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Synthesis of Cyclic Sulfilimines and Sulfoximines via Copper-Mediated C(sp2)–H Sulfanylation of Benzylamines with a Catalytic Transient Directing Group 铜介导的C(sp2) -H磺胺基催化合成环亚胺和亚砜亚胺

ChemistryEurope Pub Date : 2025-08-02 DOI: 10.1002/ceur.202500209

Tsz-Kan Ma, Peerawat Saejong, King-Long Or, Callum S. Begg, James A. Bull

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引用次数: 0

Synthesis of Cyclic Sulfilimines and Sulfoximines via Copper-Mediated C(sp2)–H Sulfanylation of Benzylamines with a Catalytic Transient Directing Group 铜介导的C(sp2) -H磺胺基催化合成环亚胺和亚砜亚胺

ChemistryEurope Pub Date : 2025-08-02 DOI: 10.1002/ceur.202500209

Tsz-Kan Ma, Peerawat Saejong, King-Long Or, Callum S. Begg, James A. Bull

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引用次数: 0

Cover Feature: Alcohol and Carbonyl Redox Reactions in Electrochemical Organic Synthesis (ChemistryEurope 4/2025) 封面专题：电化学有机合成中的醇和羰基氧化还原反应（ChemistryEurope 4/2025）

ChemistryEurope Pub Date : 2025-07-16 DOI: 10.1002/ceur.70006

Fiammetta Vitulano, Andrea Solida, Letizia Sorti, Carlo F. Morelli, Alessandro Minguzzi, Alberto Vertova

引用次数: 0

Cover Feature: Introduction of a Phosphine Group onto the Ferrocene Moiety in Ferrociphenol Opens Access to New Heterobimetallic Complexes with Anticancer Activity (ChemistryEurope 4/2025) 封面特写：在铁酚二茂铁基团上引入磷化氢基团开辟了具有抗癌活性的新型杂双金属配合物的途径（ChemistryEurope 4/2025）

ChemistryEurope Pub Date : 2025-07-16 DOI: 10.1002/ceur.70008

Magda Křelinová, Michèle Salmain, Petr Štěpnička, Ivana Císařová, Benoît Bertrand, Jiří Schulz

引用次数: 0

Front Cover: pH-Controlled Gliding Motions in Pillar[5]arene-Containing Molecular Shuttles (ChemistryEurope 4/2025) 封面：柱[5]含芳烃分子航天飞机的ph控制滑动运动（chemstreurope 4/2025）

ChemistryEurope Pub Date : 2025-07-16 DOI: 10.1002/ceur.70005

Nihed Becharguia, Iwona Nierengarten, Alix Sournia-Saquet, Emeric Wasielewski, Rym Abidi, Béatrice Delavaux-Nicot, Jean-François Nierengarten

引用次数: 0

Cover Feature: Self-Assembly of Silver Nanoclusters by Cooperative Acetylene Bonding with Mutual Pyridyl Coordination (ChemistryEurope 4/2025) 封面特征：通过相互吡啶配合的乙炔键自组装银纳米团簇（ChemistryEurope 4/2025）

ChemistryEurope Pub Date : 2025-07-16 DOI: 10.1002/ceur.70007

Tasuki Tsurumi, Takahiro Nakagawa, Takashi Kikuchi, Kiyohiro Adachi, Hironobu Hayashi, Atsuro Takai, Takuma Kaneko, Tomoya Uruga, Daisuke Hashizume, Yosuke Nakamura, Makoto Fujita, Yuya Domoto

引用次数: 0

Small Molecule Activation by Metallylenes and their Follow-Up Reactions 金属小分子活化及其后续反应

ChemistryEurope Pub Date : 2025-07-11 DOI: 10.1002/ceur.202500119

Eveline H. Tiekink, Matthijs W. Kragtwijk, Trevor A. Hamlin

{"title":"Small Molecule Activation by Metallylenes and their Follow-Up Reactions","authors":"Eveline H. Tiekink, Matthijs W. Kragtwijk, Trevor A. Hamlin","doi":"10.1002/ceur.202500119","DOIUrl":"https://doi.org/10.1002/ceur.202500119","url":null,"abstract":"The activation of small molecules is a crucial step in advancing sustainable chemistry, enabling key transformations in fine chemical synthesis and energy storage. While transition metals have traditionally dominated this field, main-group elements—specifically metallylenes, which are heavier analogs of carbenes (silylenes, germylenes, stannylenes, and plumbylenes)—have emerged as viable alternatives due to their unique electronic properties and tunable reactivity. This review explores the mechanisms by which metallylenes activate small molecules, highlighting the influence of ligand design, electronic structure, and geometric factors. We discuss recent advances in the field, including computational insights into metallylene-mediated bond activation and experimental demonstrations of their catalytic potential. Additionally, we examine follow-up reactions such as hydrogenation and hydroboration, which illustrate the versatility of metallylenes in small-molecule transformation. By providing a comprehensive overview of the latest developments, this review aims to bridge fundamental principles with potential applications, paving the way for metallylene-based catalysis in sustainable chemistry.","PeriodicalId":100234,"journal":{"name":"ChemistryEurope","volume":"3 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/ceur.202500119","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145129061","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Small Molecule Activation by Metallylenes and their Follow-Up Reactions 金属小分子活化及其后续反应

