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Substantial Global Radial Variations of Basalt Content Near the 660-km Discontinuity 660 千米不连续面附近玄武岩含量的巨大全球径向变化
IF 8.3
AGU Advances Pub Date : 2024-11-06 DOI: 10.1029/2024AV001409
Shangqin Hao, S. Shawn Wei, Peter M. Shearer
{"title":"Substantial Global Radial Variations of Basalt Content Near the 660-km Discontinuity","authors":"Shangqin Hao,&nbsp;S. Shawn Wei,&nbsp;Peter M. Shearer","doi":"10.1029/2024AV001409","DOIUrl":"https://doi.org/10.1029/2024AV001409","url":null,"abstract":"<p>Mid-ocean ridges generate basalt and harzburgite, which are introduced into the mantle through subduction as a mechanical mixture, contributing to both lateral and radial compositional heterogeneity. The possible accumulation of basalt in the mantle transition zone has been examined, but details of the mantle composition below the 660-km discontinuity (hereafter d660) remain poorly constrained. In this study, we utilize the subtle waveform details of <i>S660S</i>, the underside shear-wave reflection off the d660, to interpret the seismic velocity, density, and compositional structure near, and particularly below, the d660. We identify a significant difference in <i>S660S</i> waveform shape in subduction zones compared to other regions. The inversion results reveal globally enriched basalt at the d660, with a notably higher content in subduction zones, consistent with the smaller impedance jump and <i>S660S</i> peak amplitude. The basalt fraction decreases significantly to less than 10% near 800-km depth, forming a global harzburgite-enriched layer and resulting in a steep seismic velocity gradient just below the d660, in agreement with 1D global reference models. The striking compositional radial variations near the d660 verify geodynamic predictions and challenge the applicability of homogeneous radial compositional models in the mantle. These variations may also affect the viscosity profile and, consequently, the dynamics at the boundary between the upper and lower mantle.</p>","PeriodicalId":100067,"journal":{"name":"AGU Advances","volume":"5 6","pages":""},"PeriodicalIF":8.3,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024AV001409","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142599002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Toward Modeling Continental-Scale Inland Water Carbon Dioxide Emissions 建立大陆尺度内陆水域二氧化碳排放模型
IF 8.3
AGU Advances Pub Date : 2024-11-04 DOI: 10.1029/2024AV001294
Brian Saccardi, Craig B. Brinkerhoff, Colin J. Gleason, Matthew J. Winnick
{"title":"Toward Modeling Continental-Scale Inland Water Carbon Dioxide Emissions","authors":"Brian Saccardi,&nbsp;Craig B. Brinkerhoff,&nbsp;Colin J. Gleason,&nbsp;Matthew J. Winnick","doi":"10.1029/2024AV001294","DOIUrl":"https://doi.org/10.1029/2024AV001294","url":null,"abstract":"<p>Inland waters emit significant amounts of carbon dioxide (CO<sub>2</sub>) to the atmosphere; however, the global magnitude and source distribution of inland water CO<sub>2</sub> emissions remain uncertain. These fluxes have previously been “statistically upscaled” by independently estimating dissolved CO<sub>2</sub> concentrations and gas exchange velocities to calculate fluxes. This scaling, while robust and defensible, has known limitations in representing carbon source limitations and spatial variability. Here, we develop and calibrate a CO<sub>2</sub> transport model for the continental United States, simulating carbon transport and transformation in &gt;22 million hydraulically connected rivers, lakes, and reservoirs. We estimate 25% lower CO<sub>2</sub> fluxes compared to upscaling estimates forced by the same observational calibration data. While precise CO<sub>2</sub> source distribution estimates are limited by the resolution of model parameterizations, our model suggests that stream corridor CO<sub>2</sub> production dominates over groundwater inputs at the continental scale. Our results further suggest that the lack of observational networks for groundwater CO<sub>2</sub> and scalable metabolic models of aquatic CO<sub>2</sub> production remain the most salient barriers to further coupling of our model with other Earth system components.</p>","PeriodicalId":100067,"journal":{"name":"AGU Advances","volume":"5 6","pages":""},"PeriodicalIF":8.3,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024AV001294","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142574090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Increased Occurrence of Large-Scale Windthrows Across the Amazon Basin 亚马逊流域大规模风蚀现象增多
