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Chemistry Journal of Moldova最新文献

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A new 2d coordination polymer based on zinc(ii), 1,2,3-benzenetricarboxylic acid and 4,4ʹ-bis(imidazol-1-ylmethyl)biphenyl: synthesis and crystal structure 基于锌(ii)， 1,2,3-苯三羧酸和4,4′-双(咪唑-1-甲基)联苯的新型二维配位聚合物的合成与晶体结构
IF 0.5
Chemistry Journal of Moldova Pub Date : 2023-06-01 DOI: 10.19261/cjm.2022.1021
I. Voda
{"title":"A new 2d coordination polymer based on zinc(ii), 1,2,3-benzenetricarboxylic acid and 4,4ʹ-bis(imidazol-1-ylmethyl)biphenyl: synthesis and crystal structure","authors":"I. Voda","doi":"10.19261/cjm.2022.1021","DOIUrl":"https://doi.org/10.19261/cjm.2022.1021","url":null,"abstract":"The solvothermal reaction of zinc(II) nitrate with 1,2,3-benzenetricarboxylic acid (1,2,3-H3BTC) and 4,4ʹ-bis(imidazol-1-ylmethyl)biphenyl (BIBPh) produced a crystalline solid {[Zn3(BIBPh)3(BTC)2]∙H2O}n. The product has been structurally characterised and investigated by X-ray diffraction, IR and thermogravimetric methods. The polymer has a bidimentional structure and crystallizes in the P21/c space group of the monoclinic system with the following unit cell parameters: a= 14.8687(16), b= 36.915(4), c= 13.8378(16) (Å), β= 105.584(6)°. The asymmetric unit of the crystal structure contains three zinc(II) ions, three BIBPh ligands and two BTC3- monodentate ligands with all three deprotonated carboxylate groups that balance the overall charge. All zinc centers have similar coordination environment: each metal ion is four coordinated exhibiting a slightly distorted tetrahedral coordination, where two positions are occupied by oxygen atoms of the carboxylic acid and the other two by nitrogen atoms of imidazole subunits","PeriodicalId":9922,"journal":{"name":"Chemistry Journal of Moldova","volume":"38 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88870520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of Composites Based on Caffeic Acid and Fumed Silica and Evaluation of Their Antioxidant and Antimicrobial Properties 咖啡酸与气相二氧化硅复合材料的制备及其抗氧化抗菌性能评价
IF 0.5
Chemistry Journal of Moldova Pub Date : 2022-12-01 DOI: 10.19261/cjm.2022.984
O. Stavinskaya, I. Laguta, P. Kuzema, I. Skorochod, Alla Roy, I. Kurdish
{"title":"Preparation of Composites Based on Caffeic Acid and Fumed Silica and Evaluation of Their Antioxidant and Antimicrobial Properties","authors":"O. Stavinskaya, I. Laguta, P. Kuzema, I. Skorochod, Alla Roy, I. Kurdish","doi":"10.19261/cjm.2022.984","DOIUrl":"https://doi.org/10.19261/cjm.2022.984","url":null,"abstract":"The work was aimed at preparing the CA+A300 composite consisting of caffeic acid (CA) and fumed silica (A300) and at comparing the properties of CA in the solution and in the composite. The results showed that the solution and the composite are effective antioxidant/antimicrobial agents and that inclusion of CA in the CA+A300 composite provides its gradual release into solutions and reaction mixtures, thus ensuring a prolonged action of the compound.","PeriodicalId":9922,"journal":{"name":"Chemistry Journal of Moldova","volume":"17 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73894266","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
The Road to Environmental Chemistry in the Republic of Moldova Paved by the Illustrious Scientist and Renowned Ecologist Valeriu Ropot 摩尔多瓦共和国的环境化学之路由杰出的科学家和著名的生态学家Valeriu Ropot铺就
IF 0.5
Chemistry Journal of Moldova Pub Date : 2022-12-01 DOI: 10.19261/cjm.2022.1018
T. Lupascu, M. Sandu