ChemistryEurope Pub Date : 2025-07-11 DOI: 10.1002/ceur.202500119

Eveline H. Tiekink, Matthijs W. Kragtwijk, Trevor A. Hamlin

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引用次数: 0

Magneto-Optical Correlations in a High Symmetry Dysprosium Complex Reveal an Almost “Ideal Non-SMM” and Orange-to-Red DyIII-Based Emitter 高对称镝配合物中的磁光相关揭示了一个几乎“理想的非smm”和橙色到红色的dyiii基发射极

ChemistryEurope Pub Date : 2025-07-09 DOI: 10.1002/ceur.202500193

Nimisha Jain, Gregoire David, Marie Cordier, Yan Suffren, Boris Le Guennic, Yann Sarazin, Kevin Bernot

{"title":"Magneto-Optical Correlations in a High Symmetry Dysprosium Complex Reveal an Almost “Ideal Non-SMM” and Orange-to-Red DyIII-Based Emitter","authors":"Nimisha Jain, Gregoire David, Marie Cordier, Yan Suffren, Boris Le Guennic, Yann Sarazin, Kevin Bernot","doi":"10.1002/ceur.202500193","DOIUrl":"https://doi.org/10.1002/ceur.202500193","url":null,"abstract":"The importance of investigating high-symmetry systems in order to reveal properties that would otherwise be concealed in less symmetrical compounds is demonstrated. This is particularly true for discrete coordination complexes that tend to adopt low symmetries. The magnetic, optical, and theoretical investigation of [Dy{N(SiMe3)2}3], an amido complex that features an almost trigonal electrostatic environment around the DyIII ion, is reported here. While this specific coordination is ideally suited to the stabilization of high magnetic ground state for “prolate” YbIII-based single-molecule magnet (SMM), it is the opposite for oblate DyIII. Hence, [Dy{N(SiMe3)2}3] is expected to display the lowest conceivable magnetic anisotropy. This is confirmed herein by magneto-optical and theoretical correlations. An extremely pure Kramers doublet composition is observed on a totally reversed energetic profile compared to the standard DyIII-SMM. This results in a paramagnetic but dynamically silent compound, even when an external dc field is applied. Additionally, this unusual energetic profile induces an exceptional optical signature, with orange (300 K) to red (4 K) emission, far from the traditional white-to-yellow emission expected for a DyIII ion.","PeriodicalId":100234,"journal":{"name":"ChemistryEurope","volume":"3 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/ceur.202500193","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145128997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Magneto-Optical Correlations in a High Symmetry Dysprosium Complex Reveal an Almost “Ideal Non-SMM” and Orange-to-Red DyIII-Based Emitter 高对称镝配合物中的磁光相关揭示了一个几乎“理想的非smm”和橙色到红色的dyiii基发射极

ChemistryEurope Pub Date : 2025-07-09 DOI: 10.1002/ceur.202500193

Nimisha Jain, Gregoire David, Marie Cordier, Yan Suffren, Boris Le Guennic, Yann Sarazin, Kevin Bernot

{"title":"Magneto-Optical Correlations in a High Symmetry Dysprosium Complex Reveal an Almost “Ideal Non-SMM” and Orange-to-Red DyIII-Based Emitter","authors":"Nimisha Jain, Gregoire David, Marie Cordier, Yan Suffren, Boris Le Guennic, Yann Sarazin, Kevin Bernot","doi":"10.1002/ceur.202500193","DOIUrl":"https://doi.org/10.1002/ceur.202500193","url":null,"abstract":"The importance of investigating high-symmetry systems in order to reveal properties that would otherwise be concealed in less symmetrical compounds is demonstrated. This is particularly true for discrete coordination complexes that tend to adopt low symmetries. The magnetic, optical, and theoretical investigation of [Dy{N(SiMe3)2}3], an amido complex that features an almost trigonal electrostatic environment around the DyIII ion, is reported here. While this specific coordination is ideally suited to the stabilization of high magnetic ground state for “prolate” YbIII-based single-molecule magnet (SMM), it is the opposite for oblate DyIII. Hence, [Dy{N(SiMe3)2}3] is expected to display the lowest conceivable magnetic anisotropy. This is confirmed herein by magneto-optical and theoretical correlations. An extremely pure Kramers doublet composition is observed on a totally reversed energetic profile compared to the standard DyIII-SMM. This results in a paramagnetic but dynamically silent compound, even when an external dc field is applied. Additionally, this unusual energetic profile induces an exceptional optical signature, with orange (300 K) to red (4 K) emission, far from the traditional white-to-yellow emission expected for a DyIII ion.","PeriodicalId":100234,"journal":{"name":"ChemistryEurope","volume":"3 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/ceur.202500193","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145128998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0