Lixia Li , Xiuqi Li , Feiyue Li , Xiang Zhen , Mingdong Dong , Jinxing Long , Xiaobing Wang , Zhiyong Jiang
{"title":"Light-driven site-selective O–H activation in lignin by triplet excited alkylanthraquinone at simulated natural conditions","authors":"Lixia Li , Xiuqi Li , Feiyue Li , Xiang Zhen , Mingdong Dong , Jinxing Long , Xiaobing Wang , Zhiyong Jiang","doi":"10.1016/S1872-2067(25)64764-4","DOIUrl":"10.1016/S1872-2067(25)64764-4","url":null,"abstract":"<div><div>Harnessing photocatalyzed hydrogen atom transfer (HAT) for the precise activation of C–H/O–H bonds is a pivotal yet challenging strategy to selectively drive oxidative C–C bond scission in renewable lignin, yielding value-added chemicals with exceptional selectivity. Herein, we present a metal-free photochemical strategy that enables selective C–C bond scission in lignin <em>via</em> a unique synergistic HAT pathway driven by triplet-excited 2-ethylanthraquinone (EAQ*) and hydroxyl radicals (<sup>•</sup>OH) generated <em>in situ</em> from EAQH<sub>2</sub> and O<sub>2</sub>. Under simulated natural conditions, this process achieves a benzaldehyde yield of 146.6 mol% from a lignin-derived phenolic dimer. Mechanistic investigations reveal that preferential activation of the C<sub><em>α</em></sub>-OH in lignin facilitates a tandem HAT process, forming alkoxy radical intermediates that undergo <em>β</em>–scission to produce benzaldehyde, as corroborated by extensive control reactions and density functional theory calculations. Furthermore, this straightforward protocol efficiently cleaves the C–C bonds of technical kraft lignins, providing a rapid, scalable, and metal-free protocol for lignin valorization under mild conditions.</div></div>","PeriodicalId":9832,"journal":{"name":"Chinese Journal of Catalysis","volume":"76 ","pages":"Pages 65-80"},"PeriodicalIF":17.7,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144895851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shijie Li , Rui Li , Kexin Dong , Yanping Liu , Xin Yu , Wenyao Li , Tong Liu , Zaiwang Zhao , Mingyi Zhang , Bin Zhang , Xiaobo Chen
{"title":"Self-floating Bi4O5Br2/P-doped C3N4/carbon fiber cloth with S-scheme heterostructure for boosted photocatalytic removal of emerging organic contaminants","authors":"Shijie Li , Rui Li , Kexin Dong , Yanping Liu , Xin Yu , Wenyao Li , Tong Liu , Zaiwang Zhao , Mingyi Zhang , Bin Zhang , Xiaobo Chen","doi":"10.1016/S1872-2067(25)64780-2","DOIUrl":"10.1016/S1872-2067(25)64780-2","url":null,"abstract":"<div><div>The industrial implementation of Solar-driven photocatalysis is hampered by inefficient charge separation, poor reusability and hard retrieval of powdery catalysts. To conquer these drawbacks, a self- floating S-scheme Bi<sub>4</sub>O<sub>5</sub>Br<sub>2</sub>/P-doped C<sub>3</sub>N<sub>4</sub>/carbon fiber cloth (BB/PN/CC) composed of carbon fibers (CC) as the core and Bi<sub>4</sub>O<sub>5</sub>Br<sub>2</sub>/P-doped C<sub>3</sub>N<sub>4</sub> (BB/PN) nanosheets as the shell was constructed as a competent, recyclable cloth-shaped photocatalyst for safe and efficient degradation of aquacultural antibiotics. The BB/PN/CC fabric achieves an exceptional tetracycline degradation rate constant of 0.0118 min<sup>‒1</sup>, surpassing CN/CC (0.0015 min<sup>‒1</sup>), BB/CC (0.0066 min<sup>‒1</sup>) and PN/CC (0.0023 min<sup>‒1</sup>) by 6.9, 0.8 and 4.1 folds, respectively. Beyond its catalytic prowess, the photocatalyst’s practical superiority is evident in its effortless recovery and environmental adaptability. The superior catalytic effectiveness stems from the S-scheme configuration, which retains the maximum redox capacities of the constituent BB and PN while enabling efficient spatial detachment of photo-carriers. X-ray photoelectron spectroscopy (XPS), <em>in-situ</em> XPS, and electron paramagnetic resonance analyses corroborate the S-scheme mechanism, revealing electron accumulation on PN and hole retention on BB under illumination. Density functional theory calculations further confirm S-scheme interfacial charge redistribution and internal electric field formation. This study advances the design of macroscopic S-scheme heterojunction photocatalysts for sustainable water purification.</div></div>","PeriodicalId":9832,"journal":{"name":"Chinese Journal of Catalysis","volume":"76 ","pages":"Pages 37-49"},"PeriodicalIF":17.7,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144895849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiaobing Lan , Hao Lu , Xusheng Wang , Qing Li , Dongdong Li , Jun Chen , Peng Wang , Guangfu Liao