IF 8.3
AGU Advances Pub Date : 2024-11-01 DOI: 10.1029/2023AV001030
J. David Urquiza-Muñoz, Susan Trumbore, Robinson I. Negrón-Juárez, Yanlei Feng, Alexander Brenning, C. Michael Vasquez-Parana, Daniel Magnabosco Marra
{"title":"Increased Occurrence of Large-Scale Windthrows Across the Amazon Basin","authors":"J. David Urquiza-Muñoz,&nbsp;Susan Trumbore,&nbsp;Robinson I. Negrón-Juárez,&nbsp;Yanlei Feng,&nbsp;Alexander Brenning,&nbsp;C. Michael Vasquez-Parana,&nbsp;Daniel Magnabosco Marra","doi":"10.1029/2023AV001030","DOIUrl":"https://doi.org/10.1029/2023AV001030","url":null,"abstract":"<p>Convective storms with strong downdrafts create windthrows: snapped and uprooted trees that locally alter the structure, composition, and carbon balance of forests. Comparing Landsat imagery from subsequent years, we documented temporal and spatial variation in the occurrence of large (≥30 ha) windthrows across the Amazon basin from 1985 to 2020. Over 33 individual years, we detected 3179 large windthrows. Windthrow density was greatest in the central and western Amazon regions, with ∼33% of all events occurring in ∼3% of the monitored area. Return intervals for large windthrows in the same location of these “hotspot” regions are centuries to millennia, while over the rest of the Amazon they are &gt;10,000 years. Our data demonstrate a nearly 4-fold increase in windthrow number and affected area between 1985 (78 windthrows and 6,900 ha) and 2020 (264 events and 32,170 ha), with more events of &gt;500 ha size since 1990. Such extremely large events (&gt;500 ha up to 2,543 ha) are responsible for interannual variation in the overall median (84 ± 5.2 ha; ±95% CI) and mean (147 ± 13 ha) windthrow area, but we did not find significant temporal trends in the size distribution of windthrows with time. Our results document increased damage from convective storms over the past 40 years in the Amazon, filling a gap in temporal records for tropical regions. Our publicly accessible large windthrow database provides a valuable tool for exploring dynamic conditions leading to damaging storms and their ecological impact on Amazon forests.</p>","PeriodicalId":100067,"journal":{"name":"AGU Advances","volume":"5 6","pages":""},"PeriodicalIF":8.3,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2023AV001030","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142561628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adjustments to Climate Perturbations—Mechanisms, Implications, Observational Constraints 气候扰动调整--机制、影响和观测制约因素
IF 8.3
AGU Advances Pub Date : 2024-10-16 DOI: 10.1029/2023AV001144
Johannes Quaas, Timothy Andrews, Nicolas Bellouin, Karoline Block, Olivier Boucher, Paulo Ceppi, Guy Dagan, Sabine Doktorowski, Hannah Marie Eichholz, Piers Forster, Tom Goren, Edward Gryspeerdt, Øivind Hodnebrog, Hailing Jia, Ryan Kramer, Charlotte Lange, Amanda C. Maycock, Johannes Mülmenstädt, Gunnar Myhre, Fiona M. O’Connor, Robert Pincus, Bjørn Hallvard Samset, Fabian Senf, Keith P. Shine, Chris Smith, Camilla Weum Stjern, Toshihiko Takemura, Velle Toll, Casey J. Wall