{"title":"The Road to Environmental Chemistry in the Republic of Moldova Paved by the Illustrious Scientist and Renowned Ecologist Valeriu Ropot","authors":"T. Lupascu, M. Sandu","doi":"10.19261/cjm.2022.1018","DOIUrl":"https://doi.org/10.19261/cjm.2022.1018","url":null,"abstract":"This paper presents the the main scientific and innovative results are presented, which were obtained by the talented chemist and renowned ecologist Valeriu Ropot throughout his scientific career. The results of scientific investigations are bestowed and analysed concerning the quality of the waters of the Dniester and the Prut Rivers, Dubasari reservoirs on the Dniester River, as well as the main bodies of water in the Republic of Moldova. The paper also includes the practical recommendations for reducing the negative impact on the environment, of the discharge of hundreds of thousands of tons of brine into the Dniester River as a result of the accident at the mineral fertilizer plant in the city of Stebnik, Ukraine. Moreover, the paper presents the results of studies aimed at developing methods for determining organic and inorganic pollutants in natural waters.","PeriodicalId":9922,"journal":{"name":"Chemistry Journal of Moldova","volume":"10 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78483975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Isomerization of Limonene on Zeolite-containing Catalysts Based on Kaolin 基于高岭土的沸石催化剂上柠檬烯的异构化
IF 0.5
Chemistry Journal of Moldova Pub Date : 2022-12-01 DOI: 10.19261/cjm.2022.980
L. Patrylak, S. Zubenko, Serhy Konovalov, A. Yakovenko, V. Povazhnyi, O. Pertko, Yulianna Voloshyna, O. Melnychuk, M. Filonenko
{"title":"Isomerization of Limonene on Zeolite-containing Catalysts Based on Kaolin","authors":"L. Patrylak, S. Zubenko, Serhy Konovalov, A. Yakovenko, V. Povazhnyi, O. Pertko, Yulianna Voloshyna, O. Melnychuk, M. Filonenko","doi":"10.19261/cjm.2022.980","DOIUrl":"https://doi.org/10.19261/cjm.2022.980","url":null,"abstract":"The aim of the work was to study the isomerization of limonene on zeolite-containing biporous acid catalysts based on kaolin (from Ukraine). Results of this study show that at 160°C, the maximum isomer yield was 60–65% with an 80–90% conversion. The studied samples do not have a significant accumulation of carbonaceous deposits because limonene has high solubility, which helps to remove intermediate products of transformation from the surface of the samples.","PeriodicalId":9922,"journal":{"name":"Chemistry Journal of Moldova","volume":"55 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74015984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Mild Acidic Charcoal Catalyzed Synthesis of 3,4-dihydropyrimidin-2(1H)-one/-thione Derivatives 温和酸性炭催化合成3,4-二氢嘧啶-2(1H)- 1 /-硫酮衍生物
IF 0.5
Chemistry Journal of Moldova Pub Date : 2022-12-01 DOI: 10.19261/cjm.2022.999
R. Patil, J. Chavan, Shivnath R Patel, V. Shinde, A. Beldar
{"title":"Mild Acidic Charcoal Catalyzed Synthesis of 3,4-dihydropyrimidin-2(1H)-one/-thione Derivatives","authors":"R. Patil, J. Chavan, Shivnath R Patel, V. Shinde, A. Beldar","doi":"10.19261/cjm.2022.999","DOIUrl":"https://doi.org/10.19261/cjm.2022.999","url":null,"abstract":"A green and efficient method for the multicomponent synthesis of 3,4-dihydropyrimidin-2(1H)-ones and -thiones using acetic acid supported on activated charcoal as a mild acid catalyst in ethanol under both conventional as well as microwave irradiation conditions has been developed. The catalyst system found more efficient under microwave irradiation conditions than conventional conditions with shorter reaction times and excellent yields.","PeriodicalId":9922,"journal":{"name":"Chemistry Journal of Moldova","volume":"24 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77758089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Zn(II) Binuclear and Ni(II) 1D Polymeric Coordination Compounds Based on Dianilineglyoxime and Dicarboxylic Acids: Synthesis and Structure 基于二胺酰二肟和二羧酸的新型Zn(II)双核和Ni(II) 1D聚合物配位化合物的合成和结构