{"title":"Bonding and anti-bonding orbitals stable electron intensity difference theory","authors":"Xiaobing Lan , Hao Lu , Xusheng Wang , Qing Li , Dongdong Li , Jun Chen , Peng Wang , Guangfu Liao","doi":"10.1016/S1872-2067(25)64772-3","DOIUrl":"10.1016/S1872-2067(25)64772-3","url":null,"abstract":"","PeriodicalId":9832,"journal":{"name":"Chinese Journal of Catalysis","volume":"76 ","pages":"Pages 6-9"},"PeriodicalIF":17.7,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144895279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bicheng Ji , Xicheng Li , Shuai Gao , Zeping Qin , Changzheng Wang , Qiang Wang , Chong-Chen Wang
{"title":"Polarization-enhanced piezo-photocatalysis over hollow-sphere Bi4Ti3O12: Structure-property relationship and degradation mechanism","authors":"Bicheng Ji , Xicheng Li , Shuai Gao , Zeping Qin , Changzheng Wang , Qiang Wang , Chong-Chen Wang","doi":"10.1016/S1872-2067(25)64758-9","DOIUrl":"10.1016/S1872-2067(25)64758-9","url":null,"abstract":"<div><div>Tetracycline hydrochloride (TCH) exists in various forms in aqueous solution due to pH changes, which not only alters the reactivity of TCH, but also affects the process of reactive oxygen species (ROS) attacking the molecule. Therefore, the rational design of piezo-photocatalytic materials coupled with a comprehensive understanding of the degradation mechanisms of various TCH species constitutes a critical approach to addressing tetracycline antibiotic contamination. In the design and preparation of piezo-photocatalysts, controlling the oxygen vacancy concentration is crucial as it governs the coupling efficiency between piezoelectric response and photocatalytic activity, as well as the strength of spontaneous polarization. Meanwhile, the morphology of the material is a key factor influencing the migration pathways of charge carriers. In this work, hollow spherical Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub> was synthesized using an inorganic titanium source, demonstrating exceptional piezo-photocatalytic activity. The degradation rate was 1.57 and 5.29 times higher than that of traditional spherical and plate-like morphologies, with a rate constant of <em>k</em> = 0.127. In an innovative approach, density functional theory calculations of local softness and hyper-softness were employed to analyze the reactivity changes of TCH in its different deprotonated states toward reactive oxygen species. Combined with molecular electronegativity analysis, the factors influencing the degradation efficiency were identified. This study provides a solid foundation for developing efficient and environmentally friendly piezo-photocatalysts and offers new insights into the degradation mechanism of TCH.</div></div>","PeriodicalId":9832,"journal":{"name":"Chinese Journal of Catalysis","volume":"76 ","pages":"Pages 133-145"},"PeriodicalIF":17.7,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144895347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Suppressing catalyst reconstruction in neutral electrolyte: stabilizing Co-O-Mo point-to-point connection of cobalt molybdate by tungsten doping for oxygen evolution reaction","authors":"Zhouzhou Wang, Qiancheng Zhou, Li Luo, Yaran Shi, Haoran Li, Chunchun Wang, Kesheng Lin, Chengsi Wang, Libing Zhu, Linyun Han, Zhuo Xing, Ying Yu","doi":"10.1016/S1872-2067(25)64748-6","DOIUrl":"10.1016/S1872-2067(25)64748-6","url":null,"abstract":"<div><div>Neutral