable heterogeneous solid base catalysts for biodiesel synthesis. CaO can be derived chemically as well as from natural sources such as chicken eggshells, snail shells, biont shells and many more. CaO exhibits high catalytic activity to perform transesterification reactions. Additionally, CaO is a cheap and eco-friendly catalyst that can also be used as support material for various catalyst systems. Constructing effective CaO-based catalysts for industrial biodiesel production unlock the scope for process advancements in this area. This paper aims to review the catalytic performances of recently reported CaO as heterogeneous solid-base catalytic systems for the production of biodiesel. Moreover, the catalyst preparation conditions, various reaction parameters, properties of biodiesel obtained, advantages and disadvantages, life cycle assessment, and circular economy are discussed.</p></div>","PeriodicalId":100597,"journal":{"name":"Green Energy and Resources","volume":"1 3","pages":"Article 100032"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49703042","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation on in-situ deoxygenation performance of bio-oil model compound guaiacol over Ce-Fe/Al2O3 catalyst 生物油模型化合物愈创木酚在Ce-Fe/Al2O3催化剂上的原位脱氧性能研究
Green Energy and Resources Pub Date : 2023-06-01 DOI: 10.1016/j.gerr.2023.100021
Meiling Yang , Yanming Chen , Yong Wang , Laishun Yang , Weiwei Cui , Yanhui Liu , Cuiping Wang , Qun Chen
{"title":"Investigation on in-situ deoxygenation performance of bio-oil model compound guaiacol over Ce-Fe/Al2O3 catalyst","authors":"Meiling Yang ,&nbsp;Yanming Chen ,&nbsp;Yong Wang ,&nbsp;Laishun Yang ,&nbsp;Weiwei Cui ,&nbsp;Yanhui Liu ,&nbsp;Cuiping Wang ,&nbsp;Qun Chen","doi":"10.1016/j.gerr.2023.100021","DOIUrl":"https://doi.org/10.1016/j.gerr.2023.100021","url":null,"abstract":"<div><p>The investigation of the low-cost deoxygenation of guaiacol (GUA, a model bio-oil compound) is of importance for upgrading bio-oil. At present, common sulfide catalysts for GUA deoxygenation reactions cause contamination of the liquid product, and noble metal catalysts are economically disadvantageous. In this study, four reduced Fe-based oxides with different Ce doping ratios were prepared and their effects on the in-situ deoxygenation performance of GUA in aqueous/methanol hydrogen donor solvents were explored. The results based on the deoxygenation degree, conversion degree, and higher heating value (HHV) of the products showed that the oxide catalyst with a Fe/Ce molar ratio of 2:1 in the methanol solvent performed very well. After selecting an excellent catalyst and a better hydrogen donor solvent, four factors (reaction temperature, reaction time, volume ratio of GUA dosage and methanol dosage, and the ratio of catalyst dosage at the bottom of the reactor to that at the top) in the deoxygenation degree of GUA were investigated using an orthogonal experimental method to further explore the performance of the catalyst. The results showed that the reaction temperature and time greatly influenced GUA deoxygenation. Under optimal experimental conditions, the deoxygenation degree and conversion degree of GUA could reach 34.36% and 92.56%, respectively, based on the relative peak area of gas chromatography–mass spectrometry, and the HHV of the liquid product was 32.27 MJ/kg. Although Fe/Ce catalysts mainly promote demethoxylation, demethylation, and methylation, the stability and quality of the liquid products were improved compared with GUA owing to the reduction in phenolic hydroxyl and ether content. The reduced catalyst in the process of GUA in-situ deoxygenation reactions in methanol maintained a steady performance, as revealed by X-ray diffraction and X-ray fluorescence.</p></div>","PeriodicalId":100597,"journal":{"name":"Green Energy and Resources","volume":"1 2","pages":"Article 100021"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49843178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
New solar-biomass assisted thermophotovoltaic system and parametrical analysis 新型太阳能-生物质辅助热光伏系统及参数化分析
Green Energy and Resources Pub Date : 2023-06-01 DOI: 10.1016/j.gerr.2023.100019
Shiquan Shan , Siqi Jia , Haojin Wu , Qi Zhang , Hongxun Hui , Zhijun Zhou
{"title":"New solar-biomass assisted thermophotovoltaic system and parametrical analysis","authors":"Shiquan Shan ,&nbsp;Siqi Jia ,&nbsp;Haojin Wu ,&nbsp;Qi Zhang ,&nbsp;Hongxun Hui ,&nbsp;Zhijun Zhou","doi":"10.1016/j.gerr.2023.100019","DOIUrl":"https://doi.org/10.1016/j.gerr.2023.100019","url":null,"abstract":"<div><p>This paper proposes a new technical route of solar-biomass assisted thermophotovoltaic (TPV) system for power generation which uses renewable fuel and contributes to carbon neutrality. Here, a thermophysics model is established for solar-biomass assisted TPV based on energy-balance principle. The effects of some key parameters on the new system performance are investigated, including concentrate ratio, emitter area, biomass fuels, etc. Besides, biomass fuel saving after adding solar energy is investigated. The results show that the solar-biomass assisted TPV system can not only increase the output power of photovoltaic cells by more than 10 kW/m<sup>2</sup> compared to biomass-driven TPV but also increase the electrical efficiency by nearly 10 percentage points. It is pointed out that improving the absorptance of solar absorber is the key for system optimization. Furthermore, the annual performance analysis shows that it also saves biomass fuel by up to 60% in one year. This study provides a reference for the design and application of renewable TPV technology.