IF 0.5
Chemistry Journal of Moldova Pub Date : 2022-12-01 DOI: 10.19261/cjm.2022.954
Dumitru Ureche, I. Bulhac, S. Shova, P. Bourosh
{"title":"Novel Zn(II) Binuclear and Ni(II) 1D Polymeric Coordination Compounds Based on Dianilineglyoxime and Dicarboxylic Acids: Synthesis and Structure","authors":"Dumitru Ureche, I. Bulhac, S. Shova, P. Bourosh","doi":"10.19261/cjm.2022.954","DOIUrl":"https://doi.org/10.19261/cjm.2022.954","url":null,"abstract":"Two coordinating compounds of zinc(II) (1) [Zn2(DAnH2)2(1,3-bdc)2(DMSO)4] and nickel(II) (2) [Ni(DAnH2)(1,4-bdc)(DMF)2]n were obtained based on dianilineglyoxime (DAnH2), 1,3-benzenedicarboxylic acid (1,3-bdcH2) and 1,4-benzenedicarboxylic acid (1,4-bdcH2), where DMSO is dimethylsulfoxide and DMF is dimethylformamide. The molecular and crystalline structure of reported compounds were established by infrared spectroscopy and single crystal X-ray diffraction, and for 1, additionally, the 1H and 13C NMR spectroscopy was used. According to data, the Zn(II) molecular complex is a binuclear and the Ni(II) is a 1D polymer compound.","PeriodicalId":9922,"journal":{"name":"Chemistry Journal of Moldova","volume":"76 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88374331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, Characterization and Antibacterial Activities of Ferrocene Ligands and Their Binuclear Complexes 二茂铁配体及其双核配合物的合成、表征及抗菌活性研究
IF 0.5
Chemistry Journal of Moldova Pub Date : 2022-12-01 DOI: 10.19261/cjm.2022.957
Ozan Süleyman Ürgüt, A. Tavman, Muazzez Gürgan Eser
{"title":"Synthesis, Characterization and Antibacterial Activities of Ferrocene Ligands and Their Binuclear Complexes","authors":"Ozan Süleyman Ürgüt, A. Tavman, Muazzez Gürgan Eser","doi":"10.19261/cjm.2022.957","DOIUrl":"https://doi.org/10.19261/cjm.2022.957","url":null,"abstract":"6-Chloro-2-ferrocenyl-1H-benzimidazole and (E)-((4-chloro-2-hydroxyphenylimino)methyl)ferrocene ligands and their Fe(III), Co(II), Cu(II), Zn(II) and Pd(II) complexes were synthesized. The structure of ligands and metal complexes has been investigated by different methods. In addition, magnetic moment, molar conductivity measurements and antibacterial activity of the ligands and the complexes were investigated.","PeriodicalId":9922,"journal":{"name":"Chemistry Journal of Moldova","volume":"85 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85571254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Resin Acids as Raw Material for the Preparation of Cyclodextrin Complexes Loaded with Dehydroabietitoic Acid and Chromenol Hybrid 以树脂酸为原料制备脱氢枞酸-铬酚杂化环糊精配合物
IF 0.5
Chemistry Journal of Moldova Pub Date : 2022-12-01 DOI: 10.19261/cjm.2022.942
M. Zveaghintseva, E. Stingaci, S. Pogrebnoi, Lucian Lupascu, A. Barba, G. Duca, V. Valica, Livia Uncu, V. Kravtsov, D. Terteac, A. Brînzan, F. Macaev