oxygen evolution reaction (OER) is a crucial half-reaction for electrocatalytic chemical production under mild condition, but with limited development due to low activity and poor stability. Herein, a tungsten-doped cobalt molybdate (WDCMO) catalyst was synthesized for efficient and durable OER under neutral electrolyte. It is demonstrated that catalyst reconstruction is suppressed by W doping, which stabilizes the Co-O-Mo point-to-point connection in CoMoO<sub>4</sub> architecture and stimulates to a lower valence state of active sites over the surface phase. Thereby, the surface structure maintains to avoid compound dissolution caused by over-oxidation during OER. Meanwhile, the WDCMO catalyst promotes charge transfer and optimizes *OH intermediate adsorption, which improves reaction kinetics and intrinsic activity. Consequently, the WDCMO electrode exhibits an overpotential of 302 mV at 10 mA cm<sup>–2</sup> in neutral electrolyte with an improvement of 182 mV compared with CoMoO<sub>4</sub> electrode. Furthermore, W doping significantly improves the electrode stability from 50 h to more than 320 h, with a suppressive potential attenuation from 2.82 to 0.29 mV h<sup>–1</sup>. This work will shed new light on designing rational electrocatalysts for neutral OER.</div></div>","PeriodicalId":9832,"journal":{"name":"Chinese Journal of Catalysis","volume":"76 ","pages":"Pages 146-158"},"PeriodicalIF":17.7,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144895348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shanshan Zhu , Xinrui Mao , Zhenwei Zhang , Liuliu Yang , Jiahao Li , Zhongping Li , Yucheng Jin , Huijuan Yue , Xiaoming Liu
{"title":"2D tris(triazolo)triazine-based covalent organic frameworks for efficient photoinduced molecular oxygen activation","authors":"Shanshan Zhu , Xinrui Mao , Zhenwei Zhang , Liuliu Yang , Jiahao Li , Zhongping Li , Yucheng Jin , Huijuan Yue , Xiaoming Liu","doi":"10.1016/S1872-2067(25)64761-9","DOIUrl":"10.1016/S1872-2067(25)64761-9","url":null,"abstract":"<div><div>Photoinduced molecular oxygen activation is crucial for artificial photosynthesis. However, metal-free semiconductor photocatalysts with high activation efficiency are still lacking up to now. Herein, two isomorphic tris(triazolo)triazine-based covalent organic frameworks were successfully constructed under solvothermal conditions. And they possess high crystallinity, inherent porosity with large surface area and good stability. Strong electron donor-acceptor skeletons expand the visible light harvesting, also facilitate the charge separation and thus lead to their superior activity of photoinduced molecular oxygen activation including photosynthesis of tetrahydroquinolines and hydrogen peroxide. This work provides a way to improve the efficiency of molecular oxygen activation through the rational design of COFs, and also opens new avenues for the construction of highly active and metal-free photocatalysts toward sustainable solar-to-chemical energy conversion.</div></div>","PeriodicalId":9832,"journal":{"name":"Chinese Journal of Catalysis","volume":"76 ","pages":"Pages 120-132"},"PeriodicalIF":17.7,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144895346","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jian-Peng Wang, Guang-Hui Lu, Qian Wu, Jian-Rong Dai, Ning Li
{"title":"Toward scalable production of biobased N-substituted furfurylamines by engineered imine reductases","authors":"Jian-Peng Wang, Guang-Hui Lu, Qian Wu, Jian-Rong Dai, Ning Li","doi":"10.1016/S1872-2067(25)64765-6","DOIUrl":"10.1016/S1872-2067(25)64765-6","url":null,"abstract":"<div><div><em>N</em>-substituted furfurylamines (FAs) are valuable precursors for producing pharmacologically active compounds and polymers. However, enzymatic synthesis of the type of chemicals is still in its infancy. Here we report an imine reductase from <em>Streptomyces albidoflavus</em> (<em>Sa</em>IRED) for the reductive