{"title":"Adjustments to Climate Perturbations—Mechanisms, Implications, Observational Constraints","authors":"Johannes Quaas,&nbsp;Timothy Andrews,&nbsp;Nicolas Bellouin,&nbsp;Karoline Block,&nbsp;Olivier Boucher,&nbsp;Paulo Ceppi,&nbsp;Guy Dagan,&nbsp;Sabine Doktorowski,&nbsp;Hannah Marie Eichholz,&nbsp;Piers Forster,&nbsp;Tom Goren,&nbsp;Edward Gryspeerdt,&nbsp;Øivind Hodnebrog,&nbsp;Hailing Jia,&nbsp;Ryan Kramer,&nbsp;Charlotte Lange,&nbsp;Amanda C. Maycock,&nbsp;Johannes Mülmenstädt,&nbsp;Gunnar Myhre,&nbsp;Fiona M. O’Connor,&nbsp;Robert Pincus,&nbsp;Bjørn Hallvard Samset,&nbsp;Fabian Senf,&nbsp;Keith P. Shine,&nbsp;Chris Smith,&nbsp;Camilla Weum Stjern,&nbsp;Toshihiko Takemura,&nbsp;Velle Toll,&nbsp;Casey J. Wall","doi":"10.1029/2023AV001144","DOIUrl":"https://doi.org/10.1029/2023AV001144","url":null,"abstract":"<p>Since the 5th Assessment Report of the Intergovernmental Panel on Climate Change (AR5) an extended concept of the energetic analysis of climate change including forcings, feedbacks and adjustment processes has become widely adopted. Adjustments are defined as processes that occur in response to the introduction of a climate forcing agent, but that are independent of global-mean surface temperature changes. Most considered are the adjustments that impact the Earth energy budget and strengthen or weaken the instantaneous radiative forcing due to the forcing agent. Some adjustment mechanisms also impact other aspects of climate not related to the Earth radiation budget. Since AR5 and a following description by Sherwood et al. (2015, https://doi.org/10.1175/bams-d-13-00167.1), much research on adjustments has been performed and is reviewed here. We classify the adjustment mechanisms into six main categories, and discuss methods of quantifying these adjustments in terms of their potentials, shortcomings and practicality. We furthermore describe aspects of adjustments that act beyond the energetic framework, and we propose new ideas to observe adjustments or to make use of observations to constrain their representation in models. Altogether, the problem of adjustments is now on a robust scientific footing, and better quantification and observational constraint is possible. This allows for improvements in understanding and quantifying climate change.</p>","PeriodicalId":100067,"journal":{"name":"AGU Advances","volume":"5 5","pages":""},"PeriodicalIF":8.3,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2023AV001144","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142439077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Zircon Xenocrysts From Easter Island (Rapa Nui) Reveal Hotspot Activity Since the Middle Jurassic 复活节岛(拉帕努伊)的锆石异晶揭示了侏罗纪中期以来的热点活动
IF 8.3
AGU Advances Pub Date : 2024-10-12 DOI: 10.1029/2024AV001351
Yamirka Rojas-Agramonte, Natalia Pardo, Douwe J. J. van Hinsbergen, Christian Winter, María Paula Marroquín-Gómez, Shoujie Liu, Axel Gerdes, Richard Albert, Shitou Wu, Antonio García-Casco
{"title":"Zircon Xenocrysts From Easter Island (Rapa Nui) Reveal Hotspot Activity Since the Middle Jurassic","authors":"Yamirka Rojas-Agramonte,&nbsp;Natalia Pardo,&nbsp;Douwe J. J. van Hinsbergen,&nbsp;Christian Winter,&nbsp;María Paula Marroquín-Gómez,&nbsp;Shoujie Liu,&nbsp;Axel Gerdes,&nbsp;Richard Albert,&nbsp;Shitou Wu,&nbsp;Antonio García-Casco","doi":"10.1029/2024AV001351","DOIUrl":"https://doi.org/10.1029/2024AV001351","url":null,"abstract":"<p>We report the finding of mantle-derived zircon grains retrieved from red soils, regoliths, and beach sands from Easter Island, that are much older than the island volcanism (0–2.5 Ma) and its underlying lithosphere (Pliocene, 3–4.8 Ma). A large population of 0–165 Ma old zircons have coherent oxygen (δ<sup>18</sup>O 3.8–5.9‰) and hafnium (εHf<sub>(t)</sub>+3.5–+12.5) mantle isotopic signatures. These results are consistent with the crystallization of zircon from plume-related melts. In addition, a chemically diverse population with ages from the Paleozoic to the Archean was found. These older populations are enigmatic but they could represent remnants of ancient subducted sediments. Meanwhile, the ∼0–165 Ma population is interpreted as plume-derived, suggesting that the hotspot started at least ∼165 Ma ago. A spike of ∼164–160 Ma zircons could represent a Large Igneous Province (LIP) stage upon the first arrival of the plume. We use plate reconstructions to show that such a LIP would have formed on the Phoenix Plate and would have subducted below the Antarctic Peninsula around 100–105 Ma. There, LIP subduction would offer a solution for the enigmatic Palmer Land deformation event, previously proposed to result from a collision with an unknown indenter. The here-reported “ghost” of a prolonged hotspot activity suggests that fragments of the Easter plume and of the ambient sub-lithospheric mantle stored and re-sampled zircon xenocrysts due to convective (re)circulation at the scale of the plume head. Our study demonstrates how zircon geochronology and geochemistry provide novel insights into global-scale geodynamics, offering new perspectives on the dynamics of mantle plumes and hotspot activity.