</p></div>","PeriodicalId":100597,"journal":{"name":"Green Energy and Resources","volume":"1 2","pages":"Article 100019"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49880573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Strategies of thermodynamic alternation on organic hydrogen carriers for hydrogen storage application: A review 储氢应用中有机氢载体热力学变化策略综述
Green Energy and Resources Pub Date : 2023-06-01 DOI: 10.1016/j.gerr.2023.100020
Khai Chen Tan , Yong Shen Chua , Teng He , Ping Chen
{"title":"Strategies of thermodynamic alternation on organic hydrogen carriers for hydrogen storage application: A review","authors":"Khai Chen Tan ,&nbsp;Yong Shen Chua ,&nbsp;Teng He ,&nbsp;Ping Chen","doi":"10.1016/j.gerr.2023.100020","DOIUrl":"https://doi.org/10.1016/j.gerr.2023.100020","url":null,"abstract":"<div><p>An explosion of interest has arisen using organic-based materials, specifically cyclic organic hydrogen carriers for hydrogen storage due to their high hydrogen storage capacity, high volumetric energy density, reversibility, and non-toxicity. However, the unfavourable thermodynamic properties and high kinetic barriers of hydrogen desorption from these cyclic organic hydrogen carriers make them to be difficult in large-scale applications. In the past decades, tremendous efforts have been devoted to tailor both thermodynamic and kinetic properties of hydrogen absorption and desorption from such materials. Therefore, in this review, methods of fabrication of new materials in order to modify the dehydrogenation thermodynamic properties are discussed, which include the fusion of multiple organic rings, attachment of electron-donating substituents, incorporation of N/O/S atom into the aromatic rings, and introduction of alkali or alkaline earth metals to replace the protic H atom of O–H or N–H groups. Additionally, demonstrations for potential applications via using organic hydrogen carriers such as toluene, N-ethylcarbazole, and dibenzyl toluene are also described. The challenges and perspectives for the cyclic organic hydrogen storage materials are discussed at the end. It is expected that this review could provide new inspiration to expedite the development of cyclic organic hydrogen carriers with high hydrogen capacity and optimum thermodynamics for hydrogen storage.</p></div>","PeriodicalId":100597,"journal":{"name":"Green Energy and Resources","volume":"1 2","pages":"Article 100020"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49843173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Rationally designed tungsten trioxide nanosheets for high-efficiency aqueous battery application 合理设计三氧化钨纳米片用于高效水性电池
Green Energy and Resources Pub Date : 2023-06-01 DOI: 10.1016/j.gerr.2023.100008
Jinbin Luo , Sheng Qiu , Hao Wang , Benjamin Tawiah , Bin Fei , Hao Jia
{"title":"Rationally designed tungsten trioxide nanosheets for high-efficiency aqueous battery application","authors":"Jinbin Luo ,&nbsp;Sheng Qiu ,&nbsp;Hao Wang ,&nbsp;Benjamin Tawiah ,&nbsp;Bin Fei ,&nbsp;Hao Jia","doi":"10.1016/j.gerr.2023.100008","DOIUrl":"https://doi.org/10.1016/j.gerr.2023.100008","url":null,"abstract":"<div><p>Aqueous battery (AB) with non-metallic charging carriers is a viable candidate for grid energy storage devices owing to its comparatively low cost and high safety. However, developing practical electrode materials with remarkable electrochemical performance remains a great challenge. In this study, tungsten trioxide nanosheets (WONSs) with one-dimensional tunnels were facilely synthesized through a hydrothermal reaction. When used as the cathode material in aqueous batteries, the as-prepared WONS exhibits excellent long-term cycling stability and impressively high rate capability due to the nearly zero-strain structural characteristics of super-fast proton storage. Notably, a stable cycling performance with 89% capacity retention after 10000 cycles was achieved with an increased mass loading of WONS at around 12 mg cm<sup>−2</sup>. Our work points to a new direction of promoting high-efficiency AB applications with protons as charge carriers in a mild electrolyte.</p></div>","PeriodicalId":100597,"journal":{"name":"Green Energy and Resources","volume":"1 2","pages":"Article 100008"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49843177","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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