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Sustainable management of unavoidable biomass wastes 不可避免的生物质废物的可持续管理
Green Energy and Resources Pub Date : 2023-03-01 DOI: 10.1016/j.gerr.2023.100005
Kui Wang , Jefferson William Tester
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引用次数: 8
Pollution-free recycling of lead and sulfur from spent lead-acid batteries via a facile vacuum roasting route 简易真空焙烧法无公害回收废铅酸电池中的铅和硫
Green Energy and Resources Pub Date : 2023-03-01 DOI: 10.1016/j.gerr.2022.100002
Mengmeng Wang , Quanyin Tan , Jiadong Yu , Dong Xia , Wei Zhang , Cong-Cong Zhang , Zhiyuan Zhang , Junxiong Wang , Kang Liu , Jinhui Li
{"title":"Pollution-free recycling of lead and sulfur from spent lead-acid batteries via a facile vacuum roasting route","authors":"Mengmeng Wang ,&nbsp;Quanyin Tan ,&nbsp;Jiadong Yu ,&nbsp;Dong Xia ,&nbsp;Wei Zhang ,&nbsp;Cong-Cong Zhang ,&nbsp;Zhiyuan Zhang ,&nbsp;Junxiong Wang ,&nbsp;Kang Liu ,&nbsp;Jinhui Li","doi":"10.1016/j.gerr.2022.100002","DOIUrl":"https://doi.org/10.1016/j.gerr.2022.100002","url":null,"abstract":"<div><p>Traditional pyrometallurgical recovery of spent lead-acid batteries (LABs) requires a temperature higher than 1000 °C, with accompanying hard-to-collect wastes such as lead dust and sulfur oxides. Against this background, sodium carbonate (Na<sub>2</sub>CO<sub>3</sub>) was proposed as a low-cost, safe, and non-toxic reagent for recycling the high-risk environmental elements lead (Pb) and sulfur (S), in spent LAB lead paste, enabling the one-step conservation of multi-component Pb species, including lead sulfate (PbSO<sub>4</sub>), metallic lead (Pb), and lead dioxide (PbO<sub>2</sub>), to lead oxide (PbO) and sodium sulfate (Na<sub>2</sub>SO<sub>4</sub>). The possible reaction pathways of Pb and S species in vacuum roasting was confirmed by Gibbs free energy reaction with an estimated average activation energy of 272.5 kJ/mol. The insoluble PbO in the reaction product (PbO/Na<sub>2</sub>SO<sub>4</sub>/Na<sub>2</sub>CO<sub>3</sub>) can be recycled by vacuum filtration, while Na<sub>2</sub>CO<sub>3</sub> and Na<sub>2</sub>SO<sub>4</sub> were separated using a carbonation method. Life cycle assessment revealed that for recycling 1.0 t of spent LABs, the vacuum roasting can reduce the carbon footprint −2.1 × 10<sup>3</sup> kg CO<sub>2</sub> eq, promoting global decarbonization. The designed route is highlighted with waste-free production and is outlined by the twelve principles of green chemistry, showing its great engineering application potential for spent LAB recycling.</p></div>","PeriodicalId":100597,"journal":{"name":"Green Energy and Resources","volume":"1 1","pages":"Article 100002"},"PeriodicalIF":0.0,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49877658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
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