{"title":"Resin Acids as Raw Material for the Preparation of Cyclodextrin Complexes Loaded with Dehydroabietitoic Acid and Chromenol Hybrid","authors":"M. Zveaghintseva, E. Stingaci, S. Pogrebnoi, Lucian Lupascu, A. Barba, G. Duca, V. Valica, Livia Uncu, V. Kravtsov, D. Terteac, A. Brînzan, F. Macaev","doi":"10.19261/cjm.2022.942","DOIUrl":"https://doi.org/10.19261/cjm.2022.942","url":null,"abstract":"In this work new methods to obtain complexes from β-cyclodextrin and dehydroabietic acid with chromenol-triazol hybrid with the sizes limits of approximately 0.1-250 μm are reported. Kneading, co-evaporation and co-precipitation for the resolution of racemic 2-tert-butyl-3-(1H-1,2,4-triazol-1-yl)-2H-chromen-2-ol for obtaining micro- and nanoparticles have been optimized. In vitro dissolution studies of the synthesized compounds in phosphate buffer (pH 6.8) showed an improved dissolution rate of chromenol-triazol hybrid in the inclusion complexes compared to the free form. The obtained β-complexes of β-cyclodextrin loaded with dehydroabietitoic acid and chromenol hybrid showed good antibacterial activity with MIC and MBC values ranging from 0.72 to 44.45 μM.","PeriodicalId":9922,"journal":{"name":"Chemistry Journal of Moldova","volume":"131 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85022897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Properties of Winemaking By-products of Feteasca Neagra Grape Seeds 尼格拉葡萄籽酿酒副产物的特性研究
IF 0.5
Chemistry Journal of Moldova Pub Date : 2022-12-01 DOI: 10.19261/cjm.2022.946
Angela Gurev, V. Dragancea, A. Baerle, N. Netreba, O. Boeștean, S. Haritonov, B. Gaina
{"title":"Properties of Winemaking By-products of Feteasca Neagra Grape Seeds","authors":"Angela Gurev, V. Dragancea, A. Baerle, N. Netreba, O. Boeștean, S. Haritonov, B. Gaina","doi":"10.19261/cjm.2022.946","DOIUrl":"https://doi.org/10.19261/cjm.2022.946","url":null,"abstract":"The composition of the lipophilic and hydrophilic extracts from the Feteasca Neagra ground seeds, grown in three different vineyards, was studied. The physicochemical indicators of the seeds, the oil quality indicators and the total content of polyphenols and flavonoids in the extracts were determined. Some phenolic and flavanol constituents were identified and quantified using reversed-phase HPLC by gradient-elution. The Trolox equivalent antioxidant capacity assay proved the increased antioxidant activity of the hydrophilic extracts, with the highest DPPH• scavenging effect of almost 91.70 and 93.81%, an equivalent of 281.66 and 288.27 µM/L Trolox. It was concluded that the seeds recovered from Feteasca Neagra by-products are a rich source of functional compounds, with significant antioxidant properties.","PeriodicalId":9922,"journal":{"name":"Chemistry Journal of Moldova","volume":"2 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86219796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
From (-)-sclareol to Norlabdane Heterocyclic Hybrid Compounds 从(-)-香樟醇到诺拉丹杂环杂化化合物
IF 0.5
Chemistry Journal of Moldova Pub Date : 2022-12-01 DOI: 10.19261/cjm.2022.958
A. Ciocarlan
{"title":"From (-)-sclareol to Norlabdane Heterocyclic Hybrid Compounds","authors":"A. Ciocarlan","doi":"10.19261/cjm.2022.958","DOIUrl":"https://doi.org/10.19261/cjm.2022.958","url":null,"abstract":"This review relates to chemistry of the well-known biologically active natural labdane diterpenoid (-)-sclareol easily available from Clary sage (Salvia sclarea L.). It is mainly used in industry, especially for synthesis of fragrance compounds and natural analogs. The paper covers achievements on the synthesis, structure determination and biological activity of molecular hybrid compounds bearing hydrazide and thiosemicarbazone fragments or diazine, 1,2,4-triazole, carbazole, 1,3-thiazole, 1,3,4-oxadiazole, 1,3,4-thiadiazole units prepared based on it.","PeriodicalId":9922,"journal":{"name":"Chemistry Journal of Moldova","volume":"12 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80811886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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