</p>","PeriodicalId":100067,"journal":{"name":"AGU Advances","volume":"5 5","pages":""},"PeriodicalIF":8.3,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024AV001351","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142430046","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Plume-Plateau Interaction 羽毛板相互作用
IF 8.3
AGU Advances Pub Date : 2024-10-01 DOI: 10.1029/2024AV001464
Shichun Huang
{"title":"Plume-Plateau Interaction","authors":"Shichun Huang","doi":"10.1029/2024AV001464","DOIUrl":"https://doi.org/10.1029/2024AV001464","url":null,"abstract":"&lt;p&gt;Age progressive volcanic trends, known as hotspot tracks, are thought to be produced by partial melting of buoyant mantle plumes rising from the deep mantle (Morgan, &lt;span&gt;1971&lt;/span&gt;; Wilson, &lt;span&gt;1963&lt;/span&gt;). Hotspot tracks record the relative motion between plates and mantle plumes, and they are used to reconstruct the history of plate motion and to constrain the geochemical heterogeneity within the mantle, which are important to our understanding of mantle dynamics (e.g., Koppers et al., &lt;span&gt;2021&lt;/span&gt;; Weis et al., &lt;span&gt;2023&lt;/span&gt;).&lt;/p&gt;&lt;p&gt;Through a careful examination of isotopic, geochronological, and plate motion reconstruction data, Jackson et al. (&lt;span&gt;2024&lt;/span&gt;) argued that certain Cretaceous (87–106 Ma) Magellan seamounts north of the Ontong-Java Plateau (OJP) may have been produced by the Samoan plume. This finding places the Samoan hotspot track among the longest-lived ones. However, there is a significant gap in volcanic activity from 24 to 87 Ma, excluding the 44 Ma Malaita volcanism. Raising the question, what mechanism could produce a 63 Ma gap in an otherwise enduring hotspot track?&lt;/p&gt;&lt;p&gt;It has long been observed that most hotspot tracks manifest as discrete volcanoes, exemplified by the long-lived Hawaii-Emperor Volcanic Chain, rather than continuous ridges. It is suggested that the locations of these volcanoes are controlled by fractures within the lithosphere, facilitating the migration of plume-generated magma (e.g., Hieronymus &amp; Bercovici, &lt;span&gt;1999&lt;/span&gt;). Consequently, discrete volcanoes are anticipated along hotspot tracks.&lt;/p&gt;&lt;p&gt;To explain the bilaterally zoned hotspot tracks (e.g., Abouchami et al., &lt;span&gt;2005&lt;/span&gt;; Huang et al., &lt;span&gt;2011&lt;/span&gt;; Weis et al., &lt;span&gt;2011&lt;/span&gt;), Rohde et al. (&lt;span&gt;2013&lt;/span&gt;) argued that mantle plumes originating from the lower mantle may bifurcate at the mantle transition zone (Figure 1a). Because of the different mantle viscosities in the upper and lower mantle, a plume might rise much slower in the lower mantle compared to in the upper mantle. To maintain the same plume flux, a plume would become thinner in the upper mantle, which may lead to plume bifurcation at the mantle transition zone (Rohde et al., &lt;span&gt;2013&lt;/span&gt;). Alternatively, it is also possible that after entering the upper mantle, a plume fragments into discrete upwelling diapirs rather than maintaining a continuous flow (Figure 1a), resulting in volcanic activity gaps along hotspot tracks.&lt;/p&gt;&lt;p&gt;However, neither of these theories explains the prolonged absence of volcanism within a significant period (24–87 Ma) of the Samoan hotspot track. Jackson et al. (&lt;span&gt;2024&lt;/span&gt;) noted that during this particular period of time, the Samoan plume was under the thick OJP. Mantle plumes ascend adiabatically, with a steeper pressure-temperature slope compared to that of the mantle solidus. As such, plumes start to melt and produce magma when reaching shallow depths (low pressure). The upwelling stops ","PeriodicalId":100067,"journal":{"name":"AGU Advances","volume":"5 5","pages":""},"PeriodicalIF":8.3,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024AV001464","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142404439","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetosheath High-Speed Jet Drives Multiple Auroral Arcs Near Local Noon 磁鞘高速喷流驱动当地正午附近的多个极光弧