amination of biobased furans. A simple, fast and interference-resistant high-throughput screening (HTS) method was developed, based on the coloration reaction of carbonyl compounds with 2,4-dinitrophenylhydrazine. The reductive amination activity of IREDs can be directly indicated by a colorimetric assay. With the reductive amination of furfural with allylamine as the model reaction, <em>Sa</em>IRED with the activity of 4.8 U mg<sup>–1</sup> was subjected to three rounds of protein engineering and screening by this HTS method, affording a high-activity tri-variant I127V/D241A/A242T (named M3, 20.2 U mg<sup>–1</sup>). The variant M3 showed broad substrate scope, and enabled efficient reductive amination of biobased furans with a variety of amines including small aliphatic amines and sterically hindered amines, giving the target FAs in yields up to >99%. In addition, other variants were identified for preparative-scale synthesis of commercially interesting amines such as <em>N</em>-2-(methylsulfonyl)ethyl-FA by the screen method, with isolated yields up to 87% and turnover numbers up to 9700 for enzyme. Gram-scale synthesis of <em>N</em>-allyl-FA, a valuable building block and potential polymer monomer, was implemented at 0.25 mol L<sup>–1</sup> substrate loading by a whole-cell catalyst incorporating variant M3, with 4.7 g L<sup>–1</sup> h<sup>–1</sup> space-time yield and 91% isolated yield.</div></div>","PeriodicalId":9832,"journal":{"name":"Chinese Journal of Catalysis","volume":"76 ","pages":"Pages 210-220"},"PeriodicalIF":17.7,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144895349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yongqi Zhao , Junjie Jiang , Yang Zou , Pu Wang , Xue Li , Xiaolong Liu , Tingyu Zhu
{"title":"Ultra-low doping 0.1(PtMnFeCoNi)/TiO2 catalysts: Modulating the electronic states of active metal sites to enhance CO oxidation through high entropy strategy","authors":"Yongqi Zhao , Junjie Jiang , Yang Zou , Pu Wang , Xue Li , Xiaolong Liu , Tingyu Zhu","doi":"10.1016/S1872-2067(25)64770-X","DOIUrl":"10.1016/S1872-2067(25)64770-X","url":null,"abstract":"<div><div>The catalyst cost is a key factor limiting the CO purification of sintering flue gas. Here, an ultra-low-loading high-entropy catalyst was prepared by simple calcination process. By anchoring multiple active metal sites in the stable anatase TiO<sub>2</sub> phase, it shows efficient CO catalytic oxidation activity. The metal components (Pt, Mn, Fe, Co, Ni) were uniformly dispersed on the surface of TiO<sub>2</sub> in the form of high-entropy compounds and undergo strong metal and support interaction with TiO<sub>2</sub>. The results showed that 0.1(PtMnFeCoNi)/TiO<sub>2</sub> achieved complete oxidation of CO at 230 °C, and its catalytic oxidation ability was significantly better than that of the corresponding monometallic and bimetallic catalysts. The high-entropy component adjusts the electronic environment between the TiO<sub>2</sub> support and the metal to promote the reduction of the Ti<sub>3<em>d</em></sub> band gap, enhances the electron-induced ability of the catalytic system to gas molecules (CO and O<sub>2</sub>), and exhibits excellent resistance to SO<sub>2</sub> and H<sub>2</sub>O. The work is of great significance to understand the synergistic regulation of catalyst activity by multiple metal at the atomic level and provides a strategy for effectively reducing the content of precious metals in the catalyst.</div></div>","PeriodicalId":9832,"journal":{"name":"Chinese Journal of Catalysis","volume":"76 ","pages":"Pages 173-184"},"PeriodicalIF":17.7,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144895789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wei Zhong , Aiyun Meng , Xudong Cai , Yiyao Gan, Jingtao Wang, Yaorong Su
{"title":"Enhancing photocatalytic H2 evolution by weakening S–Had bonds via Co-induced asymmetric electron distribution in NiCoS cocatalysts","authors":"Wei Zhong , Aiyun Meng , Xudong Cai , Yiyao Gan, Jingtao Wang, Yaorong Su","doi":"10.1016/S1872-2067(25)64747-4","DOIUrl":"10.1016/S1872-2067(25)64747-4","url":null,"abstract":"<div><div>The intrinsic symmetrical electron distribution in crystalline metal sulfides usually causes an improper electronic configuration between catalytic S atoms and H intermediates (H<sub>ad</sub>) to form strong S-H<sub>ad</sub> bonds, resulting in a low photocatalytic H<sub>2</sub> evolution activity. Herein, a cobalt-induced asymmetric electronic distribution is justified as an effective strategy to optimize the electronic configuration of catalytic S sites in NiCoS cocatalysts for highly active photocatalytic H<sub>2</sub> evolution. To this end, Co atoms are uniformly incorporated in NiS nanoparticles to fabricate homogeneous NiCoS cocatalyst on TiO<sub>2</sub> surface by a facile photosynthesis strategy. It is revealed that the incorporated Co atoms break the electron distribution symmetry in NiS, thus essentially increasing the electron density of S atoms to form active electron-enriched S<sup>(2+δ)–</sup> sites. The electron-enriched S<sup>(2+δ)–</sup> sites could interact with H<sub>ad</sub> <em>via</em> an increased antibonding orbital occupancy, which weakens S–H<sub>ad</sub> bonds for efficient H<sub>ad</sub> adsorption and desorption, endowing the NiCoS cocatalysts with a highly active H<sub>2</sub> evolution process. Consequently, the optimized NiCoS/TiO<sub>2</sub>(1:2) photocatalyst displays the highest H<sub>2</sub> production performance, outperforming the NiS/TiO<sub>2</sub> and CoS/TiO<sub>2</sub> samples by factors of 2.1 and 2.5, respectively. This work provides novel insights on breaking electron distribution symmetry to optimize catalytic efficiency of active sites.</div></div>","PeriodicalId":9832,"journal":{"name":"Chinese Journal of Catalysis","volume":"76 ","pages":"Pages 108-119"},"PeriodicalIF":17.7,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144895854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kelechi Uwakwe , Huan Liu , Qiming Bing , Liang Yu , Dehui Deng
{"title":"Theoretical prediction of WS2-confined metal atoms for highly efficient acetylene hydrogenation to ethylene","authors":"Kelechi Uwakwe , Huan Liu , Qiming Bing , Liang Yu , Dehui Deng","doi":"10.1016/S1872-2067(25)64734-6","DOIUrl":"10.1016/S1872-2067(25)64734-6","url":null,"abstract":"<div><div>Precise regulation of atomic and electronic structures of two-dimensional tungsten disulfide (WS<sub>2</sub>) is significant for rational design of high-performance and low-cost catalyst for acetylene hydrogenation to ethylene (AHE), yet remains a major challenge. Herein, we report that by substituting a W atom of WS<sub>2</sub> with a series of transition metal atoms, sulfur vacancy-confined Cu in the WS<sub>2</sub> basal plane (Cu@WS<sub>2</sub>-Sv) is theoretically screened as a superior non-noble metal-based catalyst with higher activity, selectivity, and stability for the AHE than other candidates. The co-adsorption of C<sub>2</sub>H<sub>2</sub> and H<sub>2</sub> and hydrogenation of C<sub>2</sub>H<sub>3</sub>* to C<sub>2</sub>H<sub>4</sub>* are revealed as the key steps establishing a volcano-like activity trend among the candidates, which present Cu@WS<sub>2</sub>-Sv as the optimum catalyst combined with molecular dynamics and reaction kinetics analyses. The kinetically more favorable desorption of C<sub>2</sub>H<sub>4</sub> than the over hydrogenation path validates a higher selectivity toward C<sub>2</sub>H<sub>4</sub> over C<sub>2</sub>H<sub>6</sub>. Furthermore, a machine-learning model reveals the significant effect of <em>d</em>-electron number and electronegativity of the metal heteroatoms in modulating the AHE activity.</div></div>","PeriodicalId":9832,"journal":{"name":"Chinese Journal of Catalysis","volume":"76 ","pages":"Pages 221-229"},"PeriodicalIF":17.7,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144895351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}