IF 8.3
AGU Advances Pub Date : 2024-09-23 DOI: 10.1029/2024AV001197
Hui-Xuan Qiu, De-Sheng Han, Run Shi, Jianjun Liu
{"title":"Magnetosheath High-Speed Jet Drives Multiple Auroral Arcs Near Local Noon","authors":"Hui-Xuan Qiu,&nbsp;De-Sheng Han,&nbsp;Run Shi,&nbsp;Jianjun Liu","doi":"10.1029/2024AV001197","DOIUrl":"https://doi.org/10.1029/2024AV001197","url":null,"abstract":"<p>Magnetosheath High-Speed Jets (HSJs) are transient disturbances characterized by increased dynamic pressure. They can cause various geoeffects, including ultra-low-frequency (ULF) waves and auroras. Theoretically, when ULF waves propagate into the ionosphere as Alfvén waves, they can accelerate electrons and generate discrete auroras. However, what types of aurora can be driven by HSJs and what are the underlying mechanisms remain unknown. Using coordinated magnetosheath in situ and ground observations, here, we showed that when a HSJ was identified in the magnetosheath, multiple auroral arcs parallel to the auroral oval were observed near local noon. The electron energy spectrogram of these arcs exhibited “inverted-V” structures, indicating the existence of quasi-static parallel electric fields. Concurrently, long-period ULF signals were detected on the ground, suggesting the arrival of Alfvén waves. These observations are represented by a kinetic simulation using realistic observational inputs, showing consistency with the theory regarding the generation of the “inverted-V” structure by long-period Alfvén waves. This study builds a previously unestablished connection among HSJ, ULF wave, and aurora, and provides a mechanism for generation of discrete auroral arcs near local noon, which may reveal the underlying mechanism behind a specific auroral activity commonly observed near local noon as shown in the paper.</p>","PeriodicalId":100067,"journal":{"name":"AGU Advances","volume":"5 5","pages":""},"PeriodicalIF":8.3,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024AV001197","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142313250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Large, Negative Atmospheric Carbon Monoxide Clumped Isotope Values Result From Kinetic Isotope Fractionation, Tracing OH• Reactivity 大气中一氧化碳的大量负同位素值来自于动力学同位素分馏,可追踪 OH- 反应性
IF 8.3
AGU Advances Pub Date : 2024-09-23 DOI: 10.1029/2023AV000922
Gregory A. Henkes, Philip F. Place, John E. Mak
{"title":"Large, Negative Atmospheric Carbon Monoxide Clumped Isotope Values Result From Kinetic Isotope Fractionation, Tracing OH• Reactivity","authors":"Gregory A. Henkes,&nbsp;Philip F. Place,&nbsp;John E. Mak","doi":"10.1029/2023AV000922","DOIUrl":"https://doi.org/10.1029/2023AV000922","url":null,"abstract":"<p>Because of its global abundance and reactivity with hydroxyl radicals (OH•), tropospheric carbon monoxide indirectly impacts the lifetimes of other OH•-reactive gases, in particular methane and reactive hydrocarbons. The origin and chemistry of atmospheric CO have been studied using stable isotopes. Both <sup>13</sup>CO and C<sup>18</sup>O undergo isotopic fractionation during its main chemical loss reaction, CO + OH•. The kinetic isotope effect (KIE) for <sup>13</sup>CO is mass dependent, with a value of ∼5‰; <sup>12</sup>CO reacts faster than <sup>13</sup>CO with OH. Whereas C<sup>18</sup>O + OH• exhibits an inversely mass dependent KIE ∼−10‰. We hypothesize these KIEs result in a relative depletion of <sup>13</sup>C<sup>18</sup>O, a CO clumped isotope. To test this, we collected CO from air samples on Long Island, NY, and discovered a −3 to −8‰ difference in the clumped isotope ratio, Δ<sub>31</sub>, relative to a random distribution of <sup>13</sup>C and <sup>18</sup>O in CO. A clear negative trend between [CO] and Δ<sub>31</sub> is driven by two factors: (a) the atmospheric addition of CO from either a primary or secondary source with a Δ<sub>31</sub> of ∼0‰ and (b) the continuing reaction of CO with OH•, leaving the remaining CO pool relatively depleted in <sup>13</sup>C<sup>18</sup>O. This is analogous to the mechanism that determines CO Δ<sup>17</sup>O values. This study is among the first to show clumped isotope fractionation resulting from atmospheric chemistry and not thermal equilibration, which may inform the identification of clumped isotope KIEs in other atmospheric trace gases. These first Δ<sub>31</sub> observations motivate future experimental and observational studies targeted at characterizing the clumped isotopes of CO sources, background CO, and experimentally fractionated CO.</p>","PeriodicalId":100067,"journal":{"name":"AGU Advances","volume":"5 5","pages":""},"PeriodicalIF":8.3,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2023AV000922","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142313249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Low-Viscosity Lower Lunar Mantle Implied by Measured Monthly and Yearly Tides 月汐和年汐测量所隐含的低粘度月球下地幔
IF 8.3
AGU Advances Pub Date : 2024-09-14 DOI: 10.1029/2024AV001285
Sander Goossens, Isamu Matsuyama, Gael Cascioli, Erwan Mazarico
{"title":"A Low-Viscosity Lower Lunar Mantle Implied by Measured Monthly and Yearly Tides","authors":"Sander Goossens,&nbsp;Isamu Matsuyama,&nbsp;Gael Cascioli,&nbsp;Erwan Mazarico","doi":"10.1029/2024AV001285","DOIUrl":"https://doi.org/10.1029/2024AV001285","url":null,"abstract":"<p>The Moon's frequency-dependent tidal response, expressed as temporal variations in its gravity field through the Love number <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msub>\u0000 <mi>k</mi>\u0000 <mn>2</mn>\u0000 </msub>\u0000 </mrow>\u0000 <annotation> ${k}_{2}$</annotation>\u0000 </semantics></math> and as dissipation through the quality factor <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>Q</mi>\u0000 </mrow>\u0000 <annotation> $Q$</annotation>\u0000 </semantics></math>, provides information about its interior structure. Lunar laser ranging has provided measurements for <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>Q</mi>\u0000 </mrow>\u0000 <annotation> $Q$</annotation>\u0000 </semantics></math>, but so far no frequency-dependent values for <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msub>\u0000 <mi>k</mi>\u0000 <mn>2</mn>\u0000 </msub>\u0000 </mrow>\u0000 <annotation> ${k}_{2}$</annotation>\u0000 </semantics></math> have been determined. We provide the first spacecraft measurements of <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <msub>\u0000 <mi>k</mi>\u0000 <mn>2</mn>\u0000 </msub>\u0000 </mrow>\u0000 <annotation> ${k}_{2}$</annotation>\u0000 </semantics></math> and <span></span><math>\u0000 <semantics>\u0000 <mrow>\u0000 <mi>Q</mi>\u0000 </mrow>\u0000 <annotation> $Q$</annotation>\u0000 </semantics></math> at two frequencies, monthly and yearly, from an analysis of Gravity Recovery and Interior Laboratory and Lunar Reconnaissance Orbiter radio tracking data. Interior modeling indicates that these values can be matched only with a low-viscosity zone at the base of the lunar mantle, even when using complex rheological laws to model the mantle's response. The existence of this zone has profound implications for the Moon's thermal state and evolution.</p>","PeriodicalId":100067,"journal":{"name":"AGU Advances","volume":"5 5","pages":""},"PeriodicalIF":8.3,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024AV001285","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142233190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Topographic Roughness as an Emergent Property of Geomorphic Processes and Events 地形崎岖是地貌过程和事件的新兴属性
IF 8.3
AGU Advances Pub Date : 2024-09-13 DOI: 10.1029/2024AV001264
T. H. Doane, J. H. Gearon, H. K. Martin, B. J. Yanites, D. A. Edmonds
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引用次